ITBN20100001A1 - "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" - Google Patents

"PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" Download PDF

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Publication number
ITBN20100001A1
ITBN20100001A1 IT000001A ITBN20100001A ITBN20100001A1 IT BN20100001 A1 ITBN20100001 A1 IT BN20100001A1 IT 000001 A IT000001 A IT 000001A IT BN20100001 A ITBN20100001 A IT BN20100001A IT BN20100001 A1 ITBN20100001 A1 IT BN20100001A1
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Italy
Prior art keywords
mold
mixture
resin
washbasins
sinks
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IT000001A
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Italian (it)
Inventor
Ferdinando Possemato
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Ch Roma Surface S R L
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Priority to IT000001A priority Critical patent/ITBN20100001A1/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Detergent Compositions (AREA)

Description

DESCRIZIONE del brevetto per invenzione industriale avente titolo: ?Processo di produzione di lavabi e lavelli in pezzi unici senza giunzioni, in agglomerato di quarzo/resina ad alta resistenza fisico-meccanica e chimica?a nome di: DESCRIPTION of the patent for industrial invention entitled:? Production process of washbasins and sinks in single pieces without joints, in quartz / resin agglomerate with high physical-mechanical and chemical resistance? In the name of:

Testo della descrizione Description text

Questa invenzione ha per oggetto il processo di produzione di lavabi e lavelli in pezzi unici senza giunzioni, in agglomerato di quarzo/resina ad alta resistenza fisicomeccanica e chimica. I processi di produzione e la composizione degli agglomerati di quarzo/resina permettono, attualmente, la sola fabbricazione di lastre piane destinate ad applicazioni di pavimenti, rivestimenti e piani cucina/bagno. La gamma di prodotti complessi (lavabi e lavelli) presenti sul mercato ? rappresentata da materiali di scarsa durabilit? e resistenza (acciaio inox, ceramica e materiali compositi con elevate quantit? di polimeri, es. Corian). I lavelli e lavabi in quarzo/resina, attualmente in commercio, sono rappresentati unicamente da elementi tagliati da lastre piane ed incollati mediante opportuni sigillanti. Ci? limita l?offerta alle sole forme quadrate o rettangolari con angoli vivi, che facilmente trattengono acqua e sporco, favorendo lo sviluppo di muffe e batteri nelle zone di incollaggio, oltre a non garantire la perfetta tenuta all?acqua. L?innovazione di prodotto e di processo, oggetto del brevetto, permette di ampliare la gamma di articoli offerti, producendo elementi complessi senza giunzioni (lavabi, lavelli, piatti doccia, vasche e etc.) di diverse forme e dimensioni, aventi composizione in agglomerato di quarzo/resina con elevate resistenze fisico-meccaniche e chimiche, perfettamente abbinabili per finitura, estetica e colore anche alle lastre piane sopra indicate. This invention relates to the production process of washbasins and sinks in single pieces without joints, in quartz / resin agglomerate with high physicomechanical and chemical resistance. The production processes and the composition of the quartz / resin agglomerates currently only allow the manufacture of flat sheets intended for floor, wall and kitchen / bathroom applications. The range of complex products (washbasins and sinks) on the market? represented by materials of poor durability? and resistance (stainless steel, ceramic and composite materials with high quantities of polymers, eg Corian). The quartz / resin sinks and washbasins currently on the market are represented solely by elements cut from flat slabs and glued using suitable sealants. There? it limits the offer only to square or rectangular shapes with sharp corners, which easily retain water and dirt, favoring the development of mold and bacteria in the bonding areas, as well as not guaranteeing perfect water tightness. The product and process innovation, object of the patent, allows to expand the range of items offered, producing complex elements without joints (washbasins, sinks, shower trays, bathtubs and etc.) of different shapes and sizes, having an agglomerate composition of quartz / resin with high physical-mechanical and chemical resistance, perfectly combinable in terms of finish, aesthetics and color even with the flat sheets indicated above.

Composizione Composition

La miscela, innovativa per tipologia e quantit? di polimero, si caratterizza per inerti/granulati silicei di quarzo bianco, trasparente o colorato di granulometria variabile tra 0,005 e 20,000 mm miscelati opportunamente con polimeri di diversa natura, tipo resine bicomponenti epossidiche, resine poliesteri ortoftaliche o isoneopentiliche o diciclopentadiene , resine vinilesteri, resine acriliche, resine poliuretane, eie. e pigmenti colorati organici o inorganici in polvere o dispersi in veicoli liquidi. Oltre alle cariche di quarzo ? possibile inserire inerti di varia natura e composizione mineralogica ( es: granito, marmo, feldspato, porfido, onici, basalti, pietre laviche, tufi, argille, inerti metallici, scaglie poliesteri, legno, plastiche, vetro, specchi, glitters). Il rapporto tra i componenti, quarzo/polimero, ? di circa 80/20 e la scelta del granulato o del polimero ? definita sulla base della destinazione d?uso del prodotto finale. Per le resine poliesteri, sopra elencate, sono fondamentali gli additivi di reticolazione a freddo tra cui l?ottoato di cobalto come accelerante e il metiletilchetoneperossido come catalizzatore a basse temperature. The blend, innovative in type and quantity? of polymer, it is characterized by inert / siliceous granulates of white, transparent or colored quartz with granulometry varying between 0.005 and 20,000 mm suitably mixed with polymers of different nature, such as two-component epoxy resins, orthophthalic or isoneopentyl polyester resins or dicyclopentadiene, vinylester resins, resins acrylics, polyurethane resins, eie. and organic or inorganic colored pigments in powder form or dispersed in liquid vehicles. In addition to the quartz fillers? It is possible to insert aggregates of various kinds and mineralogical compositions (eg: granite, marble, feldspar, porphyry, onyx, basalts, lava stones, tuffs, clays, metal aggregates, polyester flakes, wood, plastics, glass, mirrors, glitters). The relationship between the components, quartz / polymer,? about 80/20 and the choice of granulate or polymer? defined on the basis of the intended use of the final product. For the polyester resins listed above, cold crosslinking additives are essential, including cobalt octoate as an accelerator and methylethylketone peroxide as a catalyst at low temperatures.

Processo Process

Una volta pesata e preparata la miscela di ingredienti, questa viene immersa in un miscelatore continuo o discontinuo (dipendente dal numero di elementi da produrre). La composizione della girante di mescolazione ? particolarmente importante per la resistenza all?usura e all?abrasione del quarzo e pertanto la vite di miscelazione del miscelatore continuo dovr? essere realizzata con rivestimento in allumina mentre quella del miscelatore discontinuo dovr? essere cromata cos? come la bacinella contenente la miscela. Intanto si preparano gli stampi e i controstampi ( in vetroresina, in silicone, in ferro, in alluminio o in legno) trattandoli con opportuni distaccanti tipo cere o siliconici. Ogni elemento di una specifica geometria possiede il suo stampo ed il suo controstampo realizzati, nella maggior parte dei casi, in vetroresina avendo cura di utilizzare fibra di carbonio bi o tri-assiale e resine epossidiche bi-componenti che meglio garantiscono la stabilit? dimensionale nella fase di reticolazione del pezzo nello stampo. Si miscela sottovuoto (grado di vuoto variabile tra -0,8 e -1,0 bar) rimpasto per un tempo variabile in funzione degli additivi presenti in miscela (reagenti dosati al fine di ottenere la catalisi, indurimento, del pezzo finale). La miscela risultante viene introdotta nello stampo da un?apertura posizionata su un lato (pu? essere un lato qualsiasi dello stampo o pi? lati per favorire il perfetto riempimento). Durante la colata pu? essere o non applicata una vibrazione per facilitare la scorrevolezza dell?impasto nello stampo. Una volta riempito lo stampo con l?impasto vi si applica il vuoto assoluto e quindi il degassaggio (grado di vuoto variabile tra -0,8 e -1,0 bar), con l?ausilio di una pompa da vuoto e con un coperchio<1 >a tenuta ermetica posto sull?apertura dello stampo predisposto all?attacco del tubo per il degassaggio mediante un attacco ad innesto rapido. Durante l?aspirazione delFaria presente nell?impasto, e dunque nello stampo, viene eseguita la vibrazione posizionando lo stampo su una piastra/tavola vibrante. L?indurimento del pezzo colato avviene a temperatura ambiente grazie agli additivi/reagenti presenti nella formulazione in un tempo variabile tra i 5 minuti e le 10 ore. Una volta avvenuto l?indurimento si sforma il pezzo con un sistema di estrazione a barre filettate<2 >poste tra stampo e controstampo. Estratto il pezzo, viene catalizzato in un apposito forno di essiccazione a temperature variabili tra 60 e 200 ?C (in funzione della geometria e della quantit? di additivi/reagenti presenti in formulazione). Terminata la catalisi e riportando il pezzo a temperatura ambiente, questo pu? essere rifinito con opportune macchine levigatrici. Le fasi del processo sono descritte nella fig.l dell? Allegato Disegno. Once the mixture of ingredients has been weighed and prepared, it is immersed in a continuous or discontinuous mixer (depending on the number of elements to be produced). The composition of the mixing impeller? particularly important for the resistance to wear and abrasion of the quartz and therefore the mixing screw of the continuous mixer will have to? be made with alumina coating while that of the discontinuous mixer will have to? be chromed cos? such as the basin containing the mixture. In the meantime, the molds and counter-molds (in fiberglass, silicone, iron, aluminum or wood) are prepared by treating them with suitable release agents such as waxes or silicones. Each element of a specific geometry has its own mold and counter-mold made, in most cases, in fiberglass, taking care to use bi or tri-axial carbon fiber and bi-component epoxy resins that best guarantee stability. dimensional in the crosslinking phase of the piece in the mold. It is mixed under vacuum (degree of vacuum variable between -0.8 and -1.0 bar) and reshuffled for a variable time according to the additives present in the mixture (reagents dosed in order to obtain catalysis, hardening, of the final piece). The resulting mixture is introduced into the mold from an opening positioned on one side (it can be any side of the mold or multiple sides to facilitate perfect filling). During the casting can? be or not a vibration applied to facilitate the smoothness of the dough in the mold. Once the mold has been filled with the mixture, an absolute vacuum is applied and then degassing (degree of vacuum variable between -0.8 and -1.0 bar), with the help of a vacuum pump and with a lid <1> hermetic seal placed on the opening of the mold predisposed to the connection of the degassing tube by means of a quick coupling. During the suction of the air present in the dough, and therefore in the mold, the vibration is performed by positioning the mold on a vibrating plate / table. The hardening of the cast part takes place at room temperature thanks to the additives / reagents present in the formulation in a time varying between 5 minutes and 10 hours. Once hardening has taken place, the piece is demoulded with an extraction system with threaded bars <2> placed between the mold and counter-mold. Once the piece is extracted, it is catalysed in a special drying oven at temperatures ranging from 60 to 200 ° C (depending on the geometry and the quantity of additives / reagents present in the formulation). After the catalysis and bringing the piece back to room temperature, this can? be finished with suitable sanding machines. The phases of the process are described in fig. Attachment Drawing.

Claims (4)

Rivendicazioni Rivendicazioni per brevetto per invenzione industriale avente titolo: ?Processo di produzione di lavabi e lavelli in pezzi unici senza giunzioni, in agglomerato di quarzo/resina ad alta resistenza fisico-meccanica e chimica Elenco 1. Composizione della miscela per forme complesse (per lavabi, lavelli, piatti doccia, etc.)? La miscela ? costituita da una resina poliestere iso neopentilica con aggiunta di monomero acrilico per incremento delle resistenze chimiche finali, dotata di bassa viscosit? e media reattivit? per poter garantire la necessaria fluidit? alla miscela finale e da una combinazione di granulati di quarzo opportunamente selezionati in determinati range granulometrici (da 0,005 mm a 20,000 mm) dosati in modo tale da ridurre al minimo la quantit? di vuoti tra le diverse particelle (analisi delle quantit? e dosaggi con metodi di Bolomey, Fuller e Vuoti/Pieni). Gli additivi reagenti per la resina poliestere garantiscono l?indurimento a temperatura ambiente del pezzo colato nello stampo. Questi sono rappresentati da un Ottoato di Cobalto (accelerante di presa) e da un metiletilchetone perossido (catalizzatore a basse temperature) nonch? da un additivo promotore di adesione tra sostanze organiche ed inorganiche a base di Silani. Il colore della miscela viene ottenuto mediante pigmenti organici o inorganici presenti sottoforma di polveri microniche o veicolati da liquidi e dispersi nella miscela per poter ottenere una isotropia finale. Claims Patent claims for industrial invention entitled:? Production process of washbasins and sinks in single pieces without joints, in quartz / resin agglomerate with high physical-mechanical and chemical resistance List 1. Composition of the mixture for complex shapes (for washbasins, sinks, shower trays, etc.)? The mixture ? consisting of an iso neopentyl polyester resin with the addition of acrylic monomer to increase the final chemical resistance, with low viscosity? and media reactivity? in order to guarantee the necessary fluidity? to the final mixture and a combination of appropriately selected quartz granules in certain granulometric ranges (from 0.005 mm to 20.000 mm) dosed in such a way as to minimize the quantity? voids between the different particles (analysis of the quantities and dosages with methods of Bolomey, Fuller and Empty / Full). The reagent additives for the polyester resin guarantee the hardening at room temperature of the piece cast in the mold. These are represented by a cobalt octate (setting accelerator) and a methylethyl ketone peroxide (catalyst at low temperatures) as well as? from an adhesion promoter additive between organic and inorganic substances based on Silanes. The color of the mixture is obtained by means of organic or inorganic pigments present in the form of micronic powders or carried by liquids and dispersed in the mixture in order to obtain a final isotropy. 2. Miscelazione sottovuoto: la resina additivata, gli inerti e i pigmenti selezionati vengono miscelati sottovuoto (miscelatore continuo o discontinuo) al fine di ottenere un composito compatto e privo di aria. Ci? garantisce un prodotto finale non poroso e di elevata resistenza meccanica. 2. Mixing under vacuum: the additive resin, the aggregates and the selected pigments are mixed under vacuum (continuous or discontinuous mixer) in order to obtain a compact and air-free composite. There? guarantees a non-porous final product with high mechanical resistance. 3. Azione combinata di vuoto e vibrazione sugli stampi contenenti la miscela: una volta riempito lo stampo con la miscela sopra esposta, questo viene degassato, attraverso un sistema di vuoto, collegando il coperchio1 posto sullo stampo predisposto mediante un attacco ad innesto rapido, ad un?apposita pompa da vuoto , e simultaneamente vibrato per far defluire meglio Taria dallo stampo e quindi dalla miscela. 3. Combined action of vacuum and vibration on the molds containing the mixture: once the mold has been filled with the above mixture, this is degassed, through a vacuum system, by connecting the lid1 placed on the mold prepared by means of a quick coupling, to a special vacuum pump, and simultaneously vibrated to make it flow better Taria from the mold and then from the mixture. 4. Sistema di sformatura del pezzo indurito dallo stampo: con l?ausilio di apposite barre filettate2, poste tra stampo e controstampo, si esercita una pressione per poter distaccare lo stampo dal controstampo e quindi facilitare l?estrazione del pezzo indurito con appositi estrattori presenti sul fondo dello stampo. 4. Demoulding system of the hardened piece from the mold: with the help of special threaded bars2, placed between the mold and the counter-mold, a pressure is exerted to be able to detach the mold from the counter-mold and therefore facilitate the extraction of the hardened piece with special extractors present at the bottom of the mold.
IT000001A 2010-01-15 2010-01-15 "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" ITBN20100001A1 (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB966864A (en) * 1959-12-22 1964-08-19 Burns & Russell Co Cast resin surface and method of preparing same
US3574801A (en) * 1967-12-06 1971-04-13 Repla Sa Method for making panels of the artificial stone-type
US4499142A (en) * 1983-03-31 1985-02-12 Trenwyth Industris, Inc. Faced masonry units and facing composition therefor
RO111842B1 (en) * 1992-01-20 1997-02-28 Sc Azur Sa Preparation process of some objects which are made of artificial marble
EP1251113A2 (en) * 2001-04-13 2002-10-23 QUARELLA S.p.A. "Stone agglomerates manufactured in blocks and slabs, consisting of mineral fillers of mixed origin divided into selected, preset grading envelopes, with increased mechanical strength"
US20060293449A1 (en) * 2005-06-23 2006-12-28 Weberg Rolf T Solid filler containing polymerizable compositions, articles formed thereby and methods of formation
US20070244222A1 (en) * 2006-04-18 2007-10-18 Safas Corporation Engineered stone
WO2008082229A1 (en) * 2007-01-05 2008-07-10 Lg Chem, Ltd. Artificial marble and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB966864A (en) * 1959-12-22 1964-08-19 Burns & Russell Co Cast resin surface and method of preparing same
US3574801A (en) * 1967-12-06 1971-04-13 Repla Sa Method for making panels of the artificial stone-type
US4499142A (en) * 1983-03-31 1985-02-12 Trenwyth Industris, Inc. Faced masonry units and facing composition therefor
RO111842B1 (en) * 1992-01-20 1997-02-28 Sc Azur Sa Preparation process of some objects which are made of artificial marble
EP1251113A2 (en) * 2001-04-13 2002-10-23 QUARELLA S.p.A. "Stone agglomerates manufactured in blocks and slabs, consisting of mineral fillers of mixed origin divided into selected, preset grading envelopes, with increased mechanical strength"
US20060293449A1 (en) * 2005-06-23 2006-12-28 Weberg Rolf T Solid filler containing polymerizable compositions, articles formed thereby and methods of formation
US20070244222A1 (en) * 2006-04-18 2007-10-18 Safas Corporation Engineered stone
WO2008082229A1 (en) * 2007-01-05 2008-07-10 Lg Chem, Ltd. Artificial marble and preparation method thereof

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