ITBN20100001A1 - "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" - Google Patents
"PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" Download PDFInfo
- Publication number
- ITBN20100001A1 ITBN20100001A1 IT000001A ITBN20100001A ITBN20100001A1 IT BN20100001 A1 ITBN20100001 A1 IT BN20100001A1 IT 000001 A IT000001 A IT 000001A IT BN20100001 A ITBN20100001 A IT BN20100001A IT BN20100001 A1 ITBN20100001 A1 IT BN20100001A1
- Authority
- IT
- Italy
- Prior art keywords
- mold
- mixture
- resin
- washbasins
- sinks
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims description 10
- 239000011347 resin Substances 0.000 title claims description 10
- 239000000126 substance Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims description 22
- 239000010453 quartz Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 4
- 229920001225 polyester resin Polymers 0.000 claims description 4
- 239000004645 polyester resin Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 238000000605 extraction Methods 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 2
- 101100216234 Schizosaccharomyces pombe (strain 972 / ATCC 24843) cut20 gene Proteins 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000002318 adhesion promoter Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 239000001023 inorganic pigment Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 239000012860 organic pigment Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000009257 reactivity Effects 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
DESCRIZIONE del brevetto per invenzione industriale avente titolo: ?Processo di produzione di lavabi e lavelli in pezzi unici senza giunzioni, in agglomerato di quarzo/resina ad alta resistenza fisico-meccanica e chimica?a nome di: DESCRIPTION of the patent for industrial invention entitled:? Production process of washbasins and sinks in single pieces without joints, in quartz / resin agglomerate with high physical-mechanical and chemical resistance? In the name of:
Testo della descrizione Description text
Questa invenzione ha per oggetto il processo di produzione di lavabi e lavelli in pezzi unici senza giunzioni, in agglomerato di quarzo/resina ad alta resistenza fisicomeccanica e chimica. I processi di produzione e la composizione degli agglomerati di quarzo/resina permettono, attualmente, la sola fabbricazione di lastre piane destinate ad applicazioni di pavimenti, rivestimenti e piani cucina/bagno. La gamma di prodotti complessi (lavabi e lavelli) presenti sul mercato ? rappresentata da materiali di scarsa durabilit? e resistenza (acciaio inox, ceramica e materiali compositi con elevate quantit? di polimeri, es. Corian). I lavelli e lavabi in quarzo/resina, attualmente in commercio, sono rappresentati unicamente da elementi tagliati da lastre piane ed incollati mediante opportuni sigillanti. Ci? limita l?offerta alle sole forme quadrate o rettangolari con angoli vivi, che facilmente trattengono acqua e sporco, favorendo lo sviluppo di muffe e batteri nelle zone di incollaggio, oltre a non garantire la perfetta tenuta all?acqua. L?innovazione di prodotto e di processo, oggetto del brevetto, permette di ampliare la gamma di articoli offerti, producendo elementi complessi senza giunzioni (lavabi, lavelli, piatti doccia, vasche e etc.) di diverse forme e dimensioni, aventi composizione in agglomerato di quarzo/resina con elevate resistenze fisico-meccaniche e chimiche, perfettamente abbinabili per finitura, estetica e colore anche alle lastre piane sopra indicate. This invention relates to the production process of washbasins and sinks in single pieces without joints, in quartz / resin agglomerate with high physicomechanical and chemical resistance. The production processes and the composition of the quartz / resin agglomerates currently only allow the manufacture of flat sheets intended for floor, wall and kitchen / bathroom applications. The range of complex products (washbasins and sinks) on the market? represented by materials of poor durability? and resistance (stainless steel, ceramic and composite materials with high quantities of polymers, eg Corian). The quartz / resin sinks and washbasins currently on the market are represented solely by elements cut from flat slabs and glued using suitable sealants. There? it limits the offer only to square or rectangular shapes with sharp corners, which easily retain water and dirt, favoring the development of mold and bacteria in the bonding areas, as well as not guaranteeing perfect water tightness. The product and process innovation, object of the patent, allows to expand the range of items offered, producing complex elements without joints (washbasins, sinks, shower trays, bathtubs and etc.) of different shapes and sizes, having an agglomerate composition of quartz / resin with high physical-mechanical and chemical resistance, perfectly combinable in terms of finish, aesthetics and color even with the flat sheets indicated above.
Composizione Composition
La miscela, innovativa per tipologia e quantit? di polimero, si caratterizza per inerti/granulati silicei di quarzo bianco, trasparente o colorato di granulometria variabile tra 0,005 e 20,000 mm miscelati opportunamente con polimeri di diversa natura, tipo resine bicomponenti epossidiche, resine poliesteri ortoftaliche o isoneopentiliche o diciclopentadiene , resine vinilesteri, resine acriliche, resine poliuretane, eie. e pigmenti colorati organici o inorganici in polvere o dispersi in veicoli liquidi. Oltre alle cariche di quarzo ? possibile inserire inerti di varia natura e composizione mineralogica ( es: granito, marmo, feldspato, porfido, onici, basalti, pietre laviche, tufi, argille, inerti metallici, scaglie poliesteri, legno, plastiche, vetro, specchi, glitters). Il rapporto tra i componenti, quarzo/polimero, ? di circa 80/20 e la scelta del granulato o del polimero ? definita sulla base della destinazione d?uso del prodotto finale. Per le resine poliesteri, sopra elencate, sono fondamentali gli additivi di reticolazione a freddo tra cui l?ottoato di cobalto come accelerante e il metiletilchetoneperossido come catalizzatore a basse temperature. The blend, innovative in type and quantity? of polymer, it is characterized by inert / siliceous granulates of white, transparent or colored quartz with granulometry varying between 0.005 and 20,000 mm suitably mixed with polymers of different nature, such as two-component epoxy resins, orthophthalic or isoneopentyl polyester resins or dicyclopentadiene, vinylester resins, resins acrylics, polyurethane resins, eie. and organic or inorganic colored pigments in powder form or dispersed in liquid vehicles. In addition to the quartz fillers? It is possible to insert aggregates of various kinds and mineralogical compositions (eg: granite, marble, feldspar, porphyry, onyx, basalts, lava stones, tuffs, clays, metal aggregates, polyester flakes, wood, plastics, glass, mirrors, glitters). The relationship between the components, quartz / polymer,? about 80/20 and the choice of granulate or polymer? defined on the basis of the intended use of the final product. For the polyester resins listed above, cold crosslinking additives are essential, including cobalt octoate as an accelerator and methylethylketone peroxide as a catalyst at low temperatures.
Processo Process
Una volta pesata e preparata la miscela di ingredienti, questa viene immersa in un miscelatore continuo o discontinuo (dipendente dal numero di elementi da produrre). La composizione della girante di mescolazione ? particolarmente importante per la resistenza all?usura e all?abrasione del quarzo e pertanto la vite di miscelazione del miscelatore continuo dovr? essere realizzata con rivestimento in allumina mentre quella del miscelatore discontinuo dovr? essere cromata cos? come la bacinella contenente la miscela. Intanto si preparano gli stampi e i controstampi ( in vetroresina, in silicone, in ferro, in alluminio o in legno) trattandoli con opportuni distaccanti tipo cere o siliconici. Ogni elemento di una specifica geometria possiede il suo stampo ed il suo controstampo realizzati, nella maggior parte dei casi, in vetroresina avendo cura di utilizzare fibra di carbonio bi o tri-assiale e resine epossidiche bi-componenti che meglio garantiscono la stabilit? dimensionale nella fase di reticolazione del pezzo nello stampo. Si miscela sottovuoto (grado di vuoto variabile tra -0,8 e -1,0 bar) rimpasto per un tempo variabile in funzione degli additivi presenti in miscela (reagenti dosati al fine di ottenere la catalisi, indurimento, del pezzo finale). La miscela risultante viene introdotta nello stampo da un?apertura posizionata su un lato (pu? essere un lato qualsiasi dello stampo o pi? lati per favorire il perfetto riempimento). Durante la colata pu? essere o non applicata una vibrazione per facilitare la scorrevolezza dell?impasto nello stampo. Una volta riempito lo stampo con l?impasto vi si applica il vuoto assoluto e quindi il degassaggio (grado di vuoto variabile tra -0,8 e -1,0 bar), con l?ausilio di una pompa da vuoto e con un coperchio<1 >a tenuta ermetica posto sull?apertura dello stampo predisposto all?attacco del tubo per il degassaggio mediante un attacco ad innesto rapido. Durante l?aspirazione delFaria presente nell?impasto, e dunque nello stampo, viene eseguita la vibrazione posizionando lo stampo su una piastra/tavola vibrante. L?indurimento del pezzo colato avviene a temperatura ambiente grazie agli additivi/reagenti presenti nella formulazione in un tempo variabile tra i 5 minuti e le 10 ore. Una volta avvenuto l?indurimento si sforma il pezzo con un sistema di estrazione a barre filettate<2 >poste tra stampo e controstampo. Estratto il pezzo, viene catalizzato in un apposito forno di essiccazione a temperature variabili tra 60 e 200 ?C (in funzione della geometria e della quantit? di additivi/reagenti presenti in formulazione). Terminata la catalisi e riportando il pezzo a temperatura ambiente, questo pu? essere rifinito con opportune macchine levigatrici. Le fasi del processo sono descritte nella fig.l dell? Allegato Disegno. Once the mixture of ingredients has been weighed and prepared, it is immersed in a continuous or discontinuous mixer (depending on the number of elements to be produced). The composition of the mixing impeller? particularly important for the resistance to wear and abrasion of the quartz and therefore the mixing screw of the continuous mixer will have to? be made with alumina coating while that of the discontinuous mixer will have to? be chromed cos? such as the basin containing the mixture. In the meantime, the molds and counter-molds (in fiberglass, silicone, iron, aluminum or wood) are prepared by treating them with suitable release agents such as waxes or silicones. Each element of a specific geometry has its own mold and counter-mold made, in most cases, in fiberglass, taking care to use bi or tri-axial carbon fiber and bi-component epoxy resins that best guarantee stability. dimensional in the crosslinking phase of the piece in the mold. It is mixed under vacuum (degree of vacuum variable between -0.8 and -1.0 bar) and reshuffled for a variable time according to the additives present in the mixture (reagents dosed in order to obtain catalysis, hardening, of the final piece). The resulting mixture is introduced into the mold from an opening positioned on one side (it can be any side of the mold or multiple sides to facilitate perfect filling). During the casting can? be or not a vibration applied to facilitate the smoothness of the dough in the mold. Once the mold has been filled with the mixture, an absolute vacuum is applied and then degassing (degree of vacuum variable between -0.8 and -1.0 bar), with the help of a vacuum pump and with a lid <1> hermetic seal placed on the opening of the mold predisposed to the connection of the degassing tube by means of a quick coupling. During the suction of the air present in the dough, and therefore in the mold, the vibration is performed by positioning the mold on a vibrating plate / table. The hardening of the cast part takes place at room temperature thanks to the additives / reagents present in the formulation in a time varying between 5 minutes and 10 hours. Once hardening has taken place, the piece is demoulded with an extraction system with threaded bars <2> placed between the mold and counter-mold. Once the piece is extracted, it is catalysed in a special drying oven at temperatures ranging from 60 to 200 ° C (depending on the geometry and the quantity of additives / reagents present in the formulation). After the catalysis and bringing the piece back to room temperature, this can? be finished with suitable sanding machines. The phases of the process are described in fig. Attachment Drawing.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000001A ITBN20100001A1 (en) | 2010-01-15 | 2010-01-15 | "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT000001A ITBN20100001A1 (en) | 2010-01-15 | 2010-01-15 | "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" |
Publications (1)
Publication Number | Publication Date |
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ITBN20100001A1 true ITBN20100001A1 (en) | 2011-07-15 |
Family
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IT000001A ITBN20100001A1 (en) | 2010-01-15 | 2010-01-15 | "PROCESS OF PRODUCTION OF WASHBASINS AND SINKS IN UNIQUE PIECES WITHOUT JUNCTIONS, IN QUARTZ AGGLOMERATE / RESIN WITH HIGH PHYSICAL-MECHANICAL AND CHEMICAL RESISTANCE" |
Country Status (1)
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IT (1) | ITBN20100001A1 (en) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB966864A (en) * | 1959-12-22 | 1964-08-19 | Burns & Russell Co | Cast resin surface and method of preparing same |
US3574801A (en) * | 1967-12-06 | 1971-04-13 | Repla Sa | Method for making panels of the artificial stone-type |
US4499142A (en) * | 1983-03-31 | 1985-02-12 | Trenwyth Industris, Inc. | Faced masonry units and facing composition therefor |
RO111842B1 (en) * | 1992-01-20 | 1997-02-28 | Sc Azur Sa | Preparation process of some objects which are made of artificial marble |
EP1251113A2 (en) * | 2001-04-13 | 2002-10-23 | QUARELLA S.p.A. | "Stone agglomerates manufactured in blocks and slabs, consisting of mineral fillers of mixed origin divided into selected, preset grading envelopes, with increased mechanical strength" |
US20060293449A1 (en) * | 2005-06-23 | 2006-12-28 | Weberg Rolf T | Solid filler containing polymerizable compositions, articles formed thereby and methods of formation |
US20070244222A1 (en) * | 2006-04-18 | 2007-10-18 | Safas Corporation | Engineered stone |
WO2008082229A1 (en) * | 2007-01-05 | 2008-07-10 | Lg Chem, Ltd. | Artificial marble and preparation method thereof |
-
2010
- 2010-01-15 IT IT000001A patent/ITBN20100001A1/en unknown
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB966864A (en) * | 1959-12-22 | 1964-08-19 | Burns & Russell Co | Cast resin surface and method of preparing same |
US3574801A (en) * | 1967-12-06 | 1971-04-13 | Repla Sa | Method for making panels of the artificial stone-type |
US4499142A (en) * | 1983-03-31 | 1985-02-12 | Trenwyth Industris, Inc. | Faced masonry units and facing composition therefor |
RO111842B1 (en) * | 1992-01-20 | 1997-02-28 | Sc Azur Sa | Preparation process of some objects which are made of artificial marble |
EP1251113A2 (en) * | 2001-04-13 | 2002-10-23 | QUARELLA S.p.A. | "Stone agglomerates manufactured in blocks and slabs, consisting of mineral fillers of mixed origin divided into selected, preset grading envelopes, with increased mechanical strength" |
US20060293449A1 (en) * | 2005-06-23 | 2006-12-28 | Weberg Rolf T | Solid filler containing polymerizable compositions, articles formed thereby and methods of formation |
US20070244222A1 (en) * | 2006-04-18 | 2007-10-18 | Safas Corporation | Engineered stone |
WO2008082229A1 (en) * | 2007-01-05 | 2008-07-10 | Lg Chem, Ltd. | Artificial marble and preparation method thereof |
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