IT1393109B1 - PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS - Google Patents

PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS

Info

Publication number
IT1393109B1
IT1393109B1 ITMI2009A000281A ITMI20090281A IT1393109B1 IT 1393109 B1 IT1393109 B1 IT 1393109B1 IT MI2009A000281 A ITMI2009A000281 A IT MI2009A000281A IT MI20090281 A ITMI20090281 A IT MI20090281A IT 1393109 B1 IT1393109 B1 IT 1393109B1
Authority
IT
Italy
Prior art keywords
procedure
direct conversion
liquid hydrocarbons
oxygen compounds
aromatic contents
Prior art date
Application number
ITMI2009A000281A
Other languages
Italian (it)
Inventor
Franco Rivetti
Stefano Ramello
Roberto Buzzoni
Original Assignee
Eni Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni Spa filed Critical Eni Spa
Priority to ITMI2009A000281A priority Critical patent/IT1393109B1/en
Priority to PCT/EP2010/000962 priority patent/WO2010097175A1/en
Publication of ITMI20090281A1 publication Critical patent/ITMI20090281A1/en
Application granted granted Critical
Publication of IT1393109B1 publication Critical patent/IT1393109B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
ITMI2009A000281A 2009-02-26 2009-02-26 PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS IT1393109B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
ITMI2009A000281A IT1393109B1 (en) 2009-02-26 2009-02-26 PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS
PCT/EP2010/000962 WO2010097175A1 (en) 2009-02-26 2010-02-10 Process for the direct conversion of oxygenated compounds to liquid hydrocarbons having a reduced aromatic content

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI2009A000281A IT1393109B1 (en) 2009-02-26 2009-02-26 PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS

Publications (2)

Publication Number Publication Date
ITMI20090281A1 ITMI20090281A1 (en) 2010-08-27
IT1393109B1 true IT1393109B1 (en) 2012-04-11

Family

ID=41117691

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI2009A000281A IT1393109B1 (en) 2009-02-26 2009-02-26 PROCEDURE FOR DIRECT CONVERSION OF OXYGEN COMPOUNDS TO LIQUID HYDROCARBONS WITH REDUCED AROMATIC CONTENTS

Country Status (2)

Country Link
IT (1) IT1393109B1 (en)
WO (1) WO2010097175A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9090525B2 (en) * 2009-12-11 2015-07-28 Exxonmobil Research And Engineering Company Process and system to convert methanol to light olefin, gasoline and distillate
CN108349830A (en) * 2015-10-28 2018-07-31 埃克森美孚研究工程公司 Method and apparatus for the raw material containing oxygenate to be converted to gasoline and distillate
CA3154623A1 (en) 2019-09-30 2021-04-08 Gevo, Inc. Simultaneous dehydration, dimerization, and metathesis of c2-c5 alcohols
CN111170817B (en) * 2020-01-17 2022-09-23 太原理工大学 High-stability and high-selectivity catalytic reaction process for preparing aromatic hydrocarbon from methanol
KR20240000547A (en) 2021-04-23 2024-01-02 게보 인코포레이티드 Systems and methods for catalytic conversion of C1-C5 alcohols to C2-C5 olefin mixtures
WO2024091452A1 (en) 2022-10-27 2024-05-02 Gevo, Inc. Processes for catalytic conversion of c1-c5 alcohols to c2-c5 olefin mixtures
WO2024126077A1 (en) 2022-12-16 2024-06-20 Topsoe A/S Process and plant for the conversion of oxygenates to c5+ hydrocarbons boiling in the jet fuel boiling range
WO2024200429A1 (en) 2023-03-29 2024-10-03 Topsoe A/S Process and plant for the conversion of oxygenates to c5+ hydrocarbons boiling in the jet fuel boiling range

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3894106A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of ethers
US3894107A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3894103A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization reactions
US4058576A (en) 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US4025576A (en) * 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4035430A (en) 1976-07-26 1977-07-12 Mobil Oil Corporation Conversion of methanol to gasoline product
US4304951A (en) 1981-01-14 1981-12-08 Mobil Oil Corporation Hydrotreating of bottoms fractions resulting from conversion of methanol to gasoline in order to decrease durene and produce distillate
US4476338A (en) 1983-06-02 1984-10-09 Mobil Oil Corporation Olefins from methanol and/or dimethyl ether
US4482772A (en) 1983-11-03 1984-11-13 Mobil Oil Corporation Multistage process for converting oxygenates to hydrocarbons
US4506106A (en) 1984-01-04 1985-03-19 Mobil Oil Corporation Multistage process for converting oxygenates to distillate hydrocarbons with interstage ethene recovery
US4497968A (en) 1984-04-11 1985-02-05 Mobil Oil Corporation Multistage process for converting olefins or oxygenates to heavier hydrocarbons
US4579993A (en) 1984-08-22 1986-04-01 Mobil Oil Corporation Catalyst for methanol conversion by a combination of steaming and acid-extraction
US4689205A (en) 1985-05-14 1987-08-25 Mobil Oil Corporation Multi-stage system for converting oxygenates to liquid hydrocarbons with aliphatic recycle
US4579999A (en) 1985-01-17 1986-04-01 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle
US4543435A (en) 1985-01-17 1985-09-24 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with ethene recycle
JPS6290167A (en) 1985-10-15 1987-04-24 松下電工株式会社 Deodorant
US4929780A (en) 1988-05-12 1990-05-29 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons and ethene
US5045287A (en) 1988-07-25 1991-09-03 Mobil Oil Corporation Multireactor system for conversion of methanol to gasoline and distillate
US4899002A (en) 1988-07-25 1990-02-06 Mobil Oil Corp. Integrated staged conversion of methanol to gasoline and distillate
US4992611A (en) 1989-12-13 1991-02-12 Mobil Oil Corp. Direct conversion of C1 -C4 oxygenates to low aromatic distillate range hydrocarbons
US5177279A (en) 1990-10-23 1993-01-05 Mobil Oil Corporation Integrated process for converting methanol to gasoline and distillates
EP0625132B1 (en) * 1992-01-30 1997-07-16 Exxon Chemical Patents Inc. Alkene oligomerization
US6372949B1 (en) 1999-10-15 2002-04-16 Mobil Oil Corporation Single stage process for converting oxygenates to gasoline and distillate in the presence of undimensional ten member ring zeolite
DE102005003109B4 (en) * 2005-01-22 2015-02-12 Air Liquide Global E&C Solutions Germany Gmbh Process for the preparation of synthetic fuels from oxygenates
DE102005048931B8 (en) 2005-10-13 2015-06-18 Air Liquide Global E&C Solutions Germany Gmbh Process and plant for the production of C 2 -C 4 olefins from methanol and / or dimethyl ether

Also Published As

Publication number Publication date
ITMI20090281A1 (en) 2010-08-27
WO2010097175A1 (en) 2010-09-02

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