IT1254429B - Process for the preparation of alcohols by the reduction of epoxides through hydrogen transfer - Google Patents
Process for the preparation of alcohols by the reduction of epoxides through hydrogen transferInfo
- Publication number
- IT1254429B IT1254429B ITMI920265A IT1254429B IT 1254429 B IT1254429 B IT 1254429B IT MI920265 A ITMI920265 A IT MI920265A IT 1254429 B IT1254429 B IT 1254429B
- Authority
- IT
- Italy
- Prior art keywords
- alcohols
- preparation
- epoxides
- hydrogen transfer
- reduction
- Prior art date
Links
- 150000001298 alcohols Chemical class 0.000 title abstract 2
- 150000002118 epoxides Chemical class 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 239000000852 hydrogen donor Substances 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 150000003283 rhodium Chemical class 0.000 abstract 1
- 150000003333 secondary alcohols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the preparation of alcohols by the reaction of reducing the corresponding epoxides through hydrogen transfer using a hydrogen donor as a reducing agent (in the specific instance a secondary alcohol) in the presence of a homogeneous catalytic system comprising: a) a rhodium salt or complex, b) an at least bidentate nitrogen-containing ligand, c) an inorganic base is described.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT92MI265 IT1254429B (en) | 1992-02-11 | 1992-02-11 | Process for the preparation of alcohols by the reduction of epoxides through hydrogen transfer |
BE9300134A BE1005931A3 (en) | 1992-02-11 | 1993-02-11 | Method for preparing alcohol by reducing epoxides with a transfer of hydrogen. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT92MI265 IT1254429B (en) | 1992-02-11 | 1992-02-11 | Process for the preparation of alcohols by the reduction of epoxides through hydrogen transfer |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI920265A0 ITMI920265A0 (en) | 1992-02-11 |
ITMI920265A1 ITMI920265A1 (en) | 1993-08-11 |
IT1254429B true IT1254429B (en) | 1995-09-25 |
Family
ID=11361879
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IT92MI265 IT1254429B (en) | 1992-02-11 | 1992-02-11 | Process for the preparation of alcohols by the reduction of epoxides through hydrogen transfer |
Country Status (2)
Country | Link |
---|---|
BE (1) | BE1005931A3 (en) |
IT (1) | IT1254429B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9238783B2 (en) * | 2012-11-20 | 2016-01-19 | Chevron U.S.A. Inc. | Monoester-based lubricants and methods of making same |
-
1992
- 1992-02-11 IT IT92MI265 patent/IT1254429B/en active IP Right Grant
-
1993
- 1993-02-11 BE BE9300134A patent/BE1005931A3/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BE1005931A3 (en) | 1994-03-15 |
ITMI920265A0 (en) | 1992-02-11 |
ITMI920265A1 (en) | 1993-08-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970327 |