IT1028302B - Vinyl polymers prodn. in presence of poly-arylene-alkylenes - or their hydroperoxides, inhibiting thermo-oxidative degradation
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Vinyl polymers prodn. in presence of poly-arylene-alkylenes - or their hydroperoxides, inhibiting thermo-oxidative degradation
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IT1028302B
IT1028302BIT1918275AIT1918275AIT1028302BIT 1028302 BIT1028302 BIT 1028302BIT 1918275 AIT1918275 AIT 1918275AIT 1918275 AIT1918275 AIT 1918275AIT 1028302 BIT1028302 BIT 1028302B
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Organic Low-Molecular-Weight Compounds And Preparation Thereof
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Abstract
The prodn. of vinyl polymers (I) by polymerisation of vinyl monomers (II) is carried out in the presence of 0.01-15 wt.% w.r.t. (II) of polyarylene-alkylenes (III) of the formula:- (in which Ar1 and Ar2 are:- m+n = 2-30; k=1 or 2, if k=1, Ar1 and Ar2 can also be X is H or 1-4C alkyl) or their hydroperoxides. Polymerisation pref. also takes place in the presence of 0.1-20 wt.% w.r.t. (II) of initiators, pref. Bz2O2, NC.CM32.N:N.CMe2.CN or i-Pr.C6H4.OOH. Used in the prodn. of polymethyl methacrylatE, polybutyl methacrylate with alpha, omega - methacryl-(bis-ethylene glycol) (Ila), which are used in the chemical and electrical industries, electronics, lighting, foodstuffs industry, in aircraft construction and for other industrial purposes. (III) inhibits thermo-oxidative degradation of (I).
IT1918275A1975-01-101975-01-10Vinyl polymers prodn. in presence of poly-arylene-alkylenes - or their hydroperoxides, inhibiting thermo-oxidative degradation
IT1028302B
(en)
Catalytic solid to be used in stereospecific polymerization of alpha- olefins, process for its preparation and process for polymerizing alpha- olefins in its presence