IN2015DN02232A - - Google Patents

Info

Publication number
IN2015DN02232A
IN2015DN02232A IN2232DEN2015A IN2015DN02232A IN 2015DN02232 A IN2015DN02232 A IN 2015DN02232A IN 2232DEN2015 A IN2232DEN2015 A IN 2232DEN2015A IN 2015DN02232 A IN2015DN02232 A IN 2015DN02232A
Authority
IN
India
Prior art keywords
elasticity
harmonic
storage modulus
measured
copolymer
Prior art date
Application number
Inventor
Chem Ltd Lg
Original Assignee
Lg Chemical Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020130075873A external-priority patent/KR101585204B1/en
Priority claimed from KR1020140047679A external-priority patent/KR101684648B1/en
Priority claimed from KR1020140080039A external-priority patent/KR101446685B1/en
Application filed by Lg Chemical Ltd filed Critical Lg Chemical Ltd
Publication of IN2015DN02232A publication Critical patent/IN2015DN02232A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/06Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene-diene terpolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/20Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/02Cp or analog bridged to a non-Cp X anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09Long chain branches
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

The present invention relates to a ternary elastomeric copolymer having a long chain branch obtained in the presence of a group IV transition metal catalyst and capable of achieving both excellent processability and excellent elasticity (flexibility) and a method for preparing the same. The ternary elastomeric copolymer is a copolymer of ethylene an alpha olefin having 3 to 20 carbon atoms and a diene i) having a weight average molecular weight of 100 000 to 500 000 measured by GPC; and ii) capable of having a positive value on the LCB index which is the ratio of a first harmonic of the storage modulus of elasticity measured by a rubber process analyzer at 125°C using the Large Angles of Oscillation and high Strains (LAOS) method with respect to a fifth harmonic of the storage modulus of elasticity.
IN2232DEN2015 2013-06-28 2014-06-30 IN2015DN02232A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR1020130075873A KR101585204B1 (en) 2013-06-28 2013-06-28 Elastic diene terpolymer and preparation method thereof
KR20140040551 2014-04-04
KR1020140047679A KR101684648B1 (en) 2014-04-21 2014-04-21 Elastic diene terpolymer and preparation method thereof
KR1020140080039A KR101446685B1 (en) 2014-04-04 2014-06-27 Elastic diene terpolymer and preparation method thereof
PCT/KR2014/005811 WO2014209085A1 (en) 2013-06-28 2014-06-30 Ternary elastomeric copolymer comprising diene and method for preparing same

Publications (1)

Publication Number Publication Date
IN2015DN02232A true IN2015DN02232A (en) 2015-08-21

Family

ID=52142322

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2232DEN2015 IN2015DN02232A (en) 2013-06-28 2014-06-30

Country Status (6)

Country Link
US (1) US9493593B2 (en)
EP (1) EP2883891A4 (en)
JP (1) JP2015532362A (en)
CN (1) CN104768986A (en)
IN (1) IN2015DN02232A (en)
WO (1) WO2014209085A1 (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2883890A4 (en) 2013-06-28 2016-07-20 Lg Chemical Ltd Trinary elastic copolymer comprising diene and method for preparing same
KR101585204B1 (en) 2013-06-28 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
EP2883889A4 (en) 2013-06-28 2016-06-01 Lg Chemical Ltd Trinary elastic copolymer comprising diene and method for preparing same
KR101585206B1 (en) 2013-07-22 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof
EP2883891A4 (en) 2013-06-28 2016-06-01 Lg Chemical Ltd Ternary elastomeric copolymer comprising diene and method for preparing same
EP3078692B1 (en) 2013-12-06 2021-01-27 LG Chem, Ltd. Block copolymer
US10227438B2 (en) 2013-12-06 2019-03-12 Lg Chem, Ltd. Block copolymer
US10150832B2 (en) 2013-12-06 2018-12-11 Lg Chem, Ltd. Block copolymer
EP3078685B1 (en) 2013-12-06 2020-09-09 LG Chem, Ltd. Block copolymer
JP6483693B2 (en) 2013-12-06 2019-03-13 エルジー・ケム・リミテッド Block copolymer
JP6361893B2 (en) 2013-12-06 2018-07-25 エルジー・ケム・リミテッド Block copolymer
EP3078654B1 (en) 2013-12-06 2021-07-07 LG Chem, Ltd. Monomer and block copolymer
CN105899557B (en) 2013-12-06 2018-10-26 株式会社Lg化学 Block copolymer
EP3078689B1 (en) 2013-12-06 2020-12-02 LG Chem, Ltd. Block copolymer
US10202480B2 (en) 2013-12-06 2019-02-12 Lg Chem, Ltd. Block copolymer
JP6483695B2 (en) 2013-12-06 2019-03-13 エルジー・ケム・リミテッド Block copolymer
CN106459326B (en) 2013-12-06 2019-08-13 株式会社Lg化学 Block copolymer
WO2016053001A1 (en) 2014-09-30 2016-04-07 주식회사 엘지화학 Block copolymer
EP3202801B1 (en) 2014-09-30 2021-08-18 LG Chem, Ltd. Block copolymer
US10240035B2 (en) 2014-09-30 2019-03-26 Lg Chem, Ltd. Block copolymer
US10370529B2 (en) 2014-09-30 2019-08-06 Lg Chem, Ltd. Method of manufacturing patterned substrate
US10633533B2 (en) 2014-09-30 2020-04-28 Lg Chem, Ltd. Block copolymer
US10287430B2 (en) 2014-09-30 2019-05-14 Lg Chem, Ltd. Method of manufacturing patterned substrate
CN107075050B (en) 2014-09-30 2019-08-13 株式会社Lg化学 Block copolymer
WO2016053010A1 (en) * 2014-09-30 2016-04-07 주식회사 엘지화학 Block copolymer
US10281820B2 (en) 2014-09-30 2019-05-07 Lg Chem, Ltd. Block copolymer
EP3202800B1 (en) 2014-09-30 2021-12-29 LG Chem, Ltd. Block copolymer

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
DE4236218C2 (en) 1991-12-19 2001-08-16 Degussa Vulcanizable EPDM rubber compounds
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
NL9400758A (en) * 1994-05-06 1995-12-01 Dsm Nv Process for the preparation of a high molecular weight polymer from ethylene, alpha olefin and optionally diene.
US5571883A (en) 1995-06-14 1996-11-05 Exxon Chemical Patents Inc. Elastomeric vehicle vibration damping devices
CN1224433A (en) 1996-05-03 1999-07-28 Dsm有限公司 Process for preparing terpolymers of ethylene, alpha-olefins and diolefins
CN1254350A (en) 1997-04-30 2000-05-24 唐化学原料公司 Ethylene/alpha-olefin/diene interpolymers and their preparation
JP2001522398A (en) 1997-04-30 2001-11-13 ザ ダウ ケミカル カンパニー Ethylene / alpha-olefin / diene interpolymers and their preparation
TR200000905T2 (en) 1997-08-27 2000-07-21 The Dow Chemical Company Fluoral changes in vinyl aromatic monomers with alpha-olefin interpolymers
US5942587A (en) 1997-11-21 1999-08-24 Exxon Chemical Patents Inc. Ethylene polymers with a norbornene comonomer for LLDPE like resins of improved toughness and processibility for film production
CA2347501C (en) 1998-11-02 2010-03-23 Larry Duane Cady Shear thinning ethylene/.alpha.-olefin interpolymers and their preparation
KR100581761B1 (en) 1999-01-30 2006-05-22 주식회사 엘지화학 Olefin copolymer for rotomolding
US6369176B1 (en) 1999-08-19 2002-04-09 Dupont Dow Elastomers Llc Process for preparing in a single reactor polymer blends having a broad molecular weight distribution
US6403520B1 (en) 1999-09-17 2002-06-11 Saudi Basic Industries Corporation Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
US6977287B2 (en) 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
WO2001042323A1 (en) 1999-12-10 2001-06-14 Exxon Chemical Patents Inc. Articles formed from propylene diene copolymers
CA2292387A1 (en) 1999-12-17 2001-06-17 Bayer Inc. Process for producing olefin polymer with long chain branching
US6509431B1 (en) 2000-01-18 2003-01-21 Exxonmobil Oil Corporation Terpolymers
ES2275662T3 (en) 2000-05-10 2007-06-16 Exxonmobil Chemical Patents, Inc. POLYOLEFINIC COMPOSITIONS THAT HAVE A LOW IMPROVED LOW TEMPERATURE AND METHODS FOR IT.
JP4819313B2 (en) 2002-02-08 2011-11-24 エクソンモービル・ケミカル・パテンツ・インク Multimodal ethylene, alpha-olefin and diene polymer, method for producing the composition and apparatus comprising the composition
US6806336B2 (en) 2002-06-19 2004-10-19 Exxonmobil Chemical Patents Inc. Process for polymerizing ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene; polymers made using such processes; and articles made from such polymers
EP2261269B1 (en) 2003-07-09 2016-11-09 Arlanxeo Netherlands B.V. Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
JP5221334B2 (en) 2005-03-17 2013-06-26 ダウ グローバル テクノロジーズ エルエルシー Composition of ethylene / α-olefin multiblock copolymer suitable for film
CN101277987B (en) 2005-03-17 2011-03-23 陶氏环球技术公司 Polymer blends from interpolymers of ethylene/alpha-olefins and flexible molded articles made therefrom
KR100820542B1 (en) 2006-03-24 2008-04-08 주식회사 엘지화학 Transition metal complexes, catalysts composition containing the same and olefin polymerization theirwith
KR101396058B1 (en) 2006-05-17 2014-05-15 다우 글로벌 테크놀로지스 엘엘씨 Polyolefin solution polymerization process and polymer
KR100976131B1 (en) 2007-01-10 2010-08-16 주식회사 엘지화학 Method for preparing transition metal complexes, Transition metal complexes prepared using the mathod, Catalysts composition containing the complexes
WO2008095687A1 (en) 2007-02-08 2008-08-14 Dsm Ip Assets B.V. Elastomeric compound
US20120172548A1 (en) * 2007-05-02 2012-07-05 Lg Chem, Ltd. Polyolefin and preparation method thereof
KR100994252B1 (en) * 2007-05-09 2010-11-12 주식회사 엘지화학 Ethylene alpha-olefin copolymer
KR101066969B1 (en) 2007-05-18 2011-09-22 주식회사 엘지화학 Method for preparing olefin polymer using transition metal catalyst having better copolymerization
TW200932770A (en) 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes
CN104262520A (en) 2007-12-05 2015-01-07 三井化学株式会社 Copolymer Rubber, Rubber Composition And Rubber Molding
KR101084677B1 (en) * 2008-05-14 2011-11-22 주식회사 엘지화학 Process for preparation of olefin polymers
KR101149755B1 (en) 2009-01-06 2012-06-01 에스케이종합화학 주식회사 The Manufacture of Ethylene-Propylene-Diene Copolymer
KR101262305B1 (en) * 2009-07-01 2013-05-08 주식회사 엘지화학 Process for preparation of elastomeric polymer using transition catalyst
KR101206166B1 (en) 2009-08-13 2012-11-28 주식회사 엘지화학 Catalyst composition comprising metallocene catalyst
US8716414B2 (en) 2009-11-06 2014-05-06 Lg Chem, Ltd. Mixed metallocene catalyst composition and method for preparing polyolefin using the same
US8829106B2 (en) 2009-11-20 2014-09-09 Dow Global Technologies Llc Thermoplastic elastomer for cold and wet applications
KR101367402B1 (en) 2009-11-27 2014-02-25 주식회사 엘지화학 Process for preparation of elastomeric polymer having high diene-based monomer content and high molecular weight
KR101339391B1 (en) 2010-08-16 2013-12-09 주식회사 엘지화학 Olefin-based copolymer and method for preparation of the same
KR101889978B1 (en) 2012-01-30 2018-08-21 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 new transition metal complex with annulated ring substituted arylphenoxy ligand, catalyst composition containing the same for olefin copolymerization and methods for preparing copolymers of ethylene and α-olefins or copolymers of ethylene and olefin-diene using the same
KR101587189B1 (en) 2012-02-06 2016-02-02 주식회사 엘지화학 Polyolefin-based terpolymer and method for preparation of the same
JP6089102B2 (en) 2012-06-28 2017-03-01 ダウ グローバル テクノロジーズ エルエルシー Cross-linked foam having high hardness and low compression set
KR101391692B1 (en) 2012-11-14 2014-05-07 주식회사 엘지화학 Elastic terpolymer and preparation method thereof
KR20140144076A (en) 2013-06-10 2014-12-18 주식회사 엘지화학 Preparation method of elastic terpolymer
EP2883890A4 (en) 2013-06-28 2016-07-20 Lg Chemical Ltd Trinary elastic copolymer comprising diene and method for preparing same
EP2883891A4 (en) 2013-06-28 2016-06-01 Lg Chemical Ltd Ternary elastomeric copolymer comprising diene and method for preparing same
KR101585206B1 (en) * 2013-07-22 2016-01-13 주식회사 엘지화학 Elastic diene terpolymer and preparation method thereof

Also Published As

Publication number Publication date
US9493593B2 (en) 2016-11-15
WO2014209085A1 (en) 2014-12-31
EP2883891A4 (en) 2016-06-01
EP2883891A1 (en) 2015-06-17
CN104768986A (en) 2015-07-08
US20160280823A1 (en) 2016-09-29
JP2015532362A (en) 2015-11-09

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