IN2014MN00006A - - Google Patents

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Publication number
IN2014MN00006A
IN2014MN00006A IN6MUN2014A IN2014MN00006A IN 2014MN00006 A IN2014MN00006 A IN 2014MN00006A IN 6MUN2014 A IN6MUN2014 A IN 6MUN2014A IN 2014MN00006 A IN2014MN00006 A IN 2014MN00006A
Authority
IN
India
Prior art keywords
ufpp
equiv
processes
systems
esterification
Prior art date
Application number
Inventor
Clive Alexander Hamilton
Robert Edward Neate
Original Assignee
Invista Tech Sarl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Invista Tech Sarl filed Critical Invista Tech Sarl
Publication of IN2014MN00006A publication Critical patent/IN2014MN00006A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/006Baffles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/785Preparation processes characterised by the apparatus used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/00777Baffles attached to the reactor wall horizontal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Disclosed are processes and systems for manufacturing polyethylene terephthalate (PET) and pre polymer. The processes and systems use a variable pressure drop up flow pre polymerizer configuration. The pressure profile in the UFPP can be selected to beneficially change the relative reaction rates of the polymerization and esterification reactions. This design maximizes the esterification carried out in the UFPP while still producing a pre polymer with the optimum carboxyl end groups concentration {e.g. about 30 µ equiv./g to 60 µ equiv./g) to maximize finisher productivity. This can result in a reduction of the size and cost of the esterifier required for a given plant throughput.
IN6MUN2014 2011-06-10 2012-06-04 IN2014MN00006A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161495690P 2011-06-10 2011-06-10
PCT/US2012/040745 WO2012170351A2 (en) 2011-06-10 2012-06-04 Variable pressure drop up flow-pre-polymerizer (ufpp) systems and methods

Publications (1)

Publication Number Publication Date
IN2014MN00006A true IN2014MN00006A (en) 2015-06-12

Family

ID=47296692

Family Applications (1)

Application Number Title Priority Date Filing Date
IN6MUN2014 IN2014MN00006A (en) 2011-06-10 2012-06-04

Country Status (8)

Country Link
US (1) US20150051367A1 (en)
EP (1) EP2718002A4 (en)
CN (1) CN103717299B (en)
BR (1) BR112013031805A2 (en)
IN (1) IN2014MN00006A (en)
MX (1) MX2013014483A (en)
WO (1) WO2012170351A2 (en)
ZA (1) ZA201309231B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107469736A (en) * 2017-10-12 2017-12-15 重庆农药化工(集团)有限公司 The reactor and pressure-adjustable reactor system of adjustable reaction pressure
CN114534624B (en) * 2020-11-11 2024-04-19 中国石油化工股份有限公司 Tower type precondensation reactor

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2504258A1 (en) * 1975-02-01 1976-08-05 Dynamit Nobel Ag PROCESS AND APPARATUS FOR THE MANUFACTURING OF OLIGOMERIC ALKYLENE TEREPHTHALATES
CN1085685C (en) * 1995-12-14 2002-05-29 纳幕尔杜邦公司 Process of making polyester prepolymer
DZ3093A1 (en) * 1999-09-21 2004-06-20 Du Pont Process for adjusting the post-heating properties of polyester resins.
US6353062B1 (en) * 2000-02-11 2002-03-05 E. I. Du Pont De Nemours And Company Continuous process for producing poly(trimethylene terephthalate)
RU2323947C2 (en) * 2003-10-10 2008-05-10 Асахи Касеи Кемикалз Корпорейшн Method for preparation of polyalkylene therephthalates, method to manufacture moulded polyalkylene therephthalate part and moulded polyalkylenetherephthalate part
DE10351085A1 (en) * 2003-10-31 2005-06-16 Inventa-Fischer Gmbh & Co. Kg Tower reactor and its use for the continuous production of high molecular weight polyester
CN2767447Y (en) * 2005-02-05 2006-03-29 中国纺织工业设计院 Highly efficient simplified apparatus for producing polyethylene terephthalate
DE102005013764B3 (en) * 2005-03-22 2006-10-12 Epc Industrial Engineering Gmbh Modular device for the continuous degassing and preparation of polymeric precondensates, with high reaction surface ratio product surface to volume, with gentle treatment of the reaction product mass
US7718137B2 (en) * 2005-10-28 2010-05-18 Eastman Chemical Company Reactor with optimized internal tray design
DE102006025942B4 (en) * 2006-06-02 2011-07-07 Uhde Inventa-Fischer GmbH & Co. KG, 13509 Process for the continuous preparation of high molecular weight polyesters by esterification of dicarboxylic acids and / or transesterification of dicarboxylic acids with diols and / or mixtures thereof and device therefor
US7892498B2 (en) * 2007-03-08 2011-02-22 Eastman Chemical Company Polyester production system employing an unagitated esterification reactor
MX2011001448A (en) * 2008-08-07 2011-03-29 Invista Tech Sarl Process for production of polyesters.
CN101612544B (en) * 2009-05-27 2012-01-25 中国纺织工业设计院 Prepolycondensating reactor device

Also Published As

Publication number Publication date
WO2012170351A3 (en) 2013-04-11
MX2013014483A (en) 2015-01-27
EP2718002A2 (en) 2014-04-16
ZA201309231B (en) 2015-12-23
CN103717299B (en) 2015-12-23
CN103717299A (en) 2014-04-09
WO2012170351A2 (en) 2012-12-13
EP2718002A4 (en) 2015-03-18
US20150051367A1 (en) 2015-02-19
BR112013031805A2 (en) 2017-01-24

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