IN2014DN03217A - - Google Patents

Info

Publication number
IN2014DN03217A
IN2014DN03217A IN3217DEN2014A IN2014DN03217A IN 2014DN03217 A IN2014DN03217 A IN 2014DN03217A IN 3217DEN2014 A IN3217DEN2014 A IN 3217DEN2014A IN 2014DN03217 A IN2014DN03217 A IN 2014DN03217A
Authority
IN
India
Prior art keywords
nitrile
formula
carbon atoms
amino acid
aldéhyde
Prior art date
Application number
Inventor
Jean Luc Dubois
Jean Luc Couturier
Jean françois CARPENTIER
Jérémy Ternel
Original Assignee
Arkema France
Centre Nat Rech Scient
Univ Rennes
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France, Centre Nat Rech Scient, Univ Rennes filed Critical Arkema France
Publication of IN2014DN03217A publication Critical patent/IN2014DN03217A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/04—Formation of amino groups in compounds containing carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/26—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing carboxyl groups by reaction with HCN, or a salt thereof, and amines, or from aminonitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/22—Preparation of carboxylic acid nitriles by reaction of ammonia with carboxylic acids with replacement of carboxyl groups by cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The present invention relates to a method for synthesising a w-amino acid compound having formula HOOC-R'- CH2NH2, where R is an alkyl radical comprising between 6 and 15 carbon atoms or an alkylene radical comprising between 6 and 15 carbon atoms and between 0 and 2 unsaturations. The method comprises the foliowing steps: 1) hydroformylation of an unsaturated fatty nitrile selected from compounds having formula Ri-CH=CH -[(CH 2)q-CH=CH] m-(CH2)r-CN, wherein Ri is H or an alkyl radical comprising between 1 and 11 carbon atoms comprising, where appropriate, a hydroxyl fonction, and q, m and r are integer indices such that q = 0 o l , 0 < m < 2, and 4 < r < 13, and mixtures thereof, said step consisting in reacting the nitrile with the carbon monoxide and dihydrogen such as to obtain at least one fatty nitrile aldéhyde having formula HOC-R'-CN; 2) dioxygen oxidation, wherein the nitrile aldéhyde obtained in step 1) is converted into fatty nitrile acid having formula HOOC-R'-CN; and 3) réduction, in which the nitrile acid obtained in step 2) is converted into co-amino acid having formula HOOC-R'-CH 2NH2. The présent invention relates in particular to polyamide synthesis by means of polymérisation using the ∞-amino acid obtained in step 3).
IN3217DEN2014 2011-12-01 2012-12-03 IN2014DN03217A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1161036A FR2983478B1 (en) 2011-12-01 2011-12-01 PROCESS FOR PREPARING AMINOACID COMPRISING A HYDROFORMYLATION STEP OF UNSATURATED FATTY NITRILE
PCT/FR2012/052778 WO2013079888A1 (en) 2011-12-01 2012-12-03 Amino acid preparation method comprising a step of hydroformylation of an unsaturated fatty nitrile

Publications (1)

Publication Number Publication Date
IN2014DN03217A true IN2014DN03217A (en) 2015-06-26

Family

ID=47505192

Family Applications (1)

Application Number Title Priority Date Filing Date
IN3217DEN2014 IN2014DN03217A (en) 2011-12-01 2012-12-03

Country Status (6)

Country Link
US (1) US10125221B2 (en)
EP (1) EP2785682B1 (en)
CN (1) CN104024215B (en)
FR (1) FR2983478B1 (en)
IN (1) IN2014DN03217A (en)
WO (1) WO2013079888A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3006685B1 (en) * 2013-06-06 2016-07-22 Arkema France METHOD FOR HYDROFORMYLATION AND ISOMERIZATION CONTROLLED OF NITRIL / ESTER / OMEGA-UNSATURATED FATTY ACID
FR3013356B1 (en) * 2013-11-15 2018-03-16 Arkema France PROCESS FOR SYNTHESIZING POLYAMIDE
FR3041634B1 (en) * 2015-09-30 2017-10-20 Arkema France COMPOSITION BASED ON AMINO ACID OR ESTER OF POLYMER QUALITY AND METHODS OF OBTAINING
US10774035B2 (en) 2016-09-23 2020-09-15 Umicore Ag & Co. Kg Preparation of amino acids and amino acid derivatives
CN106622376B (en) * 2016-12-08 2019-10-11 武汉凯特立斯科技有限公司 A kind of isomerization of internal olefin and hydroformylation reaction method and catalyst
FR3107275B1 (en) 2020-02-13 2022-10-21 Eurovia UNSATURATED FLUXING AGENTS FOR HYDROCARBON BINDERS
IT202100022328A1 (en) 2021-08-25 2023-02-25 Versalis Spa METHOD FOR THE PREPARATION OF Ω-AMINO-CARBOXYLIC ACIDS AND THEIR DERIVATIVES.
EP4151670A1 (en) * 2021-09-16 2023-03-22 Evonik Operations GmbH Polyamide 12 and copolymers

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GB641955A (en) 1946-02-12 1950-08-23 Sun Chemical Corp Improvements in or relating to nitriles and process of making same
US2870030A (en) 1955-07-18 1959-01-20 Minnesota Mining & Mfg High-index glass elements
FR1156526A (en) 1955-07-27 1958-05-19 Process for obtaining sintered or vitrified surfaces
FR1157542A (en) 1956-09-03 1958-05-30 Dunlop Sa Improved sealing of chamberless enclosures
GB2074156B (en) 1980-03-28 1984-02-29 Kuraray Co Preparation of n-octadienol
US4510331A (en) 1981-07-02 1985-04-09 Kuraray Company, Ltd. Processes for producing 7-octen-1-al and derivatives thereof
TW343195B (en) * 1996-03-15 1998-10-21 Dsm Nv Process to prepare a terminal aldehyde
FR2769624B1 (en) 1997-10-09 2000-03-03 Atochem Elf Sa PROCESS FOR THE PREPARATION OF CARBOXYLIC ACID
DE10010769C1 (en) 2000-03-04 2001-10-31 Celanese Chem Europe Gmbh Non-catalytic process for the production of aliphatic carboxylic acids by oxidation in at least two stages of aldehydes
DE10010770C5 (en) 2000-03-04 2007-02-22 Celanese Chemicals Europe Gmbh Non-catalytic process for the preparation of straight-chain aliphatic carboxylic acids from aldehydes
DE10010771C1 (en) 2000-03-04 2001-05-03 Celanese Chem Europe Gmbh Production of aliphatic carboxylic acid, e.g. n-butyric, 2-methylbutyric, n-heptanoic or isononanoic acid, by oxidizing corresponding aldehyde uses group 5-11 metal or compound as catalyst
MY133839A (en) 2000-03-14 2007-11-30 Shell Int Research Process for the carbonylation of pentenenitrile
US6307108B1 (en) 2000-03-15 2001-10-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE102004055252A1 (en) 2004-11-16 2006-05-24 Celanese Chemicals Europe Gmbh Process for the preparation of aliphatic straight-chain and β-alkyl-branched carboxylic acids
DE102006022168B4 (en) 2006-05-12 2014-02-27 Oxea Gmbh Catalytic process for the preparation of aliphatic straight-chain and β-alkyl-branched carboxylic acids
AU2009269149B2 (en) 2008-06-30 2016-03-17 Mesoblast, Inc. Treatment of eye diseases and excessive neovascularization using a combined therapy
FR2933695B1 (en) * 2008-07-10 2010-08-20 Arkema France PROCESS FOR THE SYNTHESIS OF AMINO-9-NONANOIC ACID OR ESTERS THEREOF FROM UNSATURATED NATURAL FATTY ACIDS.
FR2938533B1 (en) 2008-11-17 2010-11-19 Arkema France PROCESS FOR SYNTHESIZING AN OMEGA-AMINOACIDE OR ESTERING FROM A MONO-UNSATURATED FATTY ACID OR ESTER
FR2941694B1 (en) 2009-02-05 2011-02-11 Arkema France PROCESS FOR SYNTHESIZING AN OMEGA-AMINOACIDE OR ESTERING FROM A MONO-UNSATURATED FATTY ACID OR ESTER
DE102009014626A1 (en) 2009-03-24 2010-10-07 Oxea Deutschland Gmbh Process for the preparation of aliphatic carboxylic acids from aldehydes by microreaction technology
FR2970252B1 (en) 2011-01-10 2013-11-15 Arkema France PROCESS FOR PRODUCING NITRILE-FATTY ACID COMPOUNDS
FR2978147B1 (en) 2011-07-19 2015-01-09 Arkema France PROCESS FOR SYNTHESIZING OMEGA-FUNCTIONALIZED ACIDS FROM HYDROXYLIC ACIDS OR FATTY ESTERS
FR2979342B1 (en) 2011-08-26 2013-08-09 Arkema France PROCESS FOR THE SYNTHESIS OF C11 AND C12 OMEGA-AMINOALCANOIC ACID ESTERS COMPRISING A METATHESIS STEP

Also Published As

Publication number Publication date
US20140323684A1 (en) 2014-10-30
CN104024215A (en) 2014-09-03
EP2785682B1 (en) 2019-04-03
EP2785682A1 (en) 2014-10-08
US10125221B2 (en) 2018-11-13
FR2983478A1 (en) 2013-06-07
FR2983478B1 (en) 2013-11-15
WO2013079888A1 (en) 2013-06-06
CN104024215B (en) 2016-12-07

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