IN2013MU02754A - - Google Patents

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Publication number
IN2013MU02754A
IN2013MU02754A IN2754MU2013A IN2013MU02754A IN 2013MU02754 A IN2013MU02754 A IN 2013MU02754A IN 2754MU2013 A IN2754MU2013 A IN 2754MU2013A IN 2013MU02754 A IN2013MU02754 A IN 2013MU02754A
Authority
IN
India
Prior art keywords
xylene
present disclosure
molecular sieve
isomers
alkylation catalyst
Prior art date
Application number
Inventor
Raman Ravishankar
Venkata Chalapathi Rao Peddy
Venkateswarlu Choudary Nettem
Ganapati Shanbhag
Vijaykumar Marakatti
Anand Halgeri
Sriganesh GANDHAM
Original Assignee
Hindustan Petroleum Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hindustan Petroleum Corp Ltd filed Critical Hindustan Petroleum Corp Ltd
Priority to EP13892046.7A priority Critical patent/EP3036211B1/en
Priority to IN2754MU2013 priority patent/IN2013MU02754A/en
Priority to US14/913,825 priority patent/US9919984B2/en
Priority to PCT/IN2013/000651 priority patent/WO2015025327A1/en
Publication of IN2013MU02754A publication Critical patent/IN2013MU02754A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/082—X-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

The present disclosure relates to a process for the preparation of isomers of xylene. The process includes method step of contacting an activated alkylation catalyst composite with toluene and methanol in the presence of an inert gas, at a temperature of 300 to 500°C to obtain isomers of xylene. The alkylation catalyst composite used in accordance with the present disclosure comprises a molecular sieve loaded with at least one metal ion. The metal loaded on the molecular sieve is at least one alkali earth metal selected from the group consisting of barium, strontium, magnesium and calcium.
IN2754MU2013 2013-08-23 2013-10-25 IN2013MU02754A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP13892046.7A EP3036211B1 (en) 2013-08-23 2013-10-25 A process for the preparation of isomers of xylene
IN2754MU2013 IN2013MU02754A (en) 2013-08-23 2013-10-25
US14/913,825 US9919984B2 (en) 2013-08-23 2013-10-25 Process for the preparation of isomers of xylene
PCT/IN2013/000651 WO2015025327A1 (en) 2013-08-23 2013-10-25 A process for the preparation of isomers of xylene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IN2754MU2013 IN2013MU02754A (en) 2013-08-23 2013-10-25

Publications (1)

Publication Number Publication Date
IN2013MU02754A true IN2013MU02754A (en) 2015-07-03

Family

ID=52483153

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2754MU2013 IN2013MU02754A (en) 2013-08-23 2013-10-25

Country Status (4)

Country Link
US (1) US9919984B2 (en)
EP (1) EP3036211B1 (en)
IN (1) IN2013MU02754A (en)
WO (1) WO2015025327A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110023271B (en) 2016-10-06 2022-08-19 埃克森美孚化学专利公司 Process for the selectivation of catalysts for the production of para-xylene by the methylation of benzene and/or toluene
JP6899430B2 (en) 2016-10-06 2021-07-07 エクソンモービル・ケミカル・パテンツ・インク Process of methylating aromatic hydrocarbons
US10246383B2 (en) 2016-10-06 2019-04-02 Exxonmobil Chemical Patents Inc. Process for producing paraxylene by methylation of benzene and/or toluene
US11673849B2 (en) 2016-12-21 2023-06-13 Exxonmobil Chemical Patents Inc. Process for selectivating catalyst for producing paraxylene by methylation of benzene and/or toluene
CN113574037A (en) 2019-03-28 2021-10-29 埃克森美孚化学专利公司 Method and system for converting benzene and/or toluene via methylation
US11827579B2 (en) 2019-03-28 2023-11-28 ExxonMobil Technology and Engineering Company Processes for converting benzene and/or toluene via methylation
CN110026234A (en) * 2019-04-29 2019-07-19 惠生工程（中国）有限公司 A kind of alkylation catalyst and its preparation method and application

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3965208A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Methylation of toluene
US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
US4529828A (en) * 1984-05-29 1985-07-16 Uop Inc. Separation of ortho-xylene
CA2255873A1 (en) * 1996-05-29 1997-12-04 Robert S. Smith Methylation of toluene to para-xylene
TWI240716B (en) * 2000-07-10 2005-10-01 Bp Corp North America Inc Pressure swing adsorption process for separating paraxylene and ethylbenzene from mixed C8 aromatics
US7060864B2 (en) 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US20100029467A1 (en) 2008-07-30 2010-02-04 Tomoyuki Inui Multiple zeolite catalyst
CN101885662B (en) * 2009-05-13 2013-09-18 中国石油化工股份有限公司 Toluene methanol alkylation method
US20130150640A1 (en) * 2011-12-08 2013-06-13 Gtc Technology Us, Llc Production of xylenes by methylation of aromatic compounds

Also Published As

Publication number Publication date
WO2015025327A1 (en) 2015-02-26
EP3036211A1 (en) 2016-06-29
EP3036211A4 (en) 2017-03-29
WO2015025327A8 (en) 2015-06-04
US9919984B2 (en) 2018-03-20
EP3036211B1 (en) 2019-09-25
US20160221893A1 (en) 2016-08-04

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