IN2012DN02527A - - Google Patents

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Publication number
IN2012DN02527A
IN2012DN02527A IN2527DEN2012A IN2012DN02527A IN 2012DN02527 A IN2012DN02527 A IN 2012DN02527A IN 2527DEN2012 A IN2527DEN2012 A IN 2527DEN2012A IN 2012DN02527 A IN2012DN02527 A IN 2012DN02527A
Authority
IN
India
Prior art keywords
carbonylation
ethene
catalysing
obtainable
combining
Prior art date
Application number
Inventor
Graham Eastham
Neil Tindale
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of IN2012DN02527A publication Critical patent/IN2012DN02527A/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/248—Bridged ring systems, e.g. 9-phosphabicyclononane
    • B01J31/2485—Tricyclic systems, e.g. phosphaadamantanes and hetero analogues
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process for the carbonylation of an ethylenically unsaturated compound comprising contacting ethene with carbon monoxide and a hydroxyl group containing compound in the presence of a catalyst system capable of catalysing the carbonylation of ethene which system is obtainable by combining.
IN2527DEN2012 2004-02-18 2005-02-17 IN2012DN02527A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0403592A GB0403592D0 (en) 2004-02-18 2004-02-18 A catalyst system
PCT/GB2005/000569 WO2005079981A1 (en) 2004-02-18 2005-02-17 A catalyst system

Publications (1)

Publication Number Publication Date
IN2012DN02527A true IN2012DN02527A (en) 2015-08-28

Family

ID=32039949

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2527DEN2012 IN2012DN02527A (en) 2004-02-18 2005-02-17

Country Status (16)

Country Link
US (2) US9040445B2 (en)
EP (3) EP1713582B1 (en)
JP (3) JP5350592B2 (en)
KR (1) KR101244301B1 (en)
CN (2) CN1972750A (en)
AU (1) AU2005215229B2 (en)
BR (1) BRPI0507805B1 (en)
CA (1) CA2555374C (en)
ES (3) ES2834650T3 (en)
GB (1) GB0403592D0 (en)
IN (1) IN2012DN02527A (en)
MY (1) MY143572A (en)
RU (1) RU2372989C2 (en)
TW (1) TWI377985B (en)
WO (1) WO2005079981A1 (en)
ZA (1) ZA200606472B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7767864B2 (en) 2003-07-03 2010-08-03 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) * 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
EA025600B1 (en) 2005-11-17 2017-01-30 ЛУСАЙТ ИНТЕРНЕЙШНЛ Ю Кей ЛИМИТЕД Process for carbonylation of ethylenically unsaturated compounds, catalyst system and bidentate ligand
GB0607494D0 (en) * 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
GB2437930A (en) * 2006-05-10 2007-11-14 Lucite Int Uk Ltd Mixing apparatus
WO2008065448A1 (en) 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0812297D0 (en) 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
JP2013510173A (en) * 2009-11-06 2013-03-21 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア Metal colloids with accessible metal surfaces
GB0921875D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
DE102010002809A1 (en) 2010-03-12 2011-11-17 Evonik Degussa Gmbh Process for the preparation of linear alpha, omega-dicarboxylic acid diesters
CN102205252B (en) * 2010-03-31 2014-06-11 中国科学院福建物质结构研究所 Method for synthesizing nano palladium particles with superactivity
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
US10537881B2 (en) * 2013-12-18 2020-01-21 King Abdullah University Of Science And Technology Methods of making supported Ni/Pt bimetallic nanoparticles and Ni/Pt multilayer core-shell structures and their uses for CO2 reforming
KR101982789B1 (en) 2015-12-04 2019-05-27 주식회사 엘지화학 Ligand compound, organo chromium compound, catalyst system for oligomerization of olefins and method for oligomerization of olefins using the catalyst system
FR3058909B1 (en) * 2016-11-24 2018-11-16 Arkema France SULFONIC ACID SALTS FOR THE PREPARATION OF METAL CATALYST
CN107098932A (en) * 2017-06-29 2017-08-29 管德新 A kind of synthetic method of benzyl class part available for hydroformylation reaction
PL3502085T3 (en) * 2017-12-21 2020-08-24 Evonik Operations Gmbh Method for direct conversion of alkenes to carboxylic acids
EP3502084B1 (en) * 2017-12-21 2020-02-12 Evonik Operations GmbH Method for direct conversion of di-isobutene to a carboxylic acid
CN112500430B (en) * 2021-02-08 2021-06-18 江苏欣诺科催化剂有限公司 Synthesis method of ortho-benzyl diphosphine compound
CN114392768B (en) * 2022-01-13 2023-11-10 江苏扬农化工集团有限公司 Catalyst for preparing hydroxyaldehyde by olefine aldehyde hydration and method thereof

Family Cites Families (139)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US331204A (en) * 1885-11-24 march
US2504049A (en) 1946-03-04 1950-04-11 Du Pont Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid
US3131204A (en) 1962-02-09 1964-04-28 Grace W R & Co Novel diquaternary aminophosphonium compounds
US3564020A (en) * 1968-07-17 1971-02-16 Union Oil Co Preparation of angelica lactone
FR2034147A1 (en) 1969-02-11 1970-12-11 Inst Francais Du Petrole Catalytic transition metal derivs
JPS5534784B2 (en) 1972-05-23 1980-09-09
DE2323328C2 (en) 1973-05-09 1982-04-01 Basf Ag, 6700 Ludwigshafen Process for the separation of acrylic acid from an acidified aqueous butanol-acrylic acid esterification waste liquor
US4245115A (en) * 1977-09-14 1981-01-13 Mobil Oil Corporation Selective carbonylation of olefinically unsaturated hydrocarbons using palladium-arsine or -stibine catalysts
US4377708A (en) * 1977-10-14 1983-03-22 Monsanto Company Hydrocarboxylation of vinyl alkanoates
US4142058A (en) 1977-12-08 1979-02-27 Mitsubishi Rayon Co., Ltd. Method of separating and purifying methacrylic acid
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
US4500727A (en) * 1981-03-23 1985-02-19 Kuraray Co., Ltd. Process for producing methyl lactate
JPS57168906A (en) 1981-04-13 1982-10-18 Kao Corp Maleic acid/(meth)acrylic acid copolymer
US4504684A (en) * 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
FR2530266B1 (en) * 1982-07-13 1985-07-12 Comp Generale Electricite PROCESS FOR THE PREPARATION OF ARYLACETIC AND ARYLPROPIONIC ACIDS
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
EP0121965B1 (en) 1983-04-06 1989-12-27 Shell Internationale Researchmaatschappij B.V. Process for the preparation of polyketones
CA1247640A (en) 1983-08-29 1988-12-28 James D. Burrington Alkoxycarbonylation or carbonylation with co and organic hydroxyl compound
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
NL8403035A (en) 1984-10-05 1986-05-01 Shell Int Research PROCESS FOR PREPARING POLYKETONES.
US4879412A (en) 1985-03-14 1989-11-07 Mitsui Toatsu Chemicals, Inc. Purification process of methacrylic acid
JPS6216737A (en) 1985-07-16 1987-01-24 松下電器産業株式会社 Tableware washing machine
IN166314B (en) 1985-08-29 1990-04-07 Shell Int Research
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
GB2195117B (en) * 1986-09-16 1990-10-31 Agency Ind Science Techn Process for direct carbonylation of hydrocarbons
KR880007426A (en) 1986-12-24 1988-08-27 오노 알버어스 Carbonylation Method of Olefinic Unsaturated Compound Using Palladium Catalyst
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
CA1308737C (en) 1987-04-16 1992-10-13 Syoichi Matsumoto Process for producing methacrylic ester
GB8719886D0 (en) 1987-08-22 1987-09-30 British Petroleum Co Plc Carboxylic acid esters/acids
US5196578A (en) 1987-10-09 1993-03-23 Mitsui Toatsu Chemicals, Incorporated Purification process of methacrylic acid
US4960949A (en) 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
KR0148012B1 (en) 1989-03-03 1998-08-17 오노 알버어스 Carbonylation catalyst system
US5099062A (en) 1989-03-03 1992-03-24 Shell Oil Company Carbonylation catalyst and process
US5103043A (en) 1989-03-03 1992-04-07 Shell Oil Company Carbonylation catalyst system
KR0144567B1 (en) 1989-03-03 1998-07-15 오노 알버어스 Catalyst system for carbonylation
US4950703A (en) * 1989-05-15 1990-08-21 Shell Oil Company Stabilized carbonmonoxide-olefin copolymer compositions
US5179225A (en) 1990-02-05 1993-01-12 Shell Oil Company Carbonylation catalyst system
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
GB9002491D0 (en) 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
GB9014724D0 (en) 1990-07-03 1990-08-22 Shell Int Research Process for the preparation of alpha,beta-olefinically unsaturated compounds
FI91135C (en) 1990-03-19 1994-05-25 Valmet Paper Machinery Inc Method of drilling holes in the sheath of a cylinder in a paper machine and plant for use in the method
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
GB9026211D0 (en) 1990-12-03 1991-01-16 Shell Int Research Carbonylation process
GB9105211D0 (en) 1991-03-12 1991-04-24 Shell Int Research Process for the preparation of alkanedioic acid derivatives
EP0495547B1 (en) 1991-01-15 1996-04-24 Shell Internationale Researchmaatschappij B.V. Carbonylation of olefins
ES2077337T3 (en) 1991-01-15 1995-11-16 Shell Int Research PROCEDURE FOR THE CARBONILATION OF OLEPHINS.
BE1004336A3 (en) 1991-01-15 1992-11-03 Analis Sa SEPARATION PROCESS AND QUANTIFICATION HEMOGLOBIN A1C Glycosylated HB.
AT394735B (en) 1991-01-16 1992-06-10 Chem Fab Jos Ant Zezi Ges M B AGENT FOR REMOVING THE SURFACE PROTECTIVE LAYER NEW VEHICLES OD. DGL.
EP0499329B1 (en) 1991-02-15 1994-05-04 Shell Internationale Researchmaatschappij B.V. Carbonylation catalyst system
GB9111583D0 (en) 1991-05-30 1991-07-24 Shell Int Research Carbonylation catalyst system
US5258546A (en) 1991-05-30 1993-11-02 Shell Oil Company Carbonylation catalyst system
US5247064A (en) * 1991-08-06 1993-09-21 Shell Oil Company Polymerization of co/olefin with p bidentate ligand
US5245098A (en) * 1992-01-21 1993-09-14 The University Of Akron Process for preparation of non-conjugated diolefins
EP0577205B1 (en) 1992-06-29 1997-10-08 Shell Internationale Researchmaatschappij B.V. Carbonylation of conjugated dienes
KR100295155B1 (en) * 1992-06-29 2001-11-05 오노 알버어스 Method for producing alkenic acid derivative
US5436356A (en) 1993-02-09 1995-07-25 Shell Oil Company Carbonylation process
SG42938A1 (en) * 1993-02-26 1997-10-17 Ciba Geigy Ag Ferrocenc diphosphines as ligands for homogeneous catalysts
JP2600112B2 (en) 1994-11-02 1997-04-16 工業技術院長 Method for producing silicon-containing polymer
CN1166835A (en) * 1994-11-29 1997-12-03 隆萨股份公司 Method of producing optically active metallocenyl phosphines
DE4443557A1 (en) 1994-12-07 1996-06-13 Roehm Gmbh Highly heat resistant, stress crack resistant polymethacrylate molding compounds
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5495041A (en) 1995-02-22 1996-02-27 Dsm N.W. Process for the preparation of a pentenoate ester
ATE195525T1 (en) * 1995-02-24 2000-09-15 Novartis Ag SILYLATED FERROCENYL DIPHOSPHINES, SILYLATED FERROCENYL DIPHOSPPHINS BONDED TO INORGANIC OR POLYMERIC ORGANIC SUPPORTS AND METAL COMPLEXES THEREOF, THEIR PRODUCTION AND USE
US5719313A (en) * 1995-03-16 1998-02-17 Shell Oil Company Carbonylation catalyst system and a process for the carbonylation of acetylenically unsaturated compounds
EP0820460B1 (en) * 1995-04-11 1999-07-28 Novartis AG Dihalogenated ferrocenes and processes for the preparation thereof
US5567856A (en) * 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
US5618983A (en) 1995-08-25 1997-04-08 E. I. Du Pont De Nemours And Company Hydroformylation process
DE69610844T2 (en) 1995-08-25 2001-03-29 Dsm N.V., Heerlen HYDROFORMYLATION PROCESS.
US5821389A (en) 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
US6169192B1 (en) * 1996-07-10 2001-01-02 Novartis Ag Functionalized ferrocenyldiphosphines, a process for their preparation and their use
US5710344A (en) 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
US6489506B2 (en) 1997-03-19 2002-12-03 Lucite International Uk Limited Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene
GB9705699D0 (en) 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
JP2001518833A (en) 1997-04-07 2001-10-16 ディーエスエム エヌ．ブイ． Carbonylation catalyst system
US6184391B1 (en) * 1997-04-15 2001-02-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactones and/or hydrates and/or esters thereof
DE19721601A1 (en) 1997-05-23 1998-11-26 Hoechst Ag Polybetain-stabilized, palladium-containing nanoparticles, a process for their production and catalysts made therefrom for the production of vinyl acetate
JPH10339929A (en) 1997-06-06 1998-12-22 Konica Corp Black-and-white heat developable photosensitive material and image forming method
GB9717059D0 (en) 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound
DE19745904A1 (en) 1997-10-17 1999-04-22 Hoechst Ag Water-soluble metal colloid solution, used as catalyst for fuel cells and electrolysis cells
GB9722733D0 (en) 1997-10-29 1998-10-28 Ici Plc Production of esters
DE19754304A1 (en) 1997-12-08 1999-06-10 Hoechst Ag Polybetaine-stabilized platinum nanoparticles, process for their preparation and use for electrocatalysts in fuel cells
GB9805348D0 (en) 1998-03-16 1998-05-06 Ici Plc Compound
EP0967015B1 (en) * 1998-06-19 2005-01-12 Degussa AG Use of ferrocenyl ligands in catalytic enantioselective hydrogenation
US6337406B1 (en) * 1998-08-21 2002-01-08 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
US5962732A (en) * 1998-12-17 1999-10-05 E. I. Du Pont De Nemours And Company Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst
DE19952348A1 (en) * 1998-12-19 2000-06-21 Degussa New bisphosphinyl-ferrocene ligand components for new metal complexes useful as catalysts in asymmetric hydrogenations
TW524801B (en) 1999-03-22 2003-03-21 Shell Int Research Process for the carbonylation of conjugated dienes
GB9918229D0 (en) 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
ATE324943T1 (en) * 1999-09-20 2006-06-15 Penn State Res Found CHIRAL PHOSPHINS, THEIR COMPLEXES WITH TRANSITION METALS AND THEIR USE IN ASYMMETRIC SYNTHESIS REACTIONS
WO2001028972A1 (en) 1999-10-22 2001-04-26 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of an acetylenically unsaturated compound
US6258979B1 (en) 1999-11-22 2001-07-10 Henri Kagan Chiral ferrocene phosphines active in asymmetric catalysis
EP1130614A1 (en) 2000-03-01 2001-09-05 Siemens Aktiengesellschaft Trip device
MY133839A (en) * 2000-03-14 2007-11-30 Shell Int Research Process for the carbonylation of pentenenitrile
MY127358A (en) * 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
TWI266760B (en) 2000-03-20 2006-11-21 Kvaerner Process Tech Ltd Process for the preparation of propane-1,3-diol
DE10023470A1 (en) 2000-05-12 2001-11-15 Basf Ag Production of aldehydes by hydroformylation comprises use of a source of Group VIII metals and a divalent diphosphine ligand
MY127093A (en) 2000-05-17 2006-11-30 Lucite Int Uk Ltd Bidentate ligands useful in catalyst systems
DE10037961A1 (en) 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co New phosphine ligands, their production and their use in catalytic reactions
WO2002012161A1 (en) 2000-08-10 2002-02-14 Davy Process Technology Limited Process for the carbonylation of oxiranes
DE10048874A1 (en) 2000-09-29 2002-04-11 Basf Ag Catalyst system and process for carbonylation
DE10060313A1 (en) 2000-12-04 2002-06-13 Basf Ag Process for the carbonylation of pentenoic acid and its derivatives
CN1315792C (en) 2000-12-11 2007-05-16 因维斯塔技术有限公司 Process for producing 5-cyanovaleric, adipic acid or dimethyl adidpate
DE10228293A1 (en) * 2001-07-28 2003-02-13 Basf Ag Preparation of dialkyl ketones, e.g. 3-pentanone, used as solvent or intermediate e.g. in synthesis of trimethylphenol and vitamin E, uses amide in palladium phosphine catalyst system in reductive carbonylation of olefin
AU2002363378A1 (en) 2001-11-09 2003-05-19 Shell Internationale Research Maatschappij B.V. Bidentate ligands for the carbonylation of unsaturated compounds
US20030105348A1 (en) * 2001-11-19 2003-06-05 Bunel Emilio E. Process for making 5-cyanovaleric acid, adipic acid or dimethyl adipate
JP4801321B2 (en) 2002-02-19 2011-10-26 ルーサイト インターナショナル ユーケー リミテッド Method for the carbonylation of ethylenically unsaturated compounds and their catalysts
GB0228018D0 (en) 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
TWI301481B (en) 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
GB0218613D0 (en) 2002-08-10 2002-09-18 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds
US20040115475A1 (en) * 2002-08-14 2004-06-17 Matsushita Electric Industrial Co., Ltd. Aromatic methylidene compound, methylstyrul compound for producing the same, production electroluminescent element
BR0314241B1 (en) 2002-09-12 2013-04-16 compound, processes for the preparation thereof and for the carbonylation of an ethylenically unsaturated compound, the composition, and the use of a compound or composition.
RU2326123C2 (en) 2002-09-12 2008-06-10 ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД Catalyst system
AU2003299066A1 (en) 2002-09-26 2004-04-19 Shell Internationale Research Maatschappij B.V. Process for the hydroformylation of an ethylenically unsaturated compound using a bidentate diphosphine composition with a bridging group comprising sp2 hybridized carbon atoms bound to the phosphorous atoms
WO2004072088A2 (en) 2003-02-14 2004-08-26 Takasago International Corporation Phosphine compound, intermediate, palladium-complex, and use thereof
WO2004103948A1 (en) 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene
US7767864B2 (en) 2003-07-03 2010-08-03 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
BRPI0507918A (en) 2004-02-26 2007-07-10 Shell Int Research process for the carbonylation of unsaturated compounds, catalyst composition, and asymmetric bidentate diphosphine ligand
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
CA2572845A1 (en) * 2004-07-08 2006-02-16 Merck & Co., Inc. Formation of tetra-substituted enamides and stereoselective reduction thereof
SE527991C2 (en) 2004-12-07 2006-08-01 Glow Ab Water purifier with UV lamp and filter and removable parts
WO2006084892A2 (en) 2005-02-11 2006-08-17 Shell Internationale Research Maatschappij B.V. Process for the preparation of a dicarboxylic acid
US20080269520A1 (en) * 2005-02-11 2008-10-30 Eit Drent Process for the Carbonylation of a Conjugated Diene to a Dicarboxylic Acid
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
EA025600B1 (en) 2005-11-17 2017-01-30 ЛУСАЙТ ИНТЕРНЕЙШНЛ Ю Кей ЛИМИТЕД Process for carbonylation of ethylenically unsaturated compounds, catalyst system and bidentate ligand
WO2007109365A2 (en) 2006-03-21 2007-09-27 Yale University Process for the synthesis of arylamines from the reaction of an aromatic compound with ammonia or a metal amide
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
GB2437250C (en) 2006-04-18 2012-08-15 Iti Scotland Ltd Method and system for monitoring the condition of livestock
CN101511830B (en) 2006-09-15 2013-07-24 霍夫曼-拉罗奇有限公司 Process for the preparation of pyrido[2,1-a]isoquinoline derivatives by catalytic asymmetric hydrogenation of an enamine
WO2008065448A1 (en) 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0625518D0 (en) 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
TWI473785B (en) 2007-06-01 2015-02-21 Bp Chem Int Ltd Carbonylation process for the production of acetic acid using metal-pincer ligand catalysts
GB0713624D0 (en) 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
EP2085376B1 (en) 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
FR2938536B1 (en) 2008-11-18 2012-07-13 Arkema France PROCESS FOR THE PRODUCTION OF A METHYL METHACRYLATE DERIVED FROM BIOMASS
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid
JP6216737B2 (en) 2015-04-24 2017-10-18 京楽産業．株式会社 Game machine

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