IN2012DN02527A - - Google Patents

Download PDF

Info

Publication number
IN2012DN02527A
IN2012DN02527A IN2527DEN2012A IN2012DN02527A IN 2012DN02527 A IN2012DN02527 A IN 2012DN02527A IN 2527DEN2012 A IN2527DEN2012 A IN 2527DEN2012A IN 2012DN02527 A IN2012DN02527 A IN 2012DN02527A
Authority
IN
India
Prior art keywords
carbonylation
ethene
compound
catalysing
obtainable
Prior art date
Application number
Inventor
Graham Eastham
Neil Tindale
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to GB0403592A priority Critical patent/GB0403592D0/en
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Priority to PCT/GB2005/000569 priority patent/WO2005079981A1/en
Publication of IN2012DN02527A publication Critical patent/IN2012DN02527A/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2428Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
    • B01J31/2433Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215Sulfur-containing compounds
    • B01J31/0225Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2461Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
    • B01J31/248Bridged ring systems, e.g. 9-phosphabicyclononane
    • B01J31/2485Tricyclic systems, e.g. phosphaadamantanes and hetero analogues
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202Polynuclearity
    • B01J2531/0205Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron

Abstract

A process for the carbonylation of an ethylenically unsaturated compound comprising contacting ethene with carbon monoxide and a hydroxyl group containing compound in the presence of a catalyst system capable of catalysing the carbonylation of ethene which system is obtainable by combining.
IN2527DEN2012 2004-02-18 2005-02-17 IN2012DN02527A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB0403592A GB0403592D0 (en) 2004-02-18 2004-02-18 A catalyst system
PCT/GB2005/000569 WO2005079981A1 (en) 2004-02-18 2005-02-17 A catalyst system

Publications (1)

Publication Number Publication Date
IN2012DN02527A true IN2012DN02527A (en) 2015-08-28

Family

ID=32039949

Family Applications (1)

Application Number Title Priority Date Filing Date
IN2527DEN2012 IN2012DN02527A (en) 2004-02-18 2005-02-17

Country Status (16)

Country Link
US (2) US9040445B2 (en)
EP (3) EP2243548B1 (en)
JP (3) JP5350592B2 (en)
KR (1) KR101244301B1 (en)
CN (2) CN103223350B (en)
AU (1) AU2005215229B2 (en)
BR (1) BRPI0507805B1 (en)
CA (1) CA2555374C (en)
ES (2) ES2562631T3 (en)
GB (1) GB0403592D0 (en)
IN (1) IN2012DN02527A (en)
MY (1) MY143572A (en)
RU (1) RU2372989C2 (en)
TW (1) TWI377985B (en)
WO (1) WO2005079981A1 (en)
ZA (1) ZA200606472B (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005003070A1 (en) 2003-07-03 2005-01-13 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) * 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
WO2007057640A1 (en) * 2005-11-17 2007-05-24 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
GB0607494D0 (en) * 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
GB2437930A (en) * 2006-05-10 2007-11-14 Lucite Int Uk Ltd Mixing apparatus
AU2007327051B2 (en) 2006-12-02 2013-07-04 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0812297D0 (en) 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
WO2011057109A1 (en) * 2009-11-06 2011-05-12 The Regents Of The University Of California Metal colloids with accessible metal surfaces
GB0921875D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
DE102010002809A1 (en) 2010-03-12 2011-11-17 Evonik Degussa Gmbh Process for the preparation of linear alpha, omega-dicarboxylic acid diesters
CN102205252B (en) * 2010-03-31 2014-06-11 中国科学院福建物质结构研究所 Method for synthesizing nano palladium particles with superactivity
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
US10537881B2 (en) * 2013-12-18 2020-01-21 King Abdullah University Of Science And Technology Methods of making supported Ni/Pt bimetallic nanoparticles and Ni/Pt multilayer core-shell structures and their uses for CO2 reforming
KR101982789B1 (en) 2015-12-04 2019-05-27 주식회사 엘지화학 Ligand compound, organo chromium compound, catalyst system for oligomerization of olefins and method for oligomerization of olefins using the catalyst system
PL3502084T3 (en) * 2017-12-21 2020-07-13 Evonik Operations Gmbh Method for direct conversion of di-isobutene to a carboxylic acid
EP3502085B1 (en) * 2017-12-21 2020-03-11 Evonik Operations GmbH Method for direct conversion of alkenes to carboxylic acids

Family Cites Families (139)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US331204A (en) * 1885-11-24 march
US2504049A (en) 1946-03-04 1950-04-11 Du Pont Preparation of polymethacrylic acid and of polymeric products containing polymethacrylic acid
US3131204A (en) 1962-02-09 1964-04-28 Grace W R & Co Novel diquaternary aminophosphonium compounds
US3564020A (en) 1968-07-17 1971-02-16 Union Oil Co Preparation of angelica lactone
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
FR2034147A1 (en) 1969-02-11 1970-12-11 Inst Francais Du Petrole Catalytic transition metal derivs
JPS5534784B2 (en) 1972-05-23 1980-09-09
DE2323328C2 (en) 1973-05-09 1982-04-01 Basf Ag, 6700 Ludwigshafen, De
US4245115A (en) 1977-09-14 1981-01-13 Mobil Oil Corporation Selective carbonylation of olefinically unsaturated hydrocarbons using palladium-arsine or -stibine catalysts
US4377708A (en) 1977-10-14 1983-03-22 Monsanto Company Hydrocarboxylation of vinyl alkanoates
US4142058A (en) 1977-12-08 1979-02-27 Mitsubishi Rayon Co., Ltd. Method of separating and purifying methacrylic acid
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
US4500727A (en) 1981-03-23 1985-02-19 Kuraray Co., Ltd. Process for producing methyl lactate
JPS6256890B2 (en) 1981-04-13 1987-11-27 Kao Corp
US4504684A (en) 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
FR2530266B1 (en) 1982-07-13 1985-07-12 Comp Generale Electricite Process for the preparation of arylacetic and arylpropionic acids
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
AT49010T (en) 1983-04-06 1990-01-15 Shell Int Research Method for producing polyketones.
CA1247640A (en) 1983-08-29 1988-12-27 James D. Burrington Alkoxycarbonylation or carbonylation with co and organic hydroxyl compound
NL8403035A (en) 1984-10-05 1986-05-01 Shell Int Research Process for preparing polyketones.
US4879412A (en) 1985-03-14 1989-11-07 Mitsui Toatsu Chemicals, Inc. Purification process of methacrylic acid
JPS6216737A (en) 1985-07-16 1987-01-24 Matsushita Electric Ind Co Ltd Tableware washing machine
IN166314B (en) 1985-08-29 1990-04-07 Shell Int Research
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
GB2195117B (en) 1986-09-16 1990-10-31 Agency Ind Science Techn Process for direct carbonylation of hydrocarbons
KR880007426A (en) 1986-12-24 1988-08-27 오노 알버어스 Carbonylation Method of Olefinic Unsaturated Compound Using Palladium Catalyst
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
CA1308737C (en) 1987-04-16 1992-10-13 Syoichi Matsumoto Process for producing methacrylic ester
GB8719886D0 (en) 1987-08-22 1987-09-30 British Petroleum Co Plc Carboxylic acid esters/acids
US5196578A (en) 1987-10-09 1993-03-23 Mitsui Toatsu Chemicals, Incorporated Purification process of methacrylic acid
US4960949A (en) 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
KR0148012B1 (en) 1989-03-03 1998-08-17 오노 알버어스 Carbonylation catalyst system
KR0144567B1 (en) 1989-03-03 1998-07-15 오노 알버어스 Catalyst system for carbonylation
US5099062A (en) 1989-03-03 1992-03-24 Shell Oil Company Carbonylation catalyst and process
US5103043A (en) 1989-03-03 1992-04-07 Shell Oil Company Carbonylation catalyst system
US4950703A (en) 1989-05-15 1990-08-21 Shell Oil Company Stabilized carbonmonoxide-olefin copolymer compositions
GB9002491D0 (en) 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
US5179225A (en) 1990-02-05 1993-01-12 Shell Oil Company Carbonylation catalyst system
FI91135C (en) 1990-03-19 1994-05-25 Valmet Paper Machinery Inc Method of drilling holes in the sheath of a cylinder in a paper machine and plant for use in the method
GB9014724D0 (en) 1990-07-03 1990-08-22 Shell Int Research Process for the preparation of alpha,beta-olefinically unsaturated compounds
GB9026211D0 (en) 1990-12-03 1991-01-16 Shell Int Research Carbonylation process
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
BE1004336A3 (en) 1991-01-15 1992-11-03 Analis Sa SEPARATION PROCESS AND QUANTIFICATION HEMOGLOBIN A1C Glycosylated HB.
ES2088082T3 (en) 1991-01-15 1996-08-01 Shell Int Research Olephine carbonilation.
DE69204691T2 (en) 1991-01-15 1996-04-11 Shell Int Research Process for carbonylation of olefin.
AT394735B (en) 1991-01-16 1992-06-10 Chem Fab Jos Ant Zezi Ges M B Agent for removing the surface protective layer new vehicles od. dgl.
ES2054519T3 (en) 1991-02-15 1994-08-01 Shell Int Research CARBONILATION CATALYST SYSTEM.
GB9105211D0 (en) 1991-03-12 1991-04-24 Shell Int Research Process for the preparation of alkanedioic acid derivatives
GB9111583D0 (en) 1991-05-30 1991-07-24 Shell Int Research Carbonylation catalyst system
US5258546A (en) 1991-05-30 1993-11-02 Shell Oil Company Carbonylation catalyst system
US5247064A (en) 1991-08-06 1993-09-21 Shell Oil Company Polymerization of co/olefin with p bidentate ligand
US5245098A (en) 1992-01-21 1993-09-14 The University Of Akron Process for preparation of non-conjugated diolefins
US5350876A (en) 1992-06-29 1994-09-27 Shell Oil Company Carbonylation of conjugated dienes
EP0577205B1 (en) 1992-06-29 1997-10-08 Shell Internationale Research Maatschappij B.V. Carbonylation of conjugated dienes
US5436356A (en) 1993-02-09 1995-07-25 Shell Oil Company Carbonylation process
EP0612758B1 (en) 1993-02-26 2003-04-09 Syngenta Participations AG Ferrocenyl diphosphines as ligands for homogeneous catalysts
JP2600112B2 (en) 1994-11-02 1997-04-16 工業技術院長 Method for producing silicon-containing polymer
AT179178T (en) 1994-11-29 1999-05-15 Lonza Ag Method for producing optically active metallocenylphosphins
DE4443557A1 (en) 1994-12-07 1996-06-13 Roehm Gmbh Highly heat resistant, stress crack resistant polymethacrylate molding compounds
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5495041A (en) 1995-02-22 1996-02-27 Dsm N.W. Process for the preparation of a pentenoate ester
EP0729969B1 (en) 1995-02-24 2000-08-16 Novartis AG Silated ferrocene-diphosphine ligands, inorganic or polymeric organic support to which these ligands are bound and metal complexes thereof, and their preparation and use
US5719313A (en) 1995-03-16 1998-02-17 Shell Oil Company Carbonylation catalyst system and a process for the carbonylation of acetylenically unsaturated compounds
CZ291280B6 (en) 1995-04-11 2003-01-15 Syngenta Participations Ag Ferrocenes and processes of their preparation
US5567856A (en) 1995-05-30 1996-10-22 Hoechst Celanese Corporation Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands
US5618983A (en) 1995-08-25 1997-04-08 E. I. Du Pont De Nemours And Company Hydroformylation process
JP3285875B2 (en) * 1995-08-25 2002-05-27 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー Hydroformylation method
US5821389A (en) 1996-04-24 1998-10-13 Union Carbide Chemicals & Technology Corporation Processes for producing hydroxyaldehydes
ES2171267T3 (en) 1996-07-10 2002-09-01 Syngenta Participations Ag Ferrocenildifosfinas functionalized, a procedure for preparation and use.
US5710344A (en) 1996-11-08 1998-01-20 E. I. Du Pont De Nemours And Company Process to prepare a linear aldehyde
GB9705699D0 (en) 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6489506B2 (en) 1997-03-19 2002-12-03 Lucite International Uk Limited Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
JP2001518833A (en) 1997-04-07 2001-10-16 ディーエスエム エヌ.ブイ. Carbonylation catalyst system
US6184391B1 (en) 1997-04-15 2001-02-06 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactones and/or hydrates and/or esters thereof
DE19721601A1 (en) 1997-05-23 1998-11-26 Hoechst Ag Polybetain-stabilized, palladium-containing nanoparticles, a process for their production and catalysts made therefrom for the production of vinyl acetate
JPH10339929A (en) 1997-06-06 1998-12-22 Konica Corp Black-and-white heat developable photosensitive material and image forming method
GB9717059D0 (en) 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound
DE19745904A1 (en) 1997-10-17 1999-04-22 Hoechst Ag Water-soluble metal colloid solution, used as catalyst for fuel cells and electrolysis cells
GB9722733D0 (en) 1997-10-29 1998-10-28 Ici Plc Production of esters
DE19754304A1 (en) 1997-12-08 1999-06-10 Hoechst Ag Polybetaine-stabilized platinum nanoparticles, process for their preparation and use for electrocatalysts in fuel cells
GB9805348D0 (en) 1998-03-16 1998-05-06 Ici Plc Compound
EP0967015B1 (en) 1998-06-19 2005-01-12 Degussa AG Use of ferrocenyl ligands in catalytic enantioselective hydrogenation
US6337406B1 (en) 1998-08-21 2002-01-08 The Penn State Research Foundation Asymmetric catalysis based on chiral phospholanes and hydroxyl phospholanes
US5962732A (en) 1998-12-17 1999-10-05 E. I. Du Pont De Nemours And Company Process for the preparation of 3-pentenoic acid from butadiene using a nickel catalyst
DE19952348A1 (en) 1998-12-19 2000-06-21 Degussa New bisphosphinyl-ferrocene ligand components for new metal complexes useful as catalysts in asymmetric hydrogenations
TW524801B (en) 1999-03-22 2003-03-21 Shell Int Research Process for the carbonylation of conjugated dienes
GB9918229D0 (en) 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
CA2385421C (en) 1999-09-20 2009-12-15 The Penn State Research Foundation Chiral phosphines, transition metal complexes thereof and uses thereof in asymmetric reactions
AT265412T (en) 1999-10-22 2004-05-15 Shell Int Research Method for carbonylating an acetylenically unsaturated compound
US6258979B1 (en) 1999-11-22 2001-07-10 Henri Kagan Chiral ferrocene phosphines active in asymmetric catalysis
EP1130614A1 (en) 2000-03-01 2001-09-05 Siemens Aktiengesellschaft Trip device
US6743911B2 (en) * 2000-03-14 2004-06-01 Shell Oil Company Process for the carbonylation of pentenenitrile
US6706912B2 (en) 2000-03-14 2004-03-16 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds
TWI266760B (en) 2000-03-20 2006-11-21 Kvaerner Process Tech Ltd Process for the preparation of propane-1,3-diol
DE10023470A1 (en) 2000-05-12 2001-11-15 Basf Ag Production of aldehydes by hydroformylation comprises use of a source of Group VIII metals and a divalent diphosphine ligand
DE60101963T3 (en) 2000-05-17 2007-10-18 Shell Internationale Research Maatschappij B.V. Bidentate ligands for catalyst systems
DE10037961A1 (en) 2000-07-27 2002-02-07 Aventis Res & Tech Gmbh & Co New phosphine ligands, their production and their use in catalytic reactions
AU7859301A (en) 2000-08-10 2002-02-18 Davy Process Techn Ltd Process for the carbonylation of oxiranes
DE10048874A1 (en) 2000-09-29 2002-04-11 Basf Ag Catalyst system and process for carbonylation
DE10060313A1 (en) 2000-12-04 2002-06-13 Basf Ag Process for the carbonylation of pentenoic acid and its derivatives
JP2004515537A (en) 2000-12-11 2004-05-27 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company Method for producing 5-cyanovaleric acid, adipic acid or dimethyl adipate
DE10228293A1 (en) 2001-07-28 2003-02-13 Basf Ag Preparation of dialkyl ketones, e.g. 3-pentanone, used as solvent or intermediate e.g. in synthesis of trimethylphenol and vitamin E, uses amide in palladium phosphine catalyst system in reductive carbonylation of olefin
WO2003040159A2 (en) 2001-11-09 2003-05-15 Shell Internationale Research Maatschappij B.V. Bidentate ligands for the carbonylation of unsaturated compounds
US20030105348A1 (en) 2001-11-19 2003-06-05 Bunel Emilio E. Process for making 5-cyanovaleric acid, adipic acid or dimethyl adipate
EP1478463B1 (en) 2002-02-19 2012-04-11 Lucite International UK Limited Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
TWI301481B (en) 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
KR100924521B1 (en) 2002-09-12 2009-11-02 루싸이트 인터내셔날 유케이 리미티드 A catalyst system
CA2498293C (en) 2002-09-12 2012-05-22 Lucite International Uk Limited Catalyst system comprising chelating ligand and group viiib metal
GB0218613D0 (en) * 2002-08-10 2002-09-18 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds
US20040115475A1 (en) 2002-08-14 2004-06-17 Matsushita Electric Industrial Co., Ltd. Aromatic methylidene compound, methylstyrul compound for producing the same, production electroluminescent element
JP4101803B2 (en) 2002-09-26 2008-06-18 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Method for hydroformylating an ethylenically unsaturated compound using a bidentate diphosphine composition having a bridging group containing an SP2 hybrid carbon atom bonded to a phosphorus atom
GB0228018D0 (en) 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
WO2004072088A2 (en) 2003-02-14 2004-08-26 Takasago International Corporation Phosphine compound, intermediate, palladium-complex, and use thereof
BRPI0507918A (en) 2004-02-26 2007-07-10 Shell Int Research process for the carbonylation of unsaturated compounds, catalyst composition, and asymmetric bidentate diphosphine ligand
JP2007502315A (en) 2003-05-22 2007-02-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Method for carbonylation of conjugated dienes
WO2005003070A1 (en) 2003-07-03 2005-01-13 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
GB0411951D0 (en) 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
CA2672687A1 (en) 2004-07-08 2006-02-16 Merck & Co., Inc. Formation of tetra-substituted enamides and stereoselective reduction thereof
SE527991C2 (en) 2004-12-07 2006-08-01 Glow Ab Water purifier with UV lamp and the filter and demountable parts
CN101142162A (en) 2005-02-11 2008-03-12 国际壳牌研究有限公司 Process for the preparation of a dicarboxylic acid
US20080269520A1 (en) 2005-02-11 2008-10-30 Eit Drent Process for the Carbonylation of a Conjugated Diene to a Dicarboxylic Acid
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
WO2007057640A1 (en) 2005-11-17 2007-05-24 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
CN101437808A (en) 2006-03-21 2009-05-20 耶鲁大学 Process for the synthesis of arylamines from the reaction ofan aromaticcompounds with ammonia or a metal amide
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
GB2437250C (en) 2006-04-18 2012-08-15 Iti Scotland Ltd Method and system for monitoring the condition of livestock
CN101511830B (en) 2006-09-15 2013-07-24 霍夫曼-拉罗奇有限公司 Process for the preparation of pyrido[2,1-a]isoquinoline derivatives by catalytic asymmetric hydrogenation of an enamine
AU2007327051B2 (en) 2006-12-02 2013-07-04 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0625518D0 (en) 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
TWI473785B (en) 2007-06-01 2015-02-21 Bp Chem Int Ltd Carbonylation process for the production of acetic acid using metal-pincer ligand catalysts
GB0713624D0 (en) 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
EP2085376B1 (en) 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
FR2938536B1 (en) 2008-11-18 2012-07-13 Arkema France PROCESS FOR THE PRODUCTION OF A METHYL METHACRYLATE DERIVED FROM BIOMASS
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid
JP6216737B2 (en) 2015-04-24 2017-10-18 京楽産業.株式会社 Game machine

Also Published As

Publication number Publication date
TWI377985B (en) 2012-12-01
US9802185B2 (en) 2017-10-31
JP2013063440A (en) 2013-04-11
CN1972750A (en) 2007-05-30
CN103223350A (en) 2013-07-31
KR20070006782A (en) 2007-01-11
ES2445618T3 (en) 2014-03-04
JP2013091651A (en) 2013-05-16
CA2555374C (en) 2013-01-29
JP5746130B2 (en) 2015-07-08
ZA200606472B (en) 2008-04-30
US20070282124A1 (en) 2007-12-06
EP2243548B1 (en) 2015-11-11
JP5350592B2 (en) 2013-11-27
EP2243549B1 (en) 2020-09-02
BRPI0507805A (en) 2007-07-10
WO2005079981A8 (en) 2006-03-02
RU2372989C2 (en) 2009-11-20
RU2006133287A (en) 2008-03-27
AU2005215229A1 (en) 2005-09-01
GB0403592D0 (en) 2004-03-24
TW200538202A (en) 2005-12-01
CN103223350B (en) 2016-08-03
ES2562631T3 (en) 2016-03-07
US9040445B2 (en) 2015-05-26
WO2005079981A1 (en) 2005-09-01
US20150321186A1 (en) 2015-11-12
BRPI0507805B1 (en) 2015-06-23
MY143572A (en) 2011-05-31
CA2555374A1 (en) 2005-09-01
JP5773974B2 (en) 2015-09-02
AU2005215229B2 (en) 2010-08-26
EP2243548A1 (en) 2010-10-27
EP2243549A1 (en) 2010-10-27
EP1713582A1 (en) 2006-10-25
EP1713582B1 (en) 2013-11-06
JP2007522934A (en) 2007-08-16
KR101244301B1 (en) 2013-03-18

Similar Documents

Publication Publication Date Title
ES2536678T3 (en) Method of selective oxidation of carbohydrates through the use of supported gold catalysts
Song et al. Direct functionalization of benzylic C–Hs with vinyl acetates via Fe-catalysis
NZ601028A (en) Dialysate regeneration system with external wall having material that passes gas but not liquid.
EA201270809A1 (en) Catalysts and systems containing graphene oxide and graphite oxide
MX350097B (en) Systems and methods for removing heavy hydrocarbons and acid gases from a hydrocarbon gas stream.
TW338764B (en) Process for the production of lower aliphatic esters
MX2010005801A (en) Promoter enhanced chlled ammonia based system and method for removal of co2 from flue gas stream.
MY142914A (en) Methods for producing acetic acid
BR9813603A (en) Mixed catalyst system
ES2506440T3 (en) Procedure for the preparation of polyether carbonate polyols
WO2010078061A3 (en) Methods and systems for papr reduction in sc-fdma systems
RU2008147719A (en) Audio improvement with the possibility of repeat mixing
MY139209A (en) Process for producing polyalkylene carbonates
RU2005134237A (en) Catalyst for producing hydrocarbon from synthesis gas and method for producing the catalyst
MY121194A (en) Process for the production of acetic acid.
CO7310534A2 (en) Procedure and installation for the conversion of carbon dioxide into carbon monoxide
PT1027316E (en) Synthesis of aryl esters, methods and reagents with this related
NZ585096A (en) Systems and methods for capture and sequestration of greenhouse gases and compositions such as ceramic derived therefrom
MX2007012751A (en) Catalysts for olefin polymerization.
IL177506D0 (en) System and process for injecting catalyst and/or additives into a fluidized catalytic cracking unit
CA2476255A1 (en) Oxidation catalyst and process for its preparation and process for oxidation using it
TW200605023A (en) Audio apparatus with active noise cancellation
PH12015501928B1 (en) Method for producing solid carbon by reducing carbon oxides
HUT48646A (en) Process for producing catalyst systhem and polyolefines with producing in situ comonomeres utilizing former catalyst
MY163029A (en) Apparatus for making bio-organic compounds