IN169984B - - Google Patents
Info
- Publication number
- IN169984B IN169984B IN390/CAL/88A IN390CA1988A IN169984B IN 169984 B IN169984 B IN 169984B IN 390CA1988 A IN390CA1988 A IN 390CA1988A IN 169984 B IN169984 B IN 169984B
- Authority
- IN
- India
- Prior art keywords
- reaction medium
- potassium
- catalyst
- temperature
- dimerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/107—Alkenes with six carbon atoms
- C07C11/113—Methylpentenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/232—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/24—Catalytic processes with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/20—Carbon compounds
- C07C2527/232—Carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
The catalyst for the dimerization of propylene into methyl-4-pentene-1 comprises potassium (K) and potassium carbonate (K2CO3) and is characterized in that it further contains at least one metal (M) selected amongst manganese, chromium, cadmium, nickel, palladium and titanium. It may also include copper. The method for preparing the catalyst comprises the following steps carried out in the presence of an inert liquid having a high boiling point. In a first step, a suspension of potassium carbonate is obtained in the inert liquid. In a second step, the metal or metals (M), and optionally copper, are introduced in powder form into the highly stirred reaction medium. In a third step, after bringing the reaction medium to a temperature higher than the potassium melting temperature, potassium is introduced under high stirring conditions. In the fourth step, the reaction medium is brought to a temperature comprised between 140 and 180 DEG C during a length of time comprised between 1 and 3 hours, and the reaction medium is then allowed to cool down to room temperature. The process for dimerization of propylene into methyl-4-pentene-1 uses the catalyst disclosed hereabove.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8706828A FR2615123B1 (en) | 1987-05-15 | 1987-05-15 | CATALYST AND METHOD FOR DIMERIZING PROPYLENE TO METHYL-4-PENTENE-1 |
PCT/FR1988/000234 WO1988008834A1 (en) | 1987-05-15 | 1988-05-11 | Catalyst and process for dimerization of propylene into methyl-4-pentene-1 |
Publications (1)
Publication Number | Publication Date |
---|---|
IN169984B true IN169984B (en) | 1992-01-25 |
Family
ID=9351123
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IN390/CAL/88A IN169984B (en) | 1987-05-15 | 1988-05-13 |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP0291411B1 (en) |
JP (1) | JP2610006B2 (en) |
KR (1) | KR960004866B1 (en) |
CN (1) | CN1020863C (en) |
AT (1) | ATE74894T1 (en) |
BR (1) | BR8807504A (en) |
CA (1) | CA1327563C (en) |
DE (1) | DE3870024D1 (en) |
ES (1) | ES2030514T3 (en) |
FR (1) | FR2615123B1 (en) |
GR (1) | GR3005102T3 (en) |
IN (1) | IN169984B (en) |
WO (1) | WO1988008834A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115722240A (en) * | 2021-08-25 | 2023-03-03 | 中国石油化工股份有限公司 | Supported K-M/potassium carbonate catalyst, preparation method thereof and synthesis method of 4-methyl-1-pentene |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4895819A (en) * | 1988-07-18 | 1990-01-23 | Phillips Petroleum Company | Alkali metal carbonate supports and elemental alkali catalysis thereof for olefin dimerization |
GB2254802B (en) * | 1991-04-19 | 1995-05-03 | Ethyl Corp | Catalyst composition for coupling process |
US6265343B1 (en) * | 1994-03-07 | 2001-07-24 | Degussa Corporation | Catalyst and method for the synthesis of chlorine dioxide, and method of making catalyst for the synthesis of chlorine dioxide |
DE19845293A1 (en) * | 1998-10-01 | 2000-04-06 | Basf Ag | Production of a basic catalyst while avoiding high temperatures |
CN114230701A (en) * | 2022-01-13 | 2022-03-25 | 宁夏清研高分子新材料有限公司 | Preparation method of poly 4-methyl-1-pentene material with narrow molecular weight distribution |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2390100A (en) * | 1941-10-24 | 1945-12-04 | Standard Oil Co | Hydrocarbon polymerization |
US3816555A (en) * | 1964-11-20 | 1974-06-11 | British Petroleum Co | Process for oligomerising mono-olefins |
JPS4837241A (en) * | 1971-09-11 | 1973-06-01 | ||
IT967652B (en) * | 1972-09-20 | 1974-03-11 | Sir Soc Italiana Resine Spa | CATALYSTS FOR THE PRODUCTION OF 4 METHYL I PENTENE FOR DIMERIZATION OF PROPYLENE AND RELATED PREPARATION PROCEDURE |
US4595787A (en) * | 1985-06-24 | 1986-06-17 | Phillips Petroleum Company | Potassium carbonate supports, catalysts and olefin dimerization processes therewith |
-
1987
- 1987-05-15 FR FR8706828A patent/FR2615123B1/en not_active Expired
-
1988
- 1988-05-11 JP JP63504312A patent/JP2610006B2/en not_active Expired - Lifetime
- 1988-05-11 DE DE8888401157T patent/DE3870024D1/en not_active Expired - Fee Related
- 1988-05-11 BR BR888807504A patent/BR8807504A/en not_active IP Right Cessation
- 1988-05-11 WO PCT/FR1988/000234 patent/WO1988008834A1/en unknown
- 1988-05-11 KR KR1019890700053A patent/KR960004866B1/en not_active IP Right Cessation
- 1988-05-11 AT AT88401157T patent/ATE74894T1/en not_active IP Right Cessation
- 1988-05-11 ES ES198888401157T patent/ES2030514T3/en not_active Expired - Lifetime
- 1988-05-11 EP EP19880401157 patent/EP0291411B1/en not_active Expired - Lifetime
- 1988-05-13 CA CA000566824A patent/CA1327563C/en not_active Expired - Fee Related
- 1988-05-13 IN IN390/CAL/88A patent/IN169984B/en unknown
- 1988-05-14 CN CN88103906A patent/CN1020863C/en not_active Expired - Fee Related
-
1992
- 1992-07-07 GR GR920401442T patent/GR3005102T3/el unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115722240A (en) * | 2021-08-25 | 2023-03-03 | 中国石油化工股份有限公司 | Supported K-M/potassium carbonate catalyst, preparation method thereof and synthesis method of 4-methyl-1-pentene |
Also Published As
Publication number | Publication date |
---|---|
EP0291411B1 (en) | 1992-04-15 |
CN1034000A (en) | 1989-07-19 |
KR960004866B1 (en) | 1996-04-16 |
FR2615123A1 (en) | 1988-11-18 |
FR2615123B1 (en) | 1989-06-30 |
CN1020863C (en) | 1993-05-26 |
WO1988008834A1 (en) | 1988-11-17 |
GR3005102T3 (en) | 1993-05-24 |
JP2610006B2 (en) | 1997-05-14 |
BR8807504A (en) | 1990-04-17 |
ATE74894T1 (en) | 1992-05-15 |
ES2030514T3 (en) | 1992-11-01 |
KR890701508A (en) | 1989-12-20 |
EP0291411A1 (en) | 1988-11-17 |
JPH02504484A (en) | 1990-12-20 |
DE3870024D1 (en) | 1992-05-21 |
CA1327563C (en) | 1994-03-08 |
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