IL44210A - Process for preparing 4-hydrooxy-thiochromans - Google Patents
Process for preparing 4-hydrooxy-thiochromansInfo
- Publication number
- IL44210A IL44210A IL44210A IL4421074A IL44210A IL 44210 A IL44210 A IL 44210A IL 44210 A IL44210 A IL 44210A IL 4421074 A IL4421074 A IL 4421074A IL 44210 A IL44210 A IL 44210A
- Authority
- IL
- Israel
- Prior art keywords
- preparing
- thiochromans
- hydrooxy
- halogen
- formula
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
- C07D335/04—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D335/06—Benzothiopyrans; Hydrogenated benzothiopyrans
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
Claims (1)
1. What is claimed is. 1, A process for preparing -hydroxythiochromans having the formula wherein R and represent alkyl groups having from 1 to k carbon atoms or halogen and m and n represent integers from 0 to 3 preferably from 0 to 2, provided that not more than one of the radicals R and is halogen, which comprises catalytically reducing thiochromanones having the formula with hydrogen in an inert organic solvent in the presence of nickel catalysts, at temperatures of from +20° to 100°C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19732309282 DE2309282A1 (en) | 1973-02-24 | 1973-02-24 | PROCESS FOR THE PREPARATION OF 4-HYDROXY-THIOCHROMANS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL44210A0 IL44210A0 (en) | 1974-05-16 |
| IL44210A true IL44210A (en) | 1976-11-30 |
Family
ID=5872984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL44210A IL44210A (en) | 1973-02-24 | 1974-02-14 | Process for preparing 4-hydrooxy-thiochromans |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS49116071A (en) |
| AT (1) | ATA144774A (en) |
| BE (1) | BE811526A (en) |
| DE (1) | DE2309282A1 (en) |
| FR (1) | FR2219163A1 (en) |
| IL (1) | IL44210A (en) |
| IT (1) | IT1035071B (en) |
| NL (1) | NL7402260A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX9300312A (en) * | 1992-01-23 | 1993-07-31 | Pfizer | BENZOPYRANIC AND RELATED ANTAGONISTS OF LTB. |
| EP0629623B1 (en) * | 1992-03-03 | 1999-05-19 | Idemitsu Kosan Company Limited | Pyrazole derivative |
-
1973
- 1973-02-24 DE DE19732309282 patent/DE2309282A1/en active Pending
-
1974
- 1974-02-14 IL IL44210A patent/IL44210A/en unknown
- 1974-02-19 NL NL7402260A patent/NL7402260A/xx unknown
- 1974-02-22 JP JP49020621A patent/JPS49116071A/ja active Pending
- 1974-02-22 AT AT741447A patent/ATA144774A/en not_active IP Right Cessation
- 1974-02-22 FR FR7406110A patent/FR2219163A1/en active Granted
- 1974-02-25 IT IT48720/74A patent/IT1035071B/en active
- 1974-02-25 BE BE141346A patent/BE811526A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL44210A0 (en) | 1974-05-16 |
| IT1035071B (en) | 1979-10-20 |
| DE2309282A1 (en) | 1974-08-29 |
| NL7402260A (en) | 1974-08-27 |
| BE811526A (en) | 1974-08-26 |
| ATA144774A (en) | 1975-12-15 |
| FR2219163A1 (en) | 1974-09-20 |
| FR2219163B1 (en) | 1977-09-23 |
| JPS49116071A (en) | 1974-11-06 |
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