IL41775A - Pyridylmethyl carbamates,their preparation and their use as rodenticides - Google Patents
Pyridylmethyl carbamates,their preparation and their use as rodenticidesInfo
- Publication number
- IL41775A IL41775A IL41775A IL4177573A IL41775A IL 41775 A IL41775 A IL 41775A IL 41775 A IL41775 A IL 41775A IL 4177573 A IL4177573 A IL 4177573A IL 41775 A IL41775 A IL 41775A
- Authority
- IL
- Israel
- Prior art keywords
- composition
- compound
- pyridylmethyl
- rodenticidal
- carbamate
- Prior art date
Links
- 239000003128 rodenticide Substances 0.000 title claims 7
- -1 Pyridylmethyl carbamates Chemical class 0.000 title claims 6
- 238000002360 preparation method Methods 0.000 title claims 4
- 150000001875 compounds Chemical class 0.000 claims abstract 12
- 230000001119 rodenticidal effect Effects 0.000 claims abstract 10
- MVQVNTPHUGQQHK-UHFFFAOYSA-N 3-pyridinemethanol Chemical compound OCC1=CC=CN=C1 MVQVNTPHUGQQHK-UHFFFAOYSA-N 0.000 claims abstract 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- DGTNSSLYPYDJGL-UHFFFAOYSA-N phenyl isocyanate Chemical class O=C=NC1=CC=CC=C1 DGTNSSLYPYDJGL-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims 18
- 238000000034 method Methods 0.000 claims 16
- 241000283984 Rodentia Species 0.000 claims 7
- 241000607479 Yersinia pestis Species 0.000 claims 5
- 239000007787 solid Substances 0.000 claims 5
- 239000010408 film Substances 0.000 claims 4
- 239000000853 adhesive Substances 0.000 claims 3
- 230000001070 adhesive effect Effects 0.000 claims 3
- 239000011230 binding agent Substances 0.000 claims 3
- 239000003085 diluting agent Substances 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- 235000019733 Fish meal Nutrition 0.000 claims 2
- 241001465754 Metazoa Species 0.000 claims 2
- 241000209140 Triticum Species 0.000 claims 2
- 235000021307 Triticum Nutrition 0.000 claims 2
- 240000008042 Zea mays Species 0.000 claims 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 235000013399 edible fruits Nutrition 0.000 claims 2
- 239000004744 fabric Substances 0.000 claims 2
- 239000000835 fiber Substances 0.000 claims 2
- 239000004467 fishmeal Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- 239000000575 pesticide Substances 0.000 claims 2
- 239000004033 plastic Substances 0.000 claims 2
- 229920003023 plastic Polymers 0.000 claims 2
- 239000003755 preservative agent Substances 0.000 claims 2
- 230000002335 preservative effect Effects 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 235000000346 sugar Nutrition 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 239000004559 tracking powder Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 239000001993 wax Substances 0.000 claims 2
- 235000007319 Avena orientalis Nutrition 0.000 claims 1
- 244000075850 Avena orientalis Species 0.000 claims 1
- 229920002261 Corn starch Polymers 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 229920005822 acrylic binder Polymers 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 239000008120 corn starch Substances 0.000 claims 1
- 229940099112 cornstarch Drugs 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 235000013305 food Nutrition 0.000 claims 1
- 235000013355 food flavoring agent Nutrition 0.000 claims 1
- 239000012442 inert solvent Substances 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 235000012054 meals Nutrition 0.000 claims 1
- 235000013336 milk Nutrition 0.000 claims 1
- 239000008267 milk Substances 0.000 claims 1
- 210000004080 milk Anatomy 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 235000013379 molasses Nutrition 0.000 claims 1
- 239000005022 packaging material Substances 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 239000008188 pellet Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- NEJBEZATSQIMQM-UHFFFAOYSA-N pyridin-3-ylmethyl n-(4-nitrophenyl)carbamate Chemical compound C1=CC([N+](=O)[O-])=CC=C1NC(=O)OCC1=CC=CN=C1 NEJBEZATSQIMQM-UHFFFAOYSA-N 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 235000013580 sausages Nutrition 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- CTMMSAFINBGXIF-UHFFFAOYSA-N 1-(4-cyanophenyl)-3-(4-methylphenyl)sulfonylurea Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)NC1=CC=C(C#N)C=C1 CTMMSAFINBGXIF-UHFFFAOYSA-N 0.000 abstract 1
- VBHPTXLJMAEQHR-UHFFFAOYSA-N 4-nitro-1-(4-nitro-2-propylphenyl)sulfanyl-2-propylbenzene Chemical compound C(CC)C1=C(C=CC(=C1)[N+](=O)[O-])SC1=C(C=C(C=C1)[N+](=O)[O-])CCC VBHPTXLJMAEQHR-UHFFFAOYSA-N 0.000 abstract 1
- ULMCIKJYCADGLX-UHFFFAOYSA-N 4-sulfamoylbenzoyl azide Chemical compound NS(=O)(=O)C1=CC=C(C(=O)N=[N+]=[N-])C=C1 ULMCIKJYCADGLX-UHFFFAOYSA-N 0.000 abstract 1
- QACQFBFJQXNBCC-UHFFFAOYSA-N C(CC)C1=C(C=CC(=C1)N)S(=O)(=O)C1=C(C=C(C=C1)N)CCC Chemical compound C(CC)C1=C(C=CC(=C1)N)S(=O)(=O)C1=C(C=C(C=C1)N)CCC QACQFBFJQXNBCC-UHFFFAOYSA-N 0.000 abstract 1
- KBVSHAWWGLGKAI-UHFFFAOYSA-N pyridin-3-ylmethyl carbamate Chemical class NC(=O)OCC1=CC=CN=C1 KBVSHAWWGLGKAI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
1378993 3-Pyridylmethyl carbamates ROHM & HAAS CO 23 Feb 1973 [15 March 1972 19 April 1972 18 Oct 1972] 8943/73 Heading C2C [Also in Division A5] Novel rodenticidal compounds (I) where X is NO 2 , CN, CF 3 , SR, SOR, SO 2 R or SO 2 NH 2 and R is C 1-6 alkyl, are made by interacting 3-pyridylcarbinol and the corresponding 4-X-substituted phenyl isocyanate. The following compounds are also prepared, 1 - p - tolylsulphonyl - 3 - p - cyanophenyl - urea, propyl - p - nitrophenyl - sulphide and - sulphone: propyl - p - aminophenyl - sulphone, p - sulphamoyl - phenyl carbonyl azide and bis - p - sulphamoyl-phenylurea.
[GB1378993A]
Claims (7)
1. A compound of the formula wherein X is -N02, -CN-, - CF^, -SR -SOR, -S02R, or SOg Hj wherein R being a to C& alkyl group.
2. 3-pyridylmethyl N-( 'methylthiophenyl )-carba- mate.
3. 3-pyridylmethyl N-( 4 'nitrophenyl ) -carbamate.
4. 3-pyridylmethyl N-(4 'methylsulfinylphenyl - carbamate.
5. - 3-pyridylmethyl N-(4 'methylsulfonylphenyl )- carbamate.
6. 3-pyridylmethyl N-( · ethylsulfinylphenyl )- carbamate.
7. 3-pyridylmethyl N-( '-sulfamylphenyl ) -carbamate.
8. 3-pyriciylmethy ( 4 ' -cyanopheny1) - carbamate. 9· 3-pyridylmethyl-N-(4 ' trifluoromethyl- phenyl)-c8rbomi)te .
10. A compound according to Claim 1, except for those of Claims 2 to 7 specifically named in the foregoing specification. 1L A process for the preparation of a compound as claimed in Claim 1 which comprises reacting 3-pyridyl carbinol with a substituted phenyl isocyanate of the formula : 41775/2 wherein X is as defined in Claim 1 or an obvious chemical equivalent thereof. ¾2i. A process as claimed in Claim 11 wherein the 3-pyridyl carbinol is agitated with the isocyanate for at least 2 hours to effect the reaction.
13. A process as claimed in Claim Tilor 12 carried out under substantially anhydrous conditions. 14:. A process as claimed in Claim lias applied to the preparation of a compound as claimed in any one of Claims 2 to 8.
15. A process as claimed in any of Claims 11 to 14 carried out in the presence of an inert solvent and wherein the solvent is benzene and/or chlorobenzene.
16. A process as claimed in any of Claims 11 to 15 wherein the isocyanate is dissolved in the solvent and the 3-pyridyl carbinol is then added to the solution. 1.7. A process as claimed in any of Claims Xl to 16 wherein the rodenticide product is recovered from the reaction product by filtration.
18. A process as claimed in Claim 11 substan- .1 to' 11 tially as described in any of the foregoing Examples'.
19. A compound as claimed in Claim 1 whenever prepared by a process as claimed in any of Claims 131 to 13. 41775/2 20· A rodenticidal composition containing a compound as claimed in Claim 1 as rodenticide.
21. A compositio as claimed in Claim 20 comprising a compound as claimed in Claim 1 (A) together with one or more of the followingί an edible solid diluent or carrier, another pesticide, a, £labouring agent, a preservative, binder adhesive, film forming agejat, water repliant, wax or plastics material, or surface active agent, or (B) dispersed in a fibre film yarn, fleece, sheet, fabric, rope, cord, string or other packagin^material or dispersed throughout a coating or any shaped article useful in a location where the article might be subjec to rodent attack,
22. A composition as claimed in Claim 20, i the form of a bait; containing an edible solid carrier.
23. A composition as claimed in Claim 22, containing at least 0.05 per cent by weight of rodenticide.
24. A composition as claimed in Claim 23, containing 0.5 to 1.5 per cent by weight of the rodenticide. 25· A composition as claimed in an of claims 22 to 24 wherein the edible solid diluent or carrier is one or more of the following: whole ground corn, steel cut oats, sugar, molasses, rice, vegetable oil, salt, dehydrated fruit, fish meal, tankage, wheat, soaked wheat or other cereal, sausage rusk or other animal, mineral fruit or vegetable rodent food, paraffin wax, acrylic polymer, binder or adhesive.
26. A composition as claimed i Claim 20 or 21 in the form of a tracking powder.
27. A composition as claimed in Claim 26, containing 0.75 41775/2 if any, comprising a powdered carrier or other solid ingredient as set out in Claim 21 in powder form. 28· A composition as claimed in Claim 27 wherein the powdered carrier is one or more of talc, sugar, milk powder, Indian corn meal, fish meal, corn-starch, flour and bentonite.
29. $ composition iin accordance with Claim 2 comprising the rodenticide in finely powdered form.
30. A composition as claimed in any of the claims 20 to 29 wherein the active rodenticidal ingredient is as claimed in any one of Claims 1 to 10 and 19.
31. A method of exterminating pest rodents which comprises exposing a rodenticidally effective amount of a rodenticide as claimed in any of Claims 1 to 10 and 14 or a composition as claimed in any of claims 20 to 30 in the vicinity of a population of the pest rodents in a place where it may be easily reached and ingested by the pest rodents.
32. A method as claimed i Claim 31 wherein the rodenticidal composition is a bait. 33· method as claimed in Claim 32 wherein the rodenticidal composition is exposed in a place where i may he reached by animals other than pest rodents.
34. A method as claimed in any of Claims 31 to 33 wherein the rodenticidal composition is exposed for a period of about three days and then removed. 35· A method as claimed in Claim 31 wherein the rodenticidal composition is a tracking powder and is placed in an area upon which said pest rocLents customarily step. 36· A method as claimed in any of Claims 31 to 34 wherein the rodenticidal composition is as claimed in any of Claims 41775/2
37. A method of making a rodenticidal composition which comprises forming a powder, pellets or grannies, of a compound as claimed in any of Claims 1 to 10 and 19 or mixing a compound as claimed in any of Claims 1 to 10 and 19 with one or more of the following: an edible solid diluent or carrier, another pesticide, a flavouring agent, a preservative, binder, adhesive, film forming agent, water repellant, wax or plastics material or surface active agent or dispersing a compound as claimed in any of Claims 1 to 10 and 19 in a fibre, film, yarn, fleece, sheet, fabric, rope, cord, string or other packaging material or throughout a coating or any shaped article useful in a location where the article might be subject to rodent attack.
38. A method as claimed in Claim 37 as applied to the preparation of a rodenticidal composition ae claimed in any of Claims 22 to 30.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL49933A IL49933A (en) | 1973-03-14 | 1976-06-29 | Pyridylmethyl thiocarbamates their manufacture and their use as rodenticides |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23501572A | 1972-03-15 | 1972-03-15 | |
| US245608A US3865931A (en) | 1972-03-15 | 1972-04-19 | Pyridyl phenyl carbamate rodenticides |
| US29869272A | 1972-10-18 | 1972-10-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL41775A0 IL41775A0 (en) | 1973-05-31 |
| IL41775A true IL41775A (en) | 1976-06-30 |
Family
ID=27398675
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL41775A IL41775A (en) | 1972-03-15 | 1973-03-14 | Pyridylmethyl carbamates,their preparation and their use as rodenticides |
Country Status (20)
| Country | Link |
|---|---|
| JP (1) | JPS5716987B2 (en) |
| AR (1) | AR195706A1 (en) |
| BG (2) | BG22994A3 (en) |
| CH (1) | CH567361A5 (en) |
| DK (1) | DK132888C (en) |
| EG (1) | EG10949A (en) |
| ES (2) | ES412668A1 (en) |
| FR (1) | FR2176069B1 (en) |
| GB (1) | GB1378993A (en) |
| IE (1) | IE37413B1 (en) |
| IL (1) | IL41775A (en) |
| IT (1) | IT981360B (en) |
| LU (1) | LU67215A1 (en) |
| NL (1) | NL7303588A (en) |
| OA (1) | OA04349A (en) |
| PH (1) | PH11641A (en) |
| RO (1) | RO62362A (en) |
| SE (1) | SE391179B (en) |
| TR (1) | TR18003A (en) |
| YU (1) | YU66773A (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3284461A (en) * | 1964-11-27 | 1966-11-08 | Nepera Chemical Co Inc | O-pyridylalkyl-n-alkenyl urethanes and process for their production |
-
1973
- 1973-02-12 SE SE7301959A patent/SE391179B/en unknown
- 1973-02-23 GB GB894373A patent/GB1378993A/en not_active Expired
- 1973-02-28 AR AR246849A patent/AR195706A1/en active
- 1973-03-09 PH PH14404A patent/PH11641A/en unknown
- 1973-03-11 EG EG87/73A patent/EG10949A/en active
- 1973-03-13 IT IT21549/73A patent/IT981360B/en active
- 1973-03-13 DK DK136873A patent/DK132888C/en active
- 1973-03-14 IL IL41775A patent/IL41775A/en unknown
- 1973-03-14 LU LU67215A patent/LU67215A1/xx unknown
- 1973-03-14 TR TR18003A patent/TR18003A/en unknown
- 1973-03-14 NL NL7303588A patent/NL7303588A/xx not_active Application Discontinuation
- 1973-03-14 YU YU00667/73A patent/YU66773A/en unknown
- 1973-03-14 CH CH371873A patent/CH567361A5/xx not_active IP Right Cessation
- 1973-03-14 OA OA54855A patent/OA04349A/en unknown
- 1973-03-14 FR FR7309179A patent/FR2176069B1/fr not_active Expired
- 1973-03-15 BG BG023001A patent/BG22994A3/en unknown
- 1973-03-15 RO RO197374169A patent/RO62362A/en unknown
- 1973-03-15 IE IE427/73A patent/IE37413B1/en unknown
- 1973-03-15 BG BG024497A patent/BG23002A3/en unknown
- 1973-03-15 ES ES412668A patent/ES412668A1/en not_active Expired
-
1975
- 1975-07-16 ES ES439782A patent/ES439782A1/en not_active Expired
- 1975-11-14 JP JP13710075A patent/JPS5716987B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IT981360B (en) | 1974-10-10 |
| DK132888B (en) | 1976-02-23 |
| IE37413L (en) | 1973-09-15 |
| BG23002A3 (en) | 1977-05-20 |
| AU5336873A (en) | 1974-09-19 |
| JPS5191265A (en) | 1976-08-10 |
| IE37413B1 (en) | 1977-07-20 |
| CH567361A5 (en) | 1975-10-15 |
| AR195706A1 (en) | 1973-10-31 |
| RO62362A (en) | 1977-12-15 |
| SE391179B (en) | 1977-02-07 |
| NL7303588A (en) | 1973-09-18 |
| TR18003A (en) | 1976-08-20 |
| OA04349A (en) | 1980-01-31 |
| BG22994A3 (en) | 1977-05-20 |
| ES412668A1 (en) | 1976-06-01 |
| GB1378993A (en) | 1975-01-02 |
| EG10949A (en) | 1976-09-30 |
| JPS5716987B2 (en) | 1982-04-08 |
| IL41775A0 (en) | 1973-05-31 |
| ES439782A1 (en) | 1977-07-01 |
| YU66773A (en) | 1982-06-18 |
| FR2176069B1 (en) | 1976-11-05 |
| FR2176069A1 (en) | 1973-10-26 |
| LU67215A1 (en) | 1973-09-17 |
| DK132888C (en) | 1976-07-19 |
| PH11641A (en) | 1978-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0426705B1 (en) | Terrestrial delivery compositions | |
| JPS61501027A (en) | Seed protection coating additive | |
| JP2532894B2 (en) | Microencapsulated bactericide | |
| US3740419A (en) | Pesticidal compositions | |
| US4490352A (en) | Encapsulated efficacious zinc phosphide rodenticide | |
| KR850001266B1 (en) | Methods for pesticide composition having a reduced toxity against plants | |
| IL41775A (en) | Pyridylmethyl carbamates,their preparation and their use as rodenticides | |
| US2779669A (en) | Acyl pseudourea herbicidal composition and a method for killing weeds therewith | |
| US4226883A (en) | Carbamate derivatives and method for manufacture thereof | |
| US2872367A (en) | Insecticidal compositions containing 9,9'-bifluorylidene | |
| US3663707A (en) | Molluscicidal oxime carbamates | |
| US2395440A (en) | Insecticidal and fungicidal compositions | |
| JPS5946206A (en) | Synergistic insecticide composition | |
| US3510517A (en) | 2-dimethylamino-5-chloro-benzhydrols | |
| IL44426A (en) | 3-pyridylmethyl aryl ureas their preparation and their use as rodenticides | |
| US4378239A (en) | N-Methylcarbamoyloxy benzaldehyde imine herbicide extenders | |
| US3966947A (en) | Pyridyl phenyl-carbamate rodenticide | |
| DE2226301A1 (en) | ALKYL-1- (N-SUBSTITUTED THIOCARBAMOYL) -2-BENZIMIDAZOLE CARBAMATE | |
| RU2121273C1 (en) | Mole cricket controlling composition | |
| US4662930A (en) | Herbicide compositions of extended soil life | |
| US4033972A (en) | 3-Pyridylmethyl-(N-substituted phenyl)-carbamate derivatives | |
| US3865931A (en) | Pyridyl phenyl carbamate rodenticides | |
| US4380468A (en) | Isonitriles as herbicide extenders | |
| KR810000268B1 (en) | Process for preparing 3-pyridyl methyl n-(4-s-ubstited phenyl)thio carbamate | |
| DE2141227A1 (en) | Carbamoyloximeverbindungen and their use |