IL33776A - Process for the production of o,o-dimethyl-thionophosphoric acid (o-quinoxalyl-(2))ester - Google Patents
Process for the production of o,o-dimethyl-thionophosphoric acid (o-quinoxalyl-(2))esterInfo
- Publication number
- IL33776A IL33776A IL33776A IL3377670A IL33776A IL 33776 A IL33776 A IL 33776A IL 33776 A IL33776 A IL 33776A IL 3377670 A IL3377670 A IL 3377670A IL 33776 A IL33776 A IL 33776A
- Authority
- IL
- Israel
- Prior art keywords
- quinoxalyl
- ester
- production
- process according
- signifies
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 10
- 239000002253 acid Substances 0.000 title claims description 7
- 150000002148 esters Chemical class 0.000 title claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000002798 polar solvent Substances 0.000 claims description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims 1
- 150000003513 tertiary aromatic amines Chemical group 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- -1 Heterocyclic tertiary amines Chemical class 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- FFRYUAVNPBUEIC-UHFFFAOYSA-N quinoxalin-2-ol Chemical compound C1=CC=CC2=NC(O)=CN=C21 FFRYUAVNPBUEIC-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/650952—Six-membered rings having the nitrogen atoms in the positions 1 and 4
- C07F9/650994—Six-membered rings having the nitrogen atoms in the positions 1 and 4 condensed with carbocyclic rings or carbocyclic ring systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH125069A CH518981A (de) | 1969-01-28 | 1969-01-28 | Verfahren zur Herstellung von 0.0-Dimethyl-thionophosphorsäure-(0-chinoxalyl-(2))-ester |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL33776A0 IL33776A0 (en) | 1970-03-22 |
| IL33776A true IL33776A (en) | 1973-05-31 |
Family
ID=4205990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL33776A IL33776A (en) | 1969-01-28 | 1970-01-26 | Process for the production of o,o-dimethyl-thionophosphoric acid (o-quinoxalyl-(2))ester |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3678050A (fr) |
| BE (1) | BE744956A (fr) |
| BR (1) | BR7016299D0 (fr) |
| CA (1) | CA920597A (fr) |
| CH (1) | CH518981A (fr) |
| DE (1) | DE2002892A1 (fr) |
| FR (1) | FR2034497B1 (fr) |
| GB (1) | GB1297612A (fr) |
| IE (1) | IE34303B1 (fr) |
| IL (1) | IL33776A (fr) |
| NL (1) | NL7000752A (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE788358A (fr) * | 1971-09-04 | 1973-03-05 | Bayer Ag | Nouveaux esters de quinoxalyle d'acides (thiono)- phosphoriques(phosphoniques), leur procede de preparation et leur application comme insecticides et acaricides |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1545817B1 (de) * | 1965-05-26 | 1971-04-22 | Bayer Ag | Phosphor-,Phosphon-,Thionophosphor- und Thionophosphonsaeureester des 2-Hydroxychinoxalins |
| CH478843A (de) * | 1965-09-03 | 1969-09-30 | Sandoz Ag | Verfahren zur Herstellung neuer (Thio-) Phosphorsäureester |
| FR1491135A (fr) * | 1965-09-03 | 1967-08-04 | Sandoz Sa | Nouveaux esters et amides phosphoriques et thiophosphoriques et leur procédé de préparation |
| CH488402A (de) * | 1967-02-07 | 1970-04-15 | Sandoz Ag | Stabile Schädlingsbekämpfungsmittel |
-
1969
- 1969-01-28 CH CH125069A patent/CH518981A/de not_active IP Right Cessation
-
1970
- 1970-01-06 GB GB1297612D patent/GB1297612A/en not_active Expired
- 1970-01-20 NL NL7000752A patent/NL7000752A/xx unknown
- 1970-01-20 US US4423A patent/US3678050A/en not_active Expired - Lifetime
- 1970-01-23 DE DE19702002892 patent/DE2002892A1/de active Pending
- 1970-01-26 BE BE744956D patent/BE744956A/fr unknown
- 1970-01-26 IL IL33776A patent/IL33776A/en unknown
- 1970-01-27 BR BR216299/70A patent/BR7016299D0/pt unknown
- 1970-01-27 CA CA073180A patent/CA920597A/en not_active Expired
- 1970-01-27 IE IE100/70A patent/IE34303B1/xx unknown
- 1970-01-27 FR FR707002800A patent/FR2034497B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IE34303B1 (en) | 1975-04-02 |
| CH518981A (de) | 1972-02-15 |
| DE2002892A1 (de) | 1970-07-30 |
| BE744956A (fr) | 1970-07-27 |
| NL7000752A (fr) | 1970-07-30 |
| GB1297612A (fr) | 1972-11-29 |
| BR7016299D0 (pt) | 1973-03-01 |
| IL33776A0 (en) | 1970-03-22 |
| US3678050A (en) | 1972-07-18 |
| FR2034497B1 (fr) | 1973-04-06 |
| FR2034497A1 (fr) | 1970-12-11 |
| CA920597A (en) | 1973-02-06 |
| IE34303L (en) | 1970-07-28 |
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