IL302430A - Method for stabilizing an organic material using a stabilizer mixture - Google Patents
Method for stabilizing an organic material using a stabilizer mixtureInfo
- Publication number
- IL302430A IL302430A IL302430A IL30243023A IL302430A IL 302430 A IL302430 A IL 302430A IL 302430 A IL302430 A IL 302430A IL 30243023 A IL30243023 A IL 30243023A IL 302430 A IL302430 A IL 302430A
- Authority
- IL
- Israel
- Prior art keywords
- substituted
- unsubstituted
- linear
- branched
- compound
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 170
- 239000003381 stabilizer Substances 0.000 title claims description 79
- 238000000034 method Methods 0.000 title claims description 67
- 239000011368 organic material Substances 0.000 title claims description 60
- 230000000087 stabilizing effect Effects 0.000 title claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 174
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 51
- 239000000460 chlorine Substances 0.000 claims description 51
- 229910052801 chlorine Inorganic materials 0.000 claims description 51
- 229920001577 copolymer Polymers 0.000 claims description 47
- 239000006096 absorbing agent Substances 0.000 claims description 43
- 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- 229910052757 nitrogen Inorganic materials 0.000 claims description 34
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 28
- 150000004692 metal hydroxides Chemical class 0.000 claims description 27
- 230000015556 catabolic process Effects 0.000 claims description 26
- 238000006731 degradation reaction Methods 0.000 claims description 26
- 125000003545 alkoxy group Chemical group 0.000 claims description 25
- 239000004702 low-density polyethylene Substances 0.000 claims description 22
- 229940099514 low-density polyethylene Drugs 0.000 claims description 22
- 229920001684 low density polyethylene Polymers 0.000 claims description 21
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 20
- 125000000623 heterocyclic group Chemical group 0.000 claims description 19
- 239000010410 layer Substances 0.000 claims description 17
- 125000002947 alkylene group Chemical group 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 14
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical group [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 13
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 229920001903 high density polyethylene Polymers 0.000 claims description 11
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 11
- 229960001545 hydrotalcite Drugs 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 8
- 239000004611 light stabiliser Substances 0.000 claims description 8
- 239000002362 mulch Substances 0.000 claims description 7
- 229940063583 high-density polyethylene Drugs 0.000 claims description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical group OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 5
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 claims description 4
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 4
- 239000003595 mist Substances 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
- 239000012748 slip agent Substances 0.000 claims description 3
- GJFFUPBQYDLADG-UHFFFAOYSA-K aluminum;zinc;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Zn+2].[O-]C([O-])=O GJFFUPBQYDLADG-UHFFFAOYSA-K 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims 1
- 235000013350 formula milk Nutrition 0.000 description 157
- -1 polyethylenes Polymers 0.000 description 126
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 51
- 229920000642 polymer Polymers 0.000 description 30
- 239000007983 Tris buffer Substances 0.000 description 19
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 18
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 18
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 16
- 239000005977 Ethylene Substances 0.000 description 15
- 239000012964 benzotriazole Substances 0.000 description 14
- 150000002148 esters Chemical class 0.000 description 14
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 239000004952 Polyamide Substances 0.000 description 11
- 239000003905 agrochemical Substances 0.000 description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
- 239000004743 Polypropylene Substances 0.000 description 10
- 229920002647 polyamide Polymers 0.000 description 10
- 238000009472 formulation Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 9
- 229920002857 polybutadiene Polymers 0.000 description 9
- 239000005062 Polybutadiene Substances 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 8
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- 239000005038 ethylene vinyl acetate Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 150000001993 dienes Chemical class 0.000 description 7
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229920006324 polyoxymethylene Polymers 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 6
- 239000004417 polycarbonate Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229920006380 polyphenylene oxide Polymers 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- YEWBOZCFGXOUQW-UHFFFAOYSA-N 2,6,7-trioxa-1-phosphabicyclo[2.2.2]octan-4-ylmethanol Chemical compound C1OP2OCC1(CO)CO2 YEWBOZCFGXOUQW-UHFFFAOYSA-N 0.000 description 4
- KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 4
- ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
- CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 4
- FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 150000002815 nickel Chemical class 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 235000013772 propylene glycol Nutrition 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 229940116351 sebacate Drugs 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
- 239000011732 tocopherol Substances 0.000 description 4
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 229910001868 water Inorganic materials 0.000 description 4
- ZBUFTVMOMCQOFV-UHFFFAOYSA-N 2-[4,6-bis(4-phenylphenyl)-1,3,5-triazin-2-yl]-5-(2-ethylhexoxy)phenol Chemical compound OC1=CC(OCC(CC)CCCC)=CC=C1C1=NC(C=2C=CC(=CC=2)C=2C=CC=CC=2)=NC(C=2C=CC(=CC=2)C=2C=CC=CC=2)=N1 ZBUFTVMOMCQOFV-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 229920002396 Polyurea Polymers 0.000 description 3
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 125000004956 cyclohexylene group Chemical group 0.000 description 3
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 description 3
- WTVNFKVGGUWHQC-UHFFFAOYSA-N decane-2,4-dione Chemical compound CCCCCCC(=O)CC(C)=O WTVNFKVGGUWHQC-UHFFFAOYSA-N 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical group [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229920000554 ionomer Polymers 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000006178 methyl benzyl group Chemical group 0.000 description 3
- 150000005673 monoalkenes Chemical class 0.000 description 3
- 125000002757 morpholinyl group Chemical group 0.000 description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical group [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 230000009182 swimming Effects 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 229960001295 tocopherol Drugs 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
- MQQKTNDBASEZSD-UHFFFAOYSA-N 1-(octadecyldisulfanyl)octadecane Chemical compound CCCCCCCCCCCCCCCCCCSSCCCCCCCCCCCCCCCCCC MQQKTNDBASEZSD-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 2
- BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 2
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 description 2
- IXAKLSFFPBJWBS-UHFFFAOYSA-N 2-cycloundecyl-7,7,9,9-tetramethyl-1-oxa-3,8-diazaspiro[4.5]decan-4-one Chemical compound C1C(C)(C)NC(C)(C)CC21C(=O)NC(C1CCCCCCCCCC1)O2 IXAKLSFFPBJWBS-UHFFFAOYSA-N 0.000 description 2
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 2
- ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical compound [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 2
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 2
- SAEZGDDJKSBNPT-UHFFFAOYSA-N 3-dodecyl-1-(1,2,2,6,6-pentamethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)N(C)C(C)(C)C1 SAEZGDDJKSBNPT-UHFFFAOYSA-N 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical group CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 2
- FMHKPLXYWVCLME-UHFFFAOYSA-N 4-hydroxy-valeric acid Chemical group CC(O)CCC(O)=O FMHKPLXYWVCLME-UHFFFAOYSA-N 0.000 description 2
- IPRLZACALWPEGS-UHFFFAOYSA-N 7,7,9,9-tetramethyl-2-undecyl-1-oxa-3,8-diazaspiro[4.5]decan-4-one Chemical compound O1C(CCCCCCCCCCC)NC(=O)C11CC(C)(C)NC(C)(C)C1 IPRLZACALWPEGS-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- FUCCNPWRCSWXBI-UHFFFAOYSA-N C(CCCCCCC)ON1C(C(CCC1(C)C)C(C(C(=O)O)C1C(N(C(CC1)(C)C)OCCCCCCCC)(C)C)C(=O)O)(C)C Chemical compound C(CCCCCCC)ON1C(C(CCC1(C)C)C(C(C(=O)O)C1C(N(C(CC1)(C)C)OCCCCCCCC)(C)C)C(=O)O)(C)C FUCCNPWRCSWXBI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical group OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 2
- 229920007019 PC/ABS Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 229920001585 atactic polymer Polymers 0.000 description 2
- 230000000386 athletic effect Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 125000006309 butyl amino group Chemical group 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 description 2
- 230000007775 late Effects 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001179 medium density polyethylene Polymers 0.000 description 2
- 239000004701 medium-density polyethylene Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- UJRDRFZCRQNLJM-UHFFFAOYSA-N methyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=CC=CC3=N2)=C1O UJRDRFZCRQNLJM-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 2
- GXELTROTKVKZBQ-UHFFFAOYSA-N n,n-dibenzylhydroxylamine Chemical compound C=1C=CC=CC=1CN(O)CC1=CC=CC=C1 GXELTROTKVKZBQ-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- UONLDZHKYCFZRW-UHFFFAOYSA-N n-[6-[formyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]hexyl]-n-(2,2,6,6-tetramethylpiperidin-4-yl)formamide Chemical compound C1C(C)(C)NC(C)(C)CC1N(C=O)CCCCCCN(C=O)C1CC(C)(C)NC(C)(C)C1 UONLDZHKYCFZRW-UHFFFAOYSA-N 0.000 description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 description 2
- 229920002961 polybutylene succinate Polymers 0.000 description 2
- 239000004631 polybutylene succinate Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229940068886 polyethylene glycol 300 Drugs 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000005056 polyisocyanate Substances 0.000 description 2
- 229920001228 polyisocyanate Polymers 0.000 description 2
- 239000004626 polylactic acid Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
- 239000001384 succinic acid Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 2
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000003672 ureas Chemical class 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 2
- KJYSXRBJOSZLEL-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 KJYSXRBJOSZLEL-UHFFFAOYSA-N 0.000 description 1
- HQEPZWYPQQKFLU-UHFFFAOYSA-N (2,6-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC(O)=C1C(=O)C1=CC=CC=C1 HQEPZWYPQQKFLU-UHFFFAOYSA-N 0.000 description 1
- ATLWFAZCZPSXII-UHFFFAOYSA-N (2-octylphenyl) 2-hydroxybenzoate Chemical compound CCCCCCCCC1=CC=CC=C1OC(=O)C1=CC=CC=C1O ATLWFAZCZPSXII-UHFFFAOYSA-N 0.000 description 1
- JJYUJOJVFRXHAE-UHFFFAOYSA-N (3,5,5-trimethyl-6-oxomorpholin-3-yl)methyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC1(C)COC(=O)C(C)(C)N1 JJYUJOJVFRXHAE-UHFFFAOYSA-N 0.000 description 1
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 1
- JJTUDXZGHPGLLC-ZXZARUISSA-N (3r,6s)-3,6-dimethyl-1,4-dioxane-2,5-dione Chemical compound C[C@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-ZXZARUISSA-N 0.000 description 1
- GOZHNJTXLALKRL-UHFFFAOYSA-N (5-benzoyl-2,4-dihydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1C(=O)C1=CC=CC=C1 GOZHNJTXLALKRL-UHFFFAOYSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- UOORRWUZONOOLO-OWOJBTEDSA-N (E)-1,3-dichloropropene Chemical compound ClC\C=C\Cl UOORRWUZONOOLO-OWOJBTEDSA-N 0.000 description 1
- MPTISGUJJWJZRR-UHFFFAOYSA-N 1,1-bis[2,4-bis(2-phenylpropan-2-yl)phenyl]-2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound C(C)(C)(C1=CC=CC=C1)C1=C(C=CC(=C1)C(C)(C)C1=CC=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C1=CC=CC=C1)C(C)(C)C1=CC=CC=C1 MPTISGUJJWJZRR-UHFFFAOYSA-N 0.000 description 1
- PUZXLFQBRGGQEY-UHFFFAOYSA-N 1,3-dioxonane-4,9-dione Chemical compound O=C1CCCCC(=O)OCO1 PUZXLFQBRGGQEY-UHFFFAOYSA-N 0.000 description 1
- BUGAMLAPDQMYNZ-UHFFFAOYSA-N 1-(2,4,4-trimethylpentan-2-yl)-10h-phenothiazine Chemical class S1C2=CC=CC=C2NC2=C1C=CC=C2C(C)(C)CC(C)(C)C BUGAMLAPDQMYNZ-UHFFFAOYSA-N 0.000 description 1
- SQZCAOHYQSOZCE-UHFFFAOYSA-N 1-(diaminomethylidene)-2-(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N=C(N)N=C(N)N SQZCAOHYQSOZCE-UHFFFAOYSA-N 0.000 description 1
- XIRPMPKSZHNMST-UHFFFAOYSA-N 1-ethenyl-2-phenylbenzene Chemical class C=CC1=CC=CC=C1C1=CC=CC=C1 XIRPMPKSZHNMST-UHFFFAOYSA-N 0.000 description 1
- UVHXEHGUEKARKZ-UHFFFAOYSA-N 1-ethenylanthracene Chemical class C1=CC=C2C=C3C(C=C)=CC=CC3=CC2=C1 UVHXEHGUEKARKZ-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- BBRHQNMMUUMVDE-UHFFFAOYSA-N 1-n,2-n-diphenylpropane-1,2-diamine Chemical compound C=1C=CC=CC=1NC(C)CNC1=CC=CC=C1 BBRHQNMMUUMVDE-UHFFFAOYSA-N 0.000 description 1
- ZJNLYGOUHDJHMG-UHFFFAOYSA-N 1-n,4-n-bis(5-methylhexan-2-yl)benzene-1,4-diamine Chemical compound CC(C)CCC(C)NC1=CC=C(NC(C)CCC(C)C)C=C1 ZJNLYGOUHDJHMG-UHFFFAOYSA-N 0.000 description 1
- PWNBRRGFUVBTQG-UHFFFAOYSA-N 1-n,4-n-di(propan-2-yl)benzene-1,4-diamine Chemical compound CC(C)NC1=CC=C(NC(C)C)C=C1 PWNBRRGFUVBTQG-UHFFFAOYSA-N 0.000 description 1
- AIMXDOGPMWDCDF-UHFFFAOYSA-N 1-n,4-n-dicyclohexylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1CCCCC1 AIMXDOGPMWDCDF-UHFFFAOYSA-N 0.000 description 1
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- GFVSLJXVNAYUJE-UHFFFAOYSA-N 10-prop-2-enylphenothiazine Chemical compound C1=CC=C2N(CC=C)C3=CC=CC=C3SC2=C1 GFVSLJXVNAYUJE-UHFFFAOYSA-N 0.000 description 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- CDWOTAMGTNNLHY-UHFFFAOYSA-N 19-(3-tert-butyl-4-hydroxy-5-methylphenyl)heptatriacontan-19-ylphosphonic acid Chemical compound CCCCCCCCCCCCCCCCCCC(CCCCCCCCCCCCCCCCCC)(P(O)(O)=O)C1=CC(C)=C(O)C(C(C)(C)C)=C1 CDWOTAMGTNNLHY-UHFFFAOYSA-N 0.000 description 1
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 1
- BWJKLDGAAPQXGO-UHFFFAOYSA-N 2,2,6,6-tetramethyl-4-octadecoxypiperidine Chemical compound CCCCCCCCCCCCCCCCCCOC1CC(C)(C)NC(C)(C)C1 BWJKLDGAAPQXGO-UHFFFAOYSA-N 0.000 description 1
- FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 description 1
- UUAIOYWXCDLHKT-UHFFFAOYSA-N 2,4,6-tricyclohexylphenol Chemical compound OC1=C(C2CCCCC2)C=C(C2CCCCC2)C=C1C1CCCCC1 UUAIOYWXCDLHKT-UHFFFAOYSA-N 0.000 description 1
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 description 1
- LXWZXEJDKYWBOW-UHFFFAOYSA-N 2,4-ditert-butyl-6-[(3,5-ditert-butyl-2-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)C)C(C)(C)C)O)=C1O LXWZXEJDKYWBOW-UHFFFAOYSA-N 0.000 description 1
- CZNRFEXEPBITDS-UHFFFAOYSA-N 2,5-bis(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=C(C(C)(C)CC)C=C1O CZNRFEXEPBITDS-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- FLLRQABPKFCXSO-UHFFFAOYSA-N 2,5-ditert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C=C1C(C)(C)C FLLRQABPKFCXSO-UHFFFAOYSA-N 0.000 description 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 description 1
- SCXYLTWTWUGEAA-UHFFFAOYSA-N 2,6-ditert-butyl-4-(methoxymethyl)phenol Chemical compound COCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SCXYLTWTWUGEAA-UHFFFAOYSA-N 0.000 description 1
- UDFARPRXWMDFQU-UHFFFAOYSA-N 2,6-ditert-butyl-4-[(3,5-ditert-butyl-4-hydroxyphenyl)methylsulfanylmethyl]phenol Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CSCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 UDFARPRXWMDFQU-UHFFFAOYSA-N 0.000 description 1
- LBOGPIWNHXHYHN-UHFFFAOYSA-N 2-(2-hydroxy-5-octylphenyl)sulfanyl-4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C(SC=2C(=CC=C(CCCCCCCC)C=2)O)=C1 LBOGPIWNHXHYHN-UHFFFAOYSA-N 0.000 description 1
- OLFNXLXEGXRUOI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-phenylpropan-2-yl)phenol Chemical compound C=1C(N2N=C3C=CC=CC3=N2)=C(O)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 OLFNXLXEGXRUOI-UHFFFAOYSA-N 0.000 description 1
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 1
- ITLDHFORLZTRJI-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-5-octoxyphenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1N1N=C2C=CC=CC2=N1 ITLDHFORLZTRJI-UHFFFAOYSA-N 0.000 description 1
- VQMHSKWEJGIXGA-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(N2N=C3C=CC=CC3=N2)=C1O VQMHSKWEJGIXGA-UHFFFAOYSA-N 0.000 description 1
- XQESJWNDTICJHW-UHFFFAOYSA-N 2-[(2-hydroxy-5-methyl-3-nonylphenyl)methyl]-4-methyl-6-nonylphenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CC=2C(=C(CCCCCCCCC)C=C(C)C=2)O)=C1O XQESJWNDTICJHW-UHFFFAOYSA-N 0.000 description 1
- UTNMPUFESIRPQP-UHFFFAOYSA-N 2-[(4-aminophenyl)methyl]aniline Chemical compound C1=CC(N)=CC=C1CC1=CC=CC=C1N UTNMPUFESIRPQP-UHFFFAOYSA-N 0.000 description 1
- YQQAAUCBTNZUQQ-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)butyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(CCC)C1=CC(C)=CC(C)=C1O YQQAAUCBTNZUQQ-UHFFFAOYSA-N 0.000 description 1
- BVNPSIYFJSSEER-UHFFFAOYSA-H 2-[2-(1,3,2-benzodioxastibol-2-yloxy)phenoxy]-1,3,2-benzodioxastibole Chemical compound O([Sb]1Oc2ccccc2O1)c1ccccc1O[Sb]1Oc2ccccc2O1 BVNPSIYFJSSEER-UHFFFAOYSA-H 0.000 description 1
- DBYBHKQEHCYBQV-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-dodecoxyphenol Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 DBYBHKQEHCYBQV-UHFFFAOYSA-N 0.000 description 1
- PIGBIZGGEUNVCV-UHFFFAOYSA-N 2-[4,6-bis[4-(3-butoxy-2-hydroxypropoxy)-2-hydroxyphenyl]-1,3,5-triazin-2-yl]-5-(3-butoxy-2-hydroxypropoxy)phenol Chemical compound OC1=CC(OCC(O)COCCCC)=CC=C1C1=NC(C=2C(=CC(OCC(O)COCCCC)=CC=2)O)=NC(C=2C(=CC(OCC(O)COCCCC)=CC=2)O)=N1 PIGBIZGGEUNVCV-UHFFFAOYSA-N 0.000 description 1
- RDDIIAYGQFICIL-UHFFFAOYSA-N 2-[4-(5,7-ditert-butyl-2-oxo-3h-1-benzofuran-3-yl)phenoxy]ethyl acetate Chemical compound C1=CC(OCCOC(=O)C)=CC=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O RDDIIAYGQFICIL-UHFFFAOYSA-N 0.000 description 1
- YJWCUAHFSOAUKV-UHFFFAOYSA-N 2-[4-(5,7-ditert-butyl-2-oxo-3h-1-benzofuran-3-yl)phenoxy]ethyl octadecanoate Chemical compound C1=CC(OCCOC(=O)CCCCCCCCCCCCCCCCC)=CC=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O YJWCUAHFSOAUKV-UHFFFAOYSA-N 0.000 description 1
- OXWDLAHVJDUQJM-UHFFFAOYSA-N 2-[[2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylamino]-2-oxoacetyl]amino]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCNC(=O)C(=O)NCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OXWDLAHVJDUQJM-UHFFFAOYSA-N 0.000 description 1
- HHPDFYDITNAMAM-UHFFFAOYSA-N 2-[cyclohexyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)C1CCCCC1 HHPDFYDITNAMAM-UHFFFAOYSA-N 0.000 description 1
- LUPQXHNQUVRJFK-UHFFFAOYSA-N 2-butyl-2-[(3,5-ditert-butyl-2-hydroxyphenyl)-bis(1,2,2,6,6-pentamethylpiperidin-3-yl)methyl]propanedioic acid Chemical compound CCCCC(C(=O)O)(C(=O)O)C(C1CCC(N(C1(C)C)C)(C)C)(C2CCC(N(C2(C)C)C)(C)C)C3=CC(=CC(=C3O)C(C)(C)C)C(C)(C)C LUPQXHNQUVRJFK-UHFFFAOYSA-N 0.000 description 1
- DOTYDHBOKPPXRB-UHFFFAOYSA-N 2-butyl-2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]propanedioic acid Chemical compound CCCCC(C(O)=O)(C(O)=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 DOTYDHBOKPPXRB-UHFFFAOYSA-N 0.000 description 1
- AKNMPWVTPUHKCG-UHFFFAOYSA-N 2-cyclohexyl-6-[(3-cyclohexyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound OC=1C(C2CCCCC2)=CC(C)=CC=1CC(C=1O)=CC(C)=CC=1C1CCCCC1 AKNMPWVTPUHKCG-UHFFFAOYSA-N 0.000 description 1
- PJISLFCKHOHLLP-UHFFFAOYSA-N 2-diethoxyphosphorylsulfanyl-n,n-diethylethanamine Chemical compound CCOP(=O)(OCC)SCCN(CC)CC PJISLFCKHOHLLP-UHFFFAOYSA-N 0.000 description 1
- NCWTZPKMFNRUAK-UHFFFAOYSA-N 2-ethyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(CC)=C(O)C(CSCCCCCCCC)=C1 NCWTZPKMFNRUAK-UHFFFAOYSA-N 0.000 description 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- AWEVLIFGIMIQHY-UHFFFAOYSA-N 2-ethylhexyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCC(CC)CCCC)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O AWEVLIFGIMIQHY-UHFFFAOYSA-N 0.000 description 1
- OMCYEZUIYGPHDJ-UHFFFAOYSA-N 2-hydroxy-N-[(2-hydroxyphenyl)methylideneamino]benzamide Chemical compound OC1=CC=CC=C1C=NNC(=O)C1=CC=CC=C1O OMCYEZUIYGPHDJ-UHFFFAOYSA-N 0.000 description 1
- UORSDGBOJHYJLV-UHFFFAOYSA-N 2-hydroxy-n'-(2-hydroxybenzoyl)benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)C1=CC=CC=C1O UORSDGBOJHYJLV-UHFFFAOYSA-N 0.000 description 1
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- ZYJXQDCMXTWHIV-UHFFFAOYSA-N 2-tert-butyl-4,6-bis(octylsulfanylmethyl)phenol Chemical compound CCCCCCCCSCC1=CC(CSCCCCCCCC)=C(O)C(C(C)(C)C)=C1 ZYJXQDCMXTWHIV-UHFFFAOYSA-N 0.000 description 1
- BCHSGIGAOYQMPC-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)-3-dodecylsulfanylbutyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CC(C)SCCCCCCCCCCCC)C1=CC(C(C)(C)C)=C(O)C=C1C BCHSGIGAOYQMPC-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 description 1
- GPNYZBKIGXGYNU-UHFFFAOYSA-N 2-tert-butyl-6-[(3-tert-butyl-5-ethyl-2-hydroxyphenyl)methyl]-4-ethylphenol Chemical compound CC(C)(C)C1=CC(CC)=CC(CC=2C(=C(C=C(CC)C=2)C(C)(C)C)O)=C1O GPNYZBKIGXGYNU-UHFFFAOYSA-N 0.000 description 1
- UHLYPUYAVHSKBN-UHFFFAOYSA-N 2-tert-butyl-6-[1-[3-tert-butyl-2-hydroxy-5-(2-methylpropyl)phenyl]ethyl]-4-(2-methylpropyl)phenol Chemical compound CC(C)(C)C1=CC(CC(C)C)=CC(C(C)C=2C(=C(C=C(CC(C)C)C=2)C(C)(C)C)O)=C1O UHLYPUYAVHSKBN-UHFFFAOYSA-N 0.000 description 1
- WMJBVALTYVXGHW-UHFFFAOYSA-N 3,3-diphenylprop-2-enoic acid Chemical compound C=1C=CC=CC=1C(=CC(=O)O)C1=CC=CC=C1 WMJBVALTYVXGHW-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- DBHUTHZPCWZNRW-UHFFFAOYSA-N 3-(3,5-dicyclohexyl-4-hydroxyphenyl)propanoic acid Chemical compound OC=1C(C2CCCCC2)=CC(CCC(=O)O)=CC=1C1CCCCC1 DBHUTHZPCWZNRW-UHFFFAOYSA-N 0.000 description 1
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 description 1
- KJEKRODBOPOEGG-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n-[3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoylamino]propyl]propanamide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NCCCNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 KJEKRODBOPOEGG-UHFFFAOYSA-N 0.000 description 1
- FLZYQMOKBVFXJS-UHFFFAOYSA-N 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoic acid Chemical compound CC1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O FLZYQMOKBVFXJS-UHFFFAOYSA-N 0.000 description 1
- YCGKJPVUGMBDDS-UHFFFAOYSA-N 3-(6-azabicyclo[3.1.1]hepta-1(7),2,4-triene-6-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2C=3C=C2C=CC=3)=C1 YCGKJPVUGMBDDS-UHFFFAOYSA-N 0.000 description 1
- KNGCBZMIRMAGJT-UHFFFAOYSA-N 3-[2-acetyl-5-(6-methylheptyl)phenyl]-5-(6-methylheptyl)-3h-1-benzofuran-2-one Chemical compound C12=CC(CCCCCC(C)C)=CC=C2OC(=O)C1C1=CC(CCCCCC(C)C)=CC=C1C(C)=O KNGCBZMIRMAGJT-UHFFFAOYSA-N 0.000 description 1
- FBIXXCXCZOZFCO-UHFFFAOYSA-N 3-dodecyl-1-(2,2,6,6-tetramethylpiperidin-4-yl)pyrrolidine-2,5-dione Chemical compound O=C1C(CCCCCCCCCCCC)CC(=O)N1C1CC(C)(C)NC(C)(C)C1 FBIXXCXCZOZFCO-UHFFFAOYSA-N 0.000 description 1
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
- GQBHYWDCHSZDQU-UHFFFAOYSA-N 4-(2,4,4-trimethylpentan-2-yl)-n-[4-(2,4,4-trimethylpentan-2-yl)phenyl]aniline Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=C(C(C)(C)CC(C)(C)C)C=C1 GQBHYWDCHSZDQU-UHFFFAOYSA-N 0.000 description 1
- VAMBUGIXOVLJEA-UHFFFAOYSA-N 4-(butylamino)phenol Chemical compound CCCCNC1=CC=C(O)C=C1 VAMBUGIXOVLJEA-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- PRWJPWSKLXYEPD-UHFFFAOYSA-N 4-[4,4-bis(5-tert-butyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-tert-butyl-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C=1)C(C)(C)C)C)C1=CC(C(C)(C)C)=C(O)C=C1C PRWJPWSKLXYEPD-UHFFFAOYSA-N 0.000 description 1
- QVXGXGJJEDTQSU-UHFFFAOYSA-N 4-[4-hydroxy-2,5-di(pentan-2-yl)phenyl]sulfanyl-2,5-di(pentan-2-yl)phenol Chemical compound C1=C(O)C(C(C)CCC)=CC(SC=2C(=CC(O)=C(C(C)CCC)C=2)C(C)CCC)=C1C(C)CCC QVXGXGJJEDTQSU-UHFFFAOYSA-N 0.000 description 1
- WTWGHNZAQVTLSQ-UHFFFAOYSA-N 4-butyl-2,6-ditert-butylphenol Chemical compound CCCCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WTWGHNZAQVTLSQ-UHFFFAOYSA-N 0.000 description 1
- OVARTXYXUGDZHU-UHFFFAOYSA-N 4-hydroxy-n-phenyldodecanamide Chemical compound CCCCCCCCC(O)CCC(=O)NC1=CC=CC=C1 OVARTXYXUGDZHU-UHFFFAOYSA-N 0.000 description 1
- SJZRECIVHVDYJC-UHFFFAOYSA-N 4-hydroxybutyric acid Chemical group OCCCC(O)=O SJZRECIVHVDYJC-UHFFFAOYSA-N 0.000 description 1
- 229940006015 4-hydroxybutyric acid Drugs 0.000 description 1
- VCOONNWIINSFBA-UHFFFAOYSA-N 4-methoxy-n-(4-methoxyphenyl)aniline Chemical compound C1=CC(OC)=CC=C1NC1=CC=C(OC)C=C1 VCOONNWIINSFBA-UHFFFAOYSA-N 0.000 description 1
- UXMKUNDWNZNECH-UHFFFAOYSA-N 4-methyl-2,6-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC(C)=CC(CCCCCCCCC)=C1O UXMKUNDWNZNECH-UHFFFAOYSA-N 0.000 description 1
- LZAIWKMQABZIDI-UHFFFAOYSA-N 4-methyl-2,6-dioctadecylphenol Chemical compound CCCCCCCCCCCCCCCCCCC1=CC(C)=CC(CCCCCCCCCCCCCCCCCC)=C1O LZAIWKMQABZIDI-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- JQTYAZKTBXWQOM-UHFFFAOYSA-N 4-n-octan-2-yl-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CCCCCC)=CC=C1NC1=CC=CC=C1 JQTYAZKTBXWQOM-UHFFFAOYSA-N 0.000 description 1
- JJHKARPEMHIIQC-UHFFFAOYSA-N 4-octadecoxy-2,6-diphenylphenol Chemical compound C=1C(OCCCCCCCCCCCCCCCCCC)=CC(C=2C=CC=CC=2)=C(O)C=1C1=CC=CC=C1 JJHKARPEMHIIQC-UHFFFAOYSA-N 0.000 description 1
- BVNWQSXXRMNYKH-UHFFFAOYSA-N 4-phenyl-2h-benzotriazole Chemical compound C1=CC=CC=C1C1=CC=CC2=C1NN=N2 BVNWQSXXRMNYKH-UHFFFAOYSA-N 0.000 description 1
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
- JJTUDXZGHPGLLC-IMJSIDKUSA-N 4511-42-6 Chemical compound C[C@@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-IMJSIDKUSA-N 0.000 description 1
- JFYKXFLSIZYLRY-UHFFFAOYSA-N 5,7-ditert-butyl-3-(2,3-dimethylphenyl)-3h-1-benzofuran-2-one Chemical compound CC1=CC=CC(C2C3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)OC2=O)=C1C JFYKXFLSIZYLRY-UHFFFAOYSA-N 0.000 description 1
- NPZINZPBUZRJNR-UHFFFAOYSA-N 5,7-ditert-butyl-3-(3,4-dimethylphenyl)-1-benzofuran Chemical compound C1=C(C)C(C)=CC=C1C1=COC2=C(C(C)(C)C)C=C(C(C)(C)C)C=C12 NPZINZPBUZRJNR-UHFFFAOYSA-N 0.000 description 1
- REYLJCJBTWQEBC-UHFFFAOYSA-N 5,7-ditert-butyl-3-[4-(2-hydroxyethoxy)phenyl]-3h-1-benzofuran-2-one Chemical compound O=C1OC=2C(C(C)(C)C)=CC(C(C)(C)C)=CC=2C1C1=CC=C(OCCO)C=C1 REYLJCJBTWQEBC-UHFFFAOYSA-N 0.000 description 1
- PHOJOSOUIAQEDH-UHFFFAOYSA-N 5-hydroxypentanoic acid Chemical group OCCCCC(O)=O PHOJOSOUIAQEDH-UHFFFAOYSA-N 0.000 description 1
- IWHLYPDWHHPVAA-UHFFFAOYSA-N 6-hydroxyhexanoic acid Chemical group OCCCCCC(O)=O IWHLYPDWHHPVAA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- OGBVRMYSNSKIEF-UHFFFAOYSA-N Benzylphosphonic acid Chemical class OP(O)(=O)CC1=CC=CC=C1 OGBVRMYSNSKIEF-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- DXJKKURIVRCYGB-UHFFFAOYSA-N C(C)(C)(C)C1=C(C(=CC(=C1)C(C)(C)C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C)C(C)(C)C)C(C)(C)C Chemical compound C(C)(C)(C)C1=C(C(=CC(=C1)C(C)(C)C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C)C(C)(C)C)C(C)(C)C DXJKKURIVRCYGB-UHFFFAOYSA-N 0.000 description 1
- ZRZFCHCIMYNMST-UHFFFAOYSA-L C=1([O-])C([O-])=CC=CC1.[Zn+2] Chemical compound C=1([O-])C([O-])=CC=CC1.[Zn+2] ZRZFCHCIMYNMST-UHFFFAOYSA-L 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 239000005745 Captan Substances 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 229930182843 D-Lactic acid Natural products 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical class [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 241001024304 Mino Species 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical compound NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N N-undecane Natural products CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
- 229920006778 PC/PBT Polymers 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 229920002347 Polypropylene succinate Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000005820 Prochloraz Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000005938 Teflubenzuron Substances 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- ZSFWKZUHCKWKGK-UHFFFAOYSA-N [4-(5,7-ditert-butyl-2-oxo-3h-1-benzofuran-3-yl)-2,6-dimethylphenyl] 2,2-dimethylpropanoate Chemical compound CC1=C(OC(=O)C(C)(C)C)C(C)=CC(C2C3=C(C(=CC(=C3)C(C)(C)C)C(C)(C)C)OC2=O)=C1 ZSFWKZUHCKWKGK-UHFFFAOYSA-N 0.000 description 1
- FXOMJIWKCOCWOU-UHFFFAOYSA-N [4-(5,7-ditert-butyl-2-oxo-3h-1-benzofuran-3-yl)-2,6-dimethylphenyl] acetate Chemical compound C1=C(C)C(OC(=O)C)=C(C)C=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O FXOMJIWKCOCWOU-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- BEIOEBMXPVYLRY-UHFFFAOYSA-N [4-[4-bis(2,4-ditert-butylphenoxy)phosphanylphenyl]phenyl]-bis(2,4-ditert-butylphenoxy)phosphane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(C=1C=CC(=CC=1)C=1C=CC(=CC=1)P(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C BEIOEBMXPVYLRY-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- BLMJOHVPLFFDMH-UHFFFAOYSA-I aluminum;zinc;pentahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[Al+3].[Zn+2] BLMJOHVPLFFDMH-UHFFFAOYSA-I 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001559 benzoic acids Chemical class 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- XTCXSNIRIUQZLY-UHFFFAOYSA-N benzyl 2-sulfanylacetate Chemical compound SCC(=O)OCC1=CC=CC=C1 XTCXSNIRIUQZLY-UHFFFAOYSA-N 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- SFFFIHNOEGSAIH-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene;ethene Chemical compound C=C.C1C2CCC1C=C2 SFFFIHNOEGSAIH-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- OSIVCXJNIBEGCL-UHFFFAOYSA-N bis(2,2,6,6-tetramethyl-1-octoxypiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(OCCCCCCCC)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(OCCCCCCCC)C(C)(C)C1 OSIVCXJNIBEGCL-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- ZEFSGHVBJCEKAZ-UHFFFAOYSA-N bis(2,4-ditert-butyl-6-methylphenyl) ethyl phosphite Chemical compound CC=1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1OP(OCC)OC1=C(C)C=C(C(C)(C)C)C=C1C(C)(C)C ZEFSGHVBJCEKAZ-UHFFFAOYSA-N 0.000 description 1
- VZRMYAIVHSRUQY-UHFFFAOYSA-N bis(2,4-ditert-butyl-6-methylphenyl) methyl phosphite Chemical compound CC=1C=C(C(C)(C)C)C=C(C(C)(C)C)C=1OP(OC)OC1=C(C)C=C(C(C)(C)C)C=C1C(C)(C)C VZRMYAIVHSRUQY-UHFFFAOYSA-N 0.000 description 1
- OJZRGIRJHDINMJ-UHFFFAOYSA-N bis(3,5-ditert-butyl-4-hydroxyphenyl) hexanedioate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(OC(=O)CCCCC(=O)OC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 OJZRGIRJHDINMJ-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical class CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229940117949 captan Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 125000003901 ceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000003869 coulometry Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000006547 cyclononyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 229940022769 d- lactic acid Drugs 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 125000006182 dimethyl benzyl group Chemical group 0.000 description 1
- KQEPQKRGTBAQRR-UHFFFAOYSA-N dioctadecyl 2-[(3-tert-butyl-4-hydroxy-5-methylphenyl)methyl]propanedioate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C(=O)OCCCCCCCCCCCCCCCCCC)CC1=CC(C)=C(O)C(C(C)(C)C)=C1 KQEPQKRGTBAQRR-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000002828 fuel tank Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920005555 halobutyl Polymers 0.000 description 1
- 125000004968 halobutyl group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000755 henicosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002818 heptacosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- NZYMWGXNIUZYRC-UHFFFAOYSA-N hexadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NZYMWGXNIUZYRC-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical class C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 125000002463 lignoceryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- OBQVOBQZMOXRAL-UHFFFAOYSA-L magnesium;docosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O OBQVOBQZMOXRAL-UHFFFAOYSA-L 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- VRBLLGLKTUGCSG-UHFFFAOYSA-N methyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O VRBLLGLKTUGCSG-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000002819 montanyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 125000001802 myricyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZJFPXDGPJMHQMW-UHFFFAOYSA-N n,n'-bis[3-(dimethylamino)propyl]oxamide Chemical compound CN(C)CCCNC(=O)C(=O)NCCCN(C)C ZJFPXDGPJMHQMW-UHFFFAOYSA-N 0.000 description 1
- FSWDLYNGJBGFJH-UHFFFAOYSA-N n,n'-di-2-butyl-1,4-phenylenediamine Chemical compound CCC(C)NC1=CC=C(NC(C)CC)C=C1 FSWDLYNGJBGFJH-UHFFFAOYSA-N 0.000 description 1
- DDLNUIWJEDITCB-UHFFFAOYSA-N n,n-di(tetradecyl)hydroxylamine Chemical compound CCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCC DDLNUIWJEDITCB-UHFFFAOYSA-N 0.000 description 1
- DHXOCDLHWYUUAG-UHFFFAOYSA-N n,n-didodecylhydroxylamine Chemical compound CCCCCCCCCCCCN(O)CCCCCCCCCCCC DHXOCDLHWYUUAG-UHFFFAOYSA-N 0.000 description 1
- WQAJFRSBFZAUPB-UHFFFAOYSA-N n,n-dioctylhydroxylamine Chemical compound CCCCCCCCN(O)CCCCCCCC WQAJFRSBFZAUPB-UHFFFAOYSA-N 0.000 description 1
- KESXDDATSRRGAH-UHFFFAOYSA-N n-(4-hydroxyphenyl)butanamide Chemical compound CCCC(=O)NC1=CC=C(O)C=C1 KESXDDATSRRGAH-UHFFFAOYSA-N 0.000 description 1
- JVKWTDRHWOSRFT-UHFFFAOYSA-N n-(4-hydroxyphenyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)NC1=CC=C(O)C=C1 JVKWTDRHWOSRFT-UHFFFAOYSA-N 0.000 description 1
- VQLURHRLTDWRLX-UHFFFAOYSA-N n-(4-hydroxyphenyl)nonanamide Chemical compound CCCCCCCCC(=O)NC1=CC=C(O)C=C1 VQLURHRLTDWRLX-UHFFFAOYSA-N 0.000 description 1
- YASWBJXTHOXPGK-UHFFFAOYSA-N n-(4-hydroxyphenyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NC1=CC=C(O)C=C1 YASWBJXTHOXPGK-UHFFFAOYSA-N 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- ZLUHLPGJUZHFAR-UHFFFAOYSA-N n-[4-(2,4,4-trimethylpentan-2-yl)phenyl]naphthalen-1-amine Chemical compound C1=CC(C(C)(C)CC(C)(C)C)=CC=C1NC1=CC=CC2=CC=CC=C12 ZLUHLPGJUZHFAR-UHFFFAOYSA-N 0.000 description 1
- UBINNYMQZVKNFF-UHFFFAOYSA-N n-benzyl-1-phenylmethanimine oxide Chemical compound C=1C=CC=CC=1C=[N+]([O-])CC1=CC=CC=C1 UBINNYMQZVKNFF-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FDAKZQLBIFPGSV-UHFFFAOYSA-N n-butyl-2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CCCCNC1CC(C)(C)NC(C)(C)C1 FDAKZQLBIFPGSV-UHFFFAOYSA-N 0.000 description 1
- BYYFPVDBAHOLDX-UHFFFAOYSA-N n-dodecyl-n-phenylaniline Chemical class C=1C=CC=CC=1N(CCCCCCCCCCCC)C1=CC=CC=C1 BYYFPVDBAHOLDX-UHFFFAOYSA-N 0.000 description 1
- GBMIPYGHTZRCRH-UHFFFAOYSA-N n-ethylethanimine oxide Chemical compound CC[N+]([O-])=CC GBMIPYGHTZRCRH-UHFFFAOYSA-N 0.000 description 1
- ZRPOKHXBOZQSOX-UHFFFAOYSA-N n-heptadecyl-n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCCC ZRPOKHXBOZQSOX-UHFFFAOYSA-N 0.000 description 1
- DBCWENWKZARTGU-UHFFFAOYSA-N n-heptadecyloctadecan-1-imine oxide Chemical compound CCCCCCCCCCCCCCCCCC=[N+]([O-])CCCCCCCCCCCCCCCCC DBCWENWKZARTGU-UHFFFAOYSA-N 0.000 description 1
- WGCBLWIBXXQTAW-UHFFFAOYSA-N n-hexadecyl-n-octadecylhydroxylamine Chemical compound CCCCCCCCCCCCCCCCCCN(O)CCCCCCCCCCCCCCCC WGCBLWIBXXQTAW-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- LVZUNTGFCXNQAF-UHFFFAOYSA-N n-nonyl-n-phenylaniline Chemical class C=1C=CC=CC=1N(CCCCCCCCC)C1=CC=CC=C1 LVZUNTGFCXNQAF-UHFFFAOYSA-N 0.000 description 1
- QXJGVICBAANVMZ-UHFFFAOYSA-N n-octyloctan-1-imine oxide Chemical compound CCCCCCCC[N+]([O-])=CCCCCCCC QXJGVICBAANVMZ-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- CVVFFUKULYKOJR-UHFFFAOYSA-N n-phenyl-4-propan-2-yloxyaniline Chemical compound C1=CC(OC(C)C)=CC=C1NC1=CC=CC=C1 CVVFFUKULYKOJR-UHFFFAOYSA-N 0.000 description 1
- NYLGUNUDTDWXQE-UHFFFAOYSA-N n-phenyl-n-prop-2-enylaniline Chemical compound C=1C=CC=CC=1N(CC=C)C1=CC=CC=C1 NYLGUNUDTDWXQE-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MHJCZOMOUCUAOI-UHFFFAOYSA-N n-tert-butyl-n-phenylaniline Chemical class C=1C=CC=CC=1N(C(C)(C)C)C1=CC=CC=C1 MHJCZOMOUCUAOI-UHFFFAOYSA-N 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 125000005487 naphthalate group Chemical group 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 125000002465 nonacosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- IXVLEAZXSJJKFR-UHFFFAOYSA-N octadecyl 2-[(4-hydroxy-3,5-dimethylphenyl)methylsulfanyl]acetate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CSCC1=CC(C)=C(O)C(C)=C1 IXVLEAZXSJJKFR-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- XQAABEDPVQWFPN-UHFFFAOYSA-N octyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCCCC)=CC(N2N=C3C=CC=CC3=N2)=C1O XQAABEDPVQWFPN-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000007353 oxidative pyrolysis Methods 0.000 description 1
- 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- KHMYONNPZWOTKW-UHFFFAOYSA-N pent-1-enylbenzene Chemical class CCCC=CC1=CC=CC=C1 KHMYONNPZWOTKW-UHFFFAOYSA-N 0.000 description 1
- 125000002460 pentacosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 229920001627 poly(4-methyl styrene) Polymers 0.000 description 1
- 229920001432 poly(L-lactide) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920003055 poly(ester-imide) Polymers 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920002480 polybenzimidazole Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000921 polyethylene adipate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000004460 silage Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- UOORRWUZONOOLO-UHFFFAOYSA-N telone II Natural products ClCC=CCl UOORRWUZONOOLO-UHFFFAOYSA-N 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 125000002469 tricosyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000002983 wood substitute Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/267—Magnesium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Description
WO 2022/096356 PCT/EP2021/079940 1 Method for stabilizing an organic material using a stabilizer mixture Field of the Invention The presently claimed invention relates to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound. The presently claimed invention further relates to a stabilizer mixture comprising at least one compound (A), at least one UV absorber, and at east one metal hydroxide. The presently claimed invention also relates to a composition comprising an organic material, and the stabilizer mixture. Further, the presently claimed invention relates to an article prepared from the said composition. StilI further, the presently claimed invention relates to a use of the stabilizer mixture for stabilizing an organic material by reducing degradation induced by a chlorine containing compound.
Background of the Invention Organic materials namely synthetic polymers such as polyolefins, polyethylenes, and the like are used in wide variety of applications due to their ease of use in the manufacturing of a variety of extruded and moulded articles. Exemplary articles such as greenhouse, mulch film or tapes are prepared using the organic material. However, these articles frequently suffer from general stability due to repeated exposure to the UV light. Sterically hindered amines are known in the art to be efficient stabilizers, preventing the ill effects of UV light on the articles prepared from the organic material. However, these articles when exposed to high level of chlorine containing agrochemicals or bleaching agents are subjected to enhanced degradation which subsequently leads to loss of tensile strength. The major cost factor of greenhouses or artificial turf is the installation. The loss of tensile strength leads to premature damage of greenhouses or artificial turf, causing a lot of effort as well as cost for the replacement.
Thus, it is an object of the present invention to provide a multilayer film with a high stability by reducing the degradation induced by a high level of chlorine containing compounds.
Summary of the Invention Surprisingly, it has been found that the multilayer film prepared in accordance with a method of the presently claimed invention using a certain stabilizer mixtures exhibits a substantia improvement of the elongation at break property and therefore stabilizes the multilayer film by reducing degradation induced by the high level of chlorine containing compounds.
Thus, in one aspect, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having WO 2022/096356 PCT/EP2021/079940 2 a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from genera formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) a wherein A! is selected from linear or branched, substituted or unsubstituted C2-C18 alkylene, substituted or unsubstituted C5-C7 cycloalkylene and C1-C4alkylenedi(C 5-C7cyclo alkylene), a2 is independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12 cycloalkyloxy, A3and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch3 ch3z c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (II) WO 2022/096356 PCT/EP2021/079940 (II) wherein x!and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, - compound (A) of general formula (III) (III) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and - compound (A) of general formula (IV) (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, WO 2022/096356 PCT/EP2021/079940 4 Y3 is selected from linear or branched, substituted or unsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii) at least one metal hydroxide.
In another aspect, the presently claimed invention is directed to a stabilizer mixture comprising: (i) at least one compound (A) selected from the general formula (A-l), generaformula (A-2), genera formula (A-4), general formula (A-5), general formula (A-6),general formula (A-7), and general formula (A-8) (A-4), N H9C4—N------------------"S---------------- N--------- (CH2)6 N N^,N .1 .1 h3cZ Tch= H,CA_Nh3c>C D (A-l), ' -- (A-2), yr x> H-----0 ' N —-------------- N—C4Hg N^,N .CH3 T H3C r 'LCH3 ch3 n-c4h9 H3CXN/^CH3 H3C>L /^CH3 C2H7 H3C CH3 O 63h7 0---------C11H23 0 V-------- c17h35-0 WO 2022/096356 PCT/EP2021/079940 (A-5); (A-6) WO 2022/096356 PCT/EP2021/079940 (A-7), and (A-8) wherein n is 2, (ii) at least one UV absorber; and (iii) at least one metal hydroxide.
In another aspect, the presently claimed invention is directed to a composition comprising: I. an organic material, and II. a stabilizer mixture, wherein the stabilizer mixture comprises at least onecompound (A) is selected from the general formula (A-l), general formula (A- 2), general formula (A-4), general formula (A-5), general formula (A-6), genera formula (A-7), and general formula (A-8), at least one UV absorber, and at least one metal hydroxide.
In another aspect, the presently claimed invention is directed to an article comprising the composition as defined above.
WO 2022/096356 PCT/EP2021/079940 7 In still another aspect, the presently claimed invention is directed to the use of the stabilizer mixture, as defined above, for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having the chlorine content in the range of 100 to 6ppm.
Detailed Description of the Invention Before the present compositions and formulations of the invention are described, it is to be under-stood that this invention is not limited to particular compositions and formulations described, since such compositions and formulation may, of course, vary. It is also to be understood that the terminology used herein is not intended to be limiting, since the scope of the presently claimed invention will be limited only by the appended claims.
If hereinafter a group is defined to comprise at least a certain number of embodiments, this is meant to also encompass a group which preferably consists of these embodiments only. Further-more, the terms "first", "second", "third" or "(a)", "(b)", "(c)", "(d)" etc. and the like in the description and in the claims, are used for distinguishing between similar elements and not necessarily for describing a sequential or chronological order. It is to be understood that the terms so used are interchangeable under appropriate circumstances and that the embodiments of the invention de-scribed herein are capable of operation in other sequences than described or illustrated herein. In case the terms "first", "second", "third" or "(A)", "(B)" and "(C)" or "(a)", "(b)", "(c)", "(d)", "i", "ii" etc. relate to steps of a method or use or assay there is no time or time interval coherence between the steps, that is, the steps may be carried out simultaneously or there may be time intervals of seconds, minutes, hours, days, weeks, months or even years between such steps, unless other-wise indicated in the application as set forth herein above or below.
In the following passages, different aspects of the invention are defined in more detail. Each aspect so defined may be combined with any other aspect or aspects unless clearly indicated to the contrary. In particular, any feature indicated as being preferred or advantageous may be combined with any other feature or features indicated as being preferred or advantageous.
Reference throughout this specification to "one embodiment" or "a preferred embodiment" means that a particular feature, structure or characteristic described in connection with the embodiment is included in at east one embodiment of the presently claimed invention. Thus, appearances of the phrases "in one embodiment" or "in a preferred embodiment" or "in another embodiment" in various places throughout this specification are not necessarily all referring to the same embodiment but may. Furthermore, the particular features, structures or characteristics may be combined in any suitable manner, as would be apparent to a person skilled in the art from this disclosure, in one or more embodiments. Furthermore, while some embodiments described herein include some, but not other features included in other embodiments, combinations of features of different embodiments are meant to be within the WO 2022/096356 PCT/EP2021/079940 8 scope of the invention, and form different embodiments, as would be understood by those in the art. For example, in the appended claims, any of the claimed embodiments can be used in any combination.
Furthermore, the ranges defined throughout the specification include the end values as well i.e. a range of 1 to 10 implies that both 1 and 10 are included in the range. For the avoidance of doubt, the applicant shall be entitled to any equivalents according to the applicable law.
Certain terms are first defined so that this disclosure can be more readily understood. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which embodiments of the invention pertain.
In an aspect, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18alkylene, substituted or unsubstituted C5-C7 cycloalkylene and C1-C4alkylenedi(C 5-C7cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), WO 2022/096356 PCT/EP2021/079940 or h3c ch.
CH3z C h3 A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and is an integer in the range of 1 to 20 and the repeating units are the same or different, compound (A) of general formula (II) wherein x! and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) a o—c—& wherein is linear or branched, substituted or unsubstituted C3 to C20alkyl, 2is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or unsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii)at least one meta hydroxide.
In a preferred embodiment, A! is selected from linear or branched, substituted or unsubstituted C2-C8 alkylene and substituted or unsubstituted cyclohexylene, A2 is independently selected from H, linear or branched, substituted or unsubstituted C1-C8alkyl, C1-C12alkyloxy, substituted or unsubstituted cyclohexyl and cyclohexyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C1-C8alkyl or a group of the formula (a-1) or A3 and A4, together with the nitrogen atom to which they are bonded, form a morpholino group, and a is an integer in the range of 1 to 10.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), WO 2022/096356 PCT/EP2021/079940 wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c chN—A2(a-1) ch3z c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, (ii) at least one UV absorber; and(iii) at least one metal hydroxide.
In another embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (II), WO 2022/096356 PCT/EP2021/079940 x! wherein o—c—& x! and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, (ii) at least one UV absorber; and (iii)at least one meta hydroxide.
In another embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (III), compound (A) of general formula (III) wherein is linear or branched, substituted or unsubstituted C3 to C20alkyl, 2is linear or branched, substituted or unsubstituted C! to C30 alkyl; (ii) at least one UV absorber; and (iii)at least one meta hydroxide.
In another embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound WO 2022/096356 PCT/EP2021/079940 13 having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (IV), compound (A) of general formula (IV) (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted orunsubstituted C3 to C20alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8; (ii) at least one UV absorber; and(iii)at least one meta hydroxide.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof,compound (A) of general formula (I) WO 2022/096356 PCT/EP2021/079940 wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, 10A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch3N—A2(a-1) ch3z c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (II) (II) WO 2022/096356 PCT/EP2021/079940 wherein x!and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, and compound (A) of general formula (III) dll) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl;and (ii) at least one UV absorber; and(iii)at least one meta hydroxide.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein WO 2022/096356 PCT/EP2021/079940 16 A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), CH3z C h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (II) (II) wherein x 7and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted orunsubstituted C3 to C20alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8; (ii) at least one UV absorber; and(iii)at least one meta hydroxide.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein WO 2022/096356 PCT/EP2021/079940 18 A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), CH3z C h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (III) (III) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl;and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted orunsubstituted C3 to C20alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8; (ii) at least one UV absorber; and(iii)at least one meta hydroxide.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein WO 2022/096356 PCT/EP2021/079940 A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), CH3z C h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, and compound (A) of general formula (II) (II) wherein x 7and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy; (ii) at least one UV absorber; and(iii)at least one meta hydroxide.
In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having WO 2022/096356 PCT/EP2021/079940 21 a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof,compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7 cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), a2 is independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, C!-C12 alkyloxy, substituted or unsubstituted C5-C12cycloalkyl and C5-C12cycloalkyloxy, A3and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), H3Cx ch3(a-1) CH3 ch3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, and compound (A) of general formula (III) WO 2022/096356 PCT/EP2021/079940 dll) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl;and (ii) at least one UV absorber; and (iii)at least one meta hydroxide.
Compound A of general formula (I): In an embodiment, the stabilizer mixture comprises at least one compound (A) selected from general formula (I), general formula (II), genera formula (III), general formula (IV), and mixtures thereof.
In an embodiment, the stabilizer mixture comprises at least one compound (A) of genera formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, C!-C12 alkyloxy, substituted or unsubstituted C5-C12cycloalkyl and C5-C12cycloalkyloxy, WO 2022/096356 PCT/EP2021/079940 23 A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted 0!-012 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch, ch3 c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, Within the context of the present invention, the term alkyl, as used herein, refers to acyclic saturated aliphatic residues, including linear or branched alkyl residues.
As used herein, "branched" denotes a chain of atoms with one or more side chains attached to it. Branching occurs by the replacement of a substituent, e.g., a hydrogen atom, with a covalently bonded aliphatic moiety.
Representative examples of linear and branched, unsubstituted C!-C12 alkyl include, but are not limited to, methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tert-butyl, 2- ethylbutyl, n-pentyl, isopentyl, 1-methylpentyl, 1,3-dimethylbutyl, n-hexyl, 1-methylhexyl, n- heptyl, isoheptyl, 1,1,3,3-tetramethylbutyl, 1-methylheptyl, 3-methylheptyl, 2-propy heptyl, n-octyl, 2-ethylhexyl, 1,1,3-trimethylhexyl, 1,1,3,3-tetramethylpentyl, n-nonyl, n-decyl, n- undecyl, isoundecyl, 1-methylundecyl, n-dodecyl, isododecyl, and 1,1,3,3,5,5- hexamethylhexyl.
Representative examples of C!-C12 alkyloxy include, but are not limited to, methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentoxy, isopentoxy, hexoxy, heptoxy, octoxy, nonyloxy, decyloxy, undecyloxy, and dodecyloxy.
In a preferred embodiment, alkyloxy is selected from methoxy, ethoxy, propoxy, isopropoxy, butoxy, isobutoxy, pentoxy, isopentoxy, hexoxy, heptoxy and octoxy. In a more preferred embodiment, alkyloxy is propoxy.
Representative examples of C5-C12 cycloalkyl are cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, cycloundecyl, and cyclododecyl.
Representative examples of C5-C12cycloalkyloxy are cyclopentoxy, cyclohexoxy, cycloheptoxy, cyclooctoxy, cyclononyloxy, cyclodecyloxy, cycloundecyloxy, and cyclododecyloxy.
WO 2022/096356 PCT/EP2021/079940 24 In a preferred embodiment the cylcoalkyloxy is cyclohexoxy.
A preferred example of phenyl substituted by 1, 2 or 3 C1-C4alkyl is 2,4-dimethylphenyl.
Preferred C2-C18 alkylene are ethylene, propylene, trimethylene, tetramethylene, pentamethylene, 2,2-dimethyltrimethylene and hexamethylene. In a more preferred embodiment, alkylene is hexamethylene.
An example of C5-C7cycloalkylene is cyclohexylene.
An example of C1-C4alkylenedi(C 5-C7cycloalkylene) is methylenedicyclohexylene.
Examples of the radicals A3 and A4 together with the nitrogen atom to which they are bonded, forming a 5- to 10-membered heterocyclic ring, are 1-pyrrolidyl, piperidyl, morpholinyl, 1- piperazinyl, 4-methyl-l-piperazinyl, 1-hexahydroazepinyl, 5,5,7-trimethyl-1-homopiperaziny or 4,5,5,7-tetramethyl-l-homopiperazinyl, preferably morpholinyl.
In the compound (A) of the general formula (I) the terminal group attached to the diamino residue is for example hydrogen or a group of the formula A3-NA4 and the terminal group attached to the triazine radical is for example a group of the formula --------N----------A־!----------- N------ H CH3 H3C l^ J_CH3CH3 H3C־> In a preferred embodiment, A! is hexamethylene, and A2 is hydrogen, and propoxy.
In a preferred embodiment, A3 is butyl, , and WO 2022/096356 PCT/EP2021/079940 In a preferred embodiment, A4 is butyl.
In a preferred embodiment, a is an integer in the range of 1 to 10.
Compound A of general formula (II): In an embodiment, the stabilizer mixture comprises at least one compound (A) of genera formula (II) (ID wherein x!and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, In a preferred embodiment, x! and x 2 are independently selected from linear or branched, unsubstituted C! to C30 alkyloxy.
Representative examples of linear or branched, unsubstituted C! to C30 alkyloxy are methyloxy, ethyloxy, propyloxy, butyloxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy, undecyloxy, dodecyloxy, tridecyloxy, tetradecyloxy, pentadecyloxy, hexadecyloxy, heptadecyloxy, octadecyloxy, nonadecyloxy, icosyloxy, henicosyloxy, docosyloxy, tricosyloxy, tetracosyloxy, pentacosyloxy, hexacosyloxy, heptacosyloxy, octacosyloxy, nonacosyloxy and triacontyloxy.
In a preferred embodiment, x! and x 2 are each undecyloxy.
Compound (A) of general formula (III): In an embodiment, the stabilizer mixture comprises at least one compound (A) of genera formula (III) WO 2022/096356 PCT/EP2021/079940 dll) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; In a preferred embodiment, Y! is linear or branched, unsubstituted C3 to C20alkyl.
In an embodiment, Y! is selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, and icosyl.
In a preferred embodiment, Y!is selected from propyl, and dodecyl.
In a preferred embodiment, Y2 is linear or branched, unsubstituted C! to C30alkyl.
In an embodiment, Y2 is selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, icosyl, henicosyl, docosyl, tricosyl, tetracosyl, pentacosyl, hexacosyl, heptacosyl, octacosyl, nonacosyl, and triacontyl.
In a preferred embodiment, Y2 is selected from pentadecyl, and heptadecyl.
Compound (A) of general formula (IV): In an embodiment, the stabilizer mixture comprises at least one compound (A) of genera formula (IV).
WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or unsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and In a preferred embodiment, Y3 is selected from linear or branched, unsubstituted C3 to Calkyl and C3 to C20 alkylidene.
Representative examples of alkylidene having up to 20 carbon atoms are methylidene, ethylidene, propylidene, butylidene, pentylidene, hexylidene, heptylidene, octylidene, nonylidene, decylidene, undecylidene, dodecylidene, tridecylidene, tetradecylidene, pentadecylidene, hexadecylidene, heptadecylidene, octadecylidene, nonadecylidene, and icosylidene.
In a preferred embodiment, Y!is selected from decyl.
In a preferred embodiment, Y3 is selected from decyl, and nonylidene.
In a preferred embodiment, the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), wherein A! is selected from C2-C18alkylene, C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7cyclo alkylene), A2 is independently selected from C1-C12 alkyloxy, and C5-C12cycloalkyloxy, A3 and A4 is independently selected from H, C1-C12 alkyl, C5-C12 cycloalkyl and a group of the formula (a-1), or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring, and a is an integer in the range of 1 to 20 and the repeating units are the same or different, WO 2022/096356 PCT/EP2021/079940 28 general formula (II), general formula (III), general formula (IV), and mixtures thereof; (ii) at least one UV absorber; and (ill) at least one metal hydroxide.
In another preferred embodiment, the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), wherein A! is selected from C2-C18 alkylene, C5-C7 cycloalkylene, and C!-C4 alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, C1-C12 alkyl, and C5-C12cycloalkyl, A3 and A4 is independently selected from H, 0012-ן alkyl, C5-C12 cycloalkyl and a group of the formula (a-1), or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units are the same or different, general formula (II), general formula (III), general formula (IV), and mixtures thereof; (ii) at least one UV absorber; and (iii) at least one metal hydroxide.
In a preferred embodiment, the compound (A) is at least one compound selected from the formula (A-1), (A-2), (A-3), (A-4), (A-5), (A-6), (A-7), and (A-8) (A-1), (A-2), WO 2022/096356 PCT/EP2021/079940 N----- C4Hg C4Hg (A-3) c4h9 N I >ף ן/ — N—C4H8 wherein a is an integer in the range of 1 to 10, (A-4), (A-5) WO 2022/096356 PCT/EP2021/079940 (A-6) (A-7), and (A-8) wherein n is 2.
WO 2022/096356 PCT/EP2021/079940 31 In a more preferred embodiment, the compound (A) is at least one compound selected from the formula (A-l), (A-3), (A-4), (A-5), (A-6), (A-7), and (A-8).
In another preferred embodiment, the compound (A) is a compound of formula (A-9) (A-9) 5 wherein a is an integer in the range of 1 to 10.
Organic Material In an embodiment, the organic materia is selected from: 1. Polymers of monoolefins and diolefins, for example polyethylene, polypropylene, polyisobutylene, polybut-l-ene, poly-4-methylpent-l-ene, polyvinylcyclohexane, polyisoprene or polybutadiene, as well as polymers of cycloolefins, for instance of cyclopentene or norbornene, (which optionally can be crosslinked), for example high density polyethylene (HOPE), high density and high molecular weight polyethylene (HDPE-HMW), high density and ultrahigh molecular weight polyethylene (HDPE-UHMW), medium density polyethylene (MDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), (VLDPE) and (ULDPE).
Polyolefins, i.e. the polymers of monoolefins exemplified in the preceding paragraph, prefe- rably polyethylene and polypropylene, can be prepared by different, and especially by the following, methods: a) radical polymerisation (normally under high pressure and at elevated temperature). b) catalytic polymerisation using a catalyst that normally contains one or more than one metal of groups IVb, Vb, Vlb or VIII of the Periodic Table. These metals usually have one or more than one ligand, typically oxides, halides, alcoholates, esters, ethers, amines, alkyls, alkenyls and/or aryls that may be either p- or s-coordinated. These metal complexes may be in the free form or a form fixed on substrates, typically on substrates such as activated magnesium chloride, titanium (III) chloride, alumina or silicon oxide. These catalysts may be soluble or insoluble in the polymerisation WO 2022/096356 PCT/EP2021/079940 32 medium. The catalysts can be used by themselves in the polymerisation or further activators may be used, typically metal alkyls, metal hydrides, metal alkyl halides, metal alkyl oxides or metal alkyloxanes, said metals being elements of groups la, Ila and/or Illa of the Periodic Table. The activators may be modified conveniently with further ester, ether, amine or silyl ether groups. These catalyst systems are usually termed Phillips, Standard Oil Indiana, Ziegler (-Natta), TNZ (DuPont), metallocene or single site catalysts (SSC). 2. Mixtures of the polymers mentioned under 1), for example mixtures of polypropylene with polyisobutylene, polypropylene with polyethylene (for example PP/HDPE, PP/LDPE) and mixtures of different types of polyethylene (for example LDPE/HDPE). 3. Copolymers of monoolefins and diolefins with each other or with other vinyl monomers, for example ethylene/propylene copolymers, linear low density polyethylene (LLDPE) and mixtures thereof with low density polyethylene (LDPE), propylene/but-l-ene copolymers, propylene/isobutylene copolymers, ethylene/but-l-ene copolymers, ethylene/hexene copo- lymers, ethylene/methylpentene copolymers, ethylene/heptene copolymers, ethylene/octene copolymers, ethylene/vinylcyclohexane copolymers, ethylene/cycloolefin copolymers (e.g. ethylene/norbornene like COC), ethylene/1-olefins copolymers, where the 1-olefin is gene- rated in-situ; propylene/butadiene copolymers, isobutylene/isoprene copolymers, ethylene/vinylcyclohexene copolymers, ethylene/alkyl acrylate copolymers, ethylene/alky methacrylate copolymers, ethylene/vinyl acetate copolymers or ethylene/acrylic acid copolymers and their salts (ionomers) as well as terpolymers of ethylene with propylene and a diene such as hexadiene, dicyclopentadiene or ethylidene-norbornene; and mixtures of such copolymers with one another and with polymers mentioned in 1) above, for example polypropylene/ethylene-propylene copolymers, LDPE/ethylene-vinyl acetate copolymers (EVA), LDPE/ethylene-acrylic acid copolymers (EAA), LLDPE/EVA, LLDPE/EAA and alternating or random polyalkylene/carbon monoxide copolymers and mixtures thereof with other polymers, for example polyamides. 4. Hydrocarbon resins (for example C5-Cg) including hydrogenated modifications thereof (e.g. tackifiers) and mixtures of polyalkylenes and starch.
Homopolymers and copolymers from 1.) - 4.) may have any stereo structure including syndic- tactic, isotactic, hemi-isotactic or atactic; where polymers atactic stereostructure are preferred. Stereoblock polymers are also included.
. Polystyrene, poly(p-methylstyrene), poly(a-methylstyrene). 6. Aromatic homopolymers and copolymers derived from vinyl aromatic monomers including styrene, a-methylstyrene, all isomers of vinyl toluene, especially p-vinyltoluene, all isomers of ethyl styrene, propyl styrene, vinyl biphenyl, vinyl naphthalene, and vinyl anthracene, and mixtures thereof. Homopolymers and copolymers may have any stereostructure including WO 2022/096356 PCT/EP2021/079940 33 syndiotactic, isotactic, hemi-isotactic or atactic; where atactic polymers are preferred. Ste- reoblock polymers are also included. 6a. Copolymers including aforementioned vinyl aromatic monomers and comonomers selec- ted from ethylene, propylene, dienes, nitriles, acids, maleic anhydrides, maleimides, viny acetate and vinyl chloride or acrylic derivatives and mixtures thereof, for example styrene/bu- tadiene, styrene/acrylonitrile, styrene/ethylene (interpolymers), styrene/alkyl methacrylate, styrene/butadiene/alkyl acrylate, styrene/butadiene/alkyl methacrylate, styrene/maleic anhydride, styrene/acrylonitrile/methyl acrylate; mixtures of high impact strength of styrene copolymers and another polymer, for example a polyacrylate, a diene polymer or an ethylene/propylene/diene terpolymer; and block copolymers of styrene such as styrene/butadiene/styrene, styrene/isoprene/styrene, styrene/ethylene/butylene/styrene or styrene/ethylene/propylene/styrene. 6b. Hydrogenated aromatic polymers derived from hydrogenation of polymers mentioned under 6.), especially including polycyclohexylethylene (PCHE) prepared by hydrogenating atactic polystyrene, often referred to as polyvinylcyclohexane (PVCH). 6c. Hydrogenated aromatic polymers derived from hydrogenation of polymers mentioned under 6a.).
Homopolymers and copolymers may have any stereostructure including syndiotactic, isotac- tic, hemi-isotactic or atactic; where atactic polymers are preferred. Stereoblock polymers are also included. 7. Graft copolymers of vinyl aromatic monomers such as styrene or a-methylstyrene, for example styrene on polybutadiene, styrene on polybutadiene-styrene or polybutadiene-acry- lonitrile copolymers; styrene and acrylonitrile (or methacrylonitrile) on polybutadiene; styrene, acrylonitrile and methyl methacrylate on polybutadiene; styrene and maleic anhydride on polybutadiene; styrene, acrylonitrile and maleic anhydride or maleimide on polybutadiene; styrene and maleimide on polybutadiene; styrene and alkyl acrylates or methacrylates on polybutadiene; styrene and acrylonitrile on ethylene/propylene/diene terpolymers; styrene and acrylonitrile on polyalkyl acrylates or polyalkyl methacrylates, styrene and acrylonitrile on acrylate/butadiene copolymers, as well as mixtures thereof with the copolymers listed under 6), for example the copolymer mixtures known as ABS, MBS, ASA or AES polymers. 8. Halogen-containing polymers such as polychloroprene, chlorinated rubbers, chlorinated and brominated copolymer of isobutylene-isoprene (halobutyl rubber), chlorinated or sulfo- chlorinated polyethylene, copolymers of ethylene and chlorinated ethylene, epichlorohydrin homo- and copolymers, especially polymers of halogen-containing vinyl compounds, for example polyvinyl chloride, polyvinylidene chloride, polyvinyl fluoride, polyvinylidene fluoride, as well as copolymers thereof such as vinyl chloride/vinylidene chloride, vinyl chloride/vinyl acetate or vinylidene chloride/vinyl acetate copolymers.
WO 2022/096356 PCT/EP2021/079940 34 9. Polymers derived from a , P -unsaturated acids and derivatives thereof such as polyacry- lates and polymethacrylates; polymethyl methacrylates, polyacrylamides and polyacryloni- triles, impact-modified with butyl acrylate.
. Copolymers of the monomers mentioned under 9) with each other or with other unsatu- rated monomers, for example acrylonitrile/ butadiene copolymers, acryIonitrile/aIky acrylate copolymers, acryIonitrile/aIkoxyaIkyI acrylate or acrylonitrile/vinyl halide copolymers or aery- lonitrile/ alkyl methacrylate/butadiene terpolymers. 11. Polymers derived from unsaturated alcohols and amines or the acyl derivatives or acetals thereof, for example polyvinyl alcohol, polyvinyl acetate, polyvinyl stearate, polyvinyl benzoate, polyvinyl maleate, polyvinyl butyral, polyallyl phthalate or polyallyl melamine; as well as their copolymers with olefins mentioned in 1) above. 12. Homo polymers and copolymers of cyclic ethers such as polyalkylene glycols, polyethylene oxide, polypropylene oxide or copolymers thereof with bisglycidyl ethers. 13. Polyacetals such as polyoxymethylene and those polyoxymethylenes which contain ethylene oxide as a comonomer; polyacetals modified with thermoplastic polyurethanes, acrylates or MBS. 14. Polyphenylene oxides and sulfides, and mixtures of polyphenylene oxides with styrene polymers or polyamides.
. Polyurethanes derived from hydroxyl-terminated polyethers, polyesters or polybutadienes on the one hand and aliphatic or aromatic polyisocyanates on the other, as well as precursors thereof. 16. Polyamides and copolyamides derived from diamines and dicarboxylic acids and/or from aminocarboxylic acids or the corresponding lactams, for example polyamide 4, polyamide 6, polyamide 6/6, 6/10, 6/9, 6/12, 4/6, 12/12, polyamide 11, polyamide 12, aromatic polyamides starting from m-xylene diamine and adipic acid; polyamides prepared from hexamethylenediamine and isophthalic or/and terephthalic acid and with or without an ela- stomer as modifier, for example poly-2,4,4,-trimethylhexamethylene terephthalamide or poly- m-phenylene isophthalamide; and also block copolymers of the aforementioned polyamides with polyolefins, olefin copolymers, ionomers or chemically bonded or grafted elastomers; or with polyethers, e.g. with polyethylene glycol, polypropylene glycol or polytetramethylene glycol; as well as polyamides or copolyamides modified with EPDM or ABS; and polyamides condensed during processing (RIM polyamide systems). 17. Polyureas, polyimides, polyamide-imides, polyetherimides, polyesterimides, polyhydan- toins and polybenzimidazoles. 18. Polyesters derived from dicarboxylic acids and diols and/or from hydroxycarboxylic acids or the corresponding lactones or lactides, for example polyethylene terephthalate, polybuty- WO 2022/096356 PCT/EP2021/079940 lene terephthalate, poly-1,4-dimethylolcyclohexane terephthalate, polyalkylene naphthalate and polyhydroxybenzoates as well as copolyether esters derived from hydroxyl-terminated polyethers, and also polyesters modified with polycarbonates or MBS. Copolyesters may comprise, for example - but are not limited to - polybutylenesuccinate/terephtalate, polybuty- I eneadipate/tere phthalate, polytetra methyleneadipate/terephthalate,polybutylensuccinate/adipate, poly butylensuccinate/car donate, poly-3-hydroxybutyrate/octa noate copolymer, poly-3-hydroxybutyrate/hexanoate/deca noate terpolymer. Furthermore, aliphatic polyesters may comprise, for example - but are not limited to - the class of poly(hydroxyalkanoates), in particular, poly(propiolactone), poly(butyrolactone), poly(pivalolactone), poly(valerolactone) and poly(caprolactone), polyethylenesuccinate, polypropylenesuccinate, poly butylenesuccinate,polyhexamethylenesuccinate, polyethyleneadipate, polypropyleneadipate, polybutyleneadi- pate, polyhexamethyleneadipate, polyethyleneoxalate, polypropyleneoxalate, polybutylene- oxalate, polyhexamethyleneoxalate, polyethylenesebacate, polypropylenesebacate, polybu- tylenesebacate and polylactic acid (PLA) as well as corresponding polyesters modified with polycarbonates or MBS. The term "polylactic acid (PLA)" designates a homo-polymer of pre- ferably poly-L-lactide and any of its blends or alloys with other polymers; a co-polymer of lactic acid or lactide with other monomers, such as hydroxy-carboxylic acids, like for example glycolic acid, 3-hydroxy-butyric acid, 4-hydroxy-butyric acid, 4-hydroxy-valeric acid, 5-hydr- oxy-valeric acid, 6-hydroxy-caproic acid and cyclic forms thereof; the terms "lactic acid" or "lactide" include L-lactic acid, D-lactic acid, mixtures and dimers thereof, i.e. L-lactide, D- lactide, meso-lactide and any mixtures thereof. 19. Polycarbonates and polyester carbonates.
. Polyketones. 21. Polysulfones, polyether sulfones and polyether ketones. 22. Crosslinked polymers derived from aldehydes on the one hand and phenols, ureas and melamines on the other hand, such as phenol/formaldehyde resins, urea/formaldehyde re- sins and melamine/formaldehyde resins. 23. Drying and non-drying alkyd resins. 24. Unsaturated polyester resins derived from copolyesters of saturated and unsaturated dicarboxylic acids with polyhydric alcohols and vinyl compounds as crosslinking agents, and also halogen-containing modifications thereof of low flammability.
. Crosslinkable acrylic resins derived from substituted acrylates, for example epoxy aery- lates, urethane acrylates or polyester acrylates. 26. Alkyd resins, polyester resins and acrylate resins crosslinked with melamine resins, urea resins, isocyanates, isocyanurates, polyisocyanates or epoxy resins.
WO 2022/096356 PCT/EP2021/079940 36 27. Crosslinked epoxy resins derived from aliphatic, cycloaliphatic, heterocyclic or aromatic glycidyl compounds, e.g. products of diglycidyl ethers of bisphenol A and bisphenol F, which are crosslinked with customary hardeners such as anhydrides or amines, with or without accelerators. 28. Natural polymers such as cellulose, rubber, gelatin and chemically modified homologous derivatives thereof, for example cellulose acetates, cellulose propionates and cellulose butyrates, or the cellulose ethers such as methyl cellulose; as well as rosins and their derivatives. 29. Blends of the aforementioned polymers (polyblends), for example PP/EPDM, Poly- amide/EPDM or ABS, PVC/EVA, PVC/ABS, PVC/MBS, PC/ABS, PBTP/ABS, PC/ASA, PC/PBT, PVC/CPE, PVC/acrylates, POM/thermoplastic PUR, PC/thermoplastic PUR, POM/acrylate, POM/MBS, PPO/HIPS, PPO/PA 6.6 and copolymers, PA/HDPE, PA/PP, PA/PPO, PBT/PC/ABS or PBT/PET/PC.
. Naturally occurring and synthetic organic materials which are pure monomeric com- pounds or mixtures of such compounds, for example mineral oils, animal and vegetable fats, oil and waxes, or oils, fats and waxes based on synthetic esters (e.g. phthalates, adipates, phosphates or trimellitates) and also mixtures of synthetic esters with mineral oils in any weight ratios, typically those used as spinning compositions, as well as aqueous emulsions of such materials. 31. Aqueous emulsions of natural or synthetic rubber, e.g. natural latex or latices of carbo- xylated styrene/butadiene copolymers.
In a preferred embodiment, the organic material is selected from linear low-density polyethylene, low-density polyethylene, high density polyethylene, ethylene-vinyl acetate copolymer, ethylene-butyl acrylate copolymer, polypropylene homopolymer and polypropylene copolymer.
In a more preferred embodiment, the organic material is low-density polyethylene.
Chlorine containing compound In an embodiment, the presently claimed invention is directed to a method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm.
The chlorine containing compound can be an agrochemical compound or a bleaching agent.
The agrochemical compound can be an insecticide, fungicide, nematicide, and mixtures thereof.
The agrochemical compound is selected from pyrethroid, dicarboximide, CICH2-CH=CHCI, Cl3C-NO2, pyrethroid, phthalimide, benzoylurea, imidazole, and mixtures thereof.
WO 2022/096356 PCT/EP2021/079940 37 The agrochemical compound is selected from permethrin, procymidone, 1,3-dichloropropene, chloropicrin, y-cyhalothrin, captan, teflubenzuron, prochloraz, and mixtures thereof.
The bleaching agent is sodium hypochlorite, chlorine dioxide, and chloramines, preferably sodium hypochlorite.
UV Absorber In an embodiment, the stabilizer mixture comprises at least one UV absorber.
In an embodiment, the at least one UV absorber is selected from 2-(2'- hydroxyphenyl)benzotriazoles, 2-hydroxy benzophenones, 2-(2-hydroxy phenyl) -1,3,5-triazines and mixtures thereof.
In an embodiment, the 2-(2'-hydroxyphenyl)benzotriazole is selected from 2-(2H- Benzotriazol-2-yl)-4,6-bis(l-methy 1-1-phenyl ethyl) phenol, 2-(2'-hydroxy-5'-methyl phenyl)- benzotriazole, 2 - (3', 5'-di-tert-butyl -2'-hydroxy phenyl) benzotriazo Ie, 2-(5'-tert-butyl-2'- hydroxyphenyl)benzotriazole, 2-(2'-hydroxy-5'- (1,1,3,3-tetramethylbutyl)phenyl)benzotriazole, 2 - (3', 5'-di-tert-butyl -2'-hydroxy phenyl) -5-ch loro-benzotriazol e,2-(3'-tert-buty I-2'-hydroxy-5'-methyl phenyl) -5-ch loro-benzotriazole, 2-(3'-sec-buty I-5'-tert-butyl -2'-hydroxy phenyl) benzotriazo Ie, 2-(2'-hydroxy-4'-octyloxyphenyl)benzotriazole, 2 - (3', 5'-di-tert-amyl -2'-hydroxy phenyl) benzotriazo Ie, 2-(3',5'- bis-( a , a -di methyl benzyl) -2'-hydroxy phenyl )benzotriazo Ie, 2-(3'-tert-butyl -2'-hydroxy-5'- (2- octyl oxycar bony I ethyl) phenyl) -5-chloro-benzotriazole, 2-(3'-tert-butyl-5'-[2-(2-ethylhexyl- oxy)-carbonylethyl]-2'-hydroxypheny I)-5-chloro-benzotriazole, 2-(3'-tert-butyl-2'-hydroxy- 5'-(2-methoxycarbonyl ethyl) phenyl)-5-ch loro-benzotriazo Ie, 2-(3'-tert-butyl -2'-hydroxy-5'- (2-methoxycarbonylethyl)phenyl)benzotriazole, 2-(3'-tert-butyl -2'-hydroxy-5'- (2-octyl oxycarbonyl ethyl) phenyl) benzotriazo Ie, 2-(3'-tert-butyl-5'-[2-(2-ethyl hexyl oxy) car bony I ethyl] -2'-hydroxy phenyl) benzotriazole, 2-(3'-dod ecyl -2'-hydroxy-5'- methyl phenyl) benzotriazole, 2-(3'-tert-butyl -2'-hydroxy-5'- (2-isooctyl oxycar bony I ethyl) phenyl benzotriazole, 2,2'-methylene-bis [4-(1,1,3,3-tetramethylbutyl)-6-benzotriazole-2-ylphenol]; the transesterification product of 2-[3'-tert- bu ty I-5'-(2-meth oxyca r bony I ethyl) -2'-hydroxy phenyl] -2 H-benzotriazole with polyethylene glycol 300; [r—CH2CH2—COO-CH2CH29־— , where R = 3'-tert-butyl-4'-hydroxy-5'-2H- benzotriazol-2-ylphenyl, 2-[2'-hydroxy-3'-(a , a -dimethylbenzyl)-5'-(l,l,3,3-tetramethylbutyI)-phenyl]benzotriazole; and 2-[2'-hydroxy-3'- (1,1,3,3-tetra methyl buty I)-5'-( a , a -dimethylbenzyl)-phenyl]benzotriazole, and mixtures thereof.
In a preferred embodiment, the 2-(2'-hydroxyphenyl)benzotriazole is 2-(2'-hydroxy-5'- (1,1,3,3-tetra methyl buty I) phenyl) benzotriazole.
WO 2022/096356 PCT/EP2021/079940 38 In an embodiment, the 2-hydroxybenzophenone is selected from 4-hydroxy, 4-methoxy, 4- octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4,2',4'-trihydroxy, 2'-hydroxy-4,4'-dimethoxy derivatives and mixtures thereof.
In an embodiment, the 2-(2-hydroxyphenyl)-l,3,5-triazine is selected from 2,4,6-tris(2- hyd roxy-4-octyloxypheny I)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-di methyl phenyl) -1,3,5-triazine, 2-(2,4-d ihyd roxypheny l)-4,6-bis(2,4-d i methyl phenyl) -1,3,5-triazine, 2,4-bis(2 - hydroxy-4-propyloxy phenyl) -6-(2,4-d imethy I pheny I)-1,3,5-triazi ne, 2-(2- hyd roxy-4-octyloxypheny I)-4,6-bis(4-methyl phenyl)-1,3,5-triazi ne, 2-(2-hydroxy-4-dodecyloxy pheny I)-4,6-bis (2,4-d imethy I pheny I)-1,3,5-triazine, 2-(2-hydroxy-4-tridecyl oxy pheny I)-4,6-bis (2,4-d imethy I pheny I)-1,3,5-triazi ne, 2-[2-hydroxy-4- (2-hydroxy-3- bu tyloxy propoxy) pheny I]-4,6-bis(2,4-d imethy I)-1,3,5-triazi ne, 2-[2-hydroxy-4-(2-hydroxy-3- octyl oxy propyl oxy) pheny I]-4,6-bis (2,4-d imethy I)-1,3,5-triazine, 2-[4-(dod ecy I oxy/t ridecy loxy-2-hydroxy pro poxy) -2-hyd roxypheny I]-4,6-bis(2,4-d imethy I pheny I)- 1,3,5-triazi ne, 2-[2-hydroxy-4- (2-hydroxy-3-dodecyl oxy pro poxy) pheny I]-4,6-bis (2,4-di methyl pheny I)-1,3,5-triazine, 2 - (2 - hyd roxy-4-hexyl oxy) pheny I-4,6-di pheny I-1,3,5-triazi ne, 2-(2-hyd roxy-4-methoxy pheny I)-4,6-di pheny I-1,3,5-triazine, 2,4,6-tris[2-hydroxy-4-(3-butoxy-2-hydroxy pro poxy) pheny I]-1,3,5-triazine, 2-(2-hyd roxypheny I)-4-(4-methoxy phenyl)- 6-pheny I-1,3,5-triazi ne, 2-{2-hydroxy-4-[3-(2-ethylhexyl-l-oxy)-2-hyd roxypropyl oxy] pheny I]-4,6-bis(2,4-d imethy I pheny I)-1,3,5-triazi ne, 2,4-bis(4-[2-ethy I hexyl oxy]-2-hyd roxypheny I)-6-(4-methoxy phenyl)-1,3,5-triazi ne, 2,4-bis (4-bi phenylyl)- 6-[2-hydroxy-4-(2-ethylhexyloxy)phenyl] -1,3,5-triazine, Dodecanedioic acid, l,12-bis[2-[4- (4,6-diphenyl-l,3,5-triazin-2-yl)-3-hydroxyphenoxy]ethyl]ester and mixtures thereof.
In a preferred embodiment, the 2-(2-hydroxyphenyl)-l,3,5-triazine is 2,4-bis(4-biphenylyl)-6- [2-hydroxy-4- (2-ethylhexyloxy)phenyl] -1,3,5-triazine.
Metal hydroxide In an embodiment, the stabilizer mixture comprises at least one metal hydroxide.
In an embodiment, the at least one metal hydroxide is selected from the group consisting of hydrotalcite, and magnesium hydroxide.
Hydrotalcite In a preferred embodiment, the hydrotalcite is a mixed hydroxide of the formula (Z-l) or (Z- II).
M2+1_gM3+g(OH)2(Ab-)g/b x c H2O (Z-l) M2+dAI3%(OH،eb(Ab )exf H20 (Z-ll) M2+ is selected from Ca 2+, Mg2+, Sr 2+, Ba 2+, Zn 2+, Pb2+, Sn 2+ and Ni2+.
WO 2022/096356 PCT/EP2021/079940 39 M3+ is selected from Al3+, B3+ and Bi3+. g is a number up to 0.5.
A׳' is an anion of valency b, selected from Ch, Br, NO3, CO32h SO/ or SeO42 b is an integer from 1 to 4. c is zero, 1 or 2. d is a number up to 6. e is a number up to 2. f is zero or a number up to 15.
In a more preferred embodiment, hydrotalcites are layered double hydroxides that contain positively charged hydroxide layers and charge balancing anions located in the interlayer region.
In an even more preferred embodiment, hydrotalcite is at least one magnesium aluminum hydroxide carbonate hydrate which is for example commercially available as Hycite®713, ‘DHT-4A, ‘DHT-4V, ‘DHT-4A-2, ‘DHT-40 or Sorbacid®911, or zinc aluminum hydroxide carbonate hydrate which is for example commercially available as aZHT-4V or Sorbacid®944, or mixtures thereof.
In a most preferred embodiment, hydrotalcite is a magnesium aluminum hydroxide carbonate hydrate which is for example commercially available as Hycite a713 or DHT-4A.
In another aspect, the presently claimed invention is directed to a stabilizer mixture comprising: (i) at least one compound (A) selected from the general formula (A-l), genera formula (A-2), genera formula (A-4), general formula (A-5), general formula (A-6), general formula (A-7), and general formula (A-8); (ii) at least one UV absorber; and (iii)at least one metal hydroxide.
In a preferred embodiment, the stabilizer mixture comprises: (i) at least one compound (A) selected from the general formula (A-l), genera formula (A-4), genera formula (A-5), general formula (A-6), general formula (A-7), and general formula (A-8); (ii) at least one UV absorber; and (iii)at least one metal hydroxide.
WO 2022/096356 PCT/EP2021/079940 In an embodiment, the weight ratio of the at least one compound (A) to the at least one UV absorber is in the range of 1:1 to 20:1, preferably is in the range of 5:1 to 15:1, more preferably is in the range of 9:1 to 13:1, and most preferably is in the range of 11.7:1.
In an embodiment, the weight ratio of the at least one compound (A) to the at least one meta hydroxide is in the range of 1:10 to 10:1, preferably is in the range of 1:5 to 5:1, more preferably is in the range of 1:3 to 3:1, and most preferably is in the range of 2.5:1.
In an embodiment, the weight ratio of the at least one UV absorber to the at least one hydroxide is in the range of 10:1 to 1:20, preferably is in the range of 5:1 to 1:15, more preferably is in the range of 3:1 to 1: 10, and most preferably is in the range of 1:4.7.
Light stabilizer: In an embodiment, the stabilizer mixture further comprises at least one light stabilizer.
In an embodiment, the light stabilizer is selected from bis(2,2,6,6-tetramethyl-4- piperidyI)sebacate, bis(2,2,6,6-tetramethyl-4-pi peridyI)succinate, bis(l,2,2,6,6-pentamethyl- 4-piperidyl)sebacate, bis(1 -octyloxy-2,2,6,6-tetramethyl -4-piperidyl)sebacate, bis(1,2,2,6,6- pen tarn ethyl -4-pi peridy I) n- butyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, thecondensate of l-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4- piperidyl)hexamethylenediamine and 4-tert-octy lamino-2,6-dich loro-1, 3,5-triazine,tris (2,2,6,6-tetramethy 1-4-piperidyl) nitrilotriacetate, tetra kis (2,2,6,6-tetra methyl -4-pi peridy I)-1,2,3,4-butanetetracarboxy I ate, 1,1'-(1,2-ethanediyl)-bis (3,3,5,5-tetrame-thyl pi perazino ne), 4-benzoy I-2,2,6,6-tetra methyl pi peridi ne, 4-stearyloxy-2,2,6,6-tetram ethyl pi peridi ne, bis(l,2,2,6,6-pentamethylpiperidyl)-2-n-butyl-2-(2-hydroxy-3,5-di- tert-butyl benzyl) ma Ion ate, 3-n-octyl-7,7,9,9-tetramethyl-l,3,8-triazaspiro[4.5]decane-2,4- dione, bis(l-octyloxy-2,2,6,6-tetra methyl pi peridy I)sebacate, bis(l-octyloxy-2,2,6,6-tetramethylpiperidyl)succinate, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl- 4-piperidyl)hexamethylenediamine and 4-morpholino-2,6-dichloro-l, 3,5-triazine, the condensate of 2-chIoro-4, 6-bis(4-n-butylamino-2,2,6,6-tetramethyl piperidyI) -1,3,5-triazine and l,2-bis(3-aminopropylamino)ethane, the condensate of 2-chloro-4,6-di-(4-n- butylamino- 1,2,2,6,6-penta methyl pi peridy I)-1,3,5-triazine and l,2-bis(3-a mi no propyl ami no) ethane, 8-acety I-3-dodecyl -7,7,9,9-tetra methyl -1,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecy I-l-(2,2,6,6-tetra methyl -4-pi peridy I) pyrrolidine- 2,5-dione, 3-dodecyl-l-(l,2,2,6,6-pentamethyl-4-piperidyl)pyrrolidine-2,5-dione, a mixture of 4-hexadecyloxy- and 4-stearyloxy-2,2,6,6-tetramethylpiperidine, a condensate of N,N'- bis(2,2,6,6-tetra methy I-4-pi peridy I) hexa methylenediamine and 4-cyc 10 hexyl a mi no-2, 6- dichloro-1, 3,5-triazine, a condensate of l,2-bis(3-aminopropylamino)ethane and 2,4,6- trichloro-1, 3,5-triazine and 4-butylamino-2,2,6,6-tetramethylpiperidine; N-(2,2,6,6- WO 2022/096356 PCT/EP2021/079940 41 tetram ethy I-4-pi peridy I)-n-dodecyl succinimide, N-(l,2,2,6,6-pentamethyl-4-piperidyl)-n- dodecylsuccinimide, 2-undecyl-7,7,9,9-tetramethyl-l-oxa-3,8-diaza-4-oxo-spiro[4,5]decane, a reaction product of 7,7,9,9-tetramethyl-2-cycloundecyl-l-oxa-3,8-diaza-4-oxospiro- [4,5]decane and epichlorohydrin, l,l-bis(l,2,2,6,6-pentamethyl-4-piperidyloxycarbonyl)-2- (4-meth oxy phenyl) ethene, N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, a diester of 4-methoxymethylenemalonic acid with l,2,2,6,6-pentamethyl-4-hydroxypiperidine, poly[methylpropyl-3-oxy-4-(2,2,6,6-tetramethyl- 4-piperidyl)]siloxane, a reaction product of maleic acid anhydride-a-olefin copolymer with 2,2,6,6-tetramethyl-4-aminopiperidine or l,2,2,6,6-pentamethyl-4-aminopiperidine, 2,4- bis[N-(l-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl)-N-butylamino]-6-(2-hydroxyethyl)amino-l,3,5-triazine, 5 -(2-ethy I hexanoy I) oxy methyl -3,3,5-tri methyl -2-morpholinone, Sanduvor, 5-(2-ethylhexanoyl)oxymethyl-3,3,5-trimethyl-2-morpholinone, the reaction product of 2,4-bis[(l-cyclohexyloxy-2,2,6,6-piperidine-4-yl)butylamino]-6-chloro-s- triazine with N,N’-bis(3-aminopropyl)ethylenediamine), l,3,5-tris(N-cyclohexyl-N-(2,2,6,6- tetramethylpiperazine-3-one-4-yl)amino)-s-triazine, l,3,5-tris(N-cyclohexyl-N-(l,2,2,6,6- pentamethylpiperazine-3-one-4-yl)amino)-s-triazine, and mixtures thereof.
In a preferred embodiment, the light stabilizer is condensate of l-(2-hydroxyethyl)-2,2,6,6- tetramethyl-4-hydroxypiperidine and succinic acid.
In another aspect, the presently claimed invention is directed to a composition comprising: I. an organic material, and II. a stabilizer mixture as defined above.
In an embodiment, the weight ratio of the organic material to the stabilizer mixture is in the range of 0.005:10%, preferably 0.005:5 %, more preferably 0.01:2.5 %, and most preferably 0.05:2 %, relative to the weight of the organic material.
The individual components of the present stabilizer mixture may be added to the organic material to be stabilized either individually or mixed with one another. They can be added to a polymer before, during or after the polymerization or before or after the crosslinking.
The composition according to the present invention or its individual components can be incorporated into the organic materia to be stabilized by known methods, for example before or during shaping or by applying the dissolved or dispersed stabilizer to the organic material, if necessary, with subsequent evaporation of the solvent. The stabilizers can be added to the organic material in the form of a powder, granules or a masterbatch, which contains said stabilizers in, for example, a concentration of from 2.5 to 90%, preferably 2.5 to 25%, by weight.
WO 2022/096356 PCT/EP2021/079940 42 Examples of processing or transformation of the materials stabilized according to the present invention are: Injection blow molding, extrusion, blow molding, rotomolding, in mold decoration (back injection), slush molding, injection molding, co-injection molding, forming, compression molding, pressing, film extrusion (cast film; blown film), fiber spinning (woven, non-woven), drawing (uniaxial, biaxial), annealing, deep drawing, calandering, mechanical transformation, sintering, coextrusion, coating, lamination, crosslinking (radiation, peroxide, silane), vapor deposition, weld together, glue, vulkanization, thermoforming, pipe extrusion, profile extrusion, sheet extrusion; sheet casting, spin coating, strapping, foaming, recycling / rework, extrusion coating, visbreaking (peroxide, thermal), fibre melt blown, spun bonded, surface treatment (corona discharge, flame, plasma), sterilization (by gamma rays, electron beams), cast polymerization (R&M process, RAM extrusion), gel-coating, tape extrusion, GMT- process, SMC-process, plastisol, and dipping (PVC, latex).
Additive (A) In an embodiment, the composition further comprising at least one additive (A) selected from antioxidants, UV absorber, slip agents, anti-block agents, thermal fillers, pigments, anti-fog agents, anti-mist agents and additional additives (B). 1. Antioxidants 1.1. Alkylated monophenols, for example 2,6-di-tert-butyl-4-methylphenol, 2-tert-butyl-4,6- dimethylphenol, 2,6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-4-n-butylphenol, 2,6-di- tert-butyl-4-isobuty I phenol, 2,6-dicyclopenty I-4-methyl phenol, 2-( a - methyl cyclohexyl) -4,6- dimethylphenol, 2,6-dioctadecyl-4-methylphenol, 2,4,6-tricyclohexylphenol, 2,6-di-tert-butyl- 4-methoxymethylphenol, nonylphenols which are linear or branched in the side chains, for example, 2,6-di-nonyl-4-methylphenol, 2,4-dimethyl-6-(l'-methylundec-l'-yl)phenol, 2,4- dimethyl-6-(l'-methylheptadec-l'-y I) phenol, 2,4-d i methy I-6-(1'-methyl tridec-l'-y I) ph eno and mixtures thereof. 1.2. Alkylthiomethylphenols, for example 2,4-dioctylthiomethyl-6-tert-butylphenol, 2,4- dioctylthiomethyl-6-methy I phenol, 2,4-dioctylthiomethyl-6-ethyl phenol, 2,6-di-dodecylthiomethyl -4-nonyl ph eno I. 1.3. Hydroquinones and alkylated hydroquinones , for example 2,6-di-tert-butyl-4-methoxy- phenol, 2,5-di-tert-butylhydroquinone, 2,5-di-tert-amylhydroquinone, 2,6-diphenyl-4-octade- cyloxyphenol, 2,6-di-tert-butylhydroquinone, 2,5-di-tert-butyl-4-hydroxyanisole, 3,5-di-tert- butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxypheny stearate, bis(3,5-di-tert-butyl-4- hydroxyphenyl) adipate. 1.4. Tocopherols , for example a-tocopherol, /3-tocopherol, y-tocopherol, 5-tocopherol and mixtures thereof (vitamin E).
WO 2022/096356 PCT/EP2021/079940 43 1.5. Hydroxylated thiodiphenyl ethers , for example 2,2'-thiobis(6-tert-butyl-4-methylphenol), 2,2'-thiobis(4-octylphenol), 4,4'-thiobis(6-tert-butyl -3-methyl phen 01), 4,4'-thiobis(6-tert- butyl-2-methyl phen 01), 4,4'-thiobis(3,6-di-sec-amylphenol), 4,4'-bis(2,6-dimethyl-4- hydroxy phenyl) disulfide. 1.6. Alkylidenebisphenols, for example 2,2'-methylenebis(6-tert-butyl-4-methylphenol), 2,2'- methylenebis(6-tert-butyl-4-ethylphenol), 2,2'-methylenebis[4-methyl-6-( a - methylcyclo hexyl) phenol], 2,2'-methylenebis(4-methyl-6-cyclohexylphenol), 2,2'- methylenebis(6-nonyl-4-methylphenol), 2,2'-methylenebis(4,6-di-tert-butylphenol), 2,2'- ethy I idenebis(4,6-di-tert-buty I phenol), 2,2'-ethylidenebis(6-tert-butyl-4-isobutylphenol),2,2'-methylenebis[6-( a - methyl benzyl) -4-nonyl phen 01], 2,2'-methylenebis[6-( a , ct -di methyl benzyl) -4-nonyl phen 01], 4,4'-methylenebis(2,6-di-tert-butylphenol), 4,4'- m ethy Ie nebis(6-tert-butyl -2-methyl phen 01), 1,1-bis (5-tert-butyl -4-hydroxy-2-methyl phenyl) butane, 2,6-bis (3-tert-butyl -5-methyl -2 -hydroxy benzyl) -4-methyl phen 01,1,1,3-tris (5-tert-butyl -4-hydroxy-2-methyl phenyl) butane, 1,1-bis(5-tert-butyl-4-hydroxy-2- methyl-phenyl)-3-n-dodecylmercaptobutane, ethylene glycol bis[3,3-bis(3'-tert-butyl-4'- hydroxypheny I) butyrate], bis (3-tert-buty I-4-hydroxy-5- met hyl -phenyl) dicyclopentadiene,bis[2-(3'-tert-butyI -2'-hydroxy-5'-methyl benzy I)-6-tert-buty I-4-methyl phenyl]terephthalate, 1,1-bis-(3,5-di methyl -2-hydroxy phenyl) butane, 2,2-bis(3,5-di-tert-butyl-4-hydroxyphe-nyl) propane, 2,2 - bis(5-tert-buty I-4-hyd roxy2 - m ethy I ph eny I)-4-n-dodecyl mercapto butane, 1,1,5,5-tetra-(5-tert-buty I-4-hydroxy-2-methyl phenyl) penta ne. 1.7. 0-, N- and S-benzyl compounds , for example 3,5,3',5'-tetra-tert-butyl-4,4'-dihydroxydi- benzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzylmercaptoacetate, tridecyl-4-hydroxy- 3,5-di-tert-buty I benzyl mercaptoacetate, tris(3,5-di-tert-butyl-4-hyd roxybenzyl)a mine, bis(4- tert-buty I-3-hydroxy-2,6-di methyl benzy I) dithioterephthalate, bis(3,5-di-tert-butyl-4-hyd roxybenzyl) sulfide, isooctyl-3,5-di-tert-buty I-4-hydroxy benzy I mercaptoacetate. 1.8. Hydroxybenzylated malonates , for example dioctadecyl-2,2-bis(3,5-di-tert-butyl-2-hy- d roxybenzyl) ma Ion ate, di-octadecyl-2-(3-tert-butyl-4-hydroxy-5-methylbenzyl)malonate, di- dodecyl mercaptoethyl -2,2-bis (3,5-di-tert-butyl -4-hydroxy benzy I) ma Ion ate, bis[4-(l,l,3,3-te- tramethylbutyl)phenyl]-2,2-bis(3,5-di-tert-butyl-4-hydroxybenzyl)malonate. 1.9. Aromatic hydroxybenzyl compounds, for example l,3,5-tris(3,5-di-tert-butyl-4-hydroxy- benzyl)-2,4,6-tri methyl benzene, l,4-bis(3,5-di-tert-butyl-4-hydroxybenzyl)-2,3,5,6-tetrame- thyl benzene, 2,4,6-tris (3,5-di-tert-buty I-4-hydroxy benzy I) pheno I. 1.10. Triazine compounds , for example 2,4-bis(octylmercapto)-6-(3,5-di-tert-butyl-4- hydroxyanilino)-l,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hyd roxyani lino)- 1,3,5-triazine, 2-octylmercapto-4,6-bis(3,5-di-tert-butyl-4-hydroxyphenoxy)-l,3,5-triazine, 2,4,6-tris(3,5-di-tert-butyl-4-hydroxyphenoxy)-l,2,3-triazine, 1,3,5-tris (3,5-di-tert-buty I-4- hydroxy benzy I) isocyan urate, 1,3,5-tris (4-tert-buty I-3-hydroxy-2, 6- WO 2022/096356 PCT/EP2021/079940 44 dimethyl benzyl) isocyan urate, 2,4,6-tris(3,5-d i-tert-buty I -4-hydroxy phenylethyl) -1,3,5-triazine, 1,3,5-tris(3,5-d i-tert-buty 1-4-hydroxy phenyl propionyl)-hexahydro-1, 3,5-triazine,1,3,5-tris (3,5-dicyclo hexyl -4-hydroxy benzyl) isocyanurate. 1.11. Benzylphosphonates , for example dimethyl-2,5-di-tert-butyl-4-hydroxybenzylphospho- nate, diet hyl -3,5-di-tert-buty I-4-hydroxy benzyl phosphonate, dioctadecyl3,5-di-tert-butyl-4- hydroxybenzyI phosphonate, dioctadecyl-5-tert-butyl-4-hydroxy-3-methylbenzylphosphonate, the calcium salt of the monoethyl ester of 3,5-di-tert-butyl-4- hydroxybenzylphosphonic acid. 1.12. Acylaminophenols , for example 4-hydroxylauranilide, 4-hydroxystearanilide, octyl N- (3,5-d i-tert-buty I-4-hydroxy phenyl) carbamate. 1.13. Esters of 3 -(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid with mono- or p01yhydric alcohols, for example with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6- hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, tri methylol pro pa ne, 4-hydroxymethyl-l-phospha-2,6,7-trioxabicyclo[2.2.2]octane. 1.14. Esters of 3 -(5-tert-butyl-4-hydroxy-3-methylphenyl)propionic acid with mono- or poly- hydric alcohols, for example with methanol, ethanol, n-octanol, i-octanol, octadecanol, 1,6- hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'-bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, tri methylol pro pa ne, 4-hydroxymethyl-l-phospha-2,6,7-trioxabicyclo[2.2.2]octane; 3,9-bis [2- {3-(3-tert-buty 1-4-hydroxy-5-methyl phenyl) propionyloxy}-l,l-dimethylethy I]-2,4,8,10- tetraoxaspiro [5.5] undeca ne. 1.15. Esters of 3 -(3,5-dicyclohexyl-4-hydroxyphenyl)propionic acid with mono- or polyhydric alcohols, for example with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9- nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'- bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, tri methylol pro pa ne, 4-hydroxymethyl-l-phospha-2,6,7-trioxabicyclo[2.2.2]octane. 1.16. Esters of 3,5-di-tert-butyl-4-hydroxypheny acetic acid with mono- or polyhydric alco- hols, for example with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9- nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris(hydroxyethyl)isocyanurate, N,N'- bis(hydroxyethyl)oxamide, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, tri methylol pro pa ne, 4-hydroxymethyl-l-phospha-2,6,7-trioxabicyclo[2.2.2]octane.
WO 2022/096356 PCT/EP2021/079940 45 1.17. Amides of /3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid, for example N,N'- bis(3,5-di-tert-buty I-4-hydroxy phenyl propionyl) hexamethylenediamide, N,N'-bis (3,5-di-tert- butyl-4-hydroxy phenyl propionyl) tri methylenediamide, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenyl propionyl) hydrazide, N,N'-bis[2-(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyloxy)ethyl]oxamide (Naugard®XL-l, supplied by Uniroyal). 1.18. Ascorbic acid (vitamin C) 1.19. Aminic antioxidants, for example N,N'-di-isopropyl-p-phenylenediamine, N,N'-di-sec- butyl-p-phenylenediamine, N,N'-bis(l,4-dimethyl pentyl) -p-phenylenediami ne, N,N'-bis(l- ethy I-3 - methy I penty I)-p-phenylenediamine, N,N'-bis(l- methyl hepty I)-p-phenylenediamine, N,N'-dicyclohexyl-p-phenylenediamine, N,N '-di phenyl -p-phenylenediami ne, N,N'-bis(2- naphthyl)-p-phenylenediami ne, N - isopro py I-N'-phenyl -p-phenylenediami ne, N-(l,3-di methyl butyl)-N'-phenyl-p-phenylenediamine, N-(l-methylheptyl)-N'-phenyl-p-phenylenediamine, N-cycl ohexy I -N'-phenyl -p-phenylenediami ne, 4-(p-toluenesulfamoyl) di phenyl a mi ne, N,N'-di methy I-N,N'-di-sec-butyl-p-phenylenediamine,diphenylamine, N-allyldiphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1- naphthylamine, N-(4-tert-octyl phenyl) -1-naphthylamine, N-phenyl-2-naphthylamine, octylated diphenylamine, for example p,p'-di-tert-octyldiphenylamine, 4-n-butylaminophenol, 4-butyrylaminophenol, 4-nonanoylaminophenol, 4-dodecanoylaminophenol, 4- octadeca noy I am inop hen 01, bis (4-methoxy phenyl)amine, 2,6-d i-tert-butyl-4-di methyl a mi no- methylphenol, 2,4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, N,N,N',N'-tetra- m ethy I-4,4'-diami nodiphenyl methane, l,2-bis[(2-methylphenyl)amino] ethane, 1,2-bis(phenylamino)propane, (o-tolyl)biguanide, bis[4-(r,3'-dimethylbutyl)phenyl]amine, tert- octylated N-phenyl-l-naphthylamine, a mixture of mono- and dialkylated tert-butyl/tert- octyldiphenylamines, a mixture of mono- and dialkylated nonyldiphenylamines, a mixture of mono- and dialkylated dodecyldiphenylamines, a mixture of mono- and dialkylated isopropyl/isohexyldiphenylamines, a mixture of mono- and dialkylated tert- butyldiphenylamines, 2,3-dihydro-3,3-dimethyl-4H-l,4-benzothiazine, phenothiazine, a mixture of mono- and dialkylated tert-butyl/tert-octylphenothiazines, a mixture of mono- and dialkylated tert-octyl-phenothiazines, N-allylphenothiazine, N,N,N',N'-tetraphenyl-l,4- diaminobut-2-ene. 2. UV absorbers and light stabilizers The composition may comprise UV absorbers, in addition to those disclosed above. 2.1. Esters of substituted and unsubstituted benzoic acids , for example 4-tert-butyl-pheny salicylate, phenyl salicylate, octylphenyl salicylate, dibenzoyl resorcinol, bis(4-tert-butylben- zoyl)resorcinol, benzoyl resorcinol, 2,4-di-tert-butylphenyl 3,5-di-tert-butyl-4-hydroxybenzo- ate, hexadecyl 3,5-di-tert-butyl-4-hydroxybenzoate, octadecyl 3,5-di-tert-butyl-4- hydroxy benzoate, 2-methy I-4,6-di-tert-butyl phenyl 3,5-di-tert-butyl -4-hydroxy benzoate.
WO 2022/096356 PCT/EP2021/079940 46 2.2. Acrylates , for example ethyl a -cyano-/? ,3 -diphenylacrylate, isooctyl a -cyano- 3,3 ־ diphenylacrylate, methyl a-carbomethoxycinnamate, methyl a -cyano- 3 -methyl-p- methoxycinnamate, butyl a-cyano-/3-methyl-p-methoxy-cinnamate, methyl a- carbomethoxy-p-methoxycinnamate, N-(/3 -carbomethoxy-/3 -cyanovinyl)-2-methylindoline, neopentyl tetra( a -cyano- 3 -3 -di phenyl aery I ate. 2.3. Nickel compounds, for example nickel complexes of 2,2'-thio-bis[4-(l,l,3,3-tetramethyl- butyl)phenol], such as the 1:1 or 1:2 complex, with or without additional ligands such as n- butylamine, triethanolamine or N-cyclohexyldiethanolamine, nickel dibutyldithiocarbamate, nickel salts of the monoalky esters, e.g. the methyl or ethyl ester, of 4-hydroxy-3,5-di-tert- butylbenzylphosphonic acid, nickel complexes of ketoximes, e.g. of 2-hydroxy-4-methylphe- nylundecylketoxime, nickel complexes of l-phenyl-4-lauroyl-5-hydroxypyrazole, with or with- out additional ligands. 2.4. Oxamides, for example 4,4'-dioctyloxyoxanilide, 2,2'-diethoxyoxanilide, 2,2'-dioctyloxy- 5,5'-di-tert-butoxanilide, 2,2'-didodecyloxy-5,5'-di-tert-butoxanilide, 2-ethoxy-2'-ethyloxani- Iide, N,N'-bis(3-dimethylaminopropyl)oxamide, 2-ethoxy-5-tert-butyl-2'-ethoxanilide and its mixture with 2-ethoxy-2'-ethyl-5,4'-di-tert-butoxanilide, mixtures of 0- and p-methoxy- disubstituted oxanilides and mixtures of 0- and p-ethoxy-disubstituted oxanilides.
Additive (B) 3. Metal deactivators , for example N,N'-diphenyloxamide, N-salicylal-N ’-salicyloyl hydrazine, N,N'-bis(salicyloyl)hydrazine, N,N'-bis(3,5-di-tert-butyl-4-hydroxyphenyl propionyl) hydrazine, 3-salicyloylamino-l,2,4-triazole, bis(benzylidene)oxaly dihydrazide, oxanilide, isophthaloyl dihydrazide, sebacoyl bisphenylhydrazide, N,N'- diacetyladipoyl dihydrazide, N,N'-bis(salicyloyl)oxalyl dihydrazide, N,N'- bis (sa I icy I oy I) th io p ro piony I di hydrazide. 4. Phosphites and phosphonites, for example triphenyl phosphite, diphenylalkyl phosphites, phenyldialkyl phosphites, tris(nonylphenyl) phosphite, trilauryl phosphite, trioctadecyl phos- phite, distearylpentaerythritol diphosphite, tris(2,4-di-tert-butylphenyl) phosphite, diisodecy pentaerythritol diphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(2,4- di-cumyl phenyl) pentaerythritol di ph os phite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythrito diphosphite, diisodecyloxypentaerythritol diphosphite, bis(2,4- di-tert-butyl -6-methyl phenyl) pentaerythritol di phosph Ite, bis(2,4,6-tris(tert-butylphenyl)pentaerythritol diphosphite, tristearyl sorbitol triphosphite, tetrakis(2,4-di-tert- butylphenyl) 4,4'-biphenylene diphosphonite, 6-isooctyloxy-2,4,8,10-tetra-tert-butyl-12H- d i be nz[d,g]- 1,3,2-dioxa phosphocin, bis (2,4-di-tert-butyl -6-methyl phenyl) methyl phosphite, bis(2,4-di-tert-butyl-6-methylphenyl)ethyl phosphite, 6-fIuoro-2, 4,8,10-tetra-tert-butyl -12- methyl-dibenz[d,g]-l,3,2-dioxaphosphocin, 2,2', 2"-nitri 10 [triethyl tris (3,3', 5,5'-tetra-tert-buty I-1,1'-bi phenyl -2,2'-diyI) phosphite], 2-ethylhexyl(3,3',5,5'-tetra-tert-butyl-l,l'-biphenyl- WO 2022/096356 PCT/EP2021/079940 47 2,2'-diy I) phosphite, 5-butyl-5-ethyl-2-(2,4,6-tri-tert-butylphenoxy)-l,3,2-dioxaphosphirane, phosphorous acid, mixed 2,4-bis(l,l-dimethylpropyl)phenyl and 4-(l,l-dimethylpropyl) phenyl triesters (CAS: 939402-02-5)., phosphorous acid, triphenyl ester, polymer with a- hydro-cu-hydroxypoly[oxy(methyl-l,2-ethanediyl)], C10-16-alkyl esters (CAS: 1227937-46- 3).
The following phosphites are especially preferred: Tris(2,4-di-tert-butylphenyl) phosphite, tris(nonylphenyl) phosphite, (D) WO 2022/096356 PCT/EP2021/079940 O^ /^0x(F) O-P Y P-O-C18H37(G) . Hydroxylamines, for example N,N-dibenzylhydroxylamine, N,N-diethylhydroxylamine, N,N- dioctylhydroxylamine, N,N-dilaurylhydroxylamine, N,N-ditetradecylhydroxylamine, N,N- di hexadecyl hydroxy la mi ne, N,N-dioctadecyl hydroxy I ami ne, N-hexadecyl-N-octadecylhydrox- ylamine, N-heptadecyl-N-octadecylhydroxylamine, N,N-dialkylhydroxylamine derived from hydrogenated tallow amine. 6. Nitrones, for example, N-benzyl-alpha-phenylnitrone, N-ethyl-alpha-methylnitrone, N-octyl-alpha-heptyl nitrone, N-lauryl-alpha-undecy I nitrone,tridecyl n nitrone, N-hexadecyl-alpha-pentadecyl nitrone,heptadecyl nitro ne, N-hexadecyl-a Ip ha-heptadecyl nit rone,pentadecyl nitro ne, N-heptadecyl-alpha-heptadecyl nitrone, N-tetradecyl-alpha-N-octadecyl-alpha-N-ocatadecyl-alpha-N-octadecyl-alpha-hexadecylnitrone, nitrone derived from N,N-dialkylhydroxylamine derived from hydrogenated tallow amine. 7. Thiosynergists , for example dilauryl thiodipropionate, dimistryl thiodipropionate, disteary thiodipropionate or distearyl disulfide. 8. Peroxide scavengers , for example esters of (3 -thiodipropionic acid, for example the lauryl, stearyl, myristyl or tridecyl esters, mercaptobenzimidazole or the zinc salt of 2-mercapto- benzimidazole, zinc dibutyldithiocarbamate, dioctadecyl disulfide, pentaerythritol tetrakis(b- dodecyl mercapto) pro pion ate. 9. Polyamide stabilizers , for example copper salts in combination with iodides and/or phos- phorus compounds and salts of divalent manganese.
. Basic co-stabilizers , for example melamine, polyvinylpyrrolidone, dicyandiamide, trially cyanurate, urea derivatives, hydrazine derivatives, amines, polyamides, polyurethanes, alkali metal salts and alkaline earth metal salts of higher fatty acids, for example calcium stearate, zinc stearate, magnesium behenate, magnesium stearate, sodium ricinoleate and potassium palmitate, antimony pyrocatecholate or zinc pyrocatecholate. 11. Nucleating agents , for example inorganic substances, such as talcum, metal oxides, such as titanium dioxide or magnesium oxide, phosphates, carbonates or sulfates of, preferably, alkaline earth metals; organic compounds, such as mono- or polycarboxylic acids and the WO 2022/096356 PCT/EP2021/079940 49 salts thereof, for example 4-tert-butylbenzoic acid, adipic acid, diphenylacetic acid, sodium succinate or sodium benzoate; polymeric compounds, such as ionic copolymers (ionomers). Especially preferred are l,3:2,4-bis(3’,4’-dimethylbenzylidene)sorbitol, 1,3:2,4- di (pa ram ethyldi benzyl ide ne) sorbitol, and 1,3:2,4-di (benzyl ide ne) sorbitol. 12. Fillers and reinforcing agents, for example calcium carbonate, silicates, surface treated silica (as described e.g. in US-A-2007/60,697 and US-A-2009/111,918), glass fibres, glass beads, asbestos, talc, kaolin, mica, barium sulfate, metal oxides and hydroxides, carbon black, graphite, wood flour and flours or fibres of other natural products, synthetic fibres. 13. Other additives , for example plasticisers, lubricants, emulsifiers, pigments, rheology additives, catalysts, flow-control agents, optical brighteners, flameproofing agents, antistatic agents and blowing agents. 14. Benzofuranones and indolinones , for example those disclosed in U.S. 4,325,863; U.S. 4,338,244; U.S. 5,175,312; U.S. 5,216,052; U.S. 5,252,643; DE-A-4316611; DE-A-4316622; DE-A-4316876; EP-A-0589839, EP-A-0591102; EP-A-1291384 or 3-[4-(2- acetoxyethoxy) phenyl] -5,7-di-tert-butyl benzofuran -2-one, 5,7-di-tert-butyl-3-[4-(2-stearoyloxyethoxy) phenyl] benzofuran -2-one, 3,3'-bis [5,7-di-tert-butyl -3-(4-[2-hydroxyethoxy] phenyl) benzofuran -2-one], 5,7-d I-te rt-bu ty I-3 -(4-ethoxy phenyl) benzofuran- 2-0 ne, 3-(4-acetoxy-3,5-di methyl phenyl) -5,7-di-tert-butyl benzofuran -2-one, 3-(3,5-di methyl -4-pivaloyloxy phenyl) -5,7-di-tert-butyl benzofuran -2-one, 3-(3,4-di methyl phenyl)- 5,7-di-tert-butyl benzofuran -2-0 ne, 3-(2,3-di methyl phenyl) -5,7-di-tert-butyl benzofuran -2- one, 3-(2-acetyl-5-isooctylphenyl)-5-isooctylbenzofuran-2-one.
In another aspect, the presently claimed invention is directed to an article comprising the composition as described above.
In an embodiment, the article is a monolayer film or a multilayer film of three to twelve layers, having a total thickness of 100 to 300 microns, preferably 120 to 220 microns, more preferably 150 to 180 microns, most preferably 160 microns.
The multilayer film contains at least one compound (A) in at east one layer, and at least one compound of the UV absorber and a compound of the at least one metal hydroxide independently in another layers.
Such a multilayer film is typically made of three, five, seven, nine or eleven layers. This can lead to a film structure like (A-3)-(B-l)-(B-2)-(C-l)-(C-2), (A-3)-(B-l)-(B-2)-(C-l)-(C-3), (A- 3)-(B-3)-(A-2)-(B-l)-(B-2)-(C-l)-(C-2), and (A-3)-(B-3)-(A-4)-(B-l)-(B-2)-(C-l)-(C-2). Compounds such as (A-3), (B-3), (A-4), (B-l), (B-2), (C-l), and (C-2) are described in the examples.
WO 2022/096356 PCT/EP2021/079940 50 However, adjacent layers can also be coupled so that the final film article can be made of an even number of layers, i.e. two, four, six, eight, ten or twelve layers such as (A-3)-(B-l)-(B- 2)-(C-l), (A-3)-(B-l)-(B-2)-(C-2), and (A-3)-(B-l)-(B-2)-(C-2) and the like.
In a preferred embodiment, the article is a greenhouse film cover, mulch film, artificial turfs, or geomembrane.
In a more preferred embodiment, the greenhouse film cover, mulch film, artificial turf, or geomembrane is in contact with an agrochemical compound or bleaching agent.
In another aspect, the present invention is directed to a use of the stabilizer mixture for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having the chlorine content in the range of 100 to 600 ppm.
In an embodiment, the stabilizer mixture is used for stabilizing an organic material by reducing degradation induced by light, heat, or oxidation.
The organic materials stabilized according to this invention is used in a wide variety of forms, for example as films, fibres, tapes, moulding compositions, profiles or as binders for paints, adhesives or putties.
In more detail, the organic materials stabilized according to the present invention may be used for the preparation of the following devices: 1-1) Automotive applications, in particular bumpers, dashboards, battery, rear and front linings, moldings parts under the hood, hat shelf, trunk linings, interior linings, air bag covers, electronic moldings for fittings (lights), panes for dashboards, headlamp glass, instrument panel, exterior linings, upholstery, automotive lights, head lights, parking lights, rear lights, stop lights, interior and exterior trims; door panels; gas tank; glazing front side; rear windows; seat backing, exterior panels, wire insulation, profile extrusion for sealing, cladding, pillar covers, chassis parts, exhaust systems, fuel filter / filler, fuel pumps, fuel tank, body side mouldings, convertible tops, exterior mirrors, exterior trim, fasteners / fixings, front end module, glass, hinges, lock systems, luggage / roof racks, pressed/stamped parts, seals, side impact protection, sound deadener / insulator and sunroof. 1-2) Devices for plane, railway, motor car (car, motorbike) including furnishings. 1-3) Devices for space applications, in particular rockets and satellites, e.g. reentry shields. 1-4) Devices for architecture and design, mining applications, acoustic quietized systems, street refuges, and shelters. 11-1) Electric appliances, in particular washing machines, tumblers, ovens (microwave oven), dishwashers, mixers, and irons. 11-2) Foils for condensers, refrigerators, heating devices, air conditioners, encapsulating of electronics, semi-conductors, coffee machines, and vacuum cleaners.
WO 2022/096356 PCT/EP2021/079940 51 lll-l) Technical articles such as cogwheel (gear), slide fittings, spacers, screws, bolts, handles, and knobs.
III-2) Rotor blades, ventilators and windmil vanes, solar devices, swimming pools, swimming poo covers, poo liners, pond liners, closets, wardrobes, dividing walls, slat walls, folding walls, roofs, shutters (e.g. roller shutters), fittings, connections between pipes, sleeves, and conveyor belts.
III-3) Profiles of any geometry (window panes) and siding.
III-4) Glass substitutes, in particular extruded plates, glazing for buildings (monolithic, twin or multiwall), aircraft, schools, extruded sheets, window film for architectural glazing, train, transportation, sanitary articles, and greenhouse.
III-5) Plates (walls, cutting board), extrusion-coating (photographic paper, tetrapack and pipe coating), silos, wood substitute, plastic lumber, wood composites, walls, surfaces, furniture, decorative foil, floor coverings (interior and exterior applications), flooring, duck boards, and tiles.
III-6) Cement-, concrete-, composite-applications and covers, siding and cladding, hand rails, banisters, kitchen work tops, roofing, roofing sheets, tiles, and tarpaulins.
IV-1) Plates (walls and cutting board), trays, artificial grass, astroturf, artificial covering for stadium rings (athletics), artificial floor for stadium rings (athletics), and tapes.
V-l) Plastic films in general (packaging, dump, laminating, swimming pools covers, waste bags, wallpaper, stretch and shrink wrap, raffia, desalination film, batteries, and connectors).
V -2) Agricultural films (greenhouse covers, tunnel, mulch, silage, bale wrap), especially in presence of intensive application of agrochemicals having high chlorine content.
V l-l) Food packing and wrapping (flexible and solid), BOPP, BOPET, bottles.
V I-2) Cartridges, syringes, medical applications, containers for any transportation, waste baskets and waste bins, waste bags, bins, dust bins, bin liners, wheely bins, container in general, tanks for water / used water / chemistry / gas / oil / gasoline / diesel; tank liners, boxes, crates, battery cases, troughs, medical devices such as piston, ophthalmic applications, diagnostic devices, and packing for pharmaceuticals blister.
Vll-l) Devices of filled polymers (talc, chalk, china clay (kaolin), wollastonite, pigments, carbon black, TiO2, mica, nanocomposites, dolomite, silica, silicates, glass, asbestos).
The presently claimed invention offers one or more of following advantages: WO 2022/096356 PCT/EP2021/079940 52 1. The multilayer film prepared in accordance with the method of the present invention exhibits high stability by reducing degradation induced by the high level of chlorine containing compounds. 2. The multilayer film prepared with the stabilizer mixtures of the present invention exhibit a substantial improvement in the elongation at break property of the film. 3. The articles prepared in accordance with the present invention are stable and has long lasting application by reducing degradation induced by the high level of chlorine containing compounds, hence use of these articles are economic.
In the following, specific embodiments of the presently claimed invention are described: 1. A method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture comprising: (i) at least one compound (A) selected from general formula (I), genera formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C1-C12 alkyl, 0!-012 alkyloxy, substituted or unsubstituted C5-C12 cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), WO 2022/096356 PCT/EP2021/079940 or H3C CH, CH3z C h3 A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and is an integer in the range of 1 to 20 and the repeating units are the same or different, compound (A) of general formula (II) wherein x! and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) a O—C-----& wherein is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or unsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii) at least one metal hydroxide. 2. The method according to embodiment 1, wherein the organic material is selected from inear low-density polyethylene, low-density polyethylene, high density polyethylene, ethylene-vinyl acetate copolymer, ethylene-butyl acrylate copolymer, polypropylene homopolymer and polypropylene copolymer. 3. The method according to embodiment 1, wherein the organic material is selected from inear low-density polyethylene, low-density polyethylene, high density polyethylene, ethylene-vinyl acetate copolymer, and ethylene-butyl acrylate copolymer. 4. The method according to embodiment 1, wherein the chlorine containing compound is selected from an agrochemical compound and a bleaching agent.
. The method according to embodiment 1, wherein A! is selected from linear or branched, substituted or unsubstituted C2-C8 alkylene and substituted or unsubstituted cyclohexylene, A2 is independently selected from H, linear or branched, substituted or unsubstituted C!-C8 alkyl, C1-C12alkyloxy, substituted or unsubstituted cyclohexyl and cyclohexyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted 0!-08 alkyl or a group of the formula (a-1) or A3 and A4, together with the nitrogen atom to which they are bonded, form a morpholinyl group, and a is an integer in the range of 1 to 10.
WO 2022/096356 PCT/EP2021/079940 55 6. The method according to one or more of embodiments 1 to 5, wherein the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), general formula (II), genera formula (III), general formula (IV), and mixtures thereof compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7 cycloalkylene and C1-C4alkylenedi(C 5-C7cyclo alkylene), A2 is independently selected from linear or branched, substituted orunsubstituted C!-C12 alkyloxy, and substituted or unsubstituted C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c chN—A2(a-1) ch3z c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (II) WO 2022/096356 PCT/EP2021/079940 (II) wherein x!and x 2 is independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, - compound (A) of general formula (III) (III) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and - compound (A) of general formula (IV) (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, WO 2022/096356 PCT/EP2021/079940 57 Y3 is independently selected from linear or branched, substituted or unsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber, and (iii) at least one metal hydroxide. 7. The method according to one or more of embodiments 1 to 6, wherein the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), genera formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18alkylene, substituted or unsubstituted C5-C7 cycloalkylene, and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted 0!-012 alkyl, and substituted or unsubstituted C5-C12 cycloalkyl, A3 and A4 are independently selected from H, linear or branched, substituted or unsubstituted C1-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch3 ch3 c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and WO 2022/096356 PCT/EP2021/079940 58 a is an integer in the range of 1 to 20 and the repeating units arethe same or different, compound (A) of general formula (II) (II) wherein x!and x 2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) (HI) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted orunsubstituted C3 to C20 alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii) at least one metal hydroxide. 8. The method according to one or more of embodiments 1 to 7, wherein the compound (A) is at east one compound selected from the formula (A-l), (A-2), (A-3), (A-4), (A-5), (A-6), (A-7), and (A-8) (A-l), N H9C4-N------------------------------------- N--------- (CH2)6----- N----- N^,N J. ־؛ c، J ־ h ؛ JLJ N --------- --------------------------- N—C4Hg N^,N .CHa T H3Cj}zCH3 ■CHa N-C4H9h3C/ WO 2022/096356 PCT/EP2021/079940 (A-2), (A-3) wherein a is an integer in the range of 1 to 10, (A-4), WO 2022/096356 PCT/EP2021/079940 (A-6) WO 2022/096356 PCT/EP2021/079940 (A-7), and (A-8) wherein n is 2. 9. The method according to one or more of embodiments 1 to 7, wherein the compound (A) is a compound of formula (A-9) WO 2022/096356 PCT/EP2021/079940 wherein a is an integer in the range of 1 to 10.
. A stabilizer mixture comprising: (i) at least one compound (A) selected from the general formula (A-l), general for-mula (A-2), general formula (A-4), general formula (A-5), general formula (A-6), general formula (A-7), and general formula (A-8) (A-l), (A-2), (A-4), WO 2022/096356 PCT/EP2021/079940 (A-5); (A-6) WO 2022/096356 PCT/EP2021/079940 (A-7), and (A-8) wherein n is 2, (ii) at least one UV absorber; and (iii)at least one metal hydroxide. 11. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to embodiment 10, wherein the at least one UV absorber is selected from 2-(2'-hydroxy phenyl )benzotriazo les, 2-hydroxy benzophenones, 2-(2-hydroxy phenyl)-1,3,5-triazines and mixtures thereof. 12. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to embodiments 10 or 11, wherein the 2-(2'-hydroxyphenyl)benzotriazole is WO 2022/096356 PCT/EP2021/079940 66 selected from 2-(2H-benzotriazol-2-yl)-4,6-bis(l-methyl-l-phenylethyl)phenol, 2-(2'- hydroxy-5'-methyl phenyl)-benzotriazole, 2 - (3', 5'-di-tert-butyl -2'-hydroxy phenyl) ben-zotriazole, 2 - (5'-tert-buty I-2'-hydroxy phenyl) benzotriazo Ie, 2-(2'-hydroxy-5'- (1,1,3,3- tetramethylbutyl)phenyl)benzotriazole, 2 - (3', 5'-di-tert-butyl -2'-hydroxy phenyl) -5-ch loro-benzotriazo le,2-(3'-tert-butyl -2'-hydroxy-5'-methyl phenyl) -5-ch I oro-benzotria- zole, 2-(3'-sec-buty I-5'-tert-butyl -2'-hydroxy phenyl) benzotriazole, 2-(2'-hydroxy-4'-oc- tyloxy phenyl) benzotriazole, 2 - (3', 5'-di-tert-a my I-2'-hydroxyphenyl) benzotriazole, 2-(3',5'-bis-(a , a -di methyl benzyl) -2'-hydroxy phenyl )ben zotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-octy I oxycar bony I ethyl) phenyl) -5-chloro-benzotriazole, 2-(3'-tert-butyl- 5'-[2-(2-ethylhexyloxy)-carbonylethyl]-2'-hydroxyphenyl)-5-chloro-benzotriazole, 2- (3'-tert-butyl-2'-hydroxy-5'-(2-methoxycarbonylethyl) phenyl)-5-chloro-benzotriazole, 2-(3'-tert-butyl -2'-hydroxy-5'- (2-meth oxycar bony I ethyl) phenyl) benzotriazo Ie, 2-(3'-tert-butyl -2'-hydroxy-5'- (2-octyl oxycarbonylethyl) phenyl) benzotriazole, 2-(3'-tert-bu- ty I-5'-[2-(2-ethyl hexyloxy) car bony I ethyl] -2'-hydroxy phenyl) benzotriazo Ie, 2-(3'-do-decy I-2'-hydroxy-5'-methyl phenyl) benzotriazole, 2-(3'-tert-butyl-2'-hydroxy-5'-(2-iso- octyl oxycarbonylethyl) phenyl benzotriazo Ie, 2,2'-methylene-bis[4-(l,l,3,3-tetramethyl- butyl)-6-benzotriazole-2-ylphenol]; the transesterification product of 2-[3'-tert-butyl- 5'-(2 - m ethoxyca rbonyl ethyl) -2'-hydroxy phenyl] -2 H-benzotriazole with polyethylene glycol 300; [r—CH2CH2—COO-CH2CH29־— , where R = 3'-tert-butyl-4'-hydroxy-5'- 2H-benzotriazol-2-ylphenyl, 2-[2'-hydroxy-3'-(ct , a -dimethylbenzyl)-5'-(l,l,3,3-tetra- methyl butyl)-phenyl] benzotriazole; and 2-[2'-hydroxy-3'-(l, 1,3,3-tetra methyl butyl)-5'-( a , a -dimethylbenzyl)-phenyl]benzotriazole, and mixtures thereof. 13. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 12, wherein the 2-hydroxybenzophe- none is selected from 4-hydroxy, 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4- benzyloxy, 4,2',4'-trihydroxy, 2'-hydroxy-4,4'-dimethoxy derivatives and mixtures thereof. 14. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 13, wherein the 2-(2-hydroxyphenyl)- 1,3,5-triazine is selected from 2,4,6-tris(2-hydroxy-4-octyloxyphenyl)-l,3,5-triazine, 2- (2-hydroxy-4-octyloxyphenyl)-4,6-bis(2,4-dimethyl phenyl)-1,3,5-triazine, 2-(2,4-dihy- droxyphenyI) -4,6-bis(2,4-dimethyl phenyl) -1,3,5-triazine, 2,4-bis(2-hydroxy-4-pro-py I-!oxy phenyl) -6-(2,4-di methyl phenyl)-1,3,5-triazine, 2-(2-hydroxy-4-octyloxyphenyl)- 4,6-bis(4-methy I phenyl)-1,3,5-triazine, 2-(2-hydroxy-4-dodecyloxyphenyl)-4,6-bis(2,4- di methyl phenyl) -1,3,5-triazine, 2-(2-hydroxy-4-tridecyloxyphenyl)-4,6-bis(2,4-dime-thy I phenyl) -1,3,5-triazine, 2-[2-hydroxy-4- (2-hydroxy-3-butyl oxy pro poxy) phenyl] -4,6- bis(2,4-dimethyl)-1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3- WO 2022/096356 PCT/EP2021/079940 67 octyloxypropyloxy)phenyl]-4,6-bis(2,4-dimethyl)-l,3,5-triazine, 2-[4-(do-decyloxy/tridecyloxy-2-hyd roxy propoxy) -2-hydroxy phenyl] -4,6-bis (2,4-di me- thy I phenyl) -1,3,5-triazine, 2-[2-hydroxy-4-(2-hydroxy-3-dodecyloxypropoxy)phenyl]-4,6-bis(2,4-di methyl phenyl)-l,3,5-triazi ne, 2-(2-hydroxy-4-hexyl oxy) phenyl-4,6-diphe- nyI -1,3,5-triazine, 2-(2-hydroxy-4-methoxyphenyl)-4,6-diphenyl-l,3,5-triazine, 2,4,6- tris [2-hydroxy-4-(3-butoxy-2-hydroxy pro poxy) phenyl] -1,3,5-triazine, 2-(2-hydroxy-phenyl)-4-(4-methoxyphenyl)-6-phenyl-l,3,5-triazine, 2-{2-hydroxy-4- [3-(2-ethyl hexy 1-1-oxy) -2-hyd roxy propyloxy]phenyl}-4, 6-bis(2,4-di-! methyl phenyl)-!, 3,5-tri- azine, 2,4-bis(4-[2-ethy I hexyl oxy] -2-hydroxy phenyl)-6-(4-methoxyphenyl)-l,3,5-tria- zine, 2,4-bis(4-biphenylyl)-6-[2-hydroxy-4-(2-ethylhexyloxy)phenyl] -1,3,5-triazine, Do- decanedioic acid, l,12-bis[2-[4-(4,6-diphenyl-l,3,5-triazin-2-yl)-3-hydroxyphenoxy] ethyl] ester and mixtures thereof.
. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 14, wherein the at east one metal hy- droxide is selected from hydrotalcite and magnesium hydroxide. 16. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of claims 10 to 15, wherein the hydrotalcite is selected from magnesium aluminum hydroxide carbonate hydrate, and zinc aluminum hydroxide car- bonate hydrate. 17. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 16, wherein the weight ratio of the at east one compound (A) to the at least one UV absorber is in the range of 1:1 to 20:1. 18. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 17, wherein the weight ratio of the at east one compound (A) to the at least one metal hydroxide is in the range of 1:10 to 10:1. 19. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 18, wherein the weight ratio of the at east one UV absorber to the at least one metal hydroxide is in the range of 10:1 to 1:20.
. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 19, wherein the stabilizer mixture further comprises at least one light stabilizers. 21. The method according to one or more of embodiments 1 to 9 or the stabilizer mixture according to one or more of embodiments 10 to 20, wherein the light stabilizer is se- ected from bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, bis(2,2,6,6-tetramethyl-4-pi- peridy I) succinate, bis(l,2,2,6,6-penta methyl -4-piperidyl)sebacate, bis (1-octyl oxy- WO 2022/096356 PCT/EP2021/079940 68 2,2,6,6-tetra methy I-4-pi peridy I) sebacate, bis (1,2,2,6,6-penta methyl -4-piperidyl) n-bu- tyl-3,5-di-tert-butyl-4-hydroxybenzylmalonate, the condensate of l-(2-hydroxyethyl)- 2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4-tert-octyla- mino-2,6-dichloro-l,3,5-triazine, tris (2,2,6,6-tetra methyl -4-piperidyl) nitrilotriacetate,tetra kis (2,2,6,6-tetra methyl -4-pi peridy I)-1,2,3,4-butanetetracar boxy I ate, 1,1'-(1,2-ethanediyl)-bis(3,3,5,5-tetrame-thylpiperazinone), 4-benzoy I-2,2,6,6-tetra methyl pi per- idine, 4-steary I oxy-2,2,6,6-tetra methy I pi peridi ne, bis (1,2,2,6,6-penta methyl piperidyl)- 2-n-butyl-2-(2-hydroxy-3,5-di-tert-butylbenzyl)malonate, 3-n-octyl-7,7,9,9-tetrame- thyl-l,3,8-triazaspiro [4.5]decane-2,4-dione, bis(1-octyloxy-2, 2,6,6-tetra methyl pi-peridyl)sebacate, bis(l-octyloxy-2,2,6,6-tetramethylpiperidyl)succinate, linear or cyclic condensates of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine and 4- morpholino-2,6-dichloro-l,3,5-triazine, the condensate of 2-chloro-4,6-bis(4-n-butyla- mino-2,2,6,6-tetramethylpiperidyl)-l,3,5-triazine and l,2-bis(3-aminopropyla- mino)ethane, the condensate of 2-chloro-4,6-di-(4-n-butylamino-l,2,2,6,6-pentame- thylpiperidyl)-l,3,5-triazine and l,2-bis(3-aminopropylamino)ethane, 8-acetyl-3-do- decyl-7,7,9,9-tetramethyl-l,3,8-triazaspiro[4.5]decane-2,4-dione, 3-dodecyl-l- (2,2,6,6-tetra methyl-4-pi peridy I) pyrrol id ine-2,5-d io ne, 3-dodecyl-l -(1,2,2,6,6-pen-tamethyl-4-piperidyl)pyrrolidine-2,5-dione, a mixture of 4-hexadecyloxy- and 4-stea- ryloxy-2,2,6,6-tetramethylpiperidine, a condensate of N,N'-bis(2,2,6,6-tetramethyl-4-pi- peridyl)hexamethylenediamine and 4-cyclohexylamino-2,6-dichloro-l,3,5-triazine, a condensate of l,2-bis(3-aminopropylamino)ethane and 2,4,6-trichloro-l,3,5-triazine and 4-butyl am in 0-2,2,6,6-tetra methyl pi peridi ne;; N-(2,2,6,6-tetramethyl-4-piperidyl)- n-dodecylsuccinimide, N-(1,2,2,6,6-pentamethyI -4-piperidyI)-n-dodecylsuccinimide, 2- undecyl-7, 7,9,9-tetramethyl-l-oxa-3,8-diaza-4-oxo-spiro[4,5]decane, a reaction prod- uct of 7,7,9,9-tetramethyl-2-cycloundecyl-l-oxa-3,8-diaza-4-oxospiro-[4,5]decane and epichlorohydrin, 1,1-bis (1,2,2,6,6-penta methy I-4-pi peridy I oxycarbonyl) -2-(4-meth oxy- phenyl) ethene, N,N'-bis-formyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexameth- ylenediamine, a diester of 4-methoxymethylenemalonic acid with 1,2,2,6,6-pentame- thyl-4-hydroxypi peridi ne, poly [methyl propyl-3-oxy-4-(2,2,6,6-tetramethyl-4-pi-peridyl)]siloxane, a reaction product of maleic acid anhydride- a -olefin copolymer with 2,2,6,6-tetra methy I-4-a mi nopiperidine or 1,2,2,6,6-penta m ethy I -4-a mi nopiperidine, 2,4-bis[N-(l-cyclohexyloxy-2,2,6,6-tetramethylpiperidine-4-yl)-N-butylamino]-6-(2- hydroxyethyl) a mi no- 1,3,5-triazine,, 5-(2-ethy I hexanoy I) oxy methy I-3,3,5-tri methy I-2-morpholinone, Sanduvor, 5 - (2-ethy I hexa noy l)oxy methy I-3,3,5-tri methy I-2 -mor pho-inone, the reaction product of 2,4-bis[(l-cyclohexyloxy-2,2,6,6-piperidine-4-yl)butyla- mino]-6-chloro-s-triazine with N,N’-bis(3-aminopropyl)ethylenediamine), l,3,5-tris(N- cyclohexyl-N-(2,2,6,6-tetramethylpiperazine-3-one-4-yl)amino)-s-triazine, 1,3,5- WO 2022/096356 PCT/EP2021/079940 69 tris(N-cyclohexyl-N-(l,2,2,6,6-pentamethylpiperazine-3-one-4-yl)amino)-s-triazine, and mixtures thereof. 22. A composition comprising: I. an organic material, and II. a stabilizer mixture according to one or more of embodiments 10 to 21. 23. The composition according to embodiment 22, further comprising at least one additive selected from the antioxidants, slip agents, anti-block agents, thermal fillers, pigments, anti-fog and anti-mist agents. 24. The composition according to embodiments 22 or 23, wherein the weight ratio of the organic material to the stabilizer mixture is in the range of 0.005:10%.
. An article comprising the composition according to one or more of embodiments 22 to 24. 26. The article according to embodiment 25, which is a monolayer film or a multilayer film of three to twelve layers. 27. The article according to embodiments 25 or 26, wherein the multilayer film contains at east one compound (A) as defined in embodiment 1 in at least one layer, and at least one compound of the UV absorber and a compound of the at least one metal hydroxide as defined in embodiment 1 independently in another layers. 28. The article according to one or more of embodiments 25 to 27, which is a greenhouse film cover, mulch film, artificial turfs, or geomembrane. 29. The article according to one or more of claim embodiments 25 to 28, wherein the green- house film cover, mulch film, artificial turf, or geomembrane is in contact with an agro- chemical compound or bleaching agent.
. Use of the stabilizer mixture according to one or more of embodiments 10 to 21 for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having the chlorine content in the range of 100 to 600 ppm. 31. The composition according to one or more of embodiments 22 to 24 or the use according to embodiment 30, wherein the organic material is selected from linear low-density pol- yethylene, low-density polyethylene, high density polyethylene, ethylene-vinyl acetate copolymer, ethylene-butyl acrylate copolymer, polypropylene homopolymer and poly- propylene copolymer, preferably linear low-density polyethylene, low-density polyeth- ylene, high density polyethylene, ethylene-vinyl acetate copolymer, and ethylene-buty acrylate copolymer.
WO 2022/096356 PCT/EP2021/079940 70 32. The use according to embodiments 30 or 31, wherein the chlorine containing compound is selected from an agrochemical compound, and a bleaching agent.
The following examples illustrate the invention in greater detail. All percentages and parts are by weight, unless stated otherwise.
EXAMPLES Compounds: Compound Bis(l- undecan oxy-2,2,6,6-tetra methyl pi peridin-4-y !)carbonate Compound (A-3) wherein a is an integer in the range of 1 to 10.
Compound (A-4): 1 - (2 - hydroxy-2- methyl pro poxy) -2,2,6,6-tetra methyl pi peridi ne-4-y I octadecenoate WO 2022/096356 PCT/EP2021/079940 71 Compound 2-(2'-hydroxy-5'- (1,1,3,3-tetra methyl butyl) phenyl) benzotriazo Ie Compound (B-2): 2,4-bis(4-biphenylyl)-6-[2-hydroxy-4-(2-ethylhexyloxy)phenyl] -1,3,5-triazine Compound (B-3): Condensate of l-(2-hydroxyethyl)-2,2,6,6-tetramethyl-4-hydroxypiperidine and succinic acid h3c ch3 N—CH2-CH2-OOC-CH2CH2-CO----- h3c ch3bwherein b is a number from 2 to 10.
Compound (C-l): (CAS number: 012304-65-3 or 11097-59-9) WO 2022/096356 PCT/EP2021/079940 72 Hydrotalcite (Magnesium aluminum hydroxide carbonate hydrate) Compound Magnifin H-5 IV (is aminosilane surface treated) (CAS number: 1309-42-8) Magnesium hydroxide Compound (C-3): Kisuma 10A (CAS number: 1309-42-8) Magnesium hydroxide A) Preparation of the film samples: Stabilization of LDPE (low density polyethylene) multi-layer films: Formulations containing LDPE powder (Polimeri Europa Riblene" FC 30, characterized by a density of 0.922 g/cm 3 and a melt flow index (190° C/2.16Kg) of 0.27 g/lOmin), 0.04% by weight, relative to the weight of the LDPE, of tris{2,4-di-tert-butyl phenyl} phosphite, 0.01% by weight, relative to the weight of the LDPE, of octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate and the stabilizer mixtures indicated in Tables 1 and 2, were prepared. The formulations were mixed in a turbo- mixer. Each formulation was extruded at a maximum temperature of 200° C in a lab-scale single-screw Collin extruder (0 42mm, L/D=25). Then, each final formulation was blown in a lab-scale Collin' " 5-layer blow-extruder (0 20-25-30mm, L/D 25), at a maximum temperature of 210° C, to give a 5-layer film having the same formulation in all layers. The overall thick- ness of the film was 160 p.m (50 p.m - 15 p.m - 30 p.m - 15 p.m - 50 ^m).
B) Test method A A bleach treatment was carried out on the prepared films before artificial weathering. Speci- mens of the films for each formulation were treated with sodium hypochlorite (NaCIO)-H 2O 1:4 solution for 24 hours at t=0 hours. The chlorine determination was performed immediately after the treatment and at every recall (every 1000 hours exposure in artificial weathering) to determine the next treatment. The chlorine content was determined using oxidative pyrolysis and coulometry.
WO 2022/096356 PCT/EP2021/079940 73 After the agrochemical treatment, the film specimens for each formulation were exposed in an Atlas Weather-O-Meter (WOM, as per ASTM G155, 0.35 W/m2 at 340 nm, dry cycle), for accelerated light weathering. Specimens of the film samples were taken at defined intervals of time after exposure and underwent tensile testing. The residual tensile strength was meas- ured, by means of a Zwick® Z1.0 constant velocity tensiometer (as per modified ISO 527), in order to evaluate the decay of the mechanical properties of the film samples, as a conse- quence of the polymer degradation after its oxidation.
The test results are listed in Tables 1 and 2.
Table 1: NOR HALS [Compound of (A-3)] and UV Package with and without Hydrotalcite Film samples contaminated with 400-500 ppm chlorine after each treatment and exposed in a WOM.
Stabilizer mixture (weight-% based on polymer composition)Time until retained elon- gation at break in hours is 50% of the initial valueExample (Comparative)0.55% of Compound (A-3)0.049% of Compound (B-l)0.015% of Compound (B-2)3489 Example 2 0.55% of Compound (A-3) 0.049% of Compound (B-l) 0.015% of Compound (B-2) 0.3% of Compound (C-l) 3724 Example 3 0.55% of Compound (A-3) 0.049% of Compound (B-l) 0.015% of Compound (B-2) 0.6% of Compound (C-l) 3713 Example 4 0.55% of Compound (A-3) 0.049% of Compound (B-l) 0.015% of Compound (B-2) 0.6% of Compound (C-2) 3831 Example 5 0.55% of Compound (A-3) 0.049% of Compound (B-l) 0.015% of Compound (B-2) 0.6% of Compound (C-3) 3857 Example 6 0.55% of Compound (A-3) 0.049% of Compound (B-l) 0.015% of Compound (B-2) 0.3% of Compound (C-l) 3827
Claims (19)
1. A method for stabilizing an organic material by reducing degradation induced by a chlorine containing compound having a chlorine content in the range of 100 to 600 ppm, wherein the method comprises incorporating into the organic material a stabilizer mixture com- prising: (i) at least one compound (A) selected from general formula (I), general formula (II), general formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7cyclo alkylene), A2 is independently selected from H, linear or branched, substitutedor unsubstituted C!-C12 alkyl, C!-C12 alkyloxy, substituted or un- substituted C5-C12cycloalkyl and C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substi- tuted or unsubstituted C!-C12alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch, ch3z c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units arethe same or different, WO 2022/096356 PCT/EP2021/079940 76 compound (A) of general formula (II) (II) wherein x!and x2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) (III) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, 10 Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) (IV) wherein WO 2022/096356 PCT/EP2021/079940 77 Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or un- substituted C3 to C20alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii) at least one metal hydroxide.
2. The method according to claim 1, wherein the organic material is selected from linear low- density polyethylene, low-density polyethylene, high density polyethylene, ethylene-viny acetate copolymer, ethylene-butyl acrylate copolymer, polypropylene homopolymer and polypropylene copolymer.
3. The method according to claims 1 or 2, wherein the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), general formula (II), gen- era formula (III), general formula (IV), and mixtures thereof compound (A) of general formula (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18 alkylene, substituted or unsubstituted C5-C7cycloalkylene and C1-C4alkylenedi(C 5-C7 cyclo alkylene), A2 is independently selected from linear or branched, substituted orunsubstituted C!-C12 alkyloxy, and substituted or unsubstituted C5-C12cycloalkyloxy, A3 and A4 are independently selected from H, linear or branched, substi- tuted or unsubstituted C!-C12alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), WO 2022/096356 PCT/EP2021/079940 78 h3c ch. CH3z C h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a 5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units are the same or different, compound (A) of general formula (II) o—c—& wherein x! and x2 is independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) wherein is linear or branched, substituted or unsubstituted linear or branched, substituted or unsubstituted C3 to C20 alkyl, 2is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) WO 2022/096356 PCT/EP2021/079940 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or un- substituted C3 to C20alkyl, and C3 to C20 alkylidene, X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber, and (iii)at least one meta hydroxide.
4. The method according to one or more of claims 1 to 3, wherein the stabilizer mixture comprises: (i) at least one compound (A) selected from general formula (I), general formula (II), genera formula (III), general formula (IV), and mixtures thereof, compound (A) of general formula (I) (I) wherein A! is selected from linear or branched, substituted or unsubstitutedC2-C18alkylene, substituted or unsubstituted C5-C7cycloalkylene, and C1-C4alkylenedi(C 5-C7 cyclo alkylene), WO 2022/096356 PCT/EP2021/079940 a2 A3and A4 80 is independently selected from H, linear or branched, substituted or unsubstituted 0!-012 alkyl, and substituted or unsubstituted C5-C12 cycloalkyl, are independently selected from H, linear or branched, substi- tuted or unsubstituted C!-C12 alkyl, substituted or unsubstituted C5-C12 cycloalkyl and a group of the formula (a-1), h3c ch3A_,CH c h3 or A3 and A4, together with the nitrogen atom to which they are bonded, form a5- to 10-membered heterocyclic ring; and a is an integer in the range of 1 to 20 and the repeating units are the same or different, compound (A) of general formula (II) x, o--c—& wherein x! and x2 are independently selected from linear or branched, substituted or unsubstituted C! to C30 alkyloxy, compound (A) of general formula (III) wherein WO 2022/096356 PCT/EP2021/079940 81 Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y2 is linear or branched, substituted or unsubstituted C! to C30 alkyl; and compound (A) of general formula (IV) 5 (IV) wherein Y! is linear or branched, substituted or unsubstituted C3 to C20alkyl, Y3 is independently selected from linear or branched, substituted or un- substituted C3 to C20alkyl, and C3 to C20 alkylidene, 10 X is linear or branched, substituted or unsubstituted C2 to C5 alkyl, n is an integer in the range of 1 to 8, and (ii) at least one UV absorber; and (iii)at least one metal hydroxide.
5. The method according to one or more of claims 1 to 4, wherein the compound (A) is at least one compound selected from the formula (A-l), (A-2), (A-3), (A-4), (A-5), (A-6), (A- 7), and (A-8) (A-l), WO 2022/096356 PCT/EP2021/079940 (A-2), (A-3) 5 wherein a is an integer in the range of 1 to 10, (A-4), WO 2022/096356 PCT/EP2021/079940 (A-6) WO 2022/096356 PCT/EP2021/079940 (A-7), and 5 (A-8) wherein n is 2.
6. The method according to one or more of claims 1 to 5, wherein the compound (A) is a compound of formula (A-9) WO 2022/096356 PCT/EP2021/079940 wherein a is an integer in the range of 1 to 10.
7. A stabilizer mixture comprising: 5 (i) at least one compound (A) selected from the general formula (A-l), general formula(A-2), general formula (A-4), general formula (A-5), general formula (A-6), genera formula (A-7), and general formula (A-8) (A-l), (A-2), (A-4), WO 2022/096356 PCT/EP2021/079940 (A-5); (A-6) WO 2022/096356 PCT/EP2021/079940 (A-7), and 5 (A-8) wherein n is 2, (ii) at least one UV absorber; and (iii)at least one metal hydroxide.
8. The method according to one or more of claims 1 to 6 or the stabilizer mixture according to claim 7, wherein the at least one UV absorber is selected from 2-(2'-hydroxy- phenyl) benzotriazoles, 2-hydroxy benzo phen ones, 2-(2-hydroxy phenyl) -1,3,5-triazines and mixtures thereof.
9.WO 2022/096356 PCT/EP2021/079940 88 9. The method according to one or more of claims 1 to 6 or the stabilizer mixture according to claims 7 or 8, wherein the at least one metal hydroxide is selected from hydrotalcite and magnesium hydroxide.
10. The method according to one or more of claims 1 to 6 or the stabilizer mixture according to one or more of claims 7 to 9, wherein the hydrotalcite is selected from magnesium alu- minum hydroxide carbonate hydrate, and zinc aluminum hydroxide carbonate hydrate.
11. The method according to one or more of claims 1 to 6 or the stabilizer mixture according to one or more of claims 7 to 10, wherein the weight ratio of the at least one compound (A) to the at least one UV absorber is in the range of 1:1 to 20:1, the weight ratio of the at east one compound (A) to the at least one metal hydroxide is in the range of 1:10 to 10:1, and the weight ratio of the at least one UV absorber to the at east one metal hydroxide is in the range of 10:1 to 1:20.
12. The method according to one or more of claims 1 to 6 or the stabilizer mixture according to one or more of claims 7 to 11, wherein the stabilizer mixture further comprises at least one light stabilizers.
13. A composition comprising: I. an organic material, and II. a stabilizer mixture according to one or more of claims 7 to 12.
14. The composition according to claim 13, further comprising at least one additive selected from the antioxidants, slip agents, anti-block agents, thermal fillers, pigments, anti-fog and anti-mist agents.
15. The composition according to claims 13 or 14, wherein the weight ratio of the organic ma- terial to the stabilizer mixture is in the range of 0.005:10%.
16. An article comprising the composition according to one or more of claims 13 to 15.
17. The article according to claim 16, which is a monolayer film or a multilayer film of three to twelve layers, wherein the multilayer film contains at least one compound (A) as defined in claim 1 in at least one layer, and at east one compound of the UV absorber and a com- pound of the at east one metal hydroxide as defined in claim 1 independently in another ayers.
18. The article according to claims 16 or 17, which is a greenhouse film cover, mulch film, artificial turfs, or geomembrane.
19. Use of the stabilizer mixture according to one or more of claims 7 to 12 for stabilizing an organic material by reducing degradation induced by a chlorine containing compound hav- Ing the chlorine content in the range of 100 to 600 ppm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20205384 | 2020-11-03 | ||
PCT/EP2021/079940 WO2022096356A1 (en) | 2020-11-03 | 2021-10-28 | Method for stabilizing an organic material using a stabilizer mixture |
Publications (1)
Publication Number | Publication Date |
---|---|
IL302430A true IL302430A (en) | 2023-06-01 |
Family
ID=73059534
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IL302430A IL302430A (en) | 2020-11-03 | 2021-10-28 | Method for stabilizing an organic material using a stabilizer mixture |
Country Status (10)
Country | Link |
---|---|
US (1) | US20230407050A1 (en) |
EP (1) | EP4240793A1 (en) |
JP (1) | JP2023548841A (en) |
KR (1) | KR20230100731A (en) |
CN (1) | CN116096803A (en) |
CA (1) | CA3197279A1 (en) |
IL (1) | IL302430A (en) |
MX (1) | MX2023005137A (en) |
TW (1) | TW202229445A (en) |
WO (1) | WO2022096356A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115558163B (en) * | 2022-11-17 | 2023-03-24 | 山东东临新材料股份有限公司 | Preparation method of composite heat stabilizer containing tris (glycidyl) isocyanurate |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2044272B (en) | 1979-02-05 | 1983-03-16 | Sandoz Ltd | Stabilising polymers |
US5175312A (en) | 1989-08-31 | 1992-12-29 | Ciba-Geigy Corporation | 3-phenylbenzofuran-2-ones |
TW206220B (en) | 1991-07-01 | 1993-05-21 | Ciba Geigy Ag | |
US5252643A (en) | 1991-07-01 | 1993-10-12 | Ciba-Geigy Corporation | Thiomethylated benzofuran-2-ones |
GB2267490B (en) | 1992-05-22 | 1995-08-09 | Ciba Geigy Ag | 3-(Carboxymethoxyphenyl)benzofuran-2-one stabilisers |
TW260686B (en) | 1992-05-22 | 1995-10-21 | Ciba Geigy | |
NL9300801A (en) | 1992-05-22 | 1993-12-16 | Ciba Geigy | 3- (ACYLOXYPHENYL) BENZOFURAN-2-ON AS STABILIZERS. |
MX9305489A (en) | 1992-09-23 | 1994-03-31 | Ciba Geigy Ag | 3- (DIHIDROBENZOFURAN-5-IL) BENZOFURAN-2-ONAS, STABILIZERS. |
TW255902B (en) | 1992-09-23 | 1995-09-01 | Ciba Geigy | |
TW593303B (en) | 2001-09-11 | 2004-06-21 | Ciba Sc Holding Ag | Stabilization of synthetic polymers |
US7781511B2 (en) | 2005-09-12 | 2010-08-24 | Milliken & Company | Silica-containing nucleating agent compositions and methods for using such compositions in polyolefins |
US7897663B2 (en) | 2007-10-25 | 2011-03-01 | Kuo Ching Chemical Co., Ltd. | Clarifying agent composition and manufacturing method thereof |
JP6953159B2 (en) * | 2017-03-29 | 2021-10-27 | バンドー化学株式会社 | Polyolefin resin film and laminate |
CN112771108B (en) * | 2018-08-22 | 2023-05-05 | 巴斯夫欧洲公司 | Stabilized rotomoulded polyolefin |
CA3122176A1 (en) * | 2018-12-21 | 2020-06-25 | Basf Se | A polypropylene composition |
-
2021
- 2021-10-28 CA CA3197279A patent/CA3197279A1/en active Pending
- 2021-10-28 US US18/035,176 patent/US20230407050A1/en active Pending
- 2021-10-28 CN CN202180054899.3A patent/CN116096803A/en active Pending
- 2021-10-28 WO PCT/EP2021/079940 patent/WO2022096356A1/en active Application Filing
- 2021-10-28 EP EP21794888.4A patent/EP4240793A1/en active Pending
- 2021-10-28 JP JP2023526501A patent/JP2023548841A/en active Pending
- 2021-10-28 MX MX2023005137A patent/MX2023005137A/en unknown
- 2021-10-28 IL IL302430A patent/IL302430A/en unknown
- 2021-10-28 KR KR1020237018345A patent/KR20230100731A/en unknown
- 2021-11-02 TW TW110140724A patent/TW202229445A/en unknown
Also Published As
Publication number | Publication date |
---|---|
EP4240793A1 (en) | 2023-09-13 |
CA3197279A1 (en) | 2022-05-12 |
KR20230100731A (en) | 2023-07-05 |
JP2023548841A (en) | 2023-11-21 |
CN116096803A (en) | 2023-05-09 |
US20230407050A1 (en) | 2023-12-21 |
MX2023005137A (en) | 2023-05-26 |
WO2022096356A1 (en) | 2022-05-12 |
TW202229445A (en) | 2022-08-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2921960C (en) | Triazine, piperidine and pyrrolidine based hindered amine light stabilizers | |
GB2387387A (en) | Ternary stabiliser mixture | |
JP7301747B2 (en) | light stabilizer mixture | |
IL302430A (en) | Method for stabilizing an organic material using a stabilizer mixture | |
EP3143082A1 (en) | Highly effective stabilizer | |
CA3167391A1 (en) | Light stabilizer mixture | |
CA3214135A1 (en) | Stabilizer mixture | |
CA3232003A1 (en) | Stabilizer formulation | |
WO2022122818A1 (en) | Additive mixtures | |
CA3226067A1 (en) | An additive mixture for stabilization of organic material | |
WO2022122868A1 (en) | An organic material based shaped article |