IL295499A - Aerosol-generating article with improved configuration - Google Patents
Aerosol-generating article with improved configurationInfo
- Publication number
- IL295499A IL295499A IL295499A IL29549922A IL295499A IL 295499 A IL295499 A IL 295499A IL 295499 A IL295499 A IL 295499A IL 29549922 A IL29549922 A IL 29549922A IL 295499 A IL295499 A IL 295499A
- Authority
- IL
- Israel
- Prior art keywords
- aerosol
- percent
- weight
- length
- millimetres
- Prior art date
Links
Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/10—Chemical features of tobacco products or tobacco substitutes
- A24B15/16—Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/14—Machines of the continuous-rod type
- A24C5/18—Forming the rod
- A24C5/1885—Forming the rod for cigarettes with an axial air duct
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/04—Cigars; Cigarettes with mouthpieces or filter-tips
- A24D1/042—Cigars; Cigarettes with mouthpieces or filter-tips with mouthpieces
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/18—Selection of materials, other than tobacco, suitable for smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
- A24D3/0275—Manufacture of tobacco smoke filters for filters with special features
- A24D3/0279—Manufacture of tobacco smoke filters for filters with special features with tubes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
- A24D3/043—Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F40/00—Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
- A24F40/20—Devices using solid inhalable precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Resistance Heating (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Chemical Vapour Deposition (AREA)
Description
WO 2021/170638 PCT/EP2021/054536 AEROSOL-GENERATING ARTICLE WITH IMPROVED CONFIGURATION The present invention relates to an aerosol-generating article comprising an aerosol- generating substrate and adapted to produce an inhalable aerosol upon heating.
Aerosol-generating articles in which an aerosol-generating substrat e,such as a tobacco-containing substrate, is heated rather than combusted, are known in the art .
Typically, in such heated smoking articles an aerosol is generate dby the transfe rof heat from a heat source to a physically separate aerosol-generating substrate or material, which may be located in contact with, within, around, or downstream of the heat source. During use of the aerosol-generating article, volatile compounds are released from the aerosol-generating substrate by heat transfe rfrom the heat source and are entrained in air drawn through the aerosol-generating article. As the released compounds cool, they condense to form an aerosol.
A number of prior art documents disclose aerosol-generating devices for consuming aerosol-generating articles. Such devices include, for example, electrically heated aerosol- generating devices in which an aerosol is generated by the transfe rof heat from one or more electrical heater elements of the aerosol-generating device to the aerosol-generating substrate of a heated aerosol-generating article. For example, electrically heated aerosol- generating devices have been proposed that comprise an internal heater blade which is adapted to be inserted into the aerosol-generating substrat e.As an alternative, inductively heatable aerosol-generating articles comprising an aerosol-generating substrate and a susceptor element arranged within the aerosol-generating substrate have been proposed by WO 2015/176898.
Aerosol-generating articles in which a tobacco-containing substrate is heated rather than combusted present a number of challenges that were not encountered with conventional smoking articles. First of all, tobacco-containing substrate ares typically heated to significantly lower temperatures compared with the temperatures reached by the combustion front in a conventional cigarette. This may have an impact on nicotine release from the tobacco- containing substrate and nicotine delivery to the consumer. At the same time, if the heating temperature is increased in an attempt to boost nicotine delivery, then the aerosol generated typically needs to be cooled to a greater extent and more rapidly before it reaches the consumer. However, technical solutions that were commonly used for cooling the mainstream smoke in conventional smoking articles, such as the provision of a high filtration efficiency segmen tat the mouth end of a cigarette, may have undesirable effect sin an aerosol- generating article wherein a tobacco-containing substrate is heated rather than combusted, as they may reduce nicotine delivery. Secondly, a need is generally felt for aerosol-generating articles that are easy to use and have improved practicality.WO 2021/170638 PCT/EP2021/054536 Therefore, it would be desirable to provide a new and improved aerosol-generating article adapted to achieve at least one of the desirable results described above. Further, it would be desirable to provide one such aerosol-generating article that can be manufactured efficientl yand at high speed ,preferably with a satisfactory RTD and low RTD variability from one article to another.
The present disclosure relates to an aerosol-generating article comprising a rod of aerosol-generating substrat e. The aerosol-generating article may further comprise a mouthpiece element having a length L1 and comprising at least one mouthpiece filter segment formed of a fibrous filtration material. The aerosol-generating article may comprise an intermediate hollow section between the rod of aerosol-generating substrate and the mouthpiece element, the intermediate hollow section having a length L2. The intermediate hollow section may comprise an aerosol-cooling element downstream of the rod of aerosol- generating substrat e.The aerosol-cooling element may comprise a hollow tubular segment defining a longitudinal cavity providing an unrestricted flow channel. The intermediate hollow section may further comprise a support element between the aerosol-cooling element and the rod of aerosol-generating substrat e.The length of the mouthpiece element (L1) may be at least 0.4 times the length of the intermediate hollow section (L2).
According to the present invention there is provided an aerosol-generating article for producing an inhalable aerosol upon heating, the aerosol-generating article comprising: a rod of aerosol-generating substrate; a mouthpiece element having a length L1 and comprising at least one mouthpiece filter segmen tformed of a fibrous filtration material ;and an intermediat e hollow section between the rod of aerosol-generating substrate and the mouthpiece element, the intermediate hollow section having a length L2. The intermediate hollow sectio n comprises: an aerosol-cooling element downstream of the rod of aerosol-generating substrat e,the aerosol-cooling element comprising a hollow tubular segment defining a longitudinal cavity providing an unrestricted flow channel; and a support element between the aerosol-cooling element and the rod of aerosol-generating substrate. According to the invention, the length of the mouthpiece element (L1) is at least 0.4 times the length of the intermediate hollow section (L2).
The term "aerosol-generating article" is used herein to denote an article wherein an aerosol-generating substrate is heated to produce an deliver inhalable aerosol to a consumer.
As used herein, the term "aerosol-generating substrate" denotes a substrate capable of releasing volatile compounds upon heating to generate an aerosol.
A conventional cigarette is lit when a user applies a flame to one end of the cigarette and draws air through the other end. The localised heat provided by the flame and the oxygen in the air drawn through the cigarette causes the end of the cigarette to ignite, and the resulting combustion generates an inhalable smoke. By contrast, in heated aerosol-generating articles, WO 2021/170638 PCT/EP2021/054536 an aerosol is generate dby heating a flavour generating substrat e,such as tobacco. Known heated aerosol-generating articles include, for example, electrically heated aerosol-generating articles and aerosol-generating articles in which an aerosol is generated by the transfe ofr heat from a combustible fuel element or heat source to a physically separate aerosol forming material. For example, aerosol-generating articles according to the invention find particular application in aerosol-generating systems comprising an electrically heated aerosol- generating device having an internal heater blade which is adapted to be inserted into the rod of aerosol-generating substrate. Aerosol-generating articles of this type are described in the prior art, for example, in EP 0822670.
As used herein, the term "aerosol-generating device" refers to a device comprising a heater element that interacts with the aerosol-generating substrate of the aerosol-generating article to generate an aerosol.
As used herein with reference to the present invention, the term "rod" is used to denote a generally cylindrical element of substantially circular, oval or elliptical cross-section.
As used herein, the term "longitudinal" refers to the directio ncorresponding to the main longitudinal axis of the aerosol-generating article, which extends between the upstream and downstream ends of the aerosol-generating article. As used herein, the terms "upstream" and "downstream" describe the relative positions of elements, or portions of elements, of the aerosol-generating article in relation to the direction in which the aerosol is transported through the aerosol-generating article during use.
During use, air is drawn through the aerosol-generating article in the longitudinal direction. The term "transverse" refers to the direction that is perpendicular to the longitudinal axis. Any reference to the "cross-section" of the aerosol-generating article or a component of the aerosol-generating article refers to the transvers ecross-section unless stated otherwise.
The term "length" denotes the dimension of a component of the aerosol-generating article in the longitudinal direction. For example, it may be used to denote the dimension of the rod or of the elongate tubular elements in the longitudinal direction.
The aerosol-generating article according to the present invention provides an improved configuration of the elements downstream of the rod of aerosol-generating substrate, which is defined by having a ratio of the length of the mouthpiece element to the length of the intermediate hollow section of at least 0.4. This ratio reflects a configuration in which a relatively long mouthpiece element is provided in combination with a shorter intermediate hollow section than has been previously provided. In particularly preferred embodiments of the present invention, the improved configuration provides a relatively long mouthpiece element in combination with a shorter aerosol-cooling element than has been previously provided.WO 2021/170638 PCT/EP2021/054536 The provision of an intermediate hollow section having a reduced length decrease sthe distance between the rod of aerosol-generating substrate and the mouthpiece element. In the aerosol-generating articles according to the present invention, the reduced length of the intermediate hollow section is typically achieved by providing a relatively short aerosol-cooling element. This reduction in the length of the aerosol-cooling element compared to known aerosol-cooling elements is made possible due to the constructio nof the aerosol-cooling element in the form of a hollow tubular segment. The hollow tubular segment provides an internal cavity with a relatively high volume, which achieves highly effective cooling and nucleation of the aerosol during use. Sufficient cooling and nucleation of the aerosol can therefor ebe provided over a relatively short distance such, to that the length of the aerosol- cooling element can be shorter than has been typically possible with other constructions of the aerosol-cooling element.
By decreasing the distance between the rod of aerosol-generating substrate and the mouthpiece element whilst at the same time increasing the length of the mouthpiece elemen t it has been found to be possible to provide a more rigid mouthpiece in the aerosol-generating article according to the invention. The aerosol-generating article is therefore able to provide a greater resistance to radial compression at a location towards the downstream end of the article. Advantageously, this benefit can be provided without affecting the overall length of the article, such that a total length that is consisten witht existing aerosol-generating articles can be maintained.
The provision of a more rigid mouthpiece has been found to contribute to a more efficient puffing action by the consumer, such that the delivery of aerosol can be optimised. In addition, by providing a more rigid mouthpiece proximal to the aerosol-cooling element, the risk of deformation of the aerosol-cooling element during use can be significantly reduced. This is important, since deformation of the aerosol-cooling element is undesirable due to the adverse impact that such a deformation may have on aerosol formation.
The mouthpiece element is typically more resilient to deformation than the other elements provided downstream of the rod of aerosol-generating substrat e.Increasing the length of the mouthpiece element relative to the length of the intermediate hollow section has therefor ebeen found to provide for improved grip by the consumer. The insertion of the aerosol-generating article into a heating device is also facilitated.
The increase in the length of the mouthpiece element relative to the length of the intermediate hollow section provides severa lother technical benefits .The longer mouthpiece element may be used to provide higher filtration and removal of undesirable aerosol constituents such as phenols, so that a higher quality aerosol can be delivered. In addition, the use of a longer mouthpiece element enables a more complex mouthpiece to be provided WO 2021/170638 PCT/EP2021/054536 since there is more space for the incorporation of mouthpiece components such as capsules, threads and restrictors.
A decrease in the length of the hollow intermediate sectio nrelative to the mouthpiece element may advantageously be provided by reducing the length of the aerosol-cooling element, as described in more detail below. The aerosol-cooling element typically has a lower resistance to deformation than the mouthpiece. The reduction of the length of the aerosol- cooling element therefore further reduces the risk of deformation of the aerosol-generating article due to compression during use. Furthermore, the reduction of the length of the aerosol- cooling element may provide a cost benefit to the manufacturer since the cost of a hollow tubular segmen tis typically higher per unit length than the cost of a mouthpiece element.
In accordance with the present invention there is provided an aerosol-generating article for generating an inhalable aerosol upon heating. The aerosol-generating article comprises a rod of aerosol-generating substrate. The aerosol-generating article further comprises a downstream sectio nat a location downstream of the rod of aerosol-generating substrat e.The downstream section may comprise one or more downstream elements.
In the aerosol-generating article according to the present invention, the downstream section comprises a mouthpiece element. The mouthpiece element may extend all the way to a mouth end of the aerosol-generating article. The downstream sectio nfurther comprises an intermediate hollow section between the mouthpiece element and the rod of aerosol- generating substrat e.The intermediate hollow section comprises a support element and an aerosol-cooling element. The aerosol-cooling element comprises a hollow tubular segment.
The support element may also comprise a hollow tubular segment.
As used herein, the term "hollow tubular segment" is denotes a generally elongate element defining a lumen or airflow passage along a longitudinal axis thereof . In particular, the term "tubular" will be used in the following with reference to a tubular element having a substantially cylindrical cross-section and defining at least one airflow conduit establishing an uninterrupted fluid communication between an upstream end of the tubular element and a downstream end of the tubular element. However, it will be understood that alternative geometries (for example, alternative cross-sectional shapes) of the tubular segmen tmay be possible. The hollow tubular segmen tis an individual, discrete element of the aerosol- generating article which has a defined length and thickness.
As used herein, the term "elongate" means that an element has a length dimension that is greater than its width dimension or its diameter dimension, for example twice or more its width dimension or its diameter dimension.
In the context of the present invention a hollow tubular segmen tprovides an unrestricted flow channel. This means that the hollow tubular segment provides a negligible level of resistance to draw (RTD). The flow channel should therefore be free from any WO 2021/170638 PCT/EP2021/054536 components that would obstruct the flow of air in a longitudinal direction. Preferably, the flow channel is substantially empty.
In some embodiments, the aerosol-generating article may comprise a ventilation zone at a location along the downstream section. In more detail ,the aerosol-generating article may comprise a ventilation zone at a location along the aerosol-cooling element. In preferred embodiments, the aerosol-cooling element comprises or is in the form of a hollow tubular segment, the ventilation zone being provided at a location along the hollow tubular segment of the aerosol-cooling element.
The aerosol-generating article may further comprise an upstream section at a location upstream of the rod of aerosol-generating substrat e.The upstream section may comprise one or more upstream elements. In some embodiments, the upstream sectio nmay comprise an upstream element arranged immediately upstream of the rod of aerosol-generating substrate.
The aerosol-generating article may further comprise a susceptor element within the aerosol-generating substrate. In some embodiments, the susceptor element may be an elongate susceptor element. In preferred embodiments, the susceptor element extend longitudinally within the aerosol-generating substrate.
These elements of the aerosol-generating article will be described in furthe rdetail below.
As defined above, the downstream section of the aerosol-generating article of the present invention comprises a mouthpiece element. The mouthpiece element is preferably located at the downstream end or mouth end of the aerosol-generating article. The mouthpiece element comprises at least one mouthpiece filte rsegment of a fibrous filtration material for filtering the aerosol that is generated from the aerosol-generating substrate.
Suitable fibrous filtration materials would be known to the skilled person. Particularly preferably, the at least one mouthpiece filte rsegmen tcomprises a cellulose acetate filte r segmen tformed of cellulose acetate tow.
In certain preferred embodiments, the mouthpiece element consists of a single mouthpiece filter segment. In alternative embodiments, the mouthpiece element includes two or more mouthpiece filter segments axially aligned in an abutting end to end relationship with each other.
Preferably, the mouthpiece element comprises a mouthpiece filte rsegmen thaving a length that is at least about 0.4 times the length of the intermediate hollow section ,more preferably at least about 0.5 times the length of the intermediate hollow section, more preferably at least about 0.6 times the length of the intermediate hollow section and more preferably at least about 0.75 times the length of the intermediate hollow section.
In certain embodiments of the invention, the downstream sectio nmay comprise a mouth end cavity at the downstream end, downstream of the mouthpiece element asWO 2021/170638 PCT/EP2021/054536 -ד- described above. The mouth end cavity may be defined by a hollow tubular element provided at the downstream end of the mouthpiece. Alternatively, the mouth end cavity may be defined by the outer wrapper of the mouthpiece element, wherein the outer wrapper extends in a downstream direction from the mouthpiece element.
The mouthpiece element may optionally comprise a flavourant, which may be provided in any suitable form. For example, the mouthpiece element may comprise one or more capsules, beads or granules of a flavourant, or one or more flavour loaded threads or filaments.
According to the present invention, the downstream sectio nof the aerosol-generating article further comprises a support element located immediately downstream of the rod of aerosol-generating substrat e.The mouthpiece element is preferably located downstream of the support element. The downstream sectio nfurther comprises an aerosol-cooling elemen t located immediately downstream of the support element. The mouthpiece element is preferably located downstream of both the support element and the aerosol-cooling element.
Particularly preferably, the mouthpiece element is located immediately downstream of the aerosol-cooling element. By way of example, the mouthpiece element may abut the downstream end of the aerosol-cooling element.
Preferably, the mouthpiece element has a low particulate filtration efficiency.
Preferably, the mouthpiece element is circumscribed by a plug wrap. Preferably, the mouthpiece element is unventilated such that air does not enter the aerosol-generating article along the mouthpiece element.
The mouthpiece element is preferably connected to one or more of the adjacent upstream components of the aerosol-generating article by means of a tipping wrapper.
Preferably, the mouthpiece element has an RTD of less than about 25 millimetres H2O.
More preferably, the mouthpiece element has an RTD of less than about 20 millimetres H2O.
Even more preferably, the mouthpiece element has an RTD of less than about 15 millimetres H2O.
Values of RTD from about 10 millimetres H2O to about to about 15 millimetres H2O are particularly preferred because a mouthpiece element having one such RTD is expected to contribute minimally to the overall RTD of the aerosol-generating article substantially does not exert a filtration action on the aerosol being delivered to the consumer.
The mouthpiece elemen tpreferably has an external diameter that is approximately equal to the external diameter of the aerosol-generating article. The mouthpiece element may have an external diamete rof between about 5 millimetre sand about 10 millimetres, or between about 6 millimetres and about 8 millimetres. In a preferred embodiment, the mouthpiece element has an external diameter of approximately 7.2 millimetres.WO 2021/170638 PCT/EP2021/054536 The mouthpiece element preferably has a length of at least about 5 millimetres, more preferably at least about 8 millimetres, more preferably at least about 10 millimetres.
Alternatively or in addition, the mouthpiece element preferably has a length of less than about millimetres, more preferably less than about 20 millimetres, more preferably less than about 15 millimetres.
In some embodiments, the mouthpiece element preferably has a length from about 5 millimetres to about 25 millimetres, more preferably from about 8 millimetre sto about 25 millimetres, even more preferably from about 10 millimetres to about 25 millimetres. In other embodiments, the mouthpiece element preferably has a length from about 5 millimetres to about 10 millimetres, more preferably from about 8 millimetre sto about 20 millimetres, even more preferably from about 10 millimetres to about 20 millimetres. In further embodiments, the mouthpiece element preferably has a length from about 5 millimetre sto about 15 millimetres, more preferably from about 8 millimetres to about 15 millimetres, even more preferably from about 10 millimetres to about 15 millimetres.
For example, the mouthpiece element may have a length of between about 5 millimetres and about 25 millimetres, or between about 8 millimetres and about 20 millimetres, or between about 10 millimetre sand about 15 millimetres. In a preferred embodiment, the mouthpiece element has a length of approximately 12 millimetres.
In certain preferred embodiments of the invention, the mouthpiece elemen thas a length of at least 10 millimetres. In such embodiments, the mouthpiece element is therefor erelatively long compared to the mouthpiece element provided in prior art articles. The provision of a relatively long mouthpiece element in the aerosol-generating articles of the present invention may provide several benefits to the consumer. The mouthpiece elemen tis typically more resilient to deformation or better adapted to recover its initial shape after deformation than other elements that may be provided downstream of the rod of aerosol-generating substrate, such as an aerosol-cooling element or support element. Increasing the length of the mouthpiece element is therefore found to provide for improved grip by the consumer and to facilitate insertion of the aerosol-generating article into a heating device. A longer mouthpiece may additionally be used to provide a higher level of filtration and removal of undesirable aerosol constituent suchs as phenols, so that a higher quality aerosol can be delivered. In addition, the use of a longer mouthpiece element enables a more complex mouthpiece to be provided since there is more space for the incorporation of mouthpiece components such as capsules, threads and restrictors.
In particularly preferred embodiments of the invention, a mouthpiece element having a length of at least 10 millimetre sis combined with a relatively short aerosol-cooling element, for example, an aerosol-cooling element having a length of less than 10 millimetres. This combination has been found to provide a more rigid mouthpiece which reduces the risk of WO 2021/170638 PCT/EP2021/054536 deformation of the aerosol-cooling element during use and to contribute to a more efficient puffing action by the consumer.
In accordance with the present invention, the length of the mouthpiece element is at least 0.4 times the total length of the intermediate hollow section, preferably at least 0.5 times the length of the intermediate hollow section, more preferably at least 0.6 times the length of the intermediate hollow section ,more preferably at least 0.75 times the length of the intermediate hollow section. The ratio between the length of the mouthpiece element and the total length of the intermediate hollow section is therefore at least about 0.4, preferably at least about 0.5, more preferably at least about 0.6 and most preferably at least about 0.75.
A ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate may be from about 0.5 to about 1.5.
Preferably, a ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate is at least about 0.6, more preferably at least about 0.7, even more preferably at least about 0.8. In preferred embodiments, a ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate is less than about 1.4, more preferably less than about 1.3, even more preferably less than about 1.2.
In some embodiments, a ratio between the length of the mouthpiece elemen tand the length of the rod of aerosol-generating substrate is from about 0.6 to about 1.4, preferably from about 0.7 to about 1.4, more preferably from about 0.8 to about 1.4. In other embodiments, a ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate is from about 0.6 to about 1.3, preferably from about 0.7 to about 1.3, more preferably from about 0.8 to about 1.3. In further embodiments, a ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate is from about 0.6 to about 1.2, preferably from about 0.7 to about 1.2, more preferably from about 0.8 to about 1.2.
In a particularly preferred embodiments, a ratio between the length of the mouthpiece element and the length of the rod of aerosol-generating substrate is about 1.
A ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate may be from about 0.2 to about 0.35.
Preferably, a ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is at least about 0.22, more preferably at least about 0.24, even more preferably at least about 0.26. A ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is preferably less than about 0.34, more preferably less than about 0.32, even more preferably less than about 0.3.
In some embodiments, a ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about WO 2021/170638 PCT/EP2021/054536 0.34, more preferably from about 0.24 to about 0.34, even more preferably from about 0.26 to about 0.34. In other embodiments, a ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about 0.32, more preferably from about 0.24 to about 0.32, even more preferably from about 0.26 to about 0.32. In furthe rembodiments, a ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about 0.3, more preferably from about 0.24 to about 0.3, even more preferably from about 0.26 to about 0.3.
In a particularly preferred embodiment, a ratio between the length of the mouthpiece element and the overall length of the aerosol-generating article substrate is about 0.27.
As described above, the downstream sectio nof the aerosol-generating articles in accordance with the present invention further comprises an intermediate hollow sectio n comprising an aerosol-cooling element arranged in alignment with, and downstream of the rod of aerosol-generating substrate. The upstream end of the aerosol-cooling element may abut the downstream end of the support element.
The aerosol-cooling element is arranged substantially in alignment with the rod. This means that the length dimension of the aerosol-cooling element is arranged to be approximately parallel to the longitudinal direction of the rod and of the article, for example within plus or minus 10 degrees of parallel to the longitudinal directio nof the rod. In preferred embodiments, the aerosol-cooling element extends along the longitudinal axis of the rod.
In aerosol-generating articles in accordance with the present invention the aerosol- cooling element is in the form of a hollow tubular segmen tthat defines a cavity extending all the way from an upstream end of the aerosol-cooling element to a downstream end of the aerosol-cooling element. Preferably, a ventilation zone is provided at a location along the hollow tubular segment.
The inventors have found that a satisfactory cooling of the stream of aerosol generated upon heating the aerosol-generating substrate and drawn through one such aerosol-cooling element is achieved by providing a ventilation zone at a location along the hollow tubular segment. Further, the inventors have found that, as will be described in more detail below, by arranging the ventilation zone at a precisely defined location along the length of the aerosol- cooling element and by preferably utilising a hollow tubular segmen thaving a predetermined peripheral wall thickness or internal volume, it may be possible to counter the effect sof the increased aerosol dilution caused by the admission of ventilation air into the article.
Without wishing to be bound by theory, it is hypothesised that, because the temperature of the aerosol stream is rapidly lowered by the introduction of ventilation air as the aerosol is travelling towards the mouthpiece segment, the ventilation air being admitted into the aerosol stream at a location relatively close to the upstream end of the aerosol-cooling WO 2021/170638 PCT/EP2021/054536 element (that is, sufficiently close to the susceptor element extendin gwithin the rod of aerosol- generating substrat e,which is the heat source during use), a dramati ccooling of the aerosol stream is achieved, which has a favourable impact on the condensation and nucleation of the aerosol particles. Accordingly, the overall proportion of the aerosol particulate phase to the aerosol gas phase may be enhanced compared with existing, non-ventilated aerosol- generating articles.
At the same time, keeping the thickness of the peripheral wall of the hollow tubular segmen trelatively low ensures that the overall internal volume of the hollow tubular segment - which is made available for the aerosol to begin the nucleation process as soon as the aerosol components leave the rod of aerosol-generating substrate - and the cross-section al surface area of the hollow tubular segment are effectively maximised, whilst at the same time ensuring that the hollow tubular segmen thas the necessary structur alstrength to prevent a collapse of the aerosol-generating article as well as to provide some support to the rod of aerosol-generating substrat e,and that the RTD of the hollow tubular segmen tis minimised.
Greater values of cross-sectional surface area of the cavity of the hollow tubular segment are understood to be associated with a reduced speed of the aerosol stream travelling along the aerosol-generating article, which is also expected to favour aerosol nucleation. Further, it would appear that by utilising a hollow tubular segmen thaving a relatively low thickness, it is possible to substantially prevent diffusion of the ventilation air prior to its contacting and mixing with the stream of aerosol, which is also understood to furthe rfavour nucleation phenomena.
In practice, by providing a more controllably localised cooling of the stream of volatilised species, it is possible to enhance the effect of cooling on the formation of new aerosol particles.
The aerosol-cooling element preferably has an outer diameter that is approximately equal to the outer diameter of the rod of aerosol-generating substrate and to the outer diameter of the aerosol-generating article.
The aerosol-cooling element may have an outer diameter of between 5 millimetres and 12 millimetres, for example of between 5 millimetres and 10 millimetres or of between 6 millimetres and 8 millimetres. In a preferred embodiment, the aerosol-cooling element has an external diameter of 7.2 millimetres plus or minus 10 percent.
Preferably, the hollow tubular segmen tof the aerosol-cooling element has an internal diameter of at least about 2 millimetres. More preferably, the hollow tubular segmen tof the aerosol-cooling element has an internal diameter of at least about 2.5 millimetres. Even more preferably, the hollow tubular segmen tof the aerosol-cooling element has an internal diameter of at least about 3 millimetres.
A peripheral wall of the aerosol-cooling element may have a thickness of less than about 2.5 millimetres, preferably less than about 1.5 millimetres, more preferably less than about 1250 micrometres, even more preferably less than about 1000 micrometres. In WO 2021/170638 PCT/EP2021/054536 particularly preferred embodiments, the peripheral wall of the aerosol-cooling element has a thickness of less than about 900 micrometres, preferably less than about 800 micrometres.
In an embodiment, a peripheral wall of the aerosol-cooling element has a thickness of about 2 millimetres.
The aerosol-cooling element may have a length of between 5 millimetres and 15 millimetres.
Preferably, the aerosol-cooling element has a length of at least about 6 millimetres, more preferably at least about 7 millimetres.
In preferred embodiments, the aerosol-cooling element has a length of less than about 12 millimetres, more preferably less than about 10 millimetres.
In some embodiments, the aerosol-cooling element has a length from about 5 millimetres to about 15 millimetres, preferably from about 6 millimetres to about 15 millimetres, more preferably from about 7 millimetre sto about 15 millimetres. In other embodiments, the aerosol-cooling element has a length from about 5 millimetres to about 12 millimetres, preferably from about 6 millimetres to about 12 millimetres, more preferably from about 7 millimetres to about 12 millimetres. In furthe rembodiments, the aerosol-cooling element has a length from about 5 millimetres to about 10 millimetres, preferably from about 6 millimetres to about 10 millimetres, more preferably from about 7 millimetres to about 10 millimetres.
In particularly preferred embodiments of the invention, the aerosol-cooling element has a length of less than 10 millimetres. For example, in one particularly preferred embodiment, the aerosol-cooling elemen thas a length of 8 millimetres. In such embodiments, the aerosol- cooling element therefore has a relatively short length compared to the aerosol-cooling elements of prior art aerosol-generating articles. A reduction in the length of the aerosol- cooling elemen tis possible due to the optimised effectiveness of the hollow tubular segment forming the aerosol-cooling element in the cooling and nucleation of the aerosol. The reduction of the length of the aerosol-cooling element advantageously reduces the risk of deformation of the aerosol-generating article due to compression during use, since the aerosol-cooling element typically has a lower resistance to deformation than the mouthpiece.
Furthermore, the reduction of the length of the aerosol-cooling element may provide a cost benefit to the manufacturer since the cost of a hollow tubular segmen tis typically higher per unit length than the cost of other elements such as a mouthpiece element.
A ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate may be from about 0.25 to about 1.
Preferably, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is at least about 0.3, more preferably at least about 0.4, even more preferably at least about 0.5. In preferred embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate WO 2021/170638 PCT/EP2021/054536 is less than about 0.9, more preferably less than about 0.8, even more preferably less than about 0.7.
In some embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.9, preferably from about 0.4 to about 0.9, more preferably from about 0.5 to about 0.9. In other embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.8, preferably from about 0.4 to about 0.8, more preferably from about 0.5 to about 0.8. In further embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol- generating substrate is from about 0.3 to about 0.7, preferably from about 0.4 to about 0.7, more preferably from about 0.5 to about 0.7.
In a particularly preferred embodiments, a ratio between the length of the aerosol- cooling element and the length of the rod of aerosol-generating substrate is about 0.66.
Preferably, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is at least about 0.13, more preferably at least about 0.14, even more preferably at least about 0.15. A ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably less than about 0.3, more preferably less than about 0.25, even more preferably less than about 0.20.
In some embodiments, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.3, more preferably from about 0.14 to about 0.3, even more preferably from about 0.15 to about 0.3. In other embodiments, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.25, more preferably from about 0.14 to about 0.25, even more preferably from about 0.15 to about 0.25. In further embodiments, a ratio between the length of the aerosol-cooling elemen tand the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.2, more preferably from about 0.14 to about 0.2, even more preferably from about 0.15 to about 0.2.
In a particularly preferred embodiment, a ratio between the length of the aerosol- cooling element and the overall length of the aerosol-generating article substrate is about 0.18.
Preferably, the length of the mouthpiece element is at least 1 millimetre greater than the length of the aerosol-cooling element, more preferably at least 2 millimetres greater than the length of the aerosol-cooling element, more preferably at least 3 millimetres greater than the length of the aerosol-cooling element. A reduction in the length of the aerosol-cooling element, as described above, can advantageous lyallow for an increase in the length of other WO 2021/170638 PCT/EP2021/054536 elements of the aerosol-generating article, such as the mouthpiece element. The potential technical benefit sof providing a relatively long mouthpiece element are described above.
A ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate may be from about 0.25 to about 1.
Preferably, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is at least about 0.3, more preferably at least about 0.4, even more preferably at least about 0.5. In preferred embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is less than about 0.9, more preferably less than about 0.8, even more preferably less than about 0.7.
In some embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.9, preferably from about 0.4 to about 0.9, more preferably from about 0.5 to about 0.9. In other embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.8, preferably from about 0.4 to about 0.8, more preferably from about 0.5 to about 0.8. In further embodiments, a ratio between the length of the aerosol-cooling element and the length of the rod of aerosol- generating substrate is from about 0.3 to about 0.7, preferably from about 0.4 to about 0.7, more preferably from about 0.5 to about 0.7.
In a particularly preferred embodiments, a ratio between the length of the aerosol- cooling element and the length of the rod of aerosol-generating substrate is about 0.66.
A ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate may be from about 0.125 to about 0.375.
Preferably, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is at least about 0.13, more preferably at least about 0.14, even more preferably at least about 0.15. A ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably less than about 0.3, more preferably less than about 0.25, even more preferably less than about 0.20.
In some embodiments, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.3, more preferably from about 0.14 to about 0.3, even more preferably from about 0.15 to about 0.3. In other embodiments, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.25, more preferably from about 0.14 to about 0.25, even more preferably from about 0.15 to about 0.25. In further embodiments, a ratio between the length of the aerosol-cooling element and the overall length of the aerosol-generating article substrate is WO 2021/170638 PCT/EP2021/054536 preferably from about 0.13 to about 0.2, more preferably from about 0.14 to about 0.2, even more preferably from about 0.15 to about 0.2.
In a particularly preferred embodiment, a ratio between the length of the aerosol- cooling element and the overall length of the aerosol-generating article substrate is about 0.18.
Preferably, the length of the mouthpiece element is at least 1 millimetre greater than the length of the aerosol-cooling element, more preferably at least 2 millimetres greater than the length of the aerosol-cooling element, more preferably at least 3 millimetres greater than the length of the aerosol-cooling element. A reduction in the length of the aerosol-cooling element, as described above, can advantageous lyallow for an increase in the length of other elements of the aerosol-generating article, such as the mouthpiece element. The potential technical benefit sof providing a relatively long mouthpiece element are described above.
Preferably, in aerosol-generating articles in accordance with the present invention the aerosol-cooling element has an average radial hardness of at least about 80 percent, more preferably at least about 85 percent, even more preferably at least about 90 percent. The aerosol-cooling element is therefore able to provide a desirable level of hardness to the aerosol-generating article.
If desired, the radial hardness of the aerosol-cooling element of aerosol-generating articles in accordance with the invention may be further increased by circumscribing the aerosol-cooling element by a stiff plug wrap, for example, a plug wrap having a basis weight of at least about 80 grams per square metre (gsm), or at least about 100 gsm, or at least about 110 gsm.
As used herein, the term "radial hardness" refers to resistance to compression in a directio ntransverse to a longitudinal axis of an element . Radial hardness of an aerosol- generating article around a given element may be determined by applying a load across the article at the location of the element, transverse to the longitudinal axis of the article, and measuring the average (mean) depressed diameters of the articles. Radial hardness is given by: hardness(%} = ——*1OO% Radial Ds where Ds is the original (undepressed) diameter ,and Dd is the depressed diameter after applying a set load for a set duration. The harder the material, the closer the hardness is to 100 percent.
To determine the hardness of a portion (such as a support element or aerosol-cooling element provided in the form of a hollow tube segment) of an aerosol article, aerosolWO 2021/170638 PCT/EP2021/054536 generating articles should be aligned parallel in a plane and the same portion of each aerosol- generating article to be tested should be subjected to a set load for a set duration. This test is performed using a known DD60A Densimeter device (manufactured and made commercially available by Heinr Borgwaldt GmbH, Germany), which is fitted with a measuring head for aerosol-generating articles, such as cigarettes, and with an aerosol-generating article receptacle.
The load is applied using two load-applying cylindrical rods, which extend across the diameter of all of the aerosol-generating articles at once. According to the standar dtest method for this instrument the, test should be performed such that twent ycontact points occur between the aerosol-generating articles and the load applying cylindrical rods. In some cases, the hollow tube segments to be tested may be long enough such that only ten aerosol- generating articles are needed to form twenty contact points, with each smoking article contacting both load applying rods (because they are long enough to extend between the rods). In other cases, if the support elements are too short to achieve this, then twenty aerosol- generating articles should be used to form the twent ycontact points, with each aerosol- generating article contacting only one of the load applying rods, as furthe rdiscussed below.
Two further stationar cylindricaly rods are located underneath the aerosol-generating articles, to support the aerosol-generating articles and counteract the load applied by each of the load applying cylindrical rods.
For the standard operating procedure for such an apparatus, an overall load of 2 kg is applied for a duration of 20 seconds. After 20 seconds have elapsed (and with the load still being applied to the smoking articles), the depression in the load applying cylindrical rods is determined, and then used to calculate the hardness from the above equation. The temperature is kept in the region of 22 degrees Celsius ± 2 degrees. The test described above is referred to as the DD60A Test. The standar dway to measure the filter hardness is when the aerosol-generating article have not been consumed. Additional information regarding measurement of average radial hardness can be found in, for example, U.S. Published Patent Application Publication Number 2016/0128378.
The aerosol-cooling element may be formed from any suitable material or combination of materials. For example, the aerosol-cooling element may be formed from one or more materials selected from the group consisting of: cellulose acetate; cardboard; crimped paper, such as crimped heat resistant paper or crimped parchment paper; and polymeric materials, such as low density polyethylene (LDPE). Other suitable materials include polyhydroxyalkanoate (PHA) fibres.
In a preferred embodiment, the aerosol-cooling element is formed from cellulose acetate.WO 2021/170638 PCT/EP2021/054536 Preferably, the hollow tubular segmen tof the aerosol-cooling element is adapted to generate a RTD between approximately 0 millimetres H2O (about 0 Pa) to approximately 20 millimetres H2O (about 100 Pa), more preferably between approximately 0 millimetre sH2O (about 0 Pa) to approximately 10 millimetres H2O (about 100 Pa).
In aerosol-generating articles in accordance with the present invention the overall RTD of the article depends essentially on the RTD of the rod and optionally on the RTD of the mouthpiece and/or upstream plug. This is because the hollow tubular segmen tof the aerosol- cooling element and the hollow tubular segment of the support element are substantially empty and, as such, substantially only marginally contribute to the overall RTD of the aerosol- generating article.
The ventilation zone comprises a plurality of perforations through the peripheral wall of the aerosol-cooling element. Preferably, the ventilation zone comprises at least one circumferentia lrow of perforations. In some embodiments, the ventilation zone may comprise two circumferentia lrows of perforations. For example, the perforations may be formed online during manufacturing of the aerosol-generating article. Preferably, each circumferentia lrow of perforations comprises from 8 to 30 perforations.
An aerosol-generating article in accordance with the present invention may have a ventilation level of at least about 5 percent.
The term "ventilation level" is used throughou tthe present specificatio nto denote a volume ratio between of the airflow admitted into the aerosol-generating article via the ventilation zone (ventilation airflow) and the sum of the aerosol airflow and the ventilation airflow. The greater the ventilation level, the higher the dilution of the aerosol flow delivered to the consumer.
The aerosol-generating article may typically have a ventilation level of at least about 10 percent, preferably at least about 15 percent, more preferably at least about 20 percent.
In preferred embodiments, the aerosol-generating article has a ventilation level of at least about 25 percent. The aerosol-generating article preferably has a ventilation level of less than about 60 percent. An aerosol-generating article in accordance with the present invention preferably has a ventilation level of less than or equal to about 45 percent. More preferably, an aerosol-generating article in accordance with the present invention has a ventilation level of less than or equal to about 40 percent, even more preferably less than or equal to about percent.
In a particularly preferred embodiments, the aerosol-generating article has a ventilation level of about 30 percent. In some embodiments, the aerosol-generating article has a ventilation level from about 20 percent to about 60 percent, preferably from about 20 percent to about 45 percent, more preferably from about 20 percent to about 40 percent. In other embodiments, the aerosol-generating article has a ventilation level from about 25 percent to WO 2021/170638 PCT/EP2021/054536 about 60 percent, preferably from about 25 percent to about 45 percent, more preferably from about 25 percent to about 40 percent. In further embodiments, the aerosol-generating article has a ventilation level from about 30 percent to about 60 percent, preferably from about 30 percent to about 45 percent, more preferably from about 30 percent to about 40 percent.
In particularly preferred embodiments, the aerosol-generating article has a ventilation level from about 28 percent to about 42 percent. In some particularly preferred embodiments, the aerosol-generating article has a ventilation level of about 30 percent.
Without wishing to be bound by theory, the inventors have found that the temperatur e drop caused by the admission of cooler, external air into the hollow tubular segmen tvia the ventilation zone may have an advantageous effect on the nucleation and growth of aerosol particles.
Formation of an aerosol from a gaseous mixture containing various chemical species depends on a delicate interplay between nucleation, evaporation, and condensation, as well as coalescence, all the while accounting for variations in vapour concentration, temperature, and velocity fields. The so-called classical nucleation theory is based on the assumptio nthat a fraction of the molecules in the gas phase are large enough to stay coherent for long times with sufficient probability (for example, a probability of one half). These molecules represent some kind of a critical, threshold molecule clusters among transient molecular aggregates, meaning that, on average, smaller molecule clusters are likely to disintegrate rather quickly into the gas phase, while larger clusters are, on average, likely to grow. Such critical cluster is identifie das the key nucleation core from which droplets are expected to grow due to condensation of molecules from the vapour. It is assumed that virgin droplet sthat just nucleated emerge with a certain original diameter ,and then may grow by several orders of magnitude. This is facilitated and may be enhanced by rapid cooling of the surrounding vapour, which induces condensation. In this connection, it helps to bear in mind that evaporation and condensation are two sides of one same mechanism , namely gas-liquid mass transfer .While evaporation relates to net mass transfe rfrom the liquid droplets to the gas phase, condensation is net mass transfe rfrom the gas phase to the droplet phase.
Evaporation (or condensation will) make the droplets shrink (or grow), but it will not change the number of droplets.
In this scenario, which may be furthe rcomplicated by coalescence phenomena, the temperature and rate of cooling can play a critical role in determining how the system responds. In general, different cooling rates may lead to significantly different temporal behaviours as concerns the formation of the liquid phase (droplets) because, the nucleation process is typically nonlinear. Withou twishing to be bound by theory, it is hypothesised that cooling can cause a rapid increase in the number concentration of droplets, which is followed by a strong, short-lived increase in this growth (nucleation burst) .This nucleation burst would WO 2021/170638 PCT/EP2021/054536 appear to be more significant at lower temperatures. Further, it would appear that higher cooling rates may favour an earlier onset of nucleation. By contrast, a reduction of the cooling rate would appear to have a favourable effect on the final size that the aerosol droplets ultimately reach.
Therefore, the rapid cooling induced by the admission of external air into the hollow tubular segment via the ventilation zone can be favourably used to favour nucleation and growth of aerosol droplets. However, at the same time, the admission of external air into the hollow tubular segmen thas the immediate drawback of diluting the aerosol stream delivered to the consumer.
The inventors have surprisingly found how the favourable effect of enhanced nucleation promoted by the rapid cooling induced by the introduction of ventilation air into the article is capable of significantly countering the less desirable effect sof dilution. As such, satisfactory values of aerosol delivery are consistently achieved with aerosol-generating articles in accordance with the invention.
The inventors have also surprisingly found that the diluting effect on the aerosol - which can be assessed by measuring, in particular ,the effect on the delivery of aerosol former (such as glycerol) included in the aerosol-generating substrate) is advantageous lyminimised when the ventilation level is within the ranges described above. In particular ,ventilation levels between 25 percent and 50 percent, and even more preferably between 28 and 42 percent, have been found to lead to particularly satisfactory values of glycerin delivery. At the same time, the extent of nucleation and, as a consequence, the delivery of nicotine and aerosol- former (for example, glycerol) are enhanced.
This is particularly advantageous with "short" aerosol-generating articles, such as ones wherein a length of the rod of aerosol-generating substrate is less than about 40 millimetres, preferably less than 25 millimetres, even more preferably less than 20 millimetres, or wherein an overall length of the aerosol-generating article is less than about 70 millimetres, preferably less than about 60 millimetres, even more preferably less than 50 millimetres. As will be appreciated ,in such aerosol-generating articles, there is little time and space for the aerosol to form and for the particulate phase of the aerosol to become available for delivery to the consumer.
Further, because the ventilated hollow tubular segmen tsubstantially does not contribute to the overall RTD of the aerosol-generating article, in aerosol-generating articles in accordance with the invention the overall RTD of the article can advantageous lybe fine- tuned by adjusting the length and density of the rod of aerosol-generating substrate or the length and optionally the length and density of a segment of filtration material forming part of the mouthpiece or the length and density of a segmen tof filtration material provided upstream of the aerosol-generating substrate and the susceptor element. Thus, aerosol-generating WO 2021/170638 PCT/EP2021/054536 articles that have a predetermined RTD can be manufactured consistently and with great precision, such that satisfactory levels of RTD can be provided for the consumer even in the presence of ventilation.
In some embodiments, the aerosol-generating article may further comprise an additional cooling element defining a plurality of longitudinally extendin gchannels such as to make a high surface area available for heat exchange. In other words, one such additional cooling element is adapted to function substantially as a heat exchanger. The plurality of longitudinally extending channels may be defined by a sheet material that has been pleated, gathered or folded to form the channels. The plurality of longitudinally extending channels may be defined by a single sheet that has been pleated, gathered or folded to form multiple channels. The sheet may also have been crimped prior to being pleated, gathered or folded.
Alternatively, the plurality of longitudinally extending channels may be defined by multiple sheet sthat have been crimped, pleated, gathered or folded to form multiple channels. In some embodiments, the plurality of longitudinally extendin gchannels may be defined by multiple sheet sthat have been crimped, pleated, gathered or folded together - that is by two or more sheet sthat have been brought into overlying arrangement and then crimped, pleated, gathered or folded as one. As used herein, the term ‘sheet’ denotes a laminar element having a width and length substantially greater than the thickness thereof.
As used herein, the term ‘longitudinal direction’ refers to a direction extending along, or parallel to, the cylindrical axis of a rod. As used herein, the term ‘crimped’ denotes a sheet having a plurality of substantiall paray llel ridges or corrugations. Preferably, when the aerosol- generating article has been assembled, the substantially parallel ridges or corrugations extend in a longitudinal direction with respect to the rod. As used herein, the terms ‘gathered’, ‘pleated’, or ‘folded’ denote that a sheet of material is convoluted, folded, or otherwise compressed or constricted substantially transversel toy the cylindrical axis of the rod. A sheet may be crimped prior to being gathered, pleated or folded. A sheet may be gathered, pleated or folded withou tprior crimping.
One such additional cooling element may have a total surface area of between about 300 square millimetre per millimetre length and about 1000 square millimetres per millimetre length.
The additional cooling element preferably offers a low resistance to the passage of air through additional cooling element. Preferably, the additional cooling element does not substantially affect the resistance to draw of the aerosol-generating article. To achieve this, it is preferred that the porosity in a longitudinal directio nis greater than 50 percent and that the airflow path through the additional cooling elemen tis relatively uninhibited. The longitudinal porosity of the additional cooling element may be defined by a ratio of the cross-sectional area WO 2021/170638 PCT/EP2021/054536 of material forming the additional cooling element and an internal cross-section alarea of the aerosol-generating article at the portion containing the additional cooling element.
The additional cooling element preferably comprises a sheet material selected from the group comprising a metallic foil, a polymeric sheet, and a substantially non-porous paper or cardboard. In some embodiments, the aerosol-cooling element may comprise a sheet material selected from the group consisting of polyethylene (PE), polypropylene (PP), polyvinylchloride (PVC), polyethylene terephthala te(PET), polylactic acid (PLA), cellulose acetate (CA), and aluminium foil. In a particularly preferred embodiment, the additional cooling element comprises a sheet of PLA.
As described above, the intermediate hollow section of aerosol-generating articles according to the invention further comprises a support element arranged in alignment with , and downstream of the rod of aerosol-generating substrate. In particular, the support element may be located immediately downstream of the rod of aerosol-generating substrate and the upstream end of the support element may abut the downstream end of the rod of aerosol- generating substrate.
The support element may be formed from any suitable material or combination of materials. For example, the support element may be formed from one or more materials selected from the group consisting of: cellulose acetate; cardboard; crimped paper, such as crimped heat resistan papert or crimped parchment paper; and polymeric materials, such as low density polyethylene (LDPE). In a preferred embodiment, the support element is formed from cellulose acetate. Other suitable materials include polyhydroxyalkanoate (PHA) fibres.
The support element may comprise a hollow tubular segment. In a preferred embodiment, the support element comprises a hollow cellulose acetate tube.
The support element is arranged substantially in alignment with the rod. This means that the length dimension of the support element is arranged to be approximately parallel to the longitudinal direction of the rod and of the article, for example within plus or minus 10 degrees of parallel to the longitudinal directio nof the rod. In preferred embodiments, the support element extends along the longitudinal axis of the rod.
The support element preferably has an outer diameter that is approximately equal to the outer diameter of the rod of aerosol-generating substrate and to the outer diameter of the aerosol-generating article.
The support element may have an outer diameter of between 5 millimetre sand 12 millimetres, for example of between 5 millimetres and 10 millimetre sor of between 6 millimetres and 8 millimetres. In a preferred embodiment, the support element has an external diameter of 7.2 millimetres plus or minus 10 percent.
A peripheral wall of the support element may have a thickness of at least 1 millimetre, preferably at least about 1.5 millimetres, more preferably at least about 2 millimetres.WO 2021/170638 PCT/EP2021/054536 The support element may have a length of between about 5 millimetres and about 15 millimetres.
Preferably, the support element has a length of at least about 6 millimetres, more preferably at least about 7 millimetres.
In preferred embodiments, the support element has a length of less than about 12 millimetres, more preferably less than about 10 millimetres.
In some embodiments, the support element has a length from about 5 millimetre sto about 15 millimetres, preferably from about 6 millimetre sto about 15 millimetres, more preferably from about 7 millimetre sto about 15 millimetres. In other embodiments, the support element has a length from about 5 millimetre sto about 12 millimetres, preferably from about 6 millimetre sto about 12 millimetres, more preferably from about 7 millimetre sto about 12 millimetres. In furthe rembodiments, the support element has a length from about 5 millimetres to about 10 millimetres, preferably from about 6 millimetres to about 10 millimetres, more preferably from about 7 millimetre sto about 10 millimetres.
In a preferred embodiment, the support element has a length of about 8 millimetres.
Preferably, the total length of the intermediate hollow section is no more than about 18 millimetres, more preferably no more than about 17 millimetres, more preferably no more than 16 millimetres.
A ratio between the length of the support element and the length of the rod of aerosol- generating substrate may be from about 0.25 to about 1.
Preferably, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is at least about 0.3, more preferably at least about 0.4, even more preferably at least about 0.5. In preferred embodiments, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is less than about 0.9, more preferably less than about 0.8, even more preferably less than about 0.7.
In some embodiments, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.9, preferably from about 0.4 to about 0.9, more preferably from about 0.5 to about 0.9. In other embodiments, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.8, preferably from about 0.4 to about 0.8, more preferably from about 0.5 to about 0.8. In further embodiments, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is from about 0.3 to about 0.7, preferably from about 0.4 to about 0.7, more preferably from about 0.5 to about 0.7.
In a particularly preferred embodiments, a ratio between the length of the support element and the length of the rod of aerosol-generating substrate is about 0.66.WO 2021/170638 PCT/EP2021/054536 A ratio between the length of the support element and the overall length of the aerosol- generating article substrate may be from about 0.125 to about 0.375.
Preferably, a ratio between the length of the support element and the overall length of the aerosol-generating article substrate is at least about 0.13, more preferably at least about 0.14, even more preferably at least about 0.15. A ratio between the length of the support element and the overall length of the aerosol-generating article substrate is preferably less than about 0.3, more preferably less than about 0.25, even more preferably less than about 0.20.
In some embodiments, a ratio between the length of the support element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.3, more preferably from about 0.14 to about 0.3, even more preferably from about 0.15 to about 0.3. In other embodiments, a ratio between the length of the support element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.25, more preferably from about 0.14 to about 0.25, even more preferably from about 0.15 to about 0.25. In furthe rembodiments, a ratio between the length of the support element and the overall length of the aerosol-generating article substrate is preferably from about 0.13 to about 0.2, more preferably from about 0.14 to about 0.2, even more preferably from about 0.15 to about 0.2.
In a particularly preferred embodiment, a ratio between the length of the support elemen t and the overall length of the aerosol-generating article substrate is about 0.18.
Preferably, in aerosol-generating articles in accordance with the present invention the support element has an average radial hardness of at least about 80 percent, more preferably at least about 85 percent, even more preferably at least about 90 percent. The support element is therefore able to provide a desirable level of hardness to the aerosol-generating article.
If desired, the radial hardness of the support element of aerosol-generating articles in accordance with the invention may be further increased by circumscribing the support elemen t by a stiff plug wrap, for example, a plug wrap having a basis weight of at least about 80 grams per square metre (gsm), or at least about 100 gsm, or at least about 110 gsm.
During insertion of an aerosol-generating article in accordance with the invention into an aerosol-generating device for heating the aerosol-generating substrate, a user may be required to apply some force in order to overcome the resistance of the aerosol-generating substrate of the aerosol-generating article to insertion. This may damage one or both of the aerosol-generating article and the aerosol-generating device. In addition, the application of force during insertion of the aerosol-generating article into the aerosol-generating device may displace the aerosol-generating substrate within the aerosol-generating article. This may resul tin the heating element of the aerosol-generating device not being properly aligned with WO 2021/170638 PCT/EP2021/054536 the susceptor element provided within the aerosol-generating substrat e,which may lead to uneven and inefficient heating of the aerosol-generating substrate of the aerosol-generating article. The support element is advantageously configured to resist downstream movement of the aerosol-generating substrate during insertio nof the article into the aerosol-generating device.
Preferably, the hollow tubular segment of the support element is adapted to generate a RTD between approximately 0 millimetres H2O (about 0 Pa) to approximately 20 millimetres H2O (about 100 Pa), more preferably between approximately 0 millimetres H2O (about 0 Pa) to approximately 10 millimetres H2O (about 100 Pa). The support element therefore preferably does not contribute to the overall RTD of the aerosol-generating article.
In some embodiments wherein the intermediate hollow section comprises both a support element comprising a first hollow tube segment and an aerosol-cooling elemen t comprising a second hollow tubular segment, the internal diameter (DSts) of the second hollow tubular segment is preferably greater than the internal diameter (DFTs) of the first hollow tubular segment.
In more detail, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFts) of the first hollow tubular segmen tis preferably at least about 1.25. More preferably, a ratio between the internal diameter (DSTs) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis preferably at least about 1.3. Even more preferably, a ratio between the internal diameter (DsTs) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segment is preferably at least about 1.4. In particularly preferred embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segment and the internal diameter (DFts) of the first hollow tubular segmen tis at least about 1.5, more preferably at least about 1.6.
A ratio between the internal diamete (Dr Sts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segment is preferably less than or equal to about 2.5. More preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis preferably less than or equal to about 2.25. Even more preferably, ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis preferably less than or equal to about 2.
In some embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.25 to about 2.5. Preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.3 to about 2.5. More preferably, a ratio between the internal diameter WO 2021/170638 PCT/EP2021/054536 (DSTs) of the second hollow tubular segmen tand the internal diameter (DFTS) of the first hollow tubular segment is from about 1.4 to about 2.5. In particularly preferred embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segment and the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.5 to about 2.5.
In other embodiments, a ratio between the internal diameter (DSTs) of the second hollow tubular segmen tand the internal diameter (DFts) of the first hollow tubular segmen tis from about 1.25 to about 2.25. Preferably, a ratio between the internal diameter (DSTs) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.3 to about 2.25. More preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segment is from about 1.4 to about 2.25. In particularly preferred embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.5 to about 2.25.
In further embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.25 to about 2. Preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.3 to about 2. More preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.4 to about 2. In particularly preferred embodiments, a ratio between the internal diameter (DSts) of the second hollow tubular segment and the internal diameter (DFTs) of the first hollow tubular segmen tis from about 1.5 to about 2.
In those embodiments wherein the article furthe rcomprises an elongate susceptor element arranged longitudinally within the aerosol-generating substrate, as described below, a ratio between the internal diameter (DFTs) of the first hollow tubular segment and a width of the susceptor element is preferably at least about 0.2. More preferably, a ratio between the internal diameter (DFTs) of the first hollow tubular segmen tand a width of the susceptor element is at least about 0.3. Even more preferably, a ratio between the internal diameter (DFTs) of the first hollow tubular segmen tand a width of the susceptor element is at least about 0.4.
In addition, or as an alternative, a ratio between the internal diameter (DSts) of the second hollow tubular segmen tand a width of the susceptor element is preferably at least about 0.2. More preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segment and a width of the susceptor element is at least about 0.5. Even more preferably, a ratio between the internal diameter (DSts) of the second hollow tubular segment and a width of the susceptor element is at least about 0.8.WO 2021/170638 PCT/EP2021/054536 Preferably, a ratio between a volume of the cavity of the first hollow tubular segment and a volume of the cavity of the second hollow tubular segmen tis at least about 0.1. More preferably, a ratio between a volume of the cavity of the first hollow tubular segment and a volume of the cavity of second hollow tubular segmen tis at least about 0.2. Even more preferably, a ratio between a volume of the cavity of first hollow tubular segmen tand a volume of the cavity of second hollow tubular segmen tis at least about 0.3.
A ratio between a volume of the cavity of the first hollow tubular segmen tand a volume of the cavity of the second hollow tubular segmen tis preferably less than or equal to about 0.9. More preferably, a ratio between a volume of the cavity of the first hollow tubular segment and a volume of the cavity of the second hollow tubular segment is preferably less than or equal to about 0.7. Even more preferably, a ratio between a volume of the cavity of the first hollow tubular segmen tand a volume of the cavity of the second hollow tubular segment is preferably less than or equal to about 0.5.
As defined above, the aerosol-generating article of the present invention comprises a rod of an aerosol-generating substrat e.The aerosol-generating substrate may be a solid aerosol-generating substrate.
In certain preferred embodiments, the aerosol-generating substrate comprises homogenised plant material, preferably a homogenised tobacco material.
As used herein, the term "homogenised plant material" encompasses any plant material formed by the agglomeration of particles of plant . For example, sheets or webs of homogenised tobacco material for the aerosol-generating substrate ofs the present invention may be formed by agglomerating particles of tobacco material obtained by pulverising, grinding or comminuting plant material and optionally one or more of tobacco leaf lamina and tobacco leaf stems. The homogenised plant material may be produced by casting ,extrusion, paper making processes or other any other suitable processes known in the art.
The homogenised plant material can be provided in any suitable form. For example, the homogenised plant material may be in the form of one or more sheets. As used herein with reference to the invention, the term "sheet" describes a laminar element having a width and length substantially greater than the thickness thereof.
Alternative lyor in addition, the homogenised plant material may be in the form of a plurality of pellets or granules.
Alternative lyor in addition, the homogenised plant material may be in the form of a plurality of strands, strips or shreds. As used herein, the term "strand" describes an elongate element of material having a length that is substantially greater than the width and thickness thereof . The term "strand" should be considered to encompass strips, shreds and any other homogenised plant material having a similar form. The strands of homogenised plant material WO 2021/170638 PCT/EP2021/054536 may be formed from a sheet of homogenised plant material, for example by cutting or shredding, or by other methods, for example, by an extrusion method.
In some embodiments, the strands may be formed in situ within the aerosol-generating substrate as a resul tof the splitting or cracking of a sheet of homogenised plant material during formation of the aerosol-generating substrat e,for example, as a resul tof crimping. The strands of homogenised plant material within the aerosol-generating substrate may be separate from each other. Alternatively, each strand of homogenised plant material within the aerosol-generating substrate may be at least partially connected to an adjacent strand or strands along the length of the strands. For example, adjacent strands may be connected by one or more fibres. This may occur, for example, where the strands have been formed due to the splittin gof a sheet of homogenised plant material during production of the aerosol- generating substrate, as described above.
Preferably, the aerosol-generating substrate is in the form of one or more sheet sof homogenised plant material. In various embodiments of the invention, the one or more sheets of homogenised plant material may be produced by a casting process. In various embodiments of the invention, the one or more sheets of homogenised plant material may be produced by a paper-making process. The one or more sheet sas described herein may each individually have a thickness of between 100 micrometres and 600 micrometres, preferably between 150 micrometres and 300 micrometres, and most preferably between 200 micrometres and 250 micrometres. Individual thickness refers to the thickness of the individual sheet, whereas combined thickness refers to the total thickness of all sheets that make up the aerosol-generating substrat e.For example, if the aerosol-generating substrate is formed from two individual sheets, then the combined thickness is the sum of the thickness of the two individual sheets or the measured thickness of the two sheets where the two sheet sare stacked in the aerosol-generating substrate.
The one or more sheet sas described herein may each individually have a grammage of between about 100 g/m2 and about 300 g/m2.
The one or more sheets as described herein may each individually have a density of from about 0.3 g/cm3 to about 1.3 g/cm3, and preferably from about 0.7 g/cm3 to about 1.0 g/cm3.
In embodiments of the present invention in which the aerosol-generating substrate comprises one or more sheets of homogenised plant material, the sheets are preferably in the form of one or more gathered sheets. As used herein, the term "gathered" denotes that the sheet of homogenised plant material is convoluted, folded, or otherwise compressed or constricted substantiall transy verse lyto the cylindrical axis of a plug or a rod.WO 2021/170638 PCT/EP2021/054536 The one or more sheets of homogenised plant material may be gathered transversely relative to the longitudinal axis thereof and circumscribed with a wrapper to form a continuous rod or a plug.
The one or more sheet sof homogenised plant material may advantageous lybe crimped or similarly treated. As used herein, the term "crimped" denotes a sheet having a plurality of substantially parallel ridges or corrugations. Alternatively or in addition to being crimped, the one or more sheets of homogenised plant material may be embossed, debossed, perforated or otherwise deformed to provide texture on one or both sides of the sheet.
Preferably, each sheet of homogenised plant material may be crimped such that it has a plurality of ridges or corrugations substantially parallel to the cylindrical axis of the plug. This treatmen advantageoust lyfacilitates gathering of the crimped sheet of homogenised plant material to form the plug. Preferably, the one or more sheets of homogenised plant material may be gathered. It will be appreciated that crimped sheets of homogenised plant material may alternative lyor in addition have a plurality of substantially parallel ridges or corrugations disposed at an acute or obtuse angle to the cylindrical axis of the plug. The sheet may be crimped to such an extent that the integrity of the sheet becomes disrupted at the plurality of parallel ridges or corrugations causing separation of the material, and results in the formation of shreds, strands or strips of homogenised plant material.
Alternatively, the one or more sheet sof homogenised plant material may be cut into strands as referred to above. In such embodiments, the aerosol-generating substrate comprises a plurality of strands of the homogenised plant material. The strands may be used to form a plug. Typically, the width of such strands is about 5 millimetres, or about 4 millimetres, or about 3 millimetres, or about 2 millimetres or less. The length of the strands may be greater than about 5 millimetres, between about 5 millimetres to about 15 millimetres, about 8 millimetres to about 12 millimetres, or about 12 millimetres. Preferably, the strands have substantially the same length as each other. The length of the strands may be determine dby the manufacturing process whereby a rod is cut into shorter plugs and the length of the strands corresponds to the length of the plug. The strands may be fragile which may resul tin breakage especially during transit. In such cases ,the length of some of the strands may be less than the length of the plug.
The plurality of strands preferably extend substantially longitudinally along the length of the aerosol-generating substrate, aligned with the longitudinal axis. Preferably, the plurality of strands are therefore aligned substantially parallel to each other.
The homogenised plant material may comprise up to about 95 percent by weight of plant particles, on a dry weight basis. Preferably, the homogenised plant material comprises up to about 90 percent by weight of plant particles, more preferably up to about 80 percent by weight of plant particles, more preferably up to about 70 percent by weight of plant particles, more WO 2021/170638 PCT/EP2021/054536 preferably up to about 60 percent by weight of plant particles, more preferably up to about 50 percent by weight of plant particles, on a dry weight basis.
For example, the homogenised plant material may comprise between about 2.5 percent and about 95 percent by weight of plant particles, or about 5 percent and about 90 percent by weight of plant particles, or between about 10 percent and about 80 percent by weight of plant particles, or between about 15 percent and about 70 percent by weight of plant particles, or between about 20 percent and about 60 percent by weight of plant particles, or between about 30 percent and about 50 percent by weight of plant particles, on a dry weight basis.
In certain embodiments of the invention, the homogenised plant material is a homogenised tobacco material comprising tobacco particles. Sheets of homogenised tobacco material for use in such embodiments of the invention may have a tobacco content of at least about 40 percent by weight on a dry weight basis, more preferably of at least about 50 percent by weight on a dry weight basis more preferably at least about 70 percent by weight on a dry weight basis and most preferably at least about 90 percent by weight on a dry weight basis.
With reference to the present invention, the term "tobacco particles" describes particles of any plant member of the genus Nicotiana. The term "tobacco particles" encompasses ground or powdered tobacco leaf lamina, ground or powdered tobacco leaf stems, tobacco dust, tobacco fines, and other particulate tobacco by-products formed during the treating , handling and shipping of tobacco. In a preferred embodiment, the tobacco particles are substantially all derived from tobacco leaf lamina. By contrast isola, ted nicotine and nicotine salts are compounds derived from tobacco but are not considered tobacco particles for purposes of the invention and are not included in the percentage of particulate plant material.
The tobacco particles may be prepared from one or more varieties of tobacco plants.
Any type of tobacco may be used in a blend. Examples of tobacco types that may be used include, but are not limited to, sun-cured tobacco, flue-cured tobacco, Burley tobacco, Maryland tobacco, Oriental tobacco, Virginia tobacco, and other speciality tobaccos.
Flue-curing is a method of curing tobacco, which is particularly used with Virginia tobaccos. During the flue-curing process, heated air is circulated through densely packed tobacco. During a first stage, the tobacco leaves turn yellow and wilt. During a second stage, the laminae of the leaves are completely dried. During a third stage, the leaf stems are completely dried.
Burley tobacco plays a significant role in many tobacco blends. Burley tobacco has a distinctive flavour and aroma and also has an ability to absorb large amounts of casing.
Oriental is a type of tobacco which has small leaves, and high aromatic qualities.
However, Oriental tobacco has a milder flavour than, for example, Burley. Generally, therefore, Oriental tobacco is used in relatively small proportions in tobacco blends.WO 2021/170638 PCT/EP2021/054536 Kasturi, Madura and Jatim are subtypes of sun-cured tobacco that can be used.
Preferably, Kasturi tobacco and flue-cured tobacco may be used in a blend to produce the tobacco particles. Accordingly, the tobacco particles in the particulate plant material may comprise a blend of Kasturi tobacco and flue-cured tobacco.
The tobacco particles may have a nicotine content of at least about 2.5 percent by weight, based on dry weight. More preferably, the tobacco particles may have a nicotine content of at least about 3 percent, even more preferably at least about 3.2 percent, even more preferably at least about 3.5 percent, most preferably at least about 4 percent by weight, based on dry weight.
In certain other embodiments of the invention, the homogenised plant material comprises tobacco particles in combination with non-tobacco plant flavour particles.
Preferably, the non-tobacco plant flavour particles are selected from one or more of: ginger particles, rosemary particles, eucalyptus particles, clove particles and star anise particles.
Preferably, in such embodiments, the homogenised plant material comprises at least about 2.5 percent by weight of the non-tobacco plant flavour particles, on a dry weight basis, with the remainder of the plant particles being tobacco particles. Preferably, the homogenised plant material comprises at least about 4 percent by weight of non-tobacco plant flavour particles, more preferably at least about 6 percent by weight of non-tobacco plant flavour particles, more preferably at least about 8 percent by weight of non-tobacco plant flavour particles and more preferably at least about 10 percent by weight of non-tobacco plant flavour particles, on a dry weight basis. Preferably, the homogenised plant material comprises up to about 20 percent by weight of non-tobacco plant flavour particles, more preferably up to about 18 percent by weight of non-tobacco plant flavour particles, more preferably up to about 16 percent by weight of non-tobacco plant flavour particles.
The weight ratio of the non-tobacco plant flavour particles and the tobacco particles in the particulate plant material forming the homogenised plant material may vary depending on the desired flavour characteristics and composition of the aerosol produced from the aerosol- generating substrate during use. Preferably, the homogenised plant material comprises at least a 1:30 weight ratio of non-tobacco plant flavour particles to tobacco particles, more preferably at least a 1:20 weight ratio of non-tobacco plant flavour particles to tobacco particles, more preferably at least a 1:10 weight ratio of non-tobacco plant flavour particles to tobacco particles and most preferably at least a1:5 weight ratio of non-tobacco plant flavour particles to tobacco particles, on a dry weight basis.
Alternative lyor in addition to the inclusion of tobacco particles into the homogenised plant material of the aerosol-generating substrate according to the invention, the homogenised plant material may comprise cannabis particles. The term "cannabis particles" refers to WO 2021/170638 PCT/EP2021/054536 particles of a cannabis plant , such as the species Cannabis saliva, Cannabis indica, and Cannabis ruderalis.
The homogenised plant material preferably comprises no more than 95 percent by weight of the particulate plant material, on a dry weight basis. The particulate plant material is therefore typically combined with one or more other components to form the homogenised plant material.
The homogenised plant material may furthe rcomprise a binder to alter the mechanical properties of the particulate plant material, wherein the binder is included in the homogenised plant material during manufacturing as described herein. Suitable exogenous binders would be known to the skilled person and include but are not limited to: gums such as, for example, guar gum, xanthan gum, arabic gum and locust bean gum; cellulosic binders such as, for example, hydroxypropyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose and ethyl cellulose; polysaccharides such as, for example, starches, organic acids, such as alginic acid, conjugate base salts of organic acids, such as sodium-alginate agar, and pectins; and combinations thereof. Preferably, the binder comprises guar gum.
The binder may be present in an amount of from about 1 percent to about 10 percent by weight, based on the dry weight of the homogenised plant material, preferably in an amount of from about 2 percent to about 5 percent by weight, based on the dry weight of the homogenised plant material.
Alternatively or in addition, the homogenised plant material may further comprise one or more lipids to facilitate the diffusivity of volatile components (for example, aerosol formers, gingerols and nicotine), wherein the lipid is included in the homogenised plant material during manufacturing as described herein. Suitable lipids for inclusion in the homogenised plant material include, but are not limited to: medium-chain triglycerides, cocoa butter, palm oil, palm kernel oil, mango oil, shea butter, soybean oil, cottonseed oil, coconut oil, hydrogenated coconut oil, candellila wax, carnauba wax, shellac, sunflower wax, sunflower oil, rice bran, and Revel A; and combinations thereof.
Alternatively or in addition, the homogenised plant material may further comprise a pH modifier.
Alternatively or in addition, the homogenised plant material may further comprise fibres to alter the mechanical properties of the homogenised plant material, wherein the fibres are included in the homogenised plant material during manufacturing as described herein.
Suitable exogenous fibres for inclusion in the homogenised plant material are known in the art and include fibres formed from non-tobacco material and non- ginger material, including but not limited to: cellulose fibres; soft-wood fibres; hard-wood fibres; jute fibres and combinations thereof .Exogenous fibres derived from tobacco and/or ginger can also be added. Any fibres added to the homogenised plant material are not considered to form part of the "particulate WO 2021/170638 PCT/EP2021/054536 plant material" as defined above. Prior to inclusion in the homogenised plant material, fibres may be treated by suitable processes known in the art including, but not limited to: mechanical pulping; refining; chemical pulping; bleaching; sulfate pulping; and combinations thereof. A fibre typically has a length greater than its width.
Suitable fibres typically have lengths of greater than 400 micrometres and less than or equal to 4 millimetres, preferably within the range of 0.7 millimetres to 4 millimetres.
Preferably, the fibres are present in an amount of about 2 percent to about 15 percent by weight, most preferably at about 4 percent by weight, based on the dry weight of the substrate.
Alternativel ory in addition, the homogenised plant material may further comprise one or more aerosol formers. Upon volatilisation, an aerosol former can convey other vaporised compounds released from the aerosol-generating substrate upon heating, such as nicotine and flavourants, in an aerosol. Suitable aerosol formers for inclusion in the homogenised plant material are known in the art and include, but are not limited to: polyhydric alcohols, such as triethylene glycol, propylene glycol, 1,3-butanediol and glycerol; esters of polyhydric alcohols, such as glycerol mono-, di- or triacetat e;and aliphatic esters of mono-, di- or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate.
The homogenised plant material may have an aerosol former content of between about percent and about 30 percent by weight on a dry weight basis, such as between about 10 percent and about 25 percent by weight on a dry weight basis, or between about 15 percent and about 20 percent by weight on a dry weight basis.
For example, if the substrate is intended for use in an aerosol-generating article for an electrically-operated aerosol-generating system having a heating element, it may preferably include an aerosol former content of between about 5 percent to about 30 percent by weight on a dry weight basis. If the substrate is intended for use in an aerosol-generating article for an electrically-operated aerosol-generating system having a heating element, the aerosol former is preferably glycerol.
In other embodiments, the homogenised plant material may have an aerosol former content of about 1 percent to about 5 percent by weight on a dry weight basis. For example, if the substrate is intended for use in an aerosol-generating article in which aerosol former is kept in a reservoi rseparate from the substrat e,the substrate may have an aerosol former content of greater than 1 percent and less than about 5 percent. In such embodiments, the aerosol former is volatilised upon heating and a stream of the aerosol former is contacted with the aerosol-generating substrate so as to entrain the flavours from the aerosol-generating substrate in the aerosol.
In other embodiments, the homogenised plant material may have an aerosol former content of about 30 percent by weight to about 45 percent by weight. This relatively high level of aerosol former is particularly suitable for aerosol-generating substrate thats are intended toWO 2021/170638 PCT/EP2021/054536 be heated at a temperature of less than 275 degrees Celsius. In such embodiments, the homogenised plant material preferably further comprises between about 2 percent by weight and about 10 percent by weight of cellulose ether, on a dry weight basis and between about percent by weight and about 50 percent by weight of additional cellulose, on a dry weight basis. The use of the combination of cellulose ether and additional cellulose has been found to provide a particularly effective delivery of aerosol when used in an aerosol-generating substrate having an aerosol former content of between 30 percent by weight and 45 percent by weight.
Suitable cellulose ether sinclude but are not limited to methyl cellulose, hydroxypropyl methyl cellulose, ethyl cellulose, hydroxyl ethyl cellulose, hydroxyl propyl cellulose, ethyl hydroxyl ethyl cellulose and carboxymethyl cellulose (CMC). In particularly preferred embodiments, the cellulose ether is carboxymethyl cellulose.
As used herein, the term "additional cellulose" encompasses any cellulosic material incorporated into the homogenised plant material which does not derive from the non-tobacco plant particles or tobacco particles provided in the homogenised plant material. The additional cellulose is therefore incorporated in the homogenised plant material in addition to the non- tobacco plant material or tobacco material, as a separate and distinct source of cellulose to any cellulose intrinsically provided within the non-tobacco plant particles or tobacco particles.
The additional cellulose will typically derive from a different plant to the non-tobacco plant particles or tobacco particles. Preferably, the additional cellulose is in the form of an inert cellulosic material ,which is seasonally inert and therefore does not substantiall impacty the organoleptic characteristics of the aerosol generate dfrom the aerosol-generating substrat e.
For example, the additional cellulose is preferably a tasteless and odourless material.
The additional cellulose may comprise cellulose powder, cellulose fibres, or a combination thereof.
The aerosol former may act as a humectant in the aerosol-generating substrate.
The wrapper circumscribing the rod of homogenised plant material may be a paper wrapper or a non-paper wrapper. Suitable paper wrappers for use in specific embodiments of the invention are known in the art and include, but are not limited to: cigarett epapers; and filte rplug wraps. Suitable non-paper wrappers for use in specific embodiments of the invention are known in the art and include, but are not limited to sheets of homogenised tobacco materials. In certain preferred embodiments, the wrapper may be formed of a laminate material comprising a plurality of layers . Preferably, the wrapper is formed of an aluminium co-laminated sheet. The use of a co-laminated sheet comprising aluminium advantageous lyprevents combustion of the aerosol-generating substrate in the event that the aerosol-generating substrate should be ignited, rather than heated in the intended manner.WO 2021/170638 PCT/EP2021/054536 In other preferred embodiments of the present invention, the aerosol-generating substrate comprises a gel composition that includes an alkaloid compound, or a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound. In particularly preferred embodiments, the aerosol-generating substrate comprises a gel composition that includes nicotine.
Preferably, the gel composition comprises an alkaloid compound, or a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound; an aerosol former; and at least one gelling agent. Preferably, the at least one gelling agent forms a solid medium and the glycerol is dispersed in the solid medium, with the alkaloid or cannabinoid dispersed in the glycerol. Preferably, the gel composition is a stable gel phase.
Advantageously, a stable gel composition comprising nicotine provides predictable composition form upon storage or transi tfrom manufacture to the consumer. The stable gel composition comprising nicotine substantially maintains its shape. The stable gel composition comprising nicotine substantially does not release a liquid phase upon storage or transi tfrom manufacture to the consumer. The stable gel composition comprising nicotine may provide for a simple consumable design. This consumable may not have to be designed to contain a liquid, thus a wider range of materials and containe rconstructions may be contemplated.
The gel composition described herein may be combined with an aerosol-generating device to provide a nicotine aerosol to the lungs at inhalation or air flow rates that are within conventional smoking regime inhalation or air flow rates. The aerosol-generating device may continuously heat the gel composition. A consumer may take a plurality of inhalations or "puffs" where each "puff" delivers an amount of nicotine aerosol. The gel composition may be capable of delivering a high nicotine/low total particulate matter (TPM) aerosol to a consumer when heated, preferably in a continuous manner.
The phrase "stable gel phase" or "stable gel" refers to gel that substantially maintains its shape and mass when exposed to a variety of environmental conditions. The stable gel may not substantially release (sweat) or absorb water when exposed to a standard temperature and pressure while varying relative humidity from about 10 percent to about 60 percent. For example, the stable gel may substantiall maintaiy n its shape and mass when exposed to a standar dtemperature and pressure while varying relative humidity from about percent to about 60 percent.
The gel composition includes an alkaloid compound, or a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound. The gel composition may include one or more alkaloids. The gel composition may include one or more cannabinoids. The gel composition may include a combination of one or more alkaloids and one or more cannabinoids.WO 2021/170638 PCT/EP2021/054536 The term "alkaloid compound" refers to any one of a class of naturally occurring organic compounds that contain one or more basic nitrogen atoms. Generally, an alkaloid contains at least one nitrogen atom in an amine-type structure. This or another nitrogen atom in the molecule of the alkaloid compound can be active as a base in acid-base reactions. Most alkaloid compounds have one or more of their nitrogen atoms as part of a cyclic system, such as for example a heterocylic ring. In nature, alkaloid compounds are found primarily in plants, and are especially common in certain families of flowering plants. However, some alkaloid compounds are found in animal species and fungi. In this disclosure, the term "alkaloid compound" refers to both naturally derived alkaloid compounds and syntheticall y manufactured alkaloid compounds.
The gel composition may preferably include an alkaloid compound selected from the group consisting of nicotine, anatabine, and combinations thereof.
Preferably the gel composition includes nicotine.
The term "nicotine" refers to nicotine and nicotine derivative ssuch as free-base nicotine, nicotine salts and the like.
The term "cannabinoid compound" refers to any one of a class of naturally occurring compounds that are found in parts of the cannabis plant - namely the species Cannabis sativa, Cannabis indica, and Cannabis ruderalis. Cannabinoid compounds are especially concentrated in the female flower heads. Cannabinoid compounds naturally occurring in the cannabis plant include cannabidiol (CBD) and tetrahydrocannabino (THC).l In this disclosure, the term "cannabinoid compounds" is used to describe both naturally derived cannabinoid compounds and synthetically manufactured cannabinoid compounds.
The gel may include a cannabinoid compound selected from the group consisting of cannabidiol (CBD), tetrahydrocannabino l(THC), tetrahydrocannabinol icacid (THCA), cannabidiolic acid (CBDA), cannabinol (CBN), cannabigerol (CBG), cannabichromene (CBC), cannabicyclol (CBL), cannabivarin (CBV), tetrahydrocannabivar in(THCV), cannabidivarin (CBDV), cannabichromevarin (CBCV), cannabigerovarin (CBGV), cannabigerol monomethyl ether (CBGM), cannabielsoin (CBE),cannabicitran (CBT), and combinations thereof.
The gel composition may preferably include a cannabinoid compound selected from the group consisting of cannabidiol (CBD), THC (tetrahydrocannabinol and) combinations thereof.
The gel may preferably include cannabidiol (CBD).
The gel composition may include nicotine and cannabidiol (CBD).
The gel composition may include nicotine, cannabidiol (CBD), and THC (tetrahydrocannabinol).
The gel composition preferably includes about 0.5 percent by weight to about 10 percent by weight of an alkaloid compound, or about 0.5 percent by weight to about 10 percent WO 2021/170638 PCT/EP2021/054536 by weight, of a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound in a total amount from about 0.5 percent by weight to about 10 percent by weight.
The gel composition may include about 0.5 percent by weight to about 5 percent by weight of an alkaloid compound, or about 0.5 percent by weight to about 5 percent by weight of a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound in a tota l amount from about 0.5 percent by weight to about 5 percent by weight . Preferably the gel composition includes about 1 percent by weight to about 3 percent by weight of an alkaloid compound, or about 1 percent by weight to about 3 percent by weight of a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound in a tota amountl from about 1 percent by weight to about 3 percent by weight. The gel composition may preferably include about 1.5 percent by weight to about 2.5 percent by weight of an alkaloid compound, or about 1.5 percent by weight to about 2.5 percent by weight of a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound in a total amount from about 1.5 percent by weight to about 2.5 percent by weight. The gel composition may preferably include about 2 percent by weight of an alkaloid compound, or about 2 percent by weight of a cannabinoid compound, or both an alkaloid compound and a cannabinoid compound in a tota l amount of about 2 percent by weight. The alkaloid compound component of the gel formulation may be the most volatile component of the gel formulation. In some aspects water may be the most volatile component of the gel formulation and the alkaloid compound component of the gel formulation may be the second most volatile component of the gel formulation. The cannabinoid compound component of the gel formulation may be the most volatile component of the gel formulation . In some aspects water may be the most volatile component of the gel formulation and the alkaloid compound component of the gel formulation may be the second most volatile component of the gel formulation.
Preferably nicotine is included in the gel compositions. The nicotine may be added to the composition in a free base form or a salt form. The gel composition includes about 0.5 percent by weight to about 10 percent by weight nicotine, or about 0.5 percent by weight to about 5 percent by weight nicotine. Preferably the gel composition includes about 1 percent by weight to about 3 percent by weight nicotine, or about 1.5 percent by weight to about 2.5 percent by weight nicotine, or about 2 percent by weight nicotine. The nicotine component of the gel formulation may be the most volatile component of the gel formulation. In some aspects water may be the most volatile component of the gel formulation and the nicotine component of the gel formulation may be the second most volatile component of the gel formulation.
The gel composition preferably includes an aerosol-former . Ideally the aerosol-former is substantially resistan tot therma ldegradation at the operating temperatur ofe the associated aerosol-generating device. Suitable aerosol-formers include, but are not limited to: polyhydric WO 2021/170638 PCT/EP2021/054536 alcohols, such as triethylene glycol, 1, 3-butanediol and glycerine; esters of polyhydric alcohols, such as glycerol mono-, di- or triacetate; and aliphatic esters of mono-, di- or polycarboxylic acids, such as dimethyl dodecanedioate and dimethyl tetradecanedioate.
Polyhydric alcohols or mixtures thereof, may be one or more of triethylene glycol, 1, 3- butanediol and, glycerine (glycerol or propane-1,2,3-triol) or polyethylene glycol. The aerosol- former is preferably glycerol.
The gel composition may include a majority of an aerosol-former . The gel composition may include a mixture of water and the aerosol-former where the aerosol-former forms a majority (by weight) of the gel composition. The aerosol-former may form at least about 50 percent by weight of the gel composition. The aerosol-former may form at least about 60 percent by weight or at least about 65 percent by weight or at least about 70 percent by weight of the gel composition. The aerosol-former may form about 70 percent by weight to about 80 percent by weight of the gel composition. The aerosol-former may form about 70 percent by weight to about 75 percent by weight of the gel composition.
The gel composition may include a majority of glycerol. The gel composition may include a mixture of water and the glycerol where the glycerol forms a majority (by weight) of the gel composition. The glycerol may form at least about 50 percent by weight of the gel composition. The glycerol may form at least about 60 percent by weight or at least about 65 percent by weight or at least about 70 percent by weight of the gel composition. The glycerol may form about 70 percent by weight to about 80 percent by weight of the gel composition.
The glycerol may form about 70 percent by weight to about 75 percent by weight of the gel composition.
The gel composition preferably includes at least one gelling agent . Preferably, the gel composition includes a total amount of gelling agents in a range from about 0.4 percent by weight to about 10 percent by weight . More preferably, the composition includes the gelling agents in a range from about 0.5 percent by weight to about 8 percent by weight. More preferably, the composition includes the gelling agents in a range from about 1 percent by weight to about 6 percent by weight . More preferably, the composition includes the gelling agents in a range from about 2 percent by weight to about 4 percent by weight. More preferably, the composition includes the gelling agents in a range from about 2 percent by weight to about 3 percent by weight.
The term "gelling agent" refers to a compound that homogeneously, when added to a 50 percent by weight water/50 percent by weight glycerol mixture, in an amount of about 0.3 percent by weight, forms a solid medium or support matrix leading to a gel. Gelling agents include, but are not limited to, hydrogen-bond crosslinking gelling agents, and ionic crosslinking gelling agents.WO 2021/170638 PCT/EP2021/054536 The gelling agent may include one or more biopolymers. The biopolymers may be formed of polysaccharides.
Biopolymers include, for example, gellan gums (native, low acyl gellan gum, high acyl gellan gums with low acyl gellan gum being preferred), xanthan gum, alginates (alginic acid), agar, guar gum, and the like. The composition may preferably include xanthan gum. The composition may include two biopolymers. The composition may include three biopolymers.
The composition may include the two biopolymers in substantially equal weights . The composition may include the three biopolymers in substantially equal weights.
Preferably, the gel composition comprises at least about 0.2 percent by weight hydrogen-bond crosslinking gelling agent. Alternatively or in addition, the gel composition preferably comprises at least about 0.2 percent by weight ionic crosslinking gelling agent.
Most preferably, the gel composition comprises at least about 0.2 percent by weight hydrogen- bond crosslinking gelling agent and at least about 0.2 percent by weight ionic crosslinking gelling agent. The gel composition may comprise about 0.5 percent by weight to about 3 percent by weight hydrogen-bond crosslinking gelling agent and about 0.5 percent by weight to about 3 percent by weight ionic crosslinking gelling agent, or about 1 percent by weight to about 2 percent by weight hydrogen-bond crosslinking gelling agent and about 1 percent by weight to about 2 percent by weight ionic crosslinking gelling agent .The hydrogen-bond crosslinking gelling agent and ionic crosslinking gelling agent may be present in the gel composition in substantially equal amounts by weight.
The term "hydrogen-bond crosslinking gelling agent" refers to a gelling agent that forms non-covalent crosslinking bonds or physical crosslinking bonds via hydrogen bonding.
Hydrogen bonding is a type of electrostatic dipole-dipole attractio betweenn molecules, not a covalent bond to a hydrogen atom. It results from the attractive force between a hydrogen atom covalently bonded to a very electronegative atom such as a N, O, or F atom and another very electronegative atom.
The hydrogen-bond crosslinking gelling agent may include one or more of a galactomannan, gelatin ,agarose, or konjac gum, or agar. The hydrogen-bond crosslinking gelling agent may preferably include agar.
The gel composition preferably includes the hydrogen-bond crosslinking gelling agent in a range from about 0.3 percent by weight to about 5 percent by weight. Preferably the composition includes the hydrogen-bond crosslinking gelling agent in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the composition includes the hydrogen-bond crosslinking gelling agent in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include a galactomannan in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the galactomannan may be in a range from WO 2021/170638 PCT/EP2021/054536 about 0.5 percent by weight to about 3 percent by weight . Preferably the galactomannan may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the galactomannan may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include a gelatin in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the gelatin may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the gelatin may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the gelatin may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include agarose in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the agarose may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the agarose may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the agarose may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include konjac gum in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the konjac gum may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the konjac gum may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the konjac gum may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include agar in a range from about 0.2 percent by weight to about 5 percent by weight . Preferably the agar may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the agar may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the agar may be in a range from about 1 percent by weight to about 2 percent by weight.
The term "ionic crosslinking gelling agent" refers to a gelling agent that forms non- covalent crosslinking bonds or physical crosslinking bonds via ionic bonding. Ionic crosslinking involves the association of polymer chains by noncovalent interactions. A crosslinked network is formed when multivalent molecules of opposite charges electrostatically attract each other giving rise to a crosslinked polymeric network.
The ionic crosslinking gelling agent may include low acyl gellan, pectin, kappa carrageenan, iota carrageenan or alginate. The ionic crosslinking gelling agent may preferably include low acyl gellan.
The gel composition may include the ionic crosslinking gelling agent in a range from about 0.3 percent by weight to about 5 percent by weight . Preferably the composition includes the ionic crosslinking gelling agent in a range from about 0.5 percent by weight to about 3 percent by weight by weight. Preferably the composition includes the ionic crosslinking gelling agent in a range from about 1 percent by weight to about 2 percent by weight.WO 2021/170638 PCT/EP2021/054536 The gel composition may include low acyl gellan in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the low acyl gellan may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the low acyl gellan may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the low acyl gellan may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include pectin in a range from about 0.2 percent by weight to about 5 percent by weight . Preferably the pectin may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the pectin may be in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the pectin may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include kappa carrageenan in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the kappa carrageenan may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the kappa carrageenan may be in a range from about 0.5 percent by weight to about 2 percent by weight.
Preferably the kappa carrageenan may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include iota carrageenan in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the iota carrageenan may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the iota carrageenan may be in a range from about 0.5 percent by weight to about 2 percent by weight.
Preferably the iota carrageenan may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include alginate in a range from about 0.2 percent by weight to about 5 percent by weight . Preferably the alginate may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the alginate may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the alginate may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include the hydrogen-bond crosslinking gelling agent and ionic crosslinking gelling agent in a ratio of about 3:1 to about 1:3. Preferably the gel composition may include the hydrogen-bond crosslinking gelling agent and ionic crosslinking gelling agent in a ratio of about 2:1 to about 1:2. Preferably the gel composition may include the hydrogen-bond crosslinking gelling agent and ionic crosslinking gelling agent in a ratio of about 1:1.
The gel composition may further include a viscosifying agent .The viscosifying agent combined with the hydrogen-bond crosslinking gelling agent and the ionic crosslinking gelling agent appears to surprisingly support the solid medium and maintain the gel composition even when the gel composition comprises a high level of glycerol.WO 2021/170638 PCT/EP2021/054536 The term "viscosifying agent" refers to a compound that, when added homogeneously into a 25°C, 50 percent by weight water/50 percent by weight glycerol mixture, in an amount of 0.3 percent by weight., increases the viscosity withou tleading to the formation of a gel, the mixture staying or remaining fluid. Preferably the viscosifying agent refers to a compound that when added homogeneously into a 25°C 50 percent by weight water/50 percent by weight glycerol mixture, in an amount of 0.3 percent by weight, increases the viscosity to at least 50 cPs, preferably at least 200 cPs, preferably at least 500 cPs, preferably at least 1000 cPs at ashear rate of 0.1 s1, withou tleading to the formation of a gel, the mixture staying or remaining fluid. Preferably the viscosifying agent refers to a compound that when added homogeneously into a 25°C 50 percent by weight water/50 percent by weight glycerol mixture, in an amount of 0.3 percent by weight, increases the viscosity at least 2 times, or at least 5 times, or at least times, or at least 100 times higher than before addition, at a shear rate of 0.1 s1־, without leading to the formation of a gel, the mixture staying or remaining fluid.
The viscosity values recited herein can be measured using a Brookfield RVT viscomete rotar ting a disc type RV#2 spindle at 25°C at a speed of 6 revolutions per minute (rpm).
The gel composition preferably includes the viscosifying agent in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the composition includes the viscosifying agent in a range from about 0.5 percent by weight to about 3 percent by weight.
Preferably the composition includes the viscosifying agent in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the composition includes the viscosifying agent in a range from about 1 percent by weight to about 2 percent by weight.
The viscosifying agent may include one or more of xanthan gum, carboxymethyl- cellulose, microcrystalline cellulose, methyl cellulose, gum Arabic, guar gum, lambda carrageenan, or starch. The viscosifying agent may preferably include xanthan gum.
The gel composition may include xanthan gum in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the xanthan gum may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the xanthan gum may be in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the xanthan gum may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include carboxymethyl-cellulose in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the carboxymethyl-cellulose may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the carboxymethyl-cellulose may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the carboxymethyl-cellulose may be in a range from about 1 percent by weight to about 2 percent by weight.WO 2021/170638 PCT/EP2021/054536 The gel composition may include microcrystalline cellulose in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the microcrystalline cellulose may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the microcrystalline cellulose may be in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the microcrystalline cellulose may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include methyl cellulose in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the methyl cellulose may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the methyl cellulose may be in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the methyl cellulose may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include gum Arabic in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the gum Arabic may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the gum Arabic may be in a range from about 0.5 percent by weight to about 2 percent by weight . Preferably the gum Arabic may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include guar gum in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the guar gum may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the guar gum may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the guar gum may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include lambda carrageenan in a range from about 0.2 percent by weight to about 5 percent by weight. Preferably the lambda carrageenan may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the lambda carrageenan may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the lambda carrageenan may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include starch in a range from about 0.2 percent by weight to about 5 percent by weight . Preferably the starch may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the starch may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the starch may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may further include a divalent cation. Preferably the divalent cation includes calcium ions, such as calcium lactate in solution. Divalent cations (such as calcium ions) may assist in the gel formation of compositions that include gelling agents such as the ionic crosslinking gelling agent, for example. The ion effect may assist in the gel WO 2021/170638 PCT/EP2021/054536 formation. The divalent cation may be present in the gel composition in a range from about 0.1 to about 1 percent by weight, or about 0.5 percent by weight t.
The gel composition may further include an acid. The acid may comprise a carboxylic acid. The carboxylic acid may include a ketone group. Preferably the carboxylic acid may include a ketone group having less than about 10 carbon atoms, or less than about 6 carbon atoms or less than about 4 carbon atoms, such as levulinic acid or lactic acid. Preferably this carboxylic acid has three carbon atoms (such as lactic acid). Lactic acid surprisingly improves the stabilit ofy the gel composition even over similar carboxylic acids. The carboxylic acid may assist in the gel formation. The carboxylic acid may reduce variation of the alkaloid compound concentration, or the cannabinoid compound concentration, or both the alkaloid compound concentration and the cannabinoid compound within the gel composition during storage. The carboxylic acid may reduce variation of the nicotine concentration within the gel composition during storage.
The gel composition may include a carboxylic acid in a range from about 0.1 percent by weight to about 5 percent by weight. Preferably the carboxylic acid may be in a range from about 0.5 percent by weight to about 3 percent by weight. Preferably the carboxylic acid may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the carboxylic acid may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include lactic acid in a range from about 0.1 percent by weight to about 5 percent by weight. Preferably the lactic acid may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the lactic acid may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the lactic acid may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition may include levulinic acid in a range from about 0.1 percent by weight to about 5 percent by weight . Preferably the levulinic acid may be in a range from about 0.5 percent by weight to about 3 percent by weight . Preferably the levulinic acid may be in a range from about 0.5 percent by weight to about 2 percent by weight. Preferably the levulinic acid may be in a range from about 1 percent by weight to about 2 percent by weight.
The gel composition preferably comprises some water . The gel composition is more stable when the composition comprises some water . Preferably the gel composition comprises at least about 1 percent by weight, or at least about 2 percent by weight., or at least about 5 percent by weight of water . Preferably the gel composition comprises at least about percent by weight or at least about 15 percent by weight water.
Preferably the gel composition comprises between about 8 percent by weight to about 32 percent by weight water . Preferably the gel composition comprises from about 15 percent by weight to about 25 percent by weight water. Preferably the gel composition comprises from WO 2021/170638 PCT/EP2021/054536 about 18 percent by weight to about 22 percent by weight water . Preferably the gel composition comprises about 20 percent by weight water.
Preferably, the aerosol-generating substrate comprises between about 150 mg and about 350 mg of the gel composition.
Preferably, in embodiments comprising a gel composition, the aerosol-generating substrate comprises a porous medium loaded with the gel composition. Advantages of a porous medium loaded with the gel composition is that the gel composition is retained within the porous medium, and this may aid manufacturing, storage or transport of the gel composition. It may assist in keeping the desired shape of the gel composition, especially during manufacture, transport, or use.
The term "porous" is used herein to refer to a material that provides a plurality of pores or openings that allow the passage of air through the material.
The porous medium may be any suitable porous material able to hold or retain the gel composition. Ideally the porous medium can allow the gel composition to move within it. In specific embodiments the porous medium comprises natural materials, synthetic, or semi- synthetic, or a combination thereof .In specific embodiments the porous medium comprises sheet material, foam, or fibres, for example loose fibres; or a combination thereof .In specific embodiments the porous medium comprises a woven, non-woven, or extruded material, or combinations thereof. Preferably the porous medium comprises, cotton paper,, viscose, PLA, or cellulose acetate, of combinations thereof. Preferably the porous medium comprises a sheet material, for example, cotton or cellulose acetate. In a particularly preferred embodiment, the porous medium comprises a sheet made from cotton fibres.
The porous medium used in the present invention may be crimped or shredded. In preferred embodiments, the porous medium is crimped. In alternativ eembodiments the porous medium comprises shredded porous medium. The crimping or shredding process can be before or after loading with the gel composition.
Crimping of the sheet material has the benefit of improving the structur eto allow passageways through the structure. The passageways though the crimped sheet material assist in loading up gel, retaining gel and also for fluid to pass through the crimped sheet material. Therefore there are advantages of using crimped sheet material as the porous medium.
Shredding gives a high surface area to volume ratio to the medium thus able to absorb gel easily.
In specific embodiments the sheet material is a composite material. Preferably the sheet material is porous. The sheet material may aid manufacture of the tubular elemen t comprising a gel. The sheet material may aid introducing an active agent to the tubular element comprising a gel. The sheet material may help stabilise the structur eof the tubular WO 2021/170638 PCT/EP2021/054536 element comprising a gel. The sheet material may assist transport or storage of the gel. Using a sheet material enables, or aids, adding structur eto the porous medium for example by crimping of the sheet material.
The porous medium may be a thread. The thread may comprise for example cotton, paper or acetate tow. The thread may also be loaded with gel like any other porous medium.
An advantage of using a thread as the porous medium is that it may aid ease of manufacturing.
The thread may be loaded with gel by any known means. The thread may be simply coated with gel, or the thread may be impregnated with gel. In the manufacture, the threads may be impregnated with gel and store dready for use to be included in the assembly of a tubular element.
The porous medium loaded with the gel composition is preferably provided within a tubular element that forms a part of the aerosol-generating article. Ideally the tubular elemen t may be longer in longitudinal length then in width but not necessarily as it may be one part of a multi- component item that ideally will be longer in its longitudinal length then its width.
Typically, the tubular element is cylindrical but not necessarily. For example, the tubular element may have an oval, polygonal like triangular or rectangular or random cross section.
The tubular element preferably comprises a first longitudinal passageway. The tubular element is preferably formed of a wrapper that defines the first longitudinal passageway. The wrapper is preferably a water-resistant wrapper. This water-resistant property the wrapper may be achieved by using a water-resista material,nt or by treating the material of the wrapper.
It may be achieved by treating one side or both sides of the wrapper. Being water -resistan t would assist in not losing structure, stiffness or rigidity. It may also assist in preventing leaks of gel or liquid, especially when gels of a fluid structure are used.
Preferably, in embodiments in which the rod of aerosol-generating substrate comprises a gel composition, as described above, the downstream sectio nof the aerosol-generating article comprises an aerosol-cooling element having a length of less than 10 millimetres. The use of a relatively short aerosol-cooling element in combination with a gel composition has found to optimise the delivery of aerosol to the consumer.
Embodiments of the invention in which the rod of aerosol-generating substrate comprises a gel composition, as described above, preferably comprise an upstream elemen t upstream of the rod of aerosol-generating substrat e.In this case, the upstream elemen t advantageous lyprevents physical contact with the gel composition. The upstream elemen t can also advantageous lycompensate for any potential reduction in RTD, for example, due to evaporation of the gel composition upon heating of the rod of aerosol-generating substrate during use. 35WO 2021/170638 PCT/EP2021/054536 In certain preferred embodiments of the present invention, an elongate susceptor element is arranged substantially longitudinally within the rod of aerosol-generating substrate and is in therma lcontact with the aerosol-generating substrate.
As used herein with reference to the present invention, the term "susceptor element" refers to a material that can convert electromagnetic energy into heat. When located within a fluctuating electromagnet icfield, eddy currents induced in the susceptor element cause heating of the susceptor element . As the elongate susceptor element is located in thermal contact with the aerosol-generating substrate, the aerosol-generating substrate is heated by the susceptor element.
When used for describing the susceptor element, the term "elongate" means that the susceptor element has a length dimension that is greater than its width dimension or its thickness dimension, for example greater than twice its width dimension or its thickness dimension.
The susceptor element is arranged substantially longitudinally within the rod. This means that the length dimension of the elongate susceptor element is arranged to be approximately parallel to the longitudinal directio nof the rod, for example within plus or minus degrees of parallel to the longitudinal direction of the rod. In preferred embodiments, the elongate susceptor elemen tmay be positione din a radially central position within the rod, and extends along the longitudinal axis of the rod.
Preferably, the susceptor elemen textends all the way to a downstream end of the rod of aerosol-generating article. In some embodiments, the susceptor element may extend all the way to an upstream end of the rod of aerosol-generating article. In particularly preferred embodiments, the susceptor element has substantiall they same length as the rod of aerosol- generating substrat e,and extends from the upstream end of the rod to the downstream end of the rod.
The susceptor element is preferably in the form of a pin, rod, strip or blade.
The susceptor element preferably has a length from about 5 millimetre sto about 15 millimetres, for example from about 6 millimetres to about 12 millimetres, or from about 8 millimetre sto about 10 millimetres.
A ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate may be from about 0.2 to about 0.35.
Preferably, a ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is at least about 0.22, more preferably at least about 0.24, even more preferably at least about 0.26. A ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is preferably less than about 0.34, more preferably less than about 0.32, even more preferably less than about 0.3.WO 2021/170638 PCT/EP2021/054536 In some embodiments, a ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about 0.34, more preferably from about 0.24 to about 0.34, even more preferably from about 0.26 to about 0.34. In other embodiments, a ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about 0.32, more preferably from about 0.24 to about 0.32, even more preferably from about 0.26 to about 0.32. In further embodiments, a ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is preferably from about 0.22 to about 0.3, more preferably from about 0.24 to about 0.3, even more preferably from about 0.26 to about 0.3.
In a particularly preferred embodiment, a ratio between the length of the susceptor element and the overall length of the aerosol-generating article substrate is about 0.27.
The susceptor element preferably has a width from about 1 millimetres to about 5 millimetres.
The susceptor element may generally have a thickness from about 0.01 millimetre sto about 2 millimetres, for example from about 0.5 millimetres to about 2 millimetres. In some embodiments, the susceptor element preferably has a thickness from about 10 micrometres to about 500 micrometres, more preferably from about 10 micrometres to about 100 micrometres.
If the susceptor element has a constant cross-section, for example a circular cross- section, it has a preferable width or diameter from about 1 millimetre to about 5 millimetres.
If the susceptor element has the form of a strip or blade, the strip or blade preferably has a rectangula rshape having a width of preferably from about 2 millimetre sto about 8 millimetres, more preferably from about 3 millimetres to about 5 millimetres. By way of example, a susceptor element in the form of a strip of blade may have a width of about 4 millimetres.
If the susceptor element has the form of a strip or blade, the strip or blade preferably has a rectangular shape and a thickness from about 0.03 millimetres to about 0.15 millimetres, more preferably from about 0.05 millimetres to about 0.09 millimetres. By way of example, a susceptor element in the form of a strip of blade may have a thickness of about 0.07 millimetres.
In a preferred embodiment, the elongate susceptor element is in the form of a strip or blade, preferably has a rectangular shape, and has a thickness from about 55 micrometres to about 65 micrometres.
More preferably, the elongate susceptor element has a thickness from about 57 micrometres to about 63 micrometres. Even more preferably, the elongate susceptor elemen t has a thickness from about 58 micrometres to about 62 micrometres. In a particularly WO 2021/170638 PCT/EP2021/054536 preferred embodiment, the elongate susceptor element has a thickness of about 60 micrometres.
Preferably, the elongate susceptor element has a length which is the same or shorte r than the length of the aerosol-generating substrate. Preferably, the elongate susceptor element has a same length as the aerosol-generating substrate.
The susceptor element may be formed from any material that can be inductively heated to a temperature sufficient to generate an aerosol from the aerosol-generating substrat e.
Preferred susceptor elements comprise a metal or carbon.
A preferred susceptor element may comprise or consist of a ferromagneti cmaterial, for example a ferromagnetic alloy, ferritic iron, or a ferromagnetic steel or stainless steel. A suitable susceptor elemen tmay be, or comprise, aluminium. Preferred susceptor element s may be formed from 400 series stainless steels, for example grade 410, or grade 420, or grade 430 stainless steel. Different materials will dissipate different amounts of energy when positione dwithin electromagnet fieldsic having similar values of frequency and field strength.
Thus, parameters of the susceptor element such as material type, length, width, and thickness may all be altered to provide a desired power dissipation within a known electromagnet icfield. Preferred susceptor elements may be heated to a temperature in excess of 250 degrees Celsius.
Suitable susceptor elements may comprise a non-metallic core with a metal layer disposed on the non-metallic core, for example metallic tracks formed on a surface of a ceramic core. A susceptor element may have a protectiv eexternal layer, for example a protective ceramic layer or protective glass layer encapsulating the susceptor element .The susceptor element may comprise a protective coating formed by a glass, a ceramic, or an inert metal ,formed over a core of susceptor element material.
The susceptor element is arranged in therma l contact with the aerosol-generating substrat e.Thus, when the susceptor element heats up the aerosol-generating substrate is heated up and an aerosol is formed. Preferably the susceptor element is arranged in direct physical contact with the aerosol-generating substrate, for example within the aerosol- generating substrate.
The susceptor element may be a multi-material susceptor element and may comprise a first susceptor element material and a second susceptor element material. The first susceptor element material is disposed in intimate physical contact with the second susceptor elemen t material. The second susceptor element material preferably has a Curie temperature that is lower than 500 degrees Celsius. The first susceptor element material is preferably used primarily to heat the susceptor element when the susceptor element is placed in a fluctuating electromagnet icfield. Any suitable material may be used. For example the first susceptor element material may be aluminium, or may be a ferrous material such as a stainless steel.WO 2021/170638 PCT/EP2021/054536 The second susceptor element material is preferably used primarily to indicate when the susceptor element has reached a specific temperature, that temperatur ebeing the Curie temperature of the second susceptor element material. The Curie temperature of the second susceptor element material can be used to regulate the temperature of the entire susceptor element during operation. Thus, the Curie temperature of the second susceptor elemen t material should be below the ignition point of the aerosol-generating substrat e.Suitable materials for the second susceptor element material may include nickel and certain nickel alloys.
By providing a susceptor element having at least a first and a second susceptor elemen t material, with either the second susceptor elemen tmaterial having a Curie temperature and the first susceptor element material not having a Curie temperatur e,or first and second susceptor element materials having first and second Curie temperatures distinct from one another, the heating of the aerosol-generating substrate and the temperature contro lof the heating may be separated. The first susceptor element material is preferably a magnetic material having a Curie temperature that is above 500 degrees Celsius. It is desirable from the point of view of heating efficiency that the Curie temperature of the first susceptor elemen t material is above any maximum temperature that the susceptor element should be capable of being heated to. The second Curie temperature may preferably be selected to be lower than 400 degrees Celsius, preferably lower than 380 degrees Celsius, or lower than 360 degrees Celsius. It is preferable that the second susceptor element material is a magnetic material selected to have a second Curie temperatur ethat is substantiall they same as a desired maximum heating temperatur e.That is, it is preferable that the second Curie temperature is approximately the same as the temperature that the susceptor element should be heated to in order to generate an aerosol from the aerosol-generating substrat e.The second Curie temperature may, for example, be within the range of 200 degrees Celsius to 400 degrees Celsius, or between 250 degrees Celsius and 360 degrees Celsius. The second Curie temperature of the second susceptor elemen tmaterial may, for example, be selected such that, upon being heated by a susceptor element that is at a temperature equal to the second Curie temperatur e,an overall average temperature of the aerosol-generating substrate does not exceed 240 degrees Celsius.
The aerosol-generating articles of the present invention may further comprise an upstream element located upstream of and adjacent to the aerosol-generating substrate, wherein the upstream section comprises at least one upstream element. The upstream element advantageous lyprevents direct physical contact with the upstream end of the aerosol- generating substrate. In particular , where the aerosol-generating substrate comprises a susceptor element, the upstream element may prevent direct physical contact with the upstream end of the susceptor element. This helps to prevent the displacement or WO 2021/170638 PCT/EP2021/054536 deformation of the susceptor element during handling or transport of the aerosol-generating article. This in turn helps to secure the form and position of the susceptor element.
Furthermore, the presence of an upstream element helps to prevent any loss of the substrat e, which may be advantageous, for example, if the substrate contains particulate plant material.
The upstream element may also provide an improved appearance to the upstream end of the aerosol-generating article. Furthermore, if desired, the upstream element may be used to provide information on the aerosol-generating article, such as information on brand, flavour, content, or details of the aerosol-generating device that the article is intended to be used with.
The upstream element may be a porous plug element . Preferably, a porous plug element does not alter the resistance to draw of the aerosol-generating article. Preferably, the upstream element has a porosity of at least about 50 percent in the longitudinal direction of the aerosol-generating article. More preferably, the upstream element has a porosity of between about 50 percent and about 90 percent in the longitudinal direction. The porosity of the upstream element in the longitudinal directio nis defined by the ratio of the cross-section al area of material forming the upstream element and the internal cross-sectional area of the aerosol-generating article at the position of the upstream element.
The upstream element may be made of a porous material or may comprise a plurality of openings. This may, for example, be achieved through laser perforation. Preferably, the plurality of openings is distributed homogeneously over the cross-section of the upstream element.
The porosity or permeabilit yof the upstream element may advantageously be varied in order to provide a desirable overall resistance to draw of the aerosol-generating article.
Preferably, the RTD of the upstream element is at least about 5 millimetres H2O. More preferably, the RTD of the upstream element is at least about 10 millimetres H2O. Even more preferably, the RTD of the upstream element is at least about 15 millimetres H2O. In particularly preferred embodiments, the RTD of the upstream element is at least about 20 millimetres H2O.
The RTD of the upstream element is preferably less than or equal to about 80 millimetres H2O. More preferably, the RTD of the upstream element is less than or equal to about 60 millimetres H2O. Even more preferably, the RTD of the upstream element is less than or equal to about 40 millimetres H2O.
In some embodiments, the RTD of the upstream element is from about 5 millimetres H2O to about 80 millimetres H2O, preferably from about 10 millimetres H2O to about 80 millimetres H2O, more preferably from about 15 millimetres H2O to about 80 millimetres H2O, even more preferably from about 20 millimetre sH2O to about 80 millimetres H2O. In other embodiments, the RTD of the upstream element is from about 5 millimetres H2O to about 60 millimetres H2O, preferably from about 10 millimetre sH2O to about 60 millimetres H2O, moreWO 2021/170638 PCT/EP2021/054536 preferably from about 15 millimetres H2O to about 60 millimetre sH2O, even more preferably from about 20 millimetres H2O to about 60 millimetres H2O. In furthe rembodiments, the RTD of the upstream element is from about 5 millimetres H2O to about 40 millimetres H2O, preferably from about 10 millimetres H2O to about 40 millimetres H2O, more preferably from about 15 millimetre sH2O to about 40 millimetres H2O, even more preferably from about 20 millimetres H2O to about 40 millimetre sH2O.
In alternative embodiments, the upstream element may be formed from a material that is impermeable to air. In such embodiments, the aerosol-generating article may be configured such that air flows into the rod of aerosol-generating substrate through suitable ventilation means provided in a wrapper.
The upstream element may be made of any material suitable for use in an aerosol- generating article. The upstream element may, for example, be made of a same material as used for one of the other components of the aerosol-generating article, such as the mouthpiece, the cooling element or the support element. Suitable materials for forming the upstream element include filte r materials, ceramic, polymer material, cellulose acetate, cardboard, zeolite or aerosol-generating substrat e.Preferably, the upstream element is formed from a plug of cellulose acetate.
Preferably, the upstream element is formed of a heat resistan material.t For example, preferably the upstream element is formed of a material that resists temperatures of up to 350 degrees Celsius. This ensures that the upstream element is not adversely affected by the heating means for heating the aerosol-generating substrate.
Preferably, the upstream element has a diameter that is approximately equal to the diameter of the aerosol-generating article.
Preferably, the upstream element has a length of between about 1 millimetre and about 10 millimetres, more preferably between about 3 millimetre sand about 8 millimetres, more preferably between about 4 millimetre sand about 6 millimetres. In a particularly preferred embodiment, the upstream element has a length of about 5 millimetres. The length of the upstream element can advantageous lybe varied in order to provide the desired total length of the aerosol-generating article. For example, where it is desired to reduce the length of one of the other components of the aerosol-generating article, the length of the upstream elemen t may be increased in order to maintain the same overall length of the article.
The upstream element preferably has a substantially homogeneous structure. For example, the upstream element may be substantially homogeneous in texture and appearance. The upstream element may, for example, have a continuous, regular surface over its entire cross section. The upstream element may, for example, have no recognisable symmetries.WO 2021/170638 PCT/EP2021/054536 The upstream element is preferably circumscribed by a wrapper. The wrapper circumscribing the upstream element is preferably a stiff plug wrap, for example, a plug wrap having a basis weight of at least about 80 grams per square metre (gsm), or at least about 100 gsm, or at least about 110 gsm. This provides structur alrigidity to the upstream element.
The aerosol-generating article according to the present invention may have a length from about 35 millimetres to about 100 millimetres.
Preferably, an overall length of an aerosol-generating article in accordance with the invention is at least about 38 millimetres. More preferably, an overall length of an aerosol- generating article in accordance with the invention is at least about 40 millimetres. Even more preferably, an overall length of an aerosol-generating article in accordance with the invention is at least about 42 millimetres.
An overall length of an aerosol-generating article in accordance with the invention is preferably less than or equal to 70 millimetres. More preferably, an overall length of an aerosol-generating article in accordance with the invention is preferably less than or equal to 60 millimetres. Even more preferably, an overall length of an aerosol-generating article in accordance with the invention is preferably less than or equal to 50 millimetres.
In some embodiments, an overall length of the aerosol-generating article is preferably from about 38 millimetres to about 70 millimetres, more preferably from about 40 millimetres to about 70 millimetres, even more preferably from about 42 millimetres to about 70 millimetres. In other embodiments, an overall length of the aerosol-generating article is preferably from about 38 millimetre sto about 60 millimetres, more preferably from about 40 millimetres to about 60 millimetres, even more preferably from about 42 millimetres to about 60 millimetres. In furthe rembodiments, an overall length of the aerosol-generating article is preferably from about 38 millimetre sto about 50 millimetres, more preferably from about 40 millimetres to about 50 millimetres, even more preferably from about 42 millimetres to about 50 millimetres. In an exemplary embodiment, an overall length of the aerosol-generating article is about 45 millimetres.
The aerosol-generating article preferably has an external diameter of at least 5 millimetres. Preferably, the aerosol-generating article has an external diameter of at least 6 millimetres. More preferably, the aerosol-generating article has an external diameter of at least 7 millimetres.
Preferably, the aerosol-generating article has an external diameter of less than or equal to about 12 millimetres. More preferably, the aerosol-generating article has an external diameter of less than or equal to about 10 millimetres. Even more preferably, the aerosol- generating article has an external diameter of less than or equal to about 8 millimetres.
In some embodiments, the aerosol-generating article has an external diameter from about 5 millimetres to about 12 millimetres, preferably from about 6 millimetres to about 12 WO 2021/170638 PCT/EP2021/054536 millimetres, more preferably from about 7 millimetres to about 12 millimetres. In other embodiments, the aerosol-generating article has an external diameter from about 5 millimetres to about 10 millimetres, preferably from about 6 millimetres to about 10 millimetres, more preferably from about 7 millimetres to about 10 millimetres. In further embodiments, the aerosol-generating article has an external diameter from about 5 millimetre sto about 8 millimetres, preferably from about 6 millimetres to about 8 millimetres, more preferably from about 7 millimetres to about 8 millimetres.
In certain preferred embodiments of the invention, a diameter (DMe) of the aerosol- generating article at the mouth end is (preferably) greater than a diameter (Dde) of the aerosol- generating article at the distal end. In more detail ,a ratio (DME/DDE) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is (preferably) at least about 1.005.
Preferably, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is (preferably) at least about 1.01. More preferably, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is at least about 1.02. Even more preferably, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is at least about 1.05.
A ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is preferably less than or equal to about 1.30. More preferably, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is less than or equal to about 1.25. Even more preferably, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is less than or equal to about 1.20. In particularly preferred embodiments, a ratio (Dme/Dde) between the diameter of the aerosol- generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is less than or equal to 1.15 or 1.10.
In some preferred embodiments, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is from about 1.01 to 1.30, more preferably from 1.02 to 1.30, even more preferably from 1.05 to 1.30.
In other embodiments, a ratio (Dme/Dde) between the diameter of the aerosol- generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is from about 1.01 to 1.25, more preferably from 1.02 to 1.25, even more preferably from 1.05 to 1.25. In further embodiments, a ratio (Dme/Dde) between the diameter of the WO 2021/170638 PCT/EP2021/054536 aerosol-generating article at the mouth end and the diameter of the aerosol-generating article at the distal end is from about 1.01 to 1.20, more preferably from 1.02 to 1.20, even more preferably from 1.05 to 1.20. In yet further embodiments, a ratio (Dme/Dde) between the diameter of the aerosol-generating article at the mouth end and the diameter of the aerosol- generating article at the distal end is from about 1.01 to 1.15, more preferably from 1.02 to 1.15, even more preferably from 1.05 to 1.15.
By way of example, the external diameter of the article may be substantiall constanty over a distal portion of the article extending from the distal end of the aerosol-generating article for at least about 5 millimetres or at least about 10 millimetres. As an alternative, the external diamete ofr the article may taper over a distal portion of the article extendin gfrom the distal end for at least about 5 millimetres or at least about 10 millimetres.
In certain preferred embodiments of the present invention, the elements of the aerosol- generating article, as described above, are arranged such that the centre of mass of the aerosol-generating article is at least about 60 percent of the way along the length of the aerosol-generating article from the downstream end. More preferably, the elements of the aerosol-generating article are arranged such that the centre of mass of the aerosol-generating article is at least about 62 percent of the way along the length of the aerosol-generating article from the downstream end, more preferably at least about 65 percent of the way along the length of the aerosol-generating article from the downstream end.
Preferably, the centre of mass is no more than about 70 percent of the way along the length of the aerosol-generating article from the downstream end.
Providing an arrangement of elements that gives a centre of mass that is closer to the upstream end than the downstream end results in an aerosol-generating article having a weight imbalance, with a heavier upstream end. This weight imbalance may advantageous ly provide haptic feedback to the consumer to enable them to distinguish between the upstream and downstream ends so that the correct end can be inserted into an aerosol-generating device. This may be particularly beneficial where an upstream element is provided such that the upstream and downstream ends of the aerosol-generating article are visually similar to each other.
In embodiments of aerosol-generating articles in accordance with the invention, wherein both aerosol-cooling element and support element are present, these are preferably wrapped together in a combined wrapper. The combined wrapper circumscribes the aerosol- cooling element and the support element, but does not circumscribe a furthe rdownstream, such as a mouthpiece element.
In these embodiments, the aerosol-cooling element and the support element are combined prior to being circumscribed by the combined wrapper, before they are further combined with the mouthpiece segment.WO 2021/170638 PCT/EP2021/054536 From a manufacturing viewpoint, this is advantageous in that it enables shorte r aerosol-generating articles to be assembled.
In general, it may be difficult to handle individual elements that have a length smaller than their diameter. For example, for elements with a diamete ofr 7 millimetres, a length of about 7 millimetres represents a threshold value close to which it is preferable not to go.
However, an aerosol-cooling element of 10 millimetres can be combined with a pair of support elements of 7 millimetres on each side (and potentially with other element slike the rod of aerosol-generating substrat e,etc.) to provide a hollow segment of 24 millimetres, which is subsequently cut into two intermediate hollow sections of 12 millimetres.
In particularly preferred embodiments, the other components of the aerosol- generating article are individually circumscribed by their own wrapper. In other words, the upstream element, the rod of aerosol-generating substrat e,the support element, and the aerosol-cooling element are all individually wrapped. The support element and the aerosol- cooling element are combined to form the intermediate hollow section. This is achieved by wrapping the support element and the aerosol-cooling element by means of a combined wrapper. The upstream element, the rod of aerosol-generating substrat e,and the intermediate hollow section are then combined together with an outer wrapper. Subsequently, they are combined with the mouthpiece element - which has a wrapper of its own - by means of tipping paper.
Preferably, at least one of the components of the aerosol-generating article is wrapped in a hydrophobic wrapper.
The term "hydrophobic" refers to a surface exhibiting water repelling properties. One useful way to determine this is to measure the water contact angle. The "water contact angle" is the angle, conventionally measured through the liquid, where a liquid/vapour interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation .
Hydrophobicity or water contact angle may be determine dby utilizing TAPPIT558 test method and the resul tis presented as an interfacial contact angle and reported in "degrees" and can range from near zero to near 180 degrees.
In preferred embodiments, the hydrophobic wrapper is one including a paper layer having a water contact angle of about 30 degrees or greater, and preferably about 35 degrees or greater, or about 40 degrees or greater, or about 45 degrees or greater.
By way of example, the paper layer may comprise PVOH (polyvinyl alcohol) or silicon.
The PVOH may be applied to the paper layer as a surface coating, or the the paper layer may comprise a surface treatmen comprisingt PVOH or silicon.
In a particularly preferred embodiment, an aerosol-generating article in accordance with the present invention comprises, in linear sequentia arrangement,l an upstream element, a rod of aerosol-generating substrate located immediately downstream of the upstreamWO 2021/170638 PCT/EP2021/054536 element, a support elemen tlocated immediately downstream of the rod of aerosol-generating substrat e,an aerosol-cooling element located immediately downstream of the support element, a mouthpiece element located immediately downstream of the aerosol-cooling element, and an outer wrapper circumscribing the upstream element, the support element, the aerosol-cooling element and the mouthpiece element.
In more detail ,the rod of aerosol-generating substrate may abut the upstream element.
The support element may abut the rod of aerosol-generating substrat e.The aerosol-cooling element may abut the support element. The mouthpiece element may abut the aerosol- cooling element.
The aerosol-generating article has a substantially cylindrical shape and an outer diameter of about 7.25 millimetres.
The upstream element has a length of about 5 millimetres, the rod of aerosol-generating article has a length of about 12 millimetres, the support element has a length of about 8 millimetres, the mouthpiece element has a length of about 12 millimetres. Thus, an overall length of the aerosol-generating article is about 45 millimetres.
The upstream element is in the form of a plug of cellulose acetate wrapped in stiff plug wrap.
The aerosol-generating article comprises an elongate susceptor element arranged substantially longitudinally within the rod of aerosol-generating substrate and is in thermal contact with the aerosol-generating substrat e.The susceptor element is in the form of a strip or blade, has a length substantially equal to the length of the rod of aerosol-generating substrate and a thickness of about 60 micrometres.
The support element is in the form of a hollow cellulose acetate tube and has an internal diameter of about 1.9 millimetres. Thus, a thickness of a peripheral wall of the support elemen t is about 2.675 millimetres.
The aerosol-cooling element is in the form of a finer hollow cellulose acetate tube and has an internal diameter of about 3.25 millimetres. Thus, a thickness of a peripheral wall of the aerosol-cooling element is about 2 millimetres.
The mouthpiece is in the form of a low-density cellulose acetate filte rsegment.
The rod of aerosol-generating substrate comprises at least one of the types of aerosol- generating substrate described above, such as homogenised tobacco, a gel formulation or a homogenised plant material comprising particles of a plant other than tobacco.
In the following, the invention will be furthe rdescribed with reference to the drawing of the accompanying Figure 1, which shows a schematic side sectional view of an aerosol- generating article in accordance with the invention.
The aerosol-generating article 10 shown in Figure 1 comprises a rod 12 of aerosol- generating substrate 12 and a downstream sectio n14 at a location downstream of the rod 12 WO 2021/170638 PCT/EP2021/054536 of aerosol-generating substrat e.Further, the aerosol-generating article 10 comprises an upstream sectio n16 at a location upstream of the rod 12 of aerosol-generating substrate.
Thus, the aerosol-generating article 10 extends from an upstream or distal end 18 to a downstream or mouth end 20.
The aerosol-generating article has an overall length of about 45 millimetres.
The downstream sectio n14 comprises a support element 22 located immediately downstream of the rod 12 of aerosol-generating substrat e,the support element 22 being in longitudinal alignment with the rod 12. In the embodiment of Figure 1, the upstream end of the support element 18 abuts the downstream end of the rod 12 of aerosol-generating substrat e.In addition, the downstream section 14 comprises an aerosol-cooling element 24 located immediately downstream of the support element 22, the aerosol-cooling element 24 being in longitudinal alignment with the rod 12 and the support element 22. In the embodiment of Figure 1, the upstream end of the aerosol-cooling element 24 abuts the downstream end of the support element 22.
As will become apparent from the following description, the support element 22 and the aerosol-cooling element 24 together define an intermediate hollow section 50 of the aerosol- generating article 10. As a whole, the intermediate hollow section 50 does not substantia lly contribute to the overall RTD of the aerosol-generating article. An RTD of the intermediate hollow section 26 as a whole is substantially 0 millimetres H2O.
The support element 22 comprises a first hollow tubular segment 26. The first hollow tubular segmen t26 is provided in the form of a hollow cylindrical tube made of cellulose acetate. The first hollow tubular segment 26 defines an internal cavity 28 that extends all the way from an upstream end 30 of the first hollow tubular segmen tto an downstream end 32 of the first hollow tubular segmen t20. The internal cavity 28 is substantially empty, and so substantially unrestricted airflow is enabled along the internal cavity 28. The first hollow tubular segment 26 - and, as a consequence, the support element 22 - does not substantiall y contribute to the overall RTD of the aerosol-generating article 10. In more detail, the RTD of the first hollow tubular segment 26 (which is essentially the RTD of the support element 22) is substantially 0 millimetres H2O.
The first hollow tubular segment 26 has a length of about 8 millimetres, an external diameter of about 7.25 millimetres, and an internal diameter (DFts) of about 1.9 millimetres.
Thus, a thickness of a peripheral wall of the first hollow tubular segmen t26 is about 2.67 millimetres.
The aerosol-cooling element 24 comprises a second hollow tubular segmen t34. The second hollow tubular segmen t34 is provided in the form of a hollow cylindrical tube made of cellulose acetate. The second hollow tubular segmen t34 defines an internal cavity 36 that extends all the way from an upstream end 38 of the second hollow tubular segmen tto a WO 2021/170638 PCT/EP2021/054536 downstream end 40 of the second hollow tubular segmen t34. The internal cavity 36 is substantially empty, and so substantially unrestricted airflow is enabled along the internal cavity 36. The second hollow tubular segmen t28 - and, as a consequence, the aerosol- cooling element 24 - does not substantiall contriby ute to the overall RTD of the aerosol- generating article 10. In more detail, the RTD of the second hollow tubular segmen t34 (which is essential lythe RTD of the aerosol-cooling element 24) is substantially 0 millimetres H2O.
The second hollow tubular segment 34 has a length of about 8 millimetres, an external diameter of about 7.25 millimetres, and an internal diamete (Dr STs) of about 3.25 millimetres.
Thus, a thickness of a peripheral wall of the second hollow tubular segmen t34 is about 2 millimetres. Thus, a ratio between the internal diameter (DFts) of the first hollow tubular segmen t26 and the internal diameter (DSts) of the second hollow tubular segmen t34 is about 0.75.
The aerosol-generating article 10 comprises a ventilation zone 60 provided at a location along the second hollow tubular segmen t34. In more detail, the ventilation zone is provided at about 2 millimetres from the upstream end of the second hollow tubular segmen t34. A ventilation level of the aerosol-generating article 10 is about 25 percent.
In the embodiment of Figure 1, the downstream section 14 furthe r comprises a mouthpiece element 42 at a location downstream of the intermediate hollow section 50. In more detail ,the mouthpiece element 42 is positione dimmediately downstream of the aerosol- cooling element 24. As shown in the drawing of Figure 1, an upstream end of the mouthpiece element 42 abuts the downstream end 40 of the aerosol-cooling element 18.
The mouthpiece element 42 is provided in the form of a cylindrical plug of low-density cellulose acetate.
The mouthpiece elemen t42 has a length of about 12 millimetre sand an external diameter of about 7.25 millimetres. The RTD of the mouthpiece element 42 is about 12 millimetres H2O. The ratio of the length of the mouthpiece element 42 to the length of the intermediate hollow section 50 is approximately 0.6.
The rod 12 comprises an aerosol-generating substrate of one of the types described above.
The rod 12 of aerosol-generating substrate has an external diameter of about 7.25 millimetres and a length of about 12 millimetres.
The aerosol-generating article 10 further comprises an elongate susceptor element 44 within the rod 12 of aerosol-generating substrat e.In more detail, the susceptor element 44 is arranged substantially longitudinally within the aerosol-generating substrat e,such as to be approximately parallel to the longitudinal directio nof the rod 12. As shown in the drawing of Figure 1, the susceptor element 44 is positione din a radially central position within the rod and extends effectively along the longitudinal axis of the rod 12.WO 2021/170638 PCT/EP2021/054536 The susceptor element 44 extends all the way from an upstream end to a downstream end of the rod 12. In effect, the susceptor element 44 has substantially the same length as the rod 12 of aerosol-generating substrate.
In the embodiment of Figure 1, the susceptor elemen t44 is provided in the form of a strip and has a length of about 12 millimetres, a thickness of about 60 micrometres, and a width of about 4 millimetres. The upstream sectio n16 comprises an upstream element 46 located immediately upstream of the rod 12 of aerosol-generating substrate, the upstream element 46 being in longitudinal alignment with the rod 12. In the embodiment of Figure 1, the downstream end of the upstream element 46 abuts the upstream end of the rod 12 of aerosol-generating substrat e.This advantageously prevents the susceptor element 44 from being dislodged. Further, this ensures that the consumer cannot accidentally contact the heated susceptor elemen t44 after use.
The upstream element 46 is provided in the form of a cylindrical plug of cellulose acetate circumscribed by a stif wrappf er. The upstream element 46 has a length of about 5 millimetres.
The RTD of the upstream elemen t46 is about 30 millimetres H2O.
Claims (14)
1. An aerosol-generating article for producing an inhalable aerosol upon heating, the aerosol-generating article comprising: a rod of aerosol-generating substrate; a mouthpiece element having a length L1 and comprising at least one mouthpiece filter segment formed of a fibrous filtration material; and an intermediate hollow section between the rod of aerosol-generating substrate and the mouthpiece element, the intermediate hollow section having a length L2 and comprising: an aerosol-cooling element downstream of the rod of aerosol-generating substrate, the aerosol-cooling element comprising a hollow tubular segment defining a longitudinal cavity providing an unrestricted flow channel, wherein the length of the aerosol-cooling element is less than 10 millimetres; and a support element between the aerosol-cooling element and the rod of aerosol- generating substrate, wherein the upstream end of the aerosol-cooling element abuts the downstream end of the support element, and wherein the length of the mouthpiece element (L1) is at least 0.4 times the length of the intermediate hollow section (L2).
2. An aerosol-generating article according to claim 1, wherein the length of the mouthpiece element (L1) is at least 0.6 times the length of the intermediate hollow section (L2).
3. An aerosol-generating article according to claim 1, wherein the length of the mouthpiece element (L1) is at least 0.75 times the length of the intermediate hollow section (L2).
4. An aerosol-generating article according to any of claims 1 to 3, wherein the length of the mouthpiece element (L1) is at least 2 millimetres greater than the length of the aerosol- cooling element.
5. An aerosol-generating article according to any preceding claim, wherein the length of the mouthpiece element is greater than 10 millimetres. - 61 -
6. An aerosol-generating article according to any preceding claim, wherein the mouthpiece element comprises a mouthpiece filter segment having a length that is at least 0.4 times the length of the intermediate hollow section (L2).
7. An aerosol-generating article according to any preceding claim, further comprising an upstream element provided upstream of the rod of aerosol-generating substrate.
8. An aerosol-generating article according to any preceding claim, wherein the resistance to draw (RTD) of the mouthpiece element is less than 15 millimetres H2O.
9. An aerosol-generating article according to any preceding claim, wherein the hollow tubular segment of the aerosol-cooling element has a wall thickness of less than 2.5 millimetres.
10. An aerosol-generating article according to any preceding claim, wherein the aerosol- cooling element further comprises a ventilation zone at a position along the hollow tubular segment.
11. An aerosol-generating article according to any preceding claim, wherein the rod of aerosol-generating substrate comprises a gel composition.
12. An aerosol-generating article according to any preceding claim, wherein the support element comprises a hollow tubular segment defining a longitudinal cavity providing an unrestricted flow channel.
13. An aerosol-generating article according to any preceding claim, wherein the length of the intermediate hollow section is no more than 18 millimetres.
14. An aerosol-generating article according to any preceding claim having a total length of 45 millimetres.
Applications Claiming Priority (2)
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EP20160206 | 2020-02-28 | ||
PCT/EP2021/054536 WO2021170638A1 (en) | 2020-02-28 | 2021-02-24 | Aerosol-generating article with improved configuration |
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IL295499A true IL295499A (en) | 2022-10-01 |
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IL295499A IL295499A (en) | 2020-02-28 | 2021-02-24 | Aerosol-generating article with improved configuration |
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US (1) | US20230093519A1 (en) |
EP (1) | EP4110098A1 (en) |
JP (1) | JP2023516959A (en) |
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US20230371585A1 (en) | 2020-10-09 | 2023-11-23 | Philip Morris Products S.A. | Aerosol-generating article with upstream section, hollow tubular element and ventilation |
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US5774493A (en) | 1996-08-02 | 1998-06-30 | General Electric Company | Sequence constructions for delay-and-correlate transmitted reference signaling |
US20070074734A1 (en) * | 2005-09-30 | 2007-04-05 | Philip Morris Usa Inc. | Smokeless cigarette system |
AU2012360831B2 (en) * | 2011-12-30 | 2017-02-16 | Philip Morris Products S.A. | Smoking article with front-plug and aerosol-forming substrate and method |
EP3794966B1 (en) | 2013-07-16 | 2024-07-24 | Philip Morris Products S.A. | Radially firm smoking article filter |
ES2944585T3 (en) | 2014-05-21 | 2023-06-22 | Philip Morris Products Sa | Aerosol-generating article with internal susceptor |
CN107087811B (en) * | 2017-05-26 | 2019-10-11 | 湖北中烟工业有限责任公司 | With the low temperature cigarette for reducing flue-gas temperature and preventing mouth stick heat from collapsing |
WO2018224679A1 (en) * | 2017-06-09 | 2018-12-13 | Philip Morris Products S.A. | Aerosol-generating article having fibrous filter segment |
CA3044945A1 (en) * | 2018-05-31 | 2019-11-30 | Xue ZHAO | Heat-not-burn cigarettes |
WO2020070184A1 (en) * | 2018-10-03 | 2020-04-09 | Nerudia Limited | Smoking substitute consumable |
WO2020128043A1 (en) * | 2018-12-20 | 2020-06-25 | Philip Morris Products S.A. | Aerosol-generating article having a ventilated cavity |
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- 2021-02-24 US US17/905,024 patent/US20230093519A1/en active Pending
- 2021-02-24 CN CN202180017027.XA patent/CN115915975A/en active Pending
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BR112022016977A2 (en) | 2022-10-25 |
WO2021170638A1 (en) | 2021-09-02 |
CN115915975A (en) | 2023-04-04 |
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KR20220148217A (en) | 2022-11-04 |
EP4110098A1 (en) | 2023-01-04 |
ZA202210614B (en) | 2024-06-26 |
CA3168776A1 (en) | 2021-09-02 |
US20230093519A1 (en) | 2023-03-23 |
AU2021228922A1 (en) | 2022-09-22 |
JP2023516959A (en) | 2023-04-21 |
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