IL135223A - Aluminum oxide coated cutting tool and processes for the preparation thereof - Google Patents

Abstract

Cutting tool comprising a body of sintered cemented carbide or cermet, ceramic or high speed steel substrate and on which at least on the functioning parts of the surface of the body, a 0.5 to 20 em, preferably 1 to 15 em, thick, adherent, hard and wear resistant coating is applied, and said coating is characterised in comprising a structure of one or more refractory compound layers, of which at least one layer with a thickness of 0.5 to 15 em, preferably 1-10 em, is deposited with a reactive, pulsed magnetron sputtering technique with a magnetron target power density in time average of at least 10 W/cm2 and at a substrate temperature in the range 450 to 700!C, preferably in the range 550 to 650!C, depending on the material of the tool body being coated whereby said coating essentially consists of very fine-grained, crystalline c-Al2O3-phase with a grain size less than 0.1em, said very fine-grained, crystalline c-Al2O3-layer exhibiting significant X-ray diffraction reflexes from at least one of the (440) and (400) crystal planes, having a hardness of at least 20 GPa, a compressive stress of at least 1 GPa and being free from any halogen impurities.

Description

ALUMINUM OXIDE COATED CUTTING TOOL AND PROCESSES FOR THE PREPARATION THEREOF The present invention describes a cutting tool for metal machining, having a body of cemented carbide, cermet, ceramics or high speed steel and on the surface of said body, a hard and wear resistant refractory coating is deposited. The coating is adherently bonded to the body and covering all functional parts of the tool. The coating is composed of one or more layers of refractory compounds of which at least one layer consists of fine-crystalline alumina, AI2O3, deposited by Physical Vapour Deposition (PVD) and the no -Al203-layer (s) , if any at all, consists of metal nitrides and/or carbides with the metal elements chosen from Ti, Nb, Hf , V, Ta, Mo, Zr, Cr, W and Al.

It is well known that for e.g. cemented carbide cutting tools used in metal machining, the wear resistance of the tool edge considerably can be increased by applying thin, hard surface layers of metal oxides, carbides or nitrides with the metal either selected from the transition metals from the groups IV, V and VI of the Periodic Table or from silicon, boron and aluminium. The coating thickness usually varies between 1 and IS am and the most widespread techniques for depositing such coat÷ ings are PVD and CVD (Chemical Vapor Deposition) . It is also known that further improvements of the performanc of a cutting tool can be achieved by applying a pure ceramic layer such as AI2O3 on top of layers of metal car.-- bides and nitrides (U.S. 5,674,564. U.S. 5,487, 625) .

Cemented carbide cutting tools coated with alumina ^ layers have been commercially available for over two- -.^r decades. The CVD technique usually employed involves he deposition of material from a reactive gas atmosphere on a substrate surface held at elevated temperatures. &l2°3 crystallizes into several different phases such as a(alpha), (kappa) and x(chi) called the "a-series" with hep (hexagonal close packing) stacking of the oxygen atoms, and into γ (gamma) , 9(theta), -n eta) and 5 (delta) called the "γ-series" with fee (face centered cubic) stacking of the oxygen atoms. The most often occurring A.I2O3 -phases in CVD coatings deposited on cemented carbides at conventional CVD temperatures, 1000°-1050°C, are the stable alpha and the metastable kappa phases, however, occasionally the metastable theta phase has also been observed.

The CVD AI2O3 -coatings of the α-, κ- and/or θ-phase are fully crystalline with a grain size in the range 0.5-5 μπι and having well-facetted grain structures.

The inherently high deposition temperature of about 1000 °C renders the total stress in CVD AI2O3-coatings on cemented carbide substrates to be tensile, hence the total stress is dominated by thermal stresses caused by the difference in thermal expansion coefficients between the substrate and the coating and less by intrinsic stresses which have their origin from the deposition process itself and are of compressive nature . The tensile stresses may exceed the rupture limit of AI2O3 and cause the coating to crack extensively and thus degrade the performance of the cutting edge in e.g. wet machining where the corrosive chemicals in the coolant fluid may exploit the cracks in the coating as diffusion paths .

Generally CVD-coated tools perform very well when machining various steels and cas irons under dry or wet cutting conditions. However, there exists a number of cutting operations or machining conditions when PVD- coated tools are more suitable e.g. in drilling, parting and threading and other operations where sharp cutting edges are required. Such cutting operations are often referred to as the "PVD coated tool application area".

Plasma assisted CVD technique, PACVD, makes it possible to deposit coatings at lower substrate tempera- tures as compared Co thermal CVD temperatures" and thus avoid the dominance of the thermal stresses. Thin AI2O3 PACVD films, free of cracks, have been deposited on cemented carbides at substrate temperatures 450-700 °C (DE 41 10 005; DE 41 10 006; DE 42 09 975) . The PACVD process for depositing AI2O3 includes the reaction between an Al-halogenide, e.g. AICI3, and an oxygen donor, e.g. CO2, and because of the Al incompleteness of this chemical reaction, chlorine is to a large extent trapped in the AI2O3 -coating and its content could be as large as 3.5 %. Furthermore, these PACVD Al2O3-coatings are generally composed of, besides the crystalline alfa-and/or ga ma- l203 -phase, a substantial amount of amorphous alumina which in combination with the high content of halogen impurities, degrades both the chemical and mechanical properties of said coating, hence making the coating material non-optimised as a tool material, The field of the present invention relates particularly to the art of PVD AI2O3 coated carbide cutting tools or tools of similar hard materials such as cermets, ceramics and high-speed steel.

There exist several PVD techniques capable of producing refractory thin films on cutting tools and the most established methods are ion plating, DC- and RF- magnetron sputtering, arc discharge evaporation, IBAD (Ion Beam Assisted Deposition) and Activated Reactive Evaporation (ARE) . Each method has its own merits and the intrinsic properties of the produced coatings such as microstructure/grain size, hardness, state of stress, intrinsic cohesion and adhesion to the underlying substrate may vary depending on the particular PVD method chosen. Early attempts to PVD deposit A 2O3 at typical PVD temperatures, 400-500 °C, resulted in amorphous alumina layers which did not offer any notable improvement in wear resistance when applied on cutting tools. PVD deposition by HF diode- or magnetron sputtering resulted in crystalline α-Αΐ2θ3 only when the substrate temperature was kept as high as 1000 °C (Thornton and Chin, Ceramic Bulletin, 56(1977)504). Likewise, applying the ARE method for depositing AI2O3, only resulted in fully dense and hard AI2O3 -coatings at substrate temperatures around lOOO °C {Bunshah and Schramm, Thin Solid Films, 40(1977)211) .

With the invention of the bipolar pulsed DMS technique (Dual Magnetron Sputtering) which is disclosed in DD 252 205 and DE 195 18 779, a wide range of opportunities opened up for the deposition of insulating layers such as AI2O3 and, furthermore, the method has made it possible to deposit crystalline AI2O3 -layers at substrate temperatures in the range 500 to 800 °C. In the bipolar dual magnetron system, the two magnetrons alternately act as an anode and a cathode and, hence, preserve a metallic anode over long process times. At high enough frequencies, possible electron charging on the insulating layers will be suppressed and the otherwise troublesome phenomenon of "arcing" will be limited.

Hence, according to DE 195 18 779, the DMS sputtering technique is capable of depositing and producing high- quality, well-adherent , crystalline 0.-AI2O3 thin films at substrate temperatures less than 800 °C. The "a- AI2O3 -layers" , with a typical size of the a-grains varying between 0.2 and 2 um, may partially also contain the gamma (γ) phase from the "γ-series" of the I2O3 -polymorphs . The size of the γ-grains in the coating is much smaller than the size of the a-grains. The γ-Αΐ2θ3 grain size typically varies between 0.05 and 0.1 μτη. In the I2O3-layers where both modifications of γ and a-phase were found, the γ- ΐ2θ3 -phase showed a preferred growth orientation with a (440) -texture. When compared to prior art plasma assisted deposition techniques such as PACVD as described in DE 49 09 975, the novel, pulsed DMS sputtering deposition method has the decisive, important advantage that no impurities such as halogen atoms, e.g. chlorine, are incorporated in the AI2O3-coating .

Fig. 1 is an EDS-analysis of an Al203-layer deposited by PACVD (with AlCI3 as a precursor) containing Cl-impurities .

Fig. 2 is an EDS-analysis of a y-A^C^j-layer according to the invention.

Fig. 3 shows an X-ray diffraction pattern from an Al203-layer containing γ-phase.

Fig. 4 shows an X-ray diffraction pattern from an I2O3- layer also containing θ-phase.

Fig. 5 shows an electron diffraction pattern from an AI2O3-layer deposited at a substrate temperature of 650 °C.

According to the present invention there is provided a cutting tool for metal machining such as turning (threading and parting) , milling and drilling comprising a body of a hard alloy of cemented carbide, cermet, ceramics or high speed steel onto which a hard and wear resistant refractory coating is deposited by the DMS PVD method at substrate temperatures of 450 to 700 °C, preferably 550 to 650 °C, depending on the particular material of the tool body, and that said wear resistant coating is composed of one or more layers of refractory compounds of which at least one layer, preferably the outermost layer, consists of AI2O3 and that the innermost layer (s), if any at all, between the tool body and the I2O3-layer, is composed of metal nitrides and/or carbides with the metal elements selected from Ti, Nb, Hf, V, Ta, Mo, Zr, Cr, W and Al. In contrast to the state of the art, the Al203~layers consist of high-quality, dense, fine-grained crystalline γ-Αΐ2θ3 with a grain size less than 0.1 μτη. Furthermore, the γ-Αΐ2θ3- layers are virtually free of cracks and halogen impurities. The latter property is illustrated in Fig, 1 which is an EDS-analysis of an Al203-layer deposited by PACVD (with AICI3 as a precursor) containing Cl-impurities and in Fig. 2 which is an EDS-analysis of a γ-Αΐ2θ3 -layer according to the invention. In the latter Al2C<3-l er no detectable impurities are present .

The γ-Αΐ2θ3~layers according to the invention further give the cutting edges of the tool an extremely smooth surface finish which, compared to prior art cc-AI2O3 coated tools, results in an improved surface finish also of the workpiece being machined. The very smooth surface finish can be attributed to the very fine crystallinity of the coating. The πγ-Αΐ2θ3η -layers may also partially contain other phases from the "γ-series" like θ, δ and η. Iden ification of the γ- and/or θ-phases in the AI2O3 -layers according to the invention can pre-ferably be made by X-ray diffraction. Reflexes from the (400) and (440) planes of the γ-Αΐ2θ3~layers occurring at the 29-angles 45.8° and 66.8° when using Cuj^ radiation, unequivocally identifies the y-phase (Fig. 3) .

Weaker reflexes from the (222) , (200) and (311) planes of the γ-phase can occasionally be identified. When the θ-phase is present in the AI2O3-layers according to the invention, said phase is identified by the reflexes from the (200, 20-2) planes (Fig. 4) .

A second identification method for the AI2O3 -phases is based on electron diffraction in a Transmission Electron Microscope (TEM) . A diffraction pattern from an Al203-layer deposited at a substrate temperature of 650 °C is shown in Fig. 5. The pattern shows rings from a polycrystalline phase with grains considerably smaller than the diameter of the electron beam and, furthermore, the intensity of the rings and the distances between the rings again unequivocally identifies the γ-phase of A1203.

The fine-grained, crystalline γ-Αΐ2θ3 according to the invention is strongly textured in the [440] -direction, A Texture Coefficient, TC, can be defined as. where I (hkl) = measured intensity of the (hkl) reflection I0(hkl) = standard intensity from the ASTM standard powder pattern diffraction data n = number of reflections used in the calculation (hkl) reflections used are: (111), (311), (222), (400) and (440) and whenever the TC(hkl) > 1, there is a texture in the [hkl] -direction. The larger the value of TC(hkl), the more pronounced is the texture. According to the present invention, the TC for the set of (440) crystal planes is greater than 1.5.

When the very fine-grained γ-Αΐ2θ3 coated cemented carbide cutting tools according to the invention are used in the machining of steel or cast iron, several important improvements compared to prior art have been observed which will be demonstrated in the forthcoming examples. Surprisingly, the PVD γ-Αΐ2θ3 without containing any portion of the coarser and thermodynamically stable α-Αΐ2θ3 -phase, shows in certain metal machining operations, a wear resistance which is equal to the wear resistance found in coarser CVD OC-AI2O3-coatings depo- sited at temperatures around 1000 °C. Furthermore, the fine-grained PVD γ-Αΐ2θ3 -coatings show a wear resistance considerably better than prior art PVD-coatings . These observations open up the possibility to considerably improve the cutting performance and prolong the tool lives of coated PVD tools. The low deposition temperature will also make it possible to deposit PVD γ-Al2O3 -coatings on high-speed steel tools.

A further improvement in cutting performance can be anticipated if the edges of the γ-Αΐ2θ3 coated cutting tools according to the invention are treated by a gentle wet-blasting process or by edge brushing with brushes based on e.g. SiC as disclosed in the Swedish patent application 9402534-4.

The total coating thickness according to the present invention varies between 0.5 and 20 μτη, preferably between 1 and 15 μπι with the thickness of the non-Al2C>3-layer(s) varying between 0.1 and 10 μτη, preferably between 0.5 and 5 μιη. The fine-grained γ-Αΐ2θ3 -coating can also be deposited directly onto the cutting tool substrate of cemented carbide, cermet, ceramics or high speed steel and the thickness of said γ-Αΐ2θ3 varies then between 0.5 and 15 μπι preferably between 1 and 10 μπι. Likewise can further coatings of metal nitrides and/or carbides with the metal elements selected from Ti, Nb, Hf , V, Ta, Mo, Zr, Cr, and Al be deposited on top of the AI2O3 -layer.

The γ-Αΐ2θ3-layer according to the invention is deposited by a bipolar dual magnetron sputtering technique at substrate temperatures of 450-700 °C, preferably 550- 650 °C, using aluminium targets, a gas mixture of Ar and O2 and a process pressure in the range 1-5 μbar. The substrate may be floating or pulsed biased, the exact conditions depending to a certain extent on the design of the equipment being used.

It is within the purview of the skilled artisan to determine whether the requisite grain size and phase compositions have been obtained and to modify the depo-. sition conditions in accordance with the present specification, if desired, to affect the nanostructure of the AI2O3 -layer within the frame of the invention.

The layer (s) described in the present invention, comprising metal nitrides and/or carbides and/or car- bonitrides and with the metal elements selected from Ti, Nb, Hf , V, Ta, Mo, Zr, Cr, W and Al can be deposited by PVD-technique, CVD- and/or MTCVD-technique (Medium Temperature Chemical Vapor Deposition) .

The superiority of the fine-grained γ-Αΐ2θ3 PVD-layers according to the present invention, compared to prior art PVD-coatings is demonstrated in Examples 1, 2 and 5. Examples 3, 4 and 6 demonstrate the surprisingly good wear resistance properties of the fine-grained γ-AI2O3-layers compared to traditionally CVD-deposited single phase K-AI2O3 and single phase C.- I2O3 -layers .

■Fframpl i 1 A) Commercially available cemented carbide threading inserts of style R166.OG-16MM01-150 having a composition of 10 w% Co and balance WC, coated with an approximately 2 μιη TiN-layer by an ion plating technique.

B) TiN coated tools from A) were coated with a 1 um fine-grained γ-Αΐ2<->3-layer in a separate experiment with the pulsed magnetron sputtering technique. The deposition temperature was 650 °C and the process pressure was 1 |ibar.

C) Cemented carbide threading inserts of style R166.OG-16 M011-150 having a composition of 10 w% Co and balance WC, coated with an approximately 3 μτιι TiN-layer by an ion plating technique.

Coated tool inserts from B) and C) were then tested in a threading operation at a customers site in the production of engine oil plugs of cast iron (SS0125,- 180- 240 HB) . The thread of the plug being produced was of size M36 x 1.5.

Cutting data: Speed: 154 m/min passages per thread The results below are expressed as the number of machined plugs per cutting edge.

C) prior art 300 plugs Large crater wear, cutting edge is worn out invention >500 plugs No detectable wear on the cutting edge. The edge can produce more plugs From the above results it is obvious that the alumina coated insert according to the invention is superior with respect to cutting performance.

Example -2.

D) Commercial PVD-TiN coated cemented carbide drilling inserts of style LCMX 040308-53 with a coating thickness of approximately 3 μπι having a cemented carbide composition of 10 w% Co and balance WC.

E) TiN coated tools from D) , coated with a 1 pin fine-grained γ-Αΐ2θ3 -layer in a separate experiment with the pulsed magnetron sputtering technique. The deposition temperature was 650 °C and the process pressure was 1 ubar.

The alumina coating from E) appeared transparent and very smooth. SEM-studies of a fracture cross section of the alumina coating showed a very fine-grained structure. An XRD-investigation identified the alumina phase as pure γ-Αΐ2θ3.

Coated tool inserts from D) and E) were then tested in a drilling operation in a workpiece material of a low alloyed, non-hardened steel (SS 2541) .

Cutting data: Speed : 150 m/min Feed: 0.12 mm/rev Hole diameter : 25 mm Hole depth: 46 mm Coolant being used Both flank and crater wear were developed on the cutting edges. The extent of the flank wear determined the life time of the cutting tool. The results below ex press the number of holes being drilled per cutting edge.

D) prior art 150 holes Flank wear 0.15 mm 200 holes Flank wear 0.22 mm, cutting edge damaged E) invention 150 holes Flank wear 0,07 mm 200 holes Flank wear 0.09 mm 250 holes Flank wear 0.10 mm cutting edge slightly damaged From the above results it is obvious that the alumina coated inserts according to the invention are able to drill more holes than the prior art inserts.

F) Cemented carbide inserts of style CNMA 120412- KR having a composition of 6 w% Co and balance WC, coated with a first layer of 8 μιη TiC and thereafter with a top layer of 4.7 μπι (X-AI2O3. Both the TiCN and the AI2O3-layer were deposited by conventional CVD- echnique. The AI2O3 -layer had an average grain size of 1.2 μπι.

G) Cemented carbide inserts of the same style and composition as in F) , first coated with an approximately 3.6 um TiCN-layer by conventional CVD-technique and thereafter coated with a 2.3 μιη fine-grained γ-Αΐ2θ3- layer in a separate experiment with the pulsed magnetron sputtering technique. The deposition temperature was 650 °C and the process pressure was 1 bar.

Coated inserts from F) and G) were then tested in a continuous turning operation in a ball bearing steel (Ovako 825) . The crater wear of the cutting edges was measured .

Cutting data: Speed: 210 m/tnin Feed: 0.25 mm/rev Depth of cut : 2.0 mm Coolant being used The cutting operation was periodically interrupted in order to measure the crater wear of the cutting edges. The crater wear was measured in an optical microscope. The machining time until the AI2O3-layer was worn through, was registered (i.e. when the inner TiCN-coat-ing just becoming visible) . In order to define a figure of merit for the intrinsic wear resistance of the AI2O3-layers, the thickness (um) of the AI2O3 -layer was divided by the above defined machining time (min) . The results below express the wear rate figure of merit.

F) prior art a-Al203~l ers 0.5 um/min C) invention 0.5 um/min From the above results it is obvious that the wear resistance of the fine-grained γ-Αΐ2θ3 -layer surprisingly is as good as the wear resistance of the coarser-grained C.-AI2O3 -layer deposited by CVD technique.

Example,.J.- H) Cemented carbide inserts of style CNMA 120412-KR having a composition of 6 w% Co and balance WC, coated with a first layer of 6 μπι TiC and thereafter with a top layer of 1.1 μπι -AI2O3. Both the TiCN and the AI2O3 -layer were deposited by conventional CVD technique. The AI2O3 -layer had an average grain size of 1 um.

I) Cemented carbide inserts of the same style and composition as in H) , coated with an approximately 2.5 um TiN-layer by an ion plating technique.

J) TiN coated tools from I), coated with a 1.2 μπι fine-grained γ-Αΐ2θ3 -layer in a separate experiment with the pulsed magnetron sputtering technique. The deposi- tion temperature was 600 °C and the process pressure was 1 ubar.

K) TiN coated tools from I), coated with a 1.7 urn fine-grained γ-Αΐ2θ3~layer in a separate experiment with the pulsed magnetron sputtering technique. The deposition temperature was 730 °C and the process pressure was 1 ubar.

Coated inserts from H) , J) and ) , were then tested in a continuous turning operation in a ball bearing steel (Ovako 825) . The crater wear of the cutting edges was measured.

Speed 250 m/min Feed 0.25 mm/rev Depth of cut 2.0 mm Coolant being used The cutting operation was periodically interrupted in order to measure the crater wear of the cutting edges. The crater wear was measured in an optical microscope. The machining time until the AI2O3-layer was worn through, was registered (i.e. when the inner TiN or TiCN-coating just becoming visible) . In order to define a figure of merit for the intrinsic wear-resistance of the AI2O3 -layers, the thickness (μπι) of the AI2O3 -layer was divided by the above defined machining time (min) . The results below express the wear rate figure of merit. H) prior art -AI2O3-layers 0.44 um/min J) invention TiN + γ-Αΐ2θ3 0.40 um/min K) invention TiN + γ-Αΐ2θ3 0.46 um/min From the above results it is obvious that the wear resistance of the fine-grained γ-Αΐ2θ3 -layer surprisingly is as good as the wear resistance of the coarser- grained K-AI2O3-layer deposited by CVD technique.

Examp .5 Coated cutting inserts from I) , J) and K) in Example 4 were tested under the same cutting conditions and cut- ting data as in Example 4. The machining time until a predetermined crater wear had developed on the rake face of the inserts was registered. The results below express said machining time until the predetermined crater wear. I) prior art TiN 4 min J) invention TiN + γ-Αΐ2©3 9 ^33 K) invention TiN + γ-Αΐ2(>3 9.7 min From the above results it is obvious that a top coating of the fine-grained γ-Αΐ2θ3-layer on PVD TiN considerably improves the crater wear resistance of the cutting tool .

Example fi L) Cemented carbide inserts of style CNMA. 120412-KR having a composition of 6 w% Co and balance WC, coated with a first layer of 6 um TiCN and thereafter with a top layer of 4.8 μπι CI-AI2O3. Both the TiCN and the AI2O3-layer were deposited by conventional CVD- echnique. The AI2O3 -layer had an average grain size of 1 um.

) Cemented carbide inserts of the same style and composition as in L) , first coated with an approximately 5 um TiAlN-layer and thereafter, without vacuum interruption, coated with a 4.4 μιη fine-grained γ-Αΐ2θ3~ layer, both layers deposited with the pulsed magnetron sputtering technique. The deposition temperature was 600 °C and the process pressure was 1 ubar.

Coated inserts from L) and M) were then tested in a continuous turning operation in a low alloyed, non-hard- ened steel (SS2541) . The crater wear of the cutting edges was measured.

Speed: 250 m/min Feed: 0.25 mm/rev Depth of cut 2.0 mm Coolant being used The cutting operation was periodically interrupted in order to measure the crater wear of the cutting . edges . The crater wear was measured in an optical microscope. The machining time until the AI2O3 -layer was worn through, was registered (i.e. when the inner TiC or TiAlN-coating just becoming visible) . In order to define a figure of merit for the intrinsic wear resistance of the AI2O3-layers, the thickness (μπι) of the AI2O3 -layer was divided by the above defined machining time (min) . The results below express the wear rate figure of merit. L) prior art (X-AI2O3 -layers 0.69 um/min M) invention 0.73 μπι/min From the above results it is obvious that the wear resistance of the fine-grained γ-Αΐ2θ3-layer surprisingly is as good as the wear resistance of the coarser-grained (X-AI2O3 -layer deposited by CVD technique.

Claims (13)

WHAT—I-S .CLAIMED IS/-_ :.. . ..

1. Cutting tool comprising a body of sintered cemented, carbide or cermet, ceramic or high speed steel substrate and on which at. least on the functioning parts of the surface of the body, a .0.5 to 20 μιτι, preferably 1 to 15 um, thick:, adherent, hard and wear resistant coating is applied, and said coating is c h a'r a c t e r- i s e d in comprising a structure of one or more refractory compound layers, of which at least one layer with a thickness of 0.5 to 15 urn, preferably 1-10 urn, is deposited with a. reactive, pulsed magnetron sputtering technique with a magnetron target power density in time average of at least 10 W/cm^ and at a substrate temperature in the range 450 to 700 °C, preferably in the range 550 to 650 °C, depending on the material of the tool body being coated whereby said coating essentially consists of very finegrained, crystalline y-A^C^-phase with a grain size less than 0.1 um, said very fine-grained, crystalline y-A^C^-layer exhibiting significant X-ray diffraction reflexes from at least one of the (440) and (400) crystal planes, having a hardness of at least 20 GPa, a compressive stress of at least 1 GFa and being free from any halogen impurities.

2. Cutting tool according to claim L c h a r a c t e r i s e d in that the Al203~layer has a preferred growth orientation in the [ 03 -direction with a text : I (hkl) =, measured intensity of the (hkl) reflection I0(hki) = standard intensity, from the ASTM standard powder pattern diffraction data ■ h = mber of reflections used in the calculation (hkl) reflections used are: (111), ( 311 ) , . ( 222 )■ , (400) and (440) .

3. Cutting tool according to any of the previous claims c h a r a c t e r i s e d in that the fine grained crystalline 7- l 03-la er contains portions (detectable by XP-D technique) . of additional alumina phases from the γ-series of the I2O3- oolvmorohs . AMENDED SHEET (ARTICLE IS)

4. Cutting tool according to claim 3 c h a r a ct e r i s e d in that the additional alumina phase is the θ-phase.

5. Cutting tool according to any of the previous claims c h a r a c t e r i s e d in having at least one layer of thickness 0.1-10 um, preferably 0.5-5 urn, comprising of metal nitrides and/or carbides with the metal elements selected from Ti, Nb, Hf, V, Ta, Mo, Zr, Cr, W and Al.

6. Cutting tool according to claim 5 c h a r a c t e r i s e d in that said layer consists of TiC, TiCN, TiN or TiAI .

7. Cutting tool according to any of the previous claims c h a r a c t e r i s e d in that the outer layer is AI2O3.

8. Cutting tool according to any of the claims 1-6 c h a r a c t e r i s e d in that the outer layer is TiN.

9. A process for producing a coated cutting tool, wherein at least one refractory layer consisting of fine-grained, crystalline γ-Αΐ2θ3 as per claim 1, is deposited by a magnetron sputtering onto the moving substrate in a vacuum, c h a r a c t e r i s e d in that the Al203-la er is deposited by a reactive, pulsed magnetron sputtering in a gas 'mixture of argon and oxygen at a pressure of 1-5 |Hbar, that the pulse frequency is set for 10 to 100 kHz, preferably 50 kHz, that deposition occurs with a rate of at least 1 nm/s with reference to a stationarily arranged substrate, that the magnetron target power density in time average is set for at least 10 W/cm2 and that the substrate temperature is set in the range 450 to 700 °C, preferably in the range 550 to 650 °C, depending on the material of the tool body being coated.

10. A process according to claim 9, c h a r a c t e r i s e d in that the Al203~layer is deposited by the sputtering of two magnetrons with Al targets that are alternatively switched as a cathode and as a anode of a magnetron sputtering apparatus.

11. A process according to at least one of the claims 9 and 10 c h a r a c t e r i s e d in that additional, non-Al203~ layers are also deposited by a PVD process (Physical Vapor Deposition), particularly by pulsed magnetron sputtering.

12. A process according to claim 11, c h a r a c.t e r i s e d in that all layers, AI2O3 and-non-Al203-layer (s) , are deposited in the same coating apparatus without vacuum interruption. ■ -

13. A process of at least one of the claims 9 and 10, c h a r a c t e r i s e d in that additional, non- l203-layers are deposited by a CVD process (Chemical Vapor Deposition) . For the Applicant WOLFF, BREG AN AND GOLLER by: i