IE921745A1 - Linear viscoelastic aqueous liquid automatic dishwasher¹detergent composition - Google Patents

Abstract

This invention relates to a detergent composition for automatic dishwashers which is formulated with an aqueous pseudoplastic viscoelastic linear product of the gel type, of exceptionally good physical stability, little residue in the bottle, low glass loss and better cleaning efficiency. The linear viscoelastic behaviour and pseudoplastic behaviour are obtained by incorporating at least one thickener of the high molecular weight cross- linked polyacrylic acid type. Potassium to sodium ratios by weight of at least 1/1 reduce the quantity of undissolved solid particles to a minimum in order better to contribute to the stability and pourability characteristics of the composition. The control of incorporated air bubbles has the function of providing the product with a bulk density of from 1.26 g/cm3 to 1.40 g/cm3 which corresponds approximately to the density of the liquid phase. The presence of a stearic acid or another fatty acid or salt in the composition further improves physical stability.

Description

Background of the Invention Liquid automatic dishwasher detergent compositions, both aqueous and nonaqueous, have recently received much attention, and the aqueous products have achieved commercial popularity.

The acceptance and popularity of the liquid formulations as compared to the more conventional powder products stems from the convenience and performance of the liquid products.

However, even the best of the currently available liquid formulations still suffer from two major problems, product phase instability and bottle residue, and to some extent cup leakage from the dispenser cup of the automatic dishwashing machine.

Representative of the relevant patent art in this area, mention is made of Rek, U.S. Patent 4,556,504; Bush, et al., U.S. Patent 4,226,736; Ulrich, U.S. Patent 4,431,559; Sabatelli, U.S. Patent 4,147,650; Paucot, U.S. Patent 25 4,079,015; Leikhem, U.S. Patent 4,116,849; Milora, U.S. Patent 4,521,332; Jones, U.S. Patent 4,597,889; Heile, U.S. Patent 4,512,908; Laitem, U.S. Patent 4,753,748; Sabatelli, U.S. Patent 3,579,455; Hynam, U.S. Patent 3,684,722: other patents relating to thickened detergent compositions include U.S.

Patent 3,985,668; U.K. Patent Applications GB 2,116,199A and GB 240,450A; U.S. Patent 4,511,487; U.S. Patent 4,752,409 GB 240,450A; U.S. Patent 4,511,437; U.S. Patent 4,752,409 (Drapier, et al.); U.S. Patent 4,801,395 (Drapier, et al.); U.S. Patent 4,801,395 (Drapier, et al.).

The present invention provides a solution to the above problems.

Brief Description of the Drawings Figures 1-13 are rheograms, plotting elastic modules G' and viscous modulus G as a function of applied strain, for the compositions of Example 1, Formulations A, C, D, G, J, H, I and K, Example 2, A and B, Example 3, L and M and Comparative Example 1, respectively.

Summary of the Invention According to the present invention there is provided a novel aqueous liquid automatic dishwasher detergent composition that is capable of removing both proteinuceous soils and carbohydrate soils. The composition is characterized by its linear viscoelastic behavior, substantially indefinite stability against phase separation or settling of dissolved or suspended particles, low levels of bottle residue, relatively high bulk density, and substantial absence of unbound or free water. This unique combination of properties is achieved by virtue of the incorporation into the aqueous mixture of dishwashing detergent surfactant, alkali metal detergent builder salt(s) and chlorine bleach compound, a small but effective amount of high molecular weight crosslinked poiyacrylic acid type thickening agent, a physical stabilizing amount of a long chain fatty acid or salt thereof, and a source of potassium ions to provide a potassium/sodium weight ratio in the range of from 1:1 to 45:1, such that substantially all of the detergent builder salts and other normally solid detergent additives present in the composition are present dissolved in the aqueous phase. The compositions are further characterized by a bulk density of at least 1.26 g/cc, such that the density of the polymeric phase and the density of the aqueous (continuous) phase are approximately the same.

Detailed Description of the Preferred Embodiments The compositions of this invention are aqueous liquids containing various cleansing active ingredients, detergent adjuvants, structuring and thickening agents and stabilizing components, although some ingredients may serve more than one of these functions.

The advantageous characteristics of the compositions of this invention, including physical stability, low bottle residue, high cleaning performance, e.g. low spotting and filming, dirt residue removal, and so on, and superior aesthetics, are believed to be attributed to several interrelated factors such as low solids, i.e. undissolved particulate content, product density and linear viscoelastic rheology. These factors are, in turn, dependent on several critical compositional components of the formulations, namely, (1) the inclusion of a thickening effective amount of polymeric thickening agent having high water absorption capacity, exemplified by nigh molecular weight cross-linked polyacrylic acid, (2) inclusion of a physical stabilizing amount of a long chain fatty acid or salt thereof, (3) potassium ion to sodium ion weight ratio K/Na in the range of from 1:1 to 45:1, especially from 1:1 to 3:1, and (4) a product bulk density of at least 1.26 g/cc, such that the bulk density and liquid phase density are the same.

The polymeric thickening agents contribute to the linear viscoelastic rheology of the invention compositions. As used herein, linear viscoelastic or linear viscoelasticity means that the elastic (storage) moduli (G') and the viscous (loss) moduli (G) are both substantially independent of strain, at least in an applied strain range of from 0-50%, and preferably over an applied strain range of from 0-80%. More specifically, a composition is considered to be linear viscoelastic for purposes of this invention, if over the strain range of 0-50% the elastic moduli G' has a minimum value of 100 dynes/sq.cm., preferably at least 250 dynes/sq.cm., and varies less than 500 dynes/sq.cm, preferably less than 300 dynes/sq.cm., especially preferably less than 100 dynes/sq.cm. Preferably, the minimum value of G' and maximum variation of G' applies over the strain range of 0 to 80%. Typically, the variation in loss moduli G will be less than that of G'. As a further characteristic of the preferred linear viscoelastic compositions the ratio of G/G (tan^J) is less than 1, preferably less than 0.8, but more than 0.05, preferably more than 0.2, at least over the strain range of 0 to 50%, and preferably over the strain range of 0 to 80%.

,E 921745 It should be noted in this regard that % strain is shear strain xlOO.

By way of further explanation, the elastic (storage) modulus G' is a measure of the energy stored and retrieved when a strain is applied to the composition while viscous (loss) modulus G is a measure to the amount of energy dissipated as heat when strain is applied. Therefore, a value of tanifi, ν' 0.05< tanB <1, preferably 0.2 < tan rj < 0.8 means that the compositions will retain sufficient energy when a stress or strain is applied, at least over the extent expected to be encountered for products of this type, for example, when poured from or shaken in the bottle, or stored in the dishwasher detergent dispenser cup of an automatic dishwashing machine, to return to its previous condition when the stress or strain is removed. The compositions with tan values in these ranges, therefore, will also have a high cohesive property, namely, when a shear or strain is applied to a portion of the composition to cause it to flow, the surrounding portions will follow. As a result of this cohesiveness of the subject linear viscoelastic compositions, the compositions will readily flow uniformly and homogeneously from a bottle when the bottle is tilted, thereby contributing to the physical (phase) stability of the formulation and the low bottle residue (low product loss in the bottle) which characterizes the invention compositions. The linear viscoelastic property also contributes to improved physical stability against phase separation of any undissolved suspended particles by providing a resistance to movement of the particles due to the strain exerted by a particle on the surrounding fluid medium.

Also contributing to the physical stability and low bottle residue of the invention compositions is the high potassium to sodium ion ratios in the range of 1:1 to 45:1, preferably 1:1 to 4:1, especially preferably from 1.05:1 to 3:1, for example 1.1:1, 1.2:1, 1.5:1, 2:1, or 2.5:1. At these ratios the solubility of the solid salt components, such as detergent builder salts, bleach, alkali metal silicates, and the like, is substantially increased since the presence of the potassium (K+) ions requires less water of hydration than the sodium (Na+) ions, such that more water is available to dissolve these salt compounds. Therefore, all or nearly all of the normally solid components are present dissolved in the aqueous phase. Since there is none or only a very low percentage, i.e. less than 5%, preferably less than 3% by weight, of suspended solids present in the formulation there is no or only reduced tendency for undissolved particles to settle out of the compositions causing, for example, formation of hard masses of particles, which could result in high bottle residues (i.e. loss of product). Furthermore, any undissolved solids tend to be present in extremely small particle sizes, usually colloidal or sub-colloidal, such as 1 micron or less, thereby further reducing the tendency for the undissolved particles to settle.

A still further attribute of the invention compositions contributing to the overall product stability and low bottle residue is the high water absorption capacity of the crosslinked polyacrylic acid type thickening agent. As a result of this high water absorption capacity virtually all of the aqueous vehicle component is held tightly bound to the polymer matrix. Therefore, there is no or substantially no free water present in the invention compositions. This absence of free water (as well as the cohesiveness of the composition) is manifested by the observation that when the composition is poured from a bottle onto a piece of water absorbent filter paper virtually no water is absorbed onto the filter paper and, furthermore, the mass of the linear viscoelastic material poured onto the filter paper will retain its shape and structure until it is again subjected to a stress or strain.

As a result of the absence of unbound or free water, there is virtually no phase separatin between the aqueous phase and the polymeric matrix or dissolved solid particles. This characteristic is manifested by the fact that when the subject compositions are subjected to centrifugation, e.g. at 1000 rpm for 30 minutes, there is no phase separation and the composition remains homogeneous.

However, it has also been discovered that linear viscoelasticity and K/Na ratios in the above-mentioned range do not, by themselves, assure long term physical stability (as determined by phase separation). In order to maximize physical (phase) stability, the density of the composition should be controlled such that the bulk density of the liquid phase is approximately the same as the bulk density of the entire composition, including the polymeric thickening agent. This control and equalization of the densities is achieved, according to the invention, by providing the composition with a bulk density of at least 1.32 g/cc, preferably at least 1.35 g/cc, up to 1.42 g/cc, preferably up to 1.40 g/cc. Furthermore, to achieve these relatively high bulk densities, it is important to minimize the amount of air incorporated into the composition (a density of 1.42 g/cc is essentially equivalent to zero air content).

It has previously been found in connection with other types of thickened aqueous liquid, automatic dishwasher detergent compositions that incorporation of finely divided air bubbles in amounts up to 8 to 10% by volume can function effectively to stabilize the composition against phase separation, but that to prevent agglomeration of or escape of the air bubbles it was important to incorporate certain surface active ingredients, especially higher fatty acids and the salts thereof, such as stearic acid, behenic acid, palmitic acid, sodium stearate, aluminum stearate, and the like. These surface active agents apparently functioned by forming an interfacial film at the bubble surface while also forming hydrogen bonds or contributing to the electrostatic attraction with the suspended particles, such that the air bubbles and attracted particles formed agglomerates of approximately the same density as the density of the continuous liquid phase.

Therefore, in a preferred embodiment of the present invention, stabilization of air bubbles which may become incorporated into the compositions during normal processing, such as during various mixing steps, is avoided by post-adding the surface active ingredients, including fatty acid or fatty acid salt stabilizer, to the remainder of the composition, under low shear conditions using mixing devices designed to minimize cavitation and vortex formation.

As will be described in greater detail below the surface active ingredients present in the composition will include the main detergent surface active cleaning agent, and will also preferably include anti-foaming agent and higher fatty acid or salt thereof as a physical stabilizer.

Exemplary of the cross-linked polyacrylic acid-type thickening agents are the products sold by B.F. Goodrich under their Carbopol trademark, especially Carbopol 941, which is the most ion-insensitive of this class of polymers, and Carbopol 940 and Carbopol 934. The Carbopol resins, also known as Carbomer, are hydrophilic high molecular weight, cross-linked acrylic acid polymers having an average equivalent weight of 76, and the general structure illustrated by the following formula: Η H Carbopol 941 has a molecular weight of 1,250,000; Carbopol 940 a molecular weight of approximately 4,000,000 and Carbopol 934 a molecular weight of approximately 3,000,000. The Carbopol resins are cross-linked with polyalkenyl polyether, e.g. 1% of a polyallyl ether of sucrose having an average of 5.8 allyl groups for each molecule of sucrose. Further detailed information on the Carbopol resins is available from B.F. Goodrich, see, for example, the B.F. Goodrich catalog GC67, Carbopol® Water Soluble Resins.

While most favorable results have been achieved with Carbopol 941 poiyacrylic resin, other lightly cross-linked poiyacrylic acid-type thickening agents can also be used in the compositions of this invention. As used herein poiyacrylic acid-type refers to water-soluble homopolymers of acrylic acid or methacrylic acid or water-dispersible or water-soluble salts, esters or amides thereof, or water15 soluble copolymers of these acids of their salts, esters or ameides with each other or with one or more other etylenically unsaturated monomers, such as, for example, styrene, maleic acid, maleic anhydride, 2-hydroxyethylacrylate, acrylonitrile, vinyl acetate, ethylene, propylene, and the like.

The homopolymers or copolymers are characterized by their high molecular weight, in the range of from 500,000 to 10,000,000, preferably 500,000 to 5,000,000, especially from 1,000,000 to 4,000,000, and by their water solubility, generally at least to an extent of up to 5% by weight, or more, in water at 25°C.

These thickening agents are used in their lightly crosslinked form wherein the cross-linking may be accomplished by means known in the polymer arts, as by irradiation, or, preferably, by the incorporation into the monomer mixture to be polymerized of known chemical cross-linking monomeric agents, typically polyunsaturated (e.g. diethylenically unsaturated) monomers, such as, for example, divinylbenzene, divinylether of diethylene glycol, N, N'-methylenebisacrylamide, polyalkenylpolyethers (such as described above), and the like. Typically, amounts of cross-linking agent to be incorporated in the final polymer may range from 0.01 to 1.5 percent, preferably from 0.05 to 1.2 percent, and especially, preferably from 0.1 to 0.9 percent, by weight of cross-linking agent to weight of total polymer. Generally, those skilled in the art will recognize that the degree of cross-linking should be sufficient to impart some coiling of the otherwise generally linear polymeric compound while maintaining the cross-linked polymer at least water dispersible and highly water-swellable in an ionic aqueous medium. It is also understood that the water-swelling of the polymer which provides the desired thickening and viscous properties generally depends on one or two mechanisms, namely, conversion of the acid group containing polymers to the corresponding salts, e.g. sodium, generating negative charges along the polymer backbone, thereby causing the coiled molecules to expand and thicken the aqueous solution; or by formation of hydrogen bonds, for example, between the carboxyl groups of the polymer and hydroxyl donor. The former mechanism is especially important in the present invention, and therefore, the preferred polyacrylic acid-type thickening agents will contain free carboxylic acid (COOH) groups along the polymer backbone. Also, it will be understood that the degree of cross-linking should not be so high as to render the cross-linked polymer completely insoluble or non-dispersible in water or inhibit or prevent the uncoiling of the polymer molecules in the presence of the ionic aqueous system.

The amount of the at least one high molecular weight, cross-linked polyacrylic acid or other high molecular weight, hydrophilic cross-linked polyacrylic acid-type thickening agent to impart the desired rheological property of linear viscoelasticity will generally be in the range of from 0.1 to 2%, preferably from 0.2 to 1.4%, by weight, based on the weight of the composition, although the amount will depend on the particular cross-linking agent, ionic strength of the composition, hydroxyl donors and the like.

The compositions of this invention must include sufficient amount of potassium ions and sodium ions to provide a weight ratio of K/Na of at least 1:1, preferably from 1:1 to 45:1, especially from 1:1 to 3:1, more preferably from 1.05:1 to 3:1, such as 1.5:1, or 2:1. When the K/Na ratio is less than 1 there is insufficient solubility of the normally solid ingredients whereas when the K/Na ratio is more than 45, especially when it is greater than 3, the product becomes too liquid and phase separation begins to occur. When the K/Na ratio is more than 45, especially when it is greater than 3, the product becomes too liquid and phase separation begins to occur. When the K/Na ratios become much larger than 45, such as in all or mostly potassium formulation, the polymer chickener loses its absorption capacity and begins to salt out of the aqueous phase.

The potassium and sodium ions can be made present in the compositions as the alkali metal cation of the detergent builder salt(s), or alkali metal silicate or alkali metal hydroxide components of the compositions. The alkali metal cation may also be present in the compositions as a component of an ionic detergent, bleach or other ionizable salt compound additive, e.g. alkali metal carbonate. In determining the K/Na weight ratios all of these sources should be taken into consideration.

Specific examples of at least one alkali metal detergent builder salts used in the composition include the polyphosphates, such as alkali metal pyrophosphate, alkali metal tripolyphosphate, alkali metal metaphosphate, and the like, for example, sodium or potassium tripolyphosphate (hydrated or anhydrous), tetrasodium or tetrapotassium pyrophosphate, sodium or potassium hexa-metaphosphate, trisodium or tripotassium orthophosphate and the like, sodium or potassium carbonate, sodium or potassium citrate, sodium or potassium nitrilotriacetate, and the like. The phosphate builders, where not precluded due to local regulations, are preferred and mixtures of tetrapotassium pyrophosphate (TKPP) and sodium tripolyphosphate (NaTPP) (especially the hexahydrate) are especially preferred. Typical ratios of NaTPP to TKPP are from 2:1 to 1:8, especially from 1:1.1 to 1:6. The total amount of detergent builder salts is preferably from 5 to 35% by weight, more preferably from 15 ¢921745 to 35%, especially from 18 to 30% by weight of the composition.

In connection with the builder salts are optionally used a low molecular weight noncrosslinked polyacrylates having a molecular weight of 1,000 to 100,000, more preferably 2,000 to 80,000. A preferred low molecular weight polyacrylate is Norasol LMW45ND manufactured by Norsoshaas and having a molecular weight of 4,500. These low molecular weight polyacrylates are employed at a concentration of 0 to 15 wt.%, more preferably 0.1 to 10 wt.%.

Other useful low molecular weight noncrosslinked polymers are Acusolttn640D provided by Rohm & Haas; Norasol QR1014 from Norsohaas having a GPC molecular weight of 10,000.

The linear viscoelastic compositions of this invention may, and preferably will, contain a small, but stabilizing effective amount of a long chain fatty acid or monovalent or polyvalent salt thereof. Although the manner by which the fatty acid or salt contributes to the rheology and stability of the composition has not been fully elucidated it is hypothesized that it may function as a hydrogen bonding agent or cross-linking agent for the polymeric thickener.

The preferred long chain fatty acids are the higher aliphatic fatty acids having from 8 to 22 carbon atoms, more preferably from 10 to 20 carbon atoms, and especially 25 preferably from 12 to 18 carbon atoms, and especially preferably from 12 to 18 carbon atoms, inclusive of the carbon atom of the carboxyl group of the fatty acid. The aliphatic radical may be saturated or unsaturated and may be straight or branched. Straight chain saturated fatty acids are preferred. Mixtures of fatty acids may be used, such as those derived from natural sources, such as tallow fatty acid, coco fatty acid, soya fatty acid, mixtures of these acids, etc. Stearic acid and mixed fatty acids, e.g. stearic acid/palmitic acid, are preferred.

When the free acid form of the fatty acid is used directly it will generally associate with the potassium and sodium ions in the aqueous phase to form the corresponding alkali metal fatty acid soap. However, the fatty acid salts may be directly added to the composition as sodium salt or potassium salt, or as a polyvalent metal salt, although the alkali metal salts of the fatty acids are preferred fatty acid salts.

The preferred polyvalent metals are the di- and trivalent metals of Groups IIA, IIB and IIIB, such as magnesium, calcium, aluminum and zinc, although other polyvalent metals, including those of Groups IIIA, IVA, VA, IB, IVB, VB VIB, VIIB ' and VIII of the Periodic Table of the Elements can also be used. Specific examples of such other polyvalent metals include Ti, Zr, V, Nb, Mn, Fe, Co, Ni, Cd, Sn, Sb, Bi, etc. Generally, the metals may be present in the divalent to pentavalent state. Preferably the metal salts are used in their higher oxidation states. Naturally, for use in automatic dishwashers, as well as any other applications where the invention composition will or may come in contact with articles used for the handling, storage or serving of food products or which otherwise may come into contact with or be IE 921745 consumed by people or animals, the metal salt should be selected by taking into consideration the toxicity of the metal. For this purpose, the alkali metal and calcium and magnesium salts are especially higher preferred as generally safe food additives.

The amount of the fatty acid or fatty acid salt stabilizer to achieve the desired enhancement of physical stability will depend on such factors as the nature of the fatty acid or its salt, the nature and amount of the thickening agent, detergent active compound, inorganic salts, other ingredients, as well as the anticipated storage and shipping conditions.

Generally, however, amounts of the fatty acid or fatty acid salt stabilizing agents in the range of from 0.005 to 2%, preferably 0.02 to 2%, more preferably from 0.04 to 1.75%, especially preferably from 0.05 to 1.25%, provide a long term stability and absence of phase separation upon standing or during transport at both low and elevated temperatures as are required for a commercially acceptable product.

Depending on the amounts, proportions and types of fatty acid physical stabilizers and polyacrylic acid-type thickening agents, the addition of the fatty acid or salt not only increases physical stability but also provides a simultaneous increase in apparent viscosity. Amounts of fatty acid or salt to polymeric thickening agent in the range of from 0.08-0.4 weight percent fatty acid salt and from 0.4-1.5 weight percent polymeric thickening agent are usually sufficient to provide these simultaneous benefits and, therefore, the use of these ingredients in these amounts is most preferred.

In order to achieve the desired benefit from the fatty acid or fatty acid salt stabilizer, without stabilization of excess incorporated air bubbles and consequent excessive lowering of the product bulk density, the fatty acid or salt should be post-added to the formulation, preferably together with the other surface active ingredients, including detergent active compound and anti-foaming agent, when present. These surface active ingredients are preferably added as an emulsion in water wherein the emulsified oily or fatty materials are finely and homogeneously dispersed throughout the aqueous phase. To achieve the desired fine emulsification of the fatty acid or fatty acid salt and other surface active ingredients, it is usually necessary to heat the emulsion (or preheat the water) to an elevated temperature near the melting temperature of the fatty acid or its salt. For example, for stearic acid having a melting point of 68OC-69°C, a temperature in the range of between 50°C and 70°C will be used. For lauric acid (m.p.=47°C) an elevated temperature of 35°C to 50°C can be used. Apparently, at these elevated temperatures the fatty acid or salt and other surface active ingredients can be more readily and uniformly dispersed (emulsified) in the form of fine droplets throughout the composition.

In contrast, as will be shown in the examples which follow, if the fatty acid is simply post-added at ambient temperature, the composition is not linear viscoelastic as defined above and the stability of the composition is clearly inferior.

Foam inhibition is important to increase dishwasher machine efficiency and minimize destabilizing effects which might occur due to the presence of excess foam within the washer during use. Foam may be reduce by suitable selection of the type and/or amount of detergent active material, the main foam-producing component. The degree of foam is also somewhat dependent on the hardness of the wash water in the machine whereby suitable adjustment of the proportions of the builder salts such as NaTPP which has a water softening effect, may aid in providing a degree of foam inhibition. However, it is generally preferred to include a chlorine bleach stable foam depressant or inhibitor. Particularly effective are the alkyl phosphoric acid esters of the formula II OR and especially the alkyl acid phosphate esters of the formula HO—P—OR OR In the above formulas, one or both R groups in each type of ester may represent independently a C12-C2O alkyl or ethoxylated alkyl group. The ethoxylated derivatives of each type of ester, for example, the condensation products of one mole of ester with from 1 to 10 moles, preferably 2 to 6 moles, more preferably 3 or 4 moles, ethylene oxide can also be used.

Some examples of the foregoing are commercially available, such as the products SAP from Hooker and LPKN-158 from Knapsack. Mixtures of the two types, or any other chlorine bleach stable types, or mixtures of mono- and di-esters of the same type, may be employed. Especially preferred is a mixture of mono- and di-C16-C18 alkyl acid phosphate esters such as monostearyl/distearyl acid phosphates 1.2/1, and the 3 to 4 mole ethylene oxide condensates thereof. When employed, proportions of 0 to 1.5 weight percent, preferably 0.05to 0.5 weight percent, of foam depressant in the composition is typical, the weight ratio of detergent active component (d) to foam depressant (e) generally ranging from 10:1 to 1:1 and preferably 5:1 to 1:1. Other defoamers which may be used include, for example, the known silicones, such as available from Dow Chemicals. In addition, it is an advantageous feature of this invention that many of the stabilizing salts, such as the stearate salts, for example, aluminum stearate, when included, are also effective as foam killers.

Hypochlorite generating compounds suitable for use in the compositions of the present invention are those water soluble dry solid materials which generate hypochlorite ion on contact with or dissolution in water. The preferred hypochlorite compounds are alkali and alkaline earth hypochlorites.

The hypochlorite generating compounds are generally soluble in the product composition. Examples thereof are the dry, particulate heterocyclic N-chlorimides such as trichlorocyanuric acid, dichloracyanuric acid and salts thereof such as sodium dichlorocyanurate and potassium dichlorocyanurate. The corresponding dichloroisocyanuric and trichloroiscyanic acid salts can also he used. Other Nchloroimides may be used such as N-chlorosuccinimide, Nchloromalonimide, N-chlorophthalimide and N5 chloronaphthalimide. Additional suitable N-chloroimides are the hydantoins such as 1.3- dichloro-5,5-dimethylhydantion; N-monochloro-C,C-dimethylhydantoin; methylene-bis (N-chloro-C,C-dimethylhydantoin); 1,3-dichloro-5-methyl-5-isobutylhydantoin; 1.3- dichloro-5-methyl- 5 -ethylhydantoin; 1.3- dichloro-5,5-diisobutylhydantoin; 1.3- dichloro-5-methyl-5-n-amylhydantoin; and the like. Other useful hypochlorite-liberating agents are trichloromelamine and dry, particulate, water soluble anhydrous inorganic salts such as lithium hypochlorite and calcium hypochlorite. The hypochlorite liberating agent may, if desired, be a stable, solid complex or hydrate such as sodium p-toluene - sulfo-chloramine-trihydrate (choramine-T), sodium benzene sulfo-chloraimine-dihydrate, calcium hypochlorite tetrahydrate, or chlorinated trisodium phosphate containing 0.5 to 5% available chlorine produced by combing trisodium phosphate in its normal Na3PO412H20 form and an alkali metal hypochlorite (e.g., sodium hypochlorite).

The preferred sources of hypochlorite are dichloro- and trichloroisocyanurates, sodium hypochlorite, lithium hypochlorite, calcium hypochlorite and chloramine-T (PToluenesulfochloramine).

Typically and instant chlorine-liberating agents, such as sodium dichloroisocyanurate dihydrate, are employed in a proportion of 1 to 15% by weight of the composition, and preferably 1.0 tol0% and more preferably 2 to 6.5%. Sodium hypochlorite chlorine liberating agent is employed in a proporation of 3.6 to 36% by weight of the composition, and preferably 4.0 to 29% and more preferably 4 to 25% The composition should contain sufficient chlorine bleach compound to provide 0.5 to 5.0% by weight of available chlorine, as determined, for example, by acidification of the composition with sulfuric acid and iodometric ticration with sodium thiosulfate monitored by a potentiometer. A composition containing 0.9 to 9% by weight of sodium dichloroisocyanurate dihydrate contains or provides 0.5 to 5% available chlorine. A composition containing 1.8 to 6.25% by weight sodium dichloroisocyanurate dihydrate contains 1 to 3.5% by weight of available chlorine and is especially preferred. A composition containing 1.6 to 5.6% by weight calcium hypochlorite contains 1 to 3.5% by weight available chlorine. A composition containing 3.6 to 36% by weight of sodium hypochlorite contains 0.5 to 5% by weight of available chlorine. A composition containing 7.4 to 22.20% by weight of sodium hypochlorite contains 1 to 3% by weight of available chlorine.

Desirably the proportion of chlorine-liberating compound employed will be such as to yield a product which contains from 0.5% to 5% available chlorine on a total weight basis, preferably 1 to 4% and more preferably 1 to 3.5% available chlorine. The amount of available chlorine corresponds to 14 to 141 milli mole %, preferably 28 to 113 milli mole % and more preferably 14 to 99 milli mole % chlorine.

The bromide compounds that can be used in accordance with the present invention are those that are insoluble or only sparingly soluble in the aqueous liquid product composition, and that are soluble in the larger volume of the water washbath at the wash temperatures of 100 to 140°F (38 to 60°C, preferably 48 or 54 to 60°C) . that is, the bromide compounds are soluble in the warm or hot water wash bath of higher water volume.

Organic compounds contianing bromide ion, such as polymer bound bromide compounds, quaternaryammonium and phosphonium bromides (carbon length from C, to C20) salts can be used.

Sparingly soluble (e.g. insoluble in the aqueous product) bromide salts are best suited and aqueous liquid LADD compositions as they will suppress the formation of the active hypobromite in the product liquid, but will generate it in the wash cycle due to higher temperature and increased water volume in the wash cycle.

Bromide salts that are soluble in the aqueous LADD product liquid cannot be used, because they react immediately to form the highly reactive and unstable hypobromite, which degrades quickly, before the shelf life of the LADD product.

A readily commercially available source of bromide compounds that can be used are the sparingly water soluble or the water insoluble long chain alkyl hydrocarbon quaternary-ammonium bromide compounds having the following formula.

- Bril) Where is a C)2 to C22 alkyl, preferable Cl6-C18 alkyl.

Where R2 is a C, to C22 alkyl, preferably C,-C2 or CI6-C18 alkyl Where R3 is a C[ to C4 alkyl, preferably C,-C2 alkyl.

Where R4 is a Ct to C4 alkyl, preferably C,-C2 alkyl, or C,-C2 alkyl aromatic.

Specific compounds coming within this formula are: Dicetyldimethylammonium bromide Dicetylethylemethylammonium bromide Cetyldimethylethylammonium bromide Cetylltrimethylammonium bromide Distearyldimethylammonium bromide Stearyldiethylmethylammonium bromide Stearyldimethylethylammonium bromide Stearyltrimethylammonium bromide Stearyldimethybenzylammonium bromide Myristylrimethylammonium bromide Benzyldimethyldecylammonium bromide The phosphonium bromide salts having the following formula can also be used Ri R·.

- - Brill) r4 The values for Rlz R2, R3 and R4 are the same as defined in the above formula I quaternaryammonium bromide compounds, with the difference that Ru R2 and R3 can also each by pheyl.

Example of suitable phosphonium bromide salts that can be used are: Hexadecyltributylphosphonium bromide Ethyltriphenylphosphonium bromide Butyltriphenylphosphonium bromide Methyltrioctylphosphonium bromide Tetraphenylphosphonium bromide There can also be used the polymer bound quaternaryammonium bromide compounds of the Amberlite Series such as IRA 404 Resin of the following formula: (III) P is a resin polymer which can be a homopholymeric or copolymeric polyacrylate or polystyrene. R3, R6 and R7 can each be aryl or alkyl aryl, or C, to C4 hydrocarbons.

Suitable commercially available polymer bound resin compounds are: 1. Amberlyst A-26 having the formula P C6H6CH2N+ (CH3) 3Br‘ and is a polymer bound benzyl trimethyl quaternary ammonium bromide. The Amberlyst AO-26 contains 3.2 milli mole of bromide per gram of resin. 2. Amberlite IRA 402 Resin styrene/divinylbenzene copolymer has the formula P -C6H4CH2N+ (CH3) 3Br'. Amerlite IRA 402 Resin contains 4.2 milli mole of bromide per gram. 3. Amberlite IRA 458 Resin has the formula P -RN+(CH3)3Br' in which the P polymer is polyacrylate polymer and the R substituent is alkyl. Amerlite IRA 458 contains 5 milli mole of bromide per gram of resin. 4. Hexyltributylphosphonium bromide on polymer support has the formula P - (CHJ 6-P+ (C^H,) 3Br and contains 0.83 milli mole of bromide per gram of resin.

. Tributylmethylphosphonium bromide has the formula P -CH2P+(C4Ha)3Br', where p is polystyrene cross-linked with 1% diviylbenzene and contains 0.9 milli mole of bromide per gram of resin. 6. Tributylmethylammonium bromide polymer bound resin has the formula P - CHjN* (C4H,) 3Br' where P - is polystyrene crosslinked with 1% divinylbenzene and contains 0.85 milli mole of bromide per gram of resin.

In another embodiment of the invention readily water soluble bromide compounds, such as alkali and alkaline earth metal bromides can be used. However, in order to prevent these readily solubloe bromide compounds from dissolving in the aqueous liquid product and reacting prematurely with the hypochlorite, the readily soluble bromide compounds are encapsulated in a protective coating that is insoluble or only sparingly soluble in the liquid product.

The protective coating is selected such that the coating is insoluble or only sparingly soluble in the concentrated aqueous liquid product. The protective coating, however, is also selected such that it is soluble in the dilute larger volume of wash bath water at temperatures of 100 to 140°F, preferably 120 or 130 to 140°F (38 to 60°C, perferably 48 or 54 to 60°C.

Suitable encapsulation matterials which meet these criteria and the method of encapsulation are known in the art and are described in Brichard USP 4,421,669, which is incorporated herein it its entirety by reference thereto.

The bromide source or compound in this protective coating embodiment can be a water soluble bromide compound which provides a ready source of bromide ions on dissolution of the protective coating in the wash bath water. It is preferred to emply alkali metal bromides such as sodium bromide, lithium bromide, and potassium bromide, although alkaline earth metal bromides such as calcium bromide and magnesium bromide may be employed in those instances in which these water hardness producing cations are not objectionable.

In accordance with this embodiment of the present invention the readily water soluble alkali metal bromide compounds are coated using coating agents that are insoluble in water and that melt at the temperature in the wash water of the automatic dishwashing machine. The alkali metal bromide compounds are stabilized by the coating while in the aqueous product liquid and the coating dissolves at the elevated temperatures in the automatic dishwashing machine to release the water soluble alkali metal bromide to the dishwashing composition. Protective coating agents are chosen which have an initial melting point of between 38° and 60°C, and preferably between 48° and 60°C. That is, the coatings melt at the wash temperature in the dishwashing machine. The coating agents that can be used can be of various types. Organic compounds compatible with the alkali metal bromide compounds are generally chosen. These are characterized by solubility in water at ambient temperature of less than 5%, preferably less than 1% by weight. These coating agents are generally chosen from waxes of the types available commercially. The waxes that can be used according to the invention can be vegetable, animal, mineral or synthetic origin. They can be based on various type of products such as high moleular weight hydrocarbons, fatty acids and their derivatives, such as estes and amides, and fatty alcohols. The best results are obtained with waxes based on high molecular weight hydrocarbons.

The fatty acids present in the waxes that can be used are generally naturral or synthetic acids containing at least 10 carbon atoms. Waxes containing saturated fatty acids containing at least 10 carbon atoms or saturated fatty acids containing at least 13 carbon atoms can be used. Waxes containing saturated fatty acids containing 10 to 30 carbon atoms are preferred.

Derivatives of fatty acids present in the waxes that can be used can be of various types. Generally they are esters of fatty acids and compounds chosen from monohydric or polyhydric alcohols and epoxides, and amides of fatty acids, as well as substituted and unsubstituted aromatic, aliphatic or acyclic amines.

The esters of fatty acids present in the waxes are preferably esters of alcohols chosen from long chain alcohols such as alcohols containing 10 to 30 carbon atoms, glycols, ethylene glycols, glycerol, and carbohydrates or esters of epoxides such as ethylene oxide and propylene oxide.

The fatty alcohols present in the waxes that can be used are preferably naturla or synthetic alcohols containing at least 12 carbon atoms. Suitable fatty alcohols contain 12 to 35 carbon atoms. The high molecular weight hydrocarbons present in the waxes are those having average molecular weights varying between 300 and 800 as aliphatic hydrocarbons and olefin polymers. Suitable waxes are microcrystalline waxes and paraffin waxes.

Particles of coating agents used can be of a size generally between 0.05 and 10 mm average diameter, preferably between 0.1 and 5 mm.

The quantity of coating agent used to coat the alkali metal bromides is generally between 0.1 and 10% of the weight of the alkali metal bromide compound to be stabilized and preferably between 0.1 and 3% weight of the alkali metal bromide compound.

The particles of alkali metal bromide compound that are stablilized by coating with the waxes can have an average diameter of between 0.1 and 2 mm, preferably between 0.2 and 1 mm.

The alkali metal bromide compound particles are stabilized by coating them with a protective coating of wax particles using the coating process described in the above metioned Brichard USP 4,421,669.

The bromide compound is employed in an amount which is the same or less than the molar equivalent of available chlorine present in the product liquid, e.g., the mole ratio of bromide to available chlorine in the product liquid is in the range of 0.04 to 1.04, preferably less than 1.0, for example 0.05 to 0.95, or 0.05 to 0.90 and typically 0.05 to 0.75. Mole ratios of bromide ion to available chloring of 0.05 to 0.095 can also advantageously be used.The bromide compounds, whether as a water insoluble bromide compound or as a water soluble bromide compound with a protective coating are used in amounts to provide in the detergent composition 0.56 to 147 milli moles%, preferably 1.4 to 102 milli moles % and more preferably 1.4 to 74 milli mole % of bromide.

A balanced aqueous liquid detergent composition is obtained which contains a small effective amount of the bromide which in the aqueous wash bath reacts with the hypochlorite to form a sufficient amount of hypobromite to remove the starchy carbohydrate soil and to leave a sufficient amount of hypochlorite ion in the wash bath to remove the proteinaceous soil.

Thus, the weight prercent available chloride and the mole ratio of bromide to available chloride are important features of the present invention.

Detergent active material useful herein should be stable in the presence of chlorine bleach, especially hypochlorite bleach, and for this purpose those of the organic anionic, amine oxide, phosphine oxide, sulphoxide or betaine water dispersible surfactant types are preferred, the first mentioned anionics being most preferred. Particularly preferred surfactants herein are the linear or branched alkali metal mono- and/or di (Cg-C]4) alkyl diphenyl oxide mono- and/or di - sulphates, commercially available for example as DOWFAX (registered trademark) 3B-2 and DOWFAX 2A-1. In addition, the surfactant should be compatible with the other ingredients of the composition. Other suitable organic anionic, non-soap surfactants include the primary alkylsulphates, alkylsulphonates, alkylarylsulphonates and sec.alkylsulphates. Examples include sodium C10-C18 alkylsulphates such as sodium dodecylsulphate and sodium tallow alcoholsulphate; sodium C10-CI8 alkanesulphonates such as sodium hexadecyl - l-sulphonate and sodium C12-C18 alkylbenzenesulphonates such as sodium dodecylbenzenesylphonates. The corresponding potassium salts may also be employed. ¢921145 As other suitable surfactants or detergents, the amine oxide surfactants are typically of the structure R2r'N0, in which each R represents a lower alkyl group, for instance, methyl, and R1 represents a long chain alkyl group having from 8 to 22 carbon atoms, for instance a lauryl, myristyl, palmityl or cetyl group. Instead of an amine oxide, a corresponding surfactant phosphine oxide R:RlPO or sulphoxide RR'SO can be employed. Betaine surfactants are typically of the structure R2R’N+RCOO-, in which each R represents a lower alkylene group having from 1 to 5 carbon atoms. Specific examples of these surfactants include lauryl-dimethylamine oxide, myristyl-dimethylamine oxide, myristyl-dimethylamine oxide, the corresponding phosphine oxides and sulphoxides, and the corresponding betaines, including dodecyldimethylammonium acetate, tetradecyldiethylammonium pentanoate, hexadecyldimethylammonium hexanoate and the like. For biodegradability, the alkyl groups in these surfactants should be linear, and such compounds are preferred.

Surfactants of the foregoing type, all well known in the art, are described, for example, in U.S. Patents 3,985,668 and 4,271,030. If chlorine bleach is not used than any of the well known low-foaming nonionic surfactants such as alkoxylated fatty alcohols, e.g. mixed ethylene oxidepropylene oxide condensates of C8 - C22 fatty alcohols can also be used.

The chlorine bleach stable, water dispersible organic detergent-active material (surfactant) will normally be present in the composition in minor amounts, generally 1% by weight of the composition in minor amounts, generally 1% by weight of the composition, although smaller or larger amounts, such as up to 5%, such as from 0 to 5%, preferably form 0.1 or 0.2 to 3% by weight of the composition, may be used.

Alkali metal (e.g. potassium or sodium) silicate, which provides alkalinity and protection of hard surfaces, such as fine china glaze and pattern, is generally employed in an amount ranging from 5 to 25 weight percent, preferably 5 to 15 weight percent, more preferably 8 to 12% in the composition. The sodium or potassium silicate is generally added in the form of an aqueous solution, preferably having Na2O:SiO2 or K2O:SiO2 ratio of 1:1.3 to 1:2.8, especially preferably 1:2.0 to 1:2.6. At this point, it should be mentioned that many of the other components of this composition, especially alkali metal hydroxide and bleach, are also often added in the form of a preliminary prepared aqueous dispersion or solution.

In addition to the detergent active surfactant, foam inhibitor, alkali metal silicate corrosion inhibitor, and detergent builder salts, which all contribute to the cleaning performance, it is also known that the effectiveness of the liquid automatic dishwasher detergent compositions is related to the alkalinity, and particularly to moderate to high alkalinity levels. Accordingly, the compositions of this invention will have pH values of at least 9.5, preferably at least 11 to as high as 14, generally up to 13 or more, and, when added to the aqueous wash bath at a typical concentration level of 10 grams per liter, will provide a pH in the wash bath of at least 9, preferably at least 10, such as 10.5, 11, 11.5 or 12 or more.

The alkalinity will be achieved, in part by the alkali metal ions contributed by the alkali metal detergent builder salts, e.g. sodium tripolyphosphate, tetrapotassium pyrophosphate, and alkali metal silicate, however, it is usually necessary to include alkali metal hydroxide, e.g. NaOH or KOH, to achieve the desired high alkalinity. Amounts of alkali metal hydroxide in the range of (on an active basis) of from 0 to 8%, preferably from 0.5 to 6%, more preferably from to 4%, by weight of the composition will be sufficient to achieve the desired pH level and/or to adjust the K/Na weight ratio.

Other alkali metal salts, such as alkali metal carbonate may also be present in the compositions in minor amounts, for example from 0 to 4%, preferably 0 to 2%, by weight of the composition.

Other conventional ingredients may be included in these compositions in small amounts, generally less than 3 weight percent, such as perfume, hydrotropic agents such as the sodium benzene, toluene, xylene and cumene sulphonates, preservatives, dyestuffs and pigments and the like, all of course being stable to chlorine bleach compound and high alkalinity. Especially preferred for coloring are the chlorinated phythalocyanines and polysuphides of aluminosilicate which provide, respectively, pleasing green and blue tints. TiO2 may be employed for whitening or neutralizing off-shades.

Although for the reasons previously discussed excessive air bubbles are not often desirable in the invention compositions, depending on the amounts of dissolved solids and liquid phase densities, incorporation of small amounts of finely divided air bubbles, generally up to 10% by volume, preferably up to 4% by volume, more preferably up to 2% by volume, can be incorporated to adjust the bulk density to approximate liquid phase density. The incorporated air bubbles should be finely divided, such as up to 100 microns in diameter, preferably from 20 to 40 microns in diameter, to assure maximum stability. Although air is the preferred gaseous medium for adjusting densities to improve physical stability of the composition other inert gases can also be used, such as nitrogen, carbon dioxide, helium, oxygen, etc.

The amount of water contained in these compositions should, of course, be neither so high as to produce unduly low viscosity and fluidity, nor so low as to produce unduly high viscosity and low flowability, linear viscoelastic properties in either case being diminished or destroyed by increasing tan 1. Such amount is readily determined by routine experimentation in any particular instance, generally ranging from 30 to 75 weight percent, preferably 35 to 65 weight percent. The water should also be preferably deionized or softened.

The manner of formulating the invention compositions is also important. As discussed above, the order of mixing the ingredients as well as the manner in which the the mixing is performed will generally have a significant effect on the properties of the composition, and in particular on product density (by incorporation and stabilization of more or less air) and physical stability (e.g. phase separation). Thus, according to the preferred practice of this invention the compositions are prepared by first forming a dispersion of the polyacrylic acid-type thickener in water under moderate to high shear conditions, neutralizing the dissolved polymer to cause gelation, and then introducing, while continuing mixing, the detergent builder salts, alkali metal silicates, chlorine bleach compound and remaining detergent additives, including any previously unused alkali metal hydroxide, if any, other than the surface-active compounds. All of the additional ingredients can be added simultaneously or sequentially. Preferably, the ingredients are added sequentially, although it is not necessary to complete the addition of one ingredient before beginning to add the next ingredient. Furthermore, one or more of these ingredients can be divided into portions and added at different times. These mixing steps should also be performed under moderate to high shear rates to achieve complete and uniform mixing. These mixing steps may be carried out at room temperature, although the polymer thickener neutralization (gelation) is usually exothermic.

The composition may be allowed to age, if necessary, to cause dissolved or dispersed air to dissipate out of the composition.

The remaining surface active ingredients, including the anti-foaming agent, organic detergent compound, and fatty acid or fatty acid salt stabilizer is post-added to the previously formed mixture in the form of an aqueous emulsion (using from 1 to 10%, preferably from 2 to 4% of the total water added to the composition other than water added as carrier for other ingredients or water of hydration) which is pre-heated to a temperature in the range of from Tm+5 to Tm-20, preferably from Tm to TM-10, where Tm is the melting point temperature of the fatty acid or fatty acid salt. For the preferred stearic acid stabilizer the heating temperature is in the range of 50°C to 70°C. However, if care is taken to avoid excessive air bubble incorporation during the gelatin step or during the mixing of the detergent builder salts and other additives, for example, by operating under vacuum, or using low shearing conditions, or special mixing operatatus, etc., the order of addition of the surface active ingredients should be less important.

In accordance with an especially preferred embodiment, the thickened linear viscoelastic aqueous automatic dishwasher detergent composition of this invention includes, on a weight basis: (a) 5 to 40%, preferably 15 to 25%, alkali metal polyphosphate detergent builder salt; (b) 5 to 25%, preferably 5 to 15%, alkali metal silicate; (c) to 6%, preferably 1.2 to 4%, alkali metal hydroxide; (d) 0 to 5%, preferably 0.1 to 3%, chlorine bleach stable, water-dispersible, low-foaming organic detergent active material, preferably non-soap anionic detergent; (e) 0 to 1.5%, preferably 0.1 to 0.5%, chlorine bleach stable foam depressant; (f) chlorine bleach compound in an amount to provide 0.2 to 4%, preferably 0.8 to 1.6%, of available chlorine; (g) sufficient bromide compound to provide a bromide to available chlorine ratio of 0.04 to 1.04; (h) at least one high molecular weight hydrophilic cross-linked poiyacrylic acid type thickening agent in an amount to provide a linear viscoelasticity to the formulation, preferably from 0.1 to 2.0%, more preferably from 0.4 to 1.75%; (i) a long chain fatty acid or a metal salt of a long chain fatty acid in an amount effective to increase the physical stability of the compositions, preferably from 0.005 to 2.0%, more preferably from 0.2 to 2.0%; and (j) balance water, preferably from 30 to 75%, more preferably from 35 to 65%; and wherein in (a) the alkali metal polyphosphate includes a mixture of from 5 to 30%, preferably from 12 to 22% of tetrapotassium pyrophosphate or potassium tripolyphosphate, and from 0 to 20%, preferably from 3 to 18% of sodium tripolyphosphate, and wherein in the entire composition the ratio, by weight, of potassium ions to sodium ions is from 45/1 to 3/1, preferably from 3/1 to 1/2, the compositions having an amount of air incorporated therein such that the bulk density of the composition is from 1.26 to 1.42 g/cc, preferably from 1.32 to 1.40 g/cc.

The compositions will be supplied to the consumer in suitable dispenser containers preferably formed of molded plastic, especially polyolefin plastic, and most preferably polyethylene, for which the invention compositions appear to have particularly favorable slip characteristics. In addition to their linear viscoelastic character, the compositions of this invention may also be characterized as pseudoplastic gels (non-thixotropic) which are typically near the borderline between liquid and solid viscoelastic gel, depending, for example, on the amount of the polymeric thickener. The invention compositions can be readily poured from their containers without any shaking or squeezing, although squeezable containers are often convenient and accepted by the consumer for gel-like products.

The liquid aqueous linear viscoelastic automatic dishwasher compositions of this invention are readily employed in known manner for washing dishes, other kitchen utensils and the like in an automatic dishwasher, provided with a suitable detergent dispenser, in an aqueous wash bath containing an effective amount of the composition, generally sufficient to fill or partially fill the automatic dispenser cup of the particular machine being used.

The invention also provides a method for cleaning dishware in an automatic dishwashing machine with an aqueous wash bath containing an effective amount of the liquid linear viscoelastic automatic dishwasher detergent composition as described above. The composition can be readily poured from the polyethylene container with little or no squeezing or shaking into the dispensing cup of the automatic dishwashing machine and will be sufficiently viscous and cohesive to remain securely within the dispensing cup until shear forces are again applied thereto, such as by the water spray from the dishwashing machine.

The invention may be put into practice in various ways 5 and a number of specific embodiments will be described to illustrate the invention with reference to the accompanying examples .

All the amounts and proportions referred to herein are by weight of the composition unless otherwise indicated.

Example 1 The following formulations A-K were prepared as described below: BAL. 1 σι o I fr'S t 1 ST m rd rd CM ) 1 CM m rd rd O cn o CM V 1 o σ ►3 in 1 m 1 CN rd in » 1 CO rf . • 1 o • rd 1 • • • CM 1 • Ηϊ CQ τ-I cm 1 CN CM 1 cn rd O V 1 rd J t I CM m o 1 1 3 1 • 1 in m rd 1 • • CN 1 1 H CQ 1 CN ) rd rd CN cn rd rd c- Λ 1 1 in , o rd a σι | V 1 1 CN rd in • » • 3 . 1 CO 1 1 N< • • • CN 1 in B ffl o 1 cn CN 1 1 cn cn rd O Λ V o kO a σι I I 1 CM rd m • 1 rd rf • • 1 GO I rd 1 • • • CN 1 • o m o CM 1 CN 1 CN 1 cn rd O r* V 1 ’Φ o in J 1 in 1 in 1 1 1 rd ♦ 1 σ 3 | • 1 O • r· 1 1 1 • CN 1 ♦ Pm « 1 m 1 CN r- rd 1 1 rd 1 σι Λ 1 rd O in j m I in 1 1 1 rd • 1 σι 3 • t O • 1 1 t • CN 1 • H CQ rd f*T1 CN c^ rd 1 1 rd 1 σι V 1 rd • O σ J cn V 1 in ( CN rd in • ( 00 3 • . 1 O • rd 1 • * • CN 1 • Q CQ o CN 1 CN CN 1 cn rd O V 1 rd o CD J σι 1 i CN rd in • 1 rd 3 • • 1 in CN rd 1 • • • CM 1 • U CQ o CN 1 rd rd CN ( m rd O P" V 1 rd o o CN ►3 σι V 1 1 CN rd tn • rd rd rf • . 1 m Γ0 rd 1 ♦ • • CN • • « ffl o cn 1 rd rd CN 1 m rd o [> V O rd o CN ►J σι 1 1 CM rd in • 1 rd 3 • • 1 m Γ0 rd 1 • • • CN 1 • rf CQ o CM 1 rd rd CN 1 cn rd O r-~ V 1 rd Pi nJ W a —* >-* E-· cn m 2 rf rd * • • o o 2 V ω W CN CN CN • . A H σ H A .. M ·· CN ca m «ΑΡ w O 2 F· ca effi rf rf! rd Η rd CQ hd rd H H rf w J O 2 CJ " rf~ cn cj o £ H »4 IS) o in o Q H — CJ in rf o z O P H CL —* in £ h3 Η Λ» *-* * a > 5 w B_S 2 o w h in ι-l rd rf ΪΗ CJ § nJ S 2 o ffl pd a CL 2 cn · H · Z Cn H rf *1 CL_O H o a CL CL i3 C* cn σ S H w — Pi a a h H "v w 3 nJ o ΪΧ CL Cd nJ N* CN CL O rf ►J ij H oi b Q cj a H e-« a a — « — J U b a o rf ft 1.37 1 00 tn •H Cn in C • rn σ Ο <3 • Ή » » 0 rH ft ο σ Γ- • ο ο 1 σ • • 1 -Η ιη ιη H 1 ft Λ Λ ΙΌ σ Ο 1 CD ο ο 1 Η CN CM n 1 ft Λ Λ r~ • m σ ο Ο ♦ •Η • • 0 i—l ο ο ο ο • • 1 ο ο 1 γ4 r-l h 1 Λ Λ Ο Ο UJ • • rn ο ο « Η rH H ι—1 Λ Λ m r- • m σ Ο Ο • •Η • • Q i—l ft ο ο CM in • m σ ο ο • Η • • U ι—1 ft ο ο F* m ο ο n i—i σ σ τ—1 • ro tn ο ο • •Η • • rt! i-l Uj ο ο 03 u ft o Μ tn • Ε >4 Χ <#> >4 2* Η 2 — Η νο rf η ω ω ο) Η 03 2 Ω Η Η ft Ω ε* - H 0 η ω ω Η Ω & cn Ο m ζ 2 w Α 0ο z ω icq 03 Ο S rtj 03 Ο — w a BWO Ε4 μ σ λ» Ω ft oa ft ft ω 03 ft Ω — - Ll Φ -H ε Ό G O υ nJ 0) Λ Φ Ω 4J G & G σ G rl Ο Ό rl G jJ φ (tf ft Ll Φ Ό r4 .. Φ Ω Φ Ll Ό tn -rl φ U Ό nJ G O -rl •ri nJ 4-) 4-1 ·' a m Φ jV> -rl u I -rl > tn G Φ Ό Ό Φ 4-) nJ 4-) u Ο -rl G Ό G tn -η Φ o Ό Li Ή nJ o Φ J5 4J G rl σ m G Φ •rl 4-) Φ 4-) Φ Ό Li Φ Χ3 Φ Ή μ 4J ε 03 8 Φ 3 G U nJ ft nJ Ό O G 4J nJ Ό ϋ Φ rl 4J Li nJ Li Φ Φ 4-) nJ tn Φ Ll o nJ Φ tn Li G O 4-) -rl X D -rl (0 2-Ω — g o 6 sr cm Li σι m O Ω 44 r4 Ο Ω Φ ft Ο X! o tn 4-) X3 Ll Li Φ Ω nj ε h u w < >-ιΩ r-ι O Ή ί> Φ υ xe -rl X3 ft O uj 4-) CM — TO G nJ o Li υ •H 4-> nJ Li Φ ft nJ Φ Ll 44 4-) ft Ο Φ σ m Φ Li φ > nJ nO Φ Li >, Li Ο Φ Ω 44 ft Φ e m Φ ftXa ω cm m cn Φ Ω xa xa Formulations A, B, C, D, E, G, J, and K are prepared byfirst forming a uniform dispersion of the Carbopol 941 or 940 thickener in 97% of the water (balance). The Carbopol is slowly added to deionized water at room temperature using a mixer equipped with a premier blade, with agitation set at a medium shear rate, as recommended by the manufacturer. The dispersion is then neutralized by addition, under mixing, of the caustic soda (50% NaOH or KOH) component to form a thickened product of gel-like consistency.

To the resulting gelled dispersion the silicate, tetrapotassium pyrophosphate (TKPP), sodium tripolyphosphate TP(TPP, Na) and bleach, are added sequentially, in the order stated, with the mixing continued at medium shear.

Separately, an emulsion of the phosphate anti-foaming agent (LPKN), stearic acid/palmitic acid mixture and detergent (Dowfax 3B2) is prepared by adding these ingredients to the remaining 3% of water (balance) and heating the resulting mixture to a temperature in the range of 50°C to 70°C.

This heated emulsion is then added to the previously prepared gelled dispersion under low shear conditions, such that a vortex is not formed.

The remaining formulations F, H and I are prepared in essentially the same manner as described above except that the heated emulsion of LPKN, stearic acid and Dowfax 3B2 is directly added to the neutralized Carbopol dispersion prior to the addition of the remaining ingredients. As a result, formulations F, H and I, have higher levels of incorporated air and densities below 1.30 g/cc.

The rheograms for the formulations A, C, D, G and J are shown in figures 1-5, respectively, and rheograms for formulations Η, I and K are shown in figures 6, 7 and 8 respectively.

These rheograms are obtained with the System 4 Rheometer from Rheometrics equipped with a Fluid Servo with a 100 gramscentimeter torque transducer and a 50 millimeter parallel plate geometry having an 0.8 millimeter gap between plates.

All measurements are made at room temperature (25°C+1°C) in a humidity chamber after a 5 minute or 10 minute holding period of the sample in the gap. The measurements are made by applying a frequency of 10 radians per second.

All of the composition formulations A, B, C, D, G and J according to the preferred embodiment of the invention which include Carbopol 941 and stearic acid exhibit linear viscoelasticity as seen from the rheograms of figure 1-5. Formulation E which includes Carbopol 941 but not stearic acid showed no phase separation at either room temperature or l00°F after 3 weeks, but exhibited 10% phase separation after 8 weeks at room temperature and after only 6 weeks at 100°F.

Formulation K, containing Carbopol 940 in place of Carbopol 941, as seen from the rheogram in figure 8, exhibits substantial linearity over the strain range of from 2% to 50% (G' at 1% strain-G' at 50% strain 500 dynes/sq.cm.) although tan ζί at a strain above 50%.

Example 2 This example demonstrates the importance of the order of addition of the surface active component premix to the remainder of the composition on product density and stability.

The following formulations are prepared by methods A and Ingredient Water, deionized Balance Carboool 941 0.5 NaOH ‘(50%) 2.4 Na Silicate (47.5%) 21 TKPP 15 TPP, Na 13 Bleach (1%) 7.5 LPKN 0.16 Stearic Acid 0.1 Dowfax 3B2 1 Method A: The Carbopol 941 is dispersed, under medium shear rate, using a premier blade mixer, in deionized water at ambient temperature. The NaOH is added, under mixing, to neutralize and gel the Carbopol 941 dispersion. To the thickened mixture the following ingredients are added sequentially while the stirring is continued: sodium silicate, TKPP, TPP, and bleach.

Separately, an emulsion is prepared by adding the Dowfax 3B2, stearic acid and LPKN to water while mixing at moderate 0 shear and heating the mixture to 65°C to finely disperse the emulsified surface active ingredients in the water phase.

This emulsion premix is then slowly added to the Carbopol dispersion while mixing under low shear conditions without forming a vortex. The results are shown below.

Method B: Method A is repeated except that the heated emulsion premix is added to the neutralized Carbopol 941 dispersion before the sodium stearate, TKPP, TPP, and bleach. The results are also shown below.

Method A Density (g/cc) 1.38 Stability (RT-8 weeks) 0.00% Rheogram Fig. 9 Method B 1.30 7.00% Fig.10 From the rheograms of figures 9 and 10 it is seen that both products are linear viscoelastic although the elastic and viscous moduli G' and G are higher for Method A than for Method B.

From the results it is seen that early addition of the surface active ingredients to the Carbopol gel significantly increases the degree of aeration and lowers the bulk density of the final product. Since the bulk density is lower than the density of the continuous liquid phase, the liquid phase undergoes inverse separation (a clear liquid phase forms on the bottom of the composition). This process of inverse separation appears to be kinetically controlled and will occur faster as the density of the product becomes lower.

Example 3 This example shows the importance of the temperature at which the premixed surfactant emulsion is prepared.

Two formulations, L and M, having the same composition as in Example 2 except that the amount of stearic acid was increased from 0.1% to 0.2% are prepared as shown in Method A for formulation L and by the following Method C for formulation M.

Method C The procedure of Method A is repeated in all details except that emulsion premix of the surface active ingredients is prepared at room temperature and is not heated before being post-added to the thickened Carbopol dispersion containing silicate, builders and bleach. The rheograms for formulations L and M are shown in figures ll and 12, respectively. From these rheograms it is seen that formulation L is linear viscoelastic in both G' and G whereas formulation M is nonlinear viscoelastic particularly for elastic modulus G' (G' at li strain-G' at 30% strain > 500 dynes/cm2) and also for G (G at 1% strain-G at 30% strain ♦ 300 dynes/cm2) .

Formulation L remains stable after storage at RT and 100°F for at least 6 weeks whereas formulation M undergoes phase separation.

Comparative Example 1 The following formulation is prepared without 20 potassium salts: Weight % Water Balance Carbopol 941 0.2 NaOH (50%) 2.4 25 TPP, Na (50%) 21.0 Na Silicate (47.5%) 17.24 Bleach (1%) 7.13 Stearic Acid 0.1 LPKN (5%) 3.2 30 Dowfax 3B2 0.8 Soda Ash 5.0 Acrysol LMW 45-N 2.0 The procedure used is analogous to Method A of Example 2 with the soda ash and Acrysol LMW 45-N (low molecular weight polyacrylate polymer) being added before and after, respectively, the silicate, TPP and bleach, to the thickened 5 Carbopol 941 dispersion, followed by addition to the heated surface active emulsion premix. The rheogram is shown in figure 13 and is non-linear with G/G' (tan/)) > 1 over the range of strain of from 5% to 80%.

Example 4 Formulations A, B, C, D and K according to this invention and comparative formulations F and a commercial liquid automatic dishwasher detergent product as shown in Table 1 above were subjected to a bottle residue test using a standard polyethylene 28 ounce bottle as used for current commercial liquid dishwasher detergent bottle.

Six bottles are filled with the respective samples and the product is dispensed, with a minimum of force, in 80 gram dosages, with a 2 minute rest period between dosages, until flow stops. At this point, the bottle was vigorously shaken to try to expel additional product.

The amount of product remaining in the bottle is measured as a percentage of the total product originally filled in the bottle. The results are shown below.

Bottle Residue Formulation Residue A 8 B 10 C 6 D 5 K 7 F* 4 Commercial Product 20 ♦The sample separates upon aging Example 5 The following formulas A-I were prepared according to the procedure of Example 1.

H in o o cq CN CN CO rd O 00 o o rd CN o o CN o in kO r* cn rd in co 0.05 I CN O o o o O in o O cq tn o c- o 44* cq r4 00 • • o in • o 00 rd o • • in • * n o CN cq m O o CN CN C~ r* co o 00 o o in O O o o in o t- o Ί4 M4 rd ao • • ♦ in • o * • rd in cq • • <0 o o H cq cq o o cq rd rd cn o rd o o o in o O O in in 00 o in v n4 rd co • ♦ • in • o * rd in cq • ♦ CN ix o o CN CN O o cq cd rd m o rd O in O m o o in O r- o (N rd o • • in in • co * • , • • rd o » ♦ Ί4 • o H o (N cq m O rd cq cq r> c* m rd rd O in o in o o cq r* LO r- o M4 cq i—1 CO « « o in • m * « • • • rd o • • in • rd Ω o cq cq co o o cq cq C m rd rd O in O in o o o o r- O r* o β· rd 00 • • « tn • co * • • • rd in cq • t- • cq U o rd cq cq o o cq rd rd c~ m rd rd o in o in o o o in o rd £ tn M4 rd CO • • • in • m * rd in cq • c- • CN ffl o o cq CN o o CN rd rd c- m rd rd O in O in o o o cq o rd M4 cq rd 00 • • • in • m * • « rd in cq • • rd rf o o cq CO o o cq rd rd m rd rd fa E 4t H fa fa E-4 w E-| O Z z rf ffl w in rf fa a a 2*4 Q CJ fa CJ m 0 H cq H rf 03 o 4fc K 5 CJ 1 ffl a o fa 04 3 ώ» rf ffl H 2 fa a >4 E-< ffl Ο ω 03 ffl 03 fa a a z o ffl in oV> CJ Η O >4 0 fa >4 o in H fa S μ a 2 J 2 H fa E-· o co fa 3 ffl m 03 fa ffl o & *-» fa fa H CQ 5m a «3 rf fa H rf o H fa H «Α» fa a 0 03 04 o W s Q t> E-* fa Q H Q cn 0 z 3 CJ n5 fa H 0 O V Ο X4 O fa Ο H rf H H fa u rf z ffl 03 Q 03 — fa fa 03 E-4 03 ·~~ z a CJ Q ϋ Brookfield viscosity measured at room temperature at 4 # spindle at 20 rpms.

LO Φ 1—I O ε nJ X W cn re) cq H ω xi 4-> d •H a; xi Φ xi Φ I—I (0 X ω 4-1 O Xl ω x) U Φ Cn 4-1 a) Xi 3 P Φ υ o ftp Φ Φ P X! C xJ 3 O O ft X) 6 O 01 U o c ω φ xi •rl P )-1 O U □ nJ Φ P £s Φ Xi Φ P nJ X! cn 4-) d Φ •H P Φ Xl Ol d -rl )-1 < Φ X! cn 4-) nJ 0 r-l Φ E ·£ C 4-1 O 4-1 r-l rd Oi nJ a i-i Φ 4J M-Ι nJ 4-1 4-) cn Φ nJ X! r-l H p φ p P nJ ω S86‘0 4.« I CN in 0 CN 33.24 J 5-18 || 9.06 0.003 0.05 || II Δ0Ό 0.79 || 1.5 Balance || in cn rd 27.80 0 φ a cn 00 co d Ό co m 1—( r-1 0 in CO c- cn nJ CO 0 cn V • • CN rd 0 0 rd 0 r~ 0 t—1 cn GO 0 m ns • O 0 N* (N ro in σι 0 0 0 0 0 rd OQ rd rO OQ Φ 0 in CN in m d 00 C O' ro in 0 in LO l> 0 in nJ O 'f • CN rd ¢3 0 r-l 0 CD CN r-l cn CD 0 m • • • • • • • nJ ♦ 0 0 N* CN cn in σι 0 0 0 0 0 0 OQ i—l rf* Φ CJ GO CO N< cn d c- GO in GO 0 in co > 0 m nJ 0 0 • CN rd 0 0 i—l 0 GO CN rd cn 0 m cd • cn 0 rf* CN m in σι 0 0 O ¢3 O 0 OQ rd N< in •rd >1 ε r- d 4J ft «1» 0 •rd M ε 03 g 0 0 Φ cn 4-) <*> 3 CJ CN JJ 3 d m r-l <—* 03 fd 0 rd rf1 •rl · u Xi Μ P X! 3 > E-< Ό O Ή 4-i Η • co — >1 r-l u CN Φ 0 P ft (jp <λ» X! m 0 Φ OQ ε — rd 0 cn ο d rd 0 υ CO cn rl CD * 0 in co λ! -—O' d in υ Xi Φ •rl GJ Q4 g 3 nJ rd •Η X 4-> P 4-) 4-1 rd q' q ft 0 X4 1 Xi nJ r-l -rl Xi •rl ft P 03 q ft ft 0 r-l Oi d nJ 4d >1 ε Φ cn 0 d ft u 0 Ό ft H 0 rd nJ w Φ 3 4-) O 4-> d ϋ ·η ο eg cfl 0 Ε-· td nJ Φ Xi ft X) 0 Φ Xl <« φ Xi ft 0 z co z Z >4 ft XJ co a 0 OQ z Q OQ CO m

Claims (13)

1. A linear viscoelastic aqueous liquid automatic dishwasher detergent composition comprising approximately by weight: 5 (a) 10 to 35% of at least one alkali metal detergent builder salt, said alkali metal detergent builder salt being selected from the group consisting essentially of alkali metal tripolyphosphate, alkali metal pyrophosphate, alkali metal metaphosphate, alkali metal carbonate, alkali 10 metal citrate and alkali metal nitrilotriacetate and mixtures thereof; b) 0 to 6% alkali metal hydroxide; (c) 0.1 to 5% chlorine bleach stable, waterdispersible, organic detergent active material; 15 (d) 0 to 1.5% chlorine bleach stable foam depressant; (e) chlorine bleach compound in an amount to provide 0.2 to 4% of available chlorine; (f) sufficient bromide compound to provide a 20 bromide to available chlorine mole ration of 0.04 to 1.04; (g) 0.1 to 2.0% of at least one cross-linked polyacrylic acid thickening agent having a molecular weight of from 500,000 to 10,000,000; (h) 0.005 to 2% of a long chain fatty acid or a 25 metal salt of a fatty acid; (i) 0 to 15% of a non-cross-linked polyacrylate having a molecular weight of 1,000 to 100,000; and IE 9217 45 (j) water, wherein said polyacrylic acid thickening agent being selected from the group consisting essentially of acrylic acid or methacrylic acid, water-dispersible or watersoluble salts, esters, or amides thereof, and water-soluble 5 copolymers of these acids or their salts, ester, or amides with each other or with one or more other ethylenically unsaturated monomers, wherein the aqueous phase includes both sodium and potassium ions at a K/Na weight ratio of from 1/1 to 45/1, wherein substantially all of the normally solid 10 components of the composition are present dissolved in the aqueous phase, and substantially all of the water in the composition is tightly bound to the cross-linked polyacrylic acid thickening agent, said composition having a bulk density of from 1.26 g/cm 3 to 1.42 g/cm 3 and said composition does not 15 exhibit phase separation and remains homogenous, when said composition is centrifuged at 1000 rpm for 30 minutes.

2. The composition of Claim 1, wherein said alkali metal builder salt is a mixture of sodium tripolyphosphate and potassium tripolyphosphate. 20

3. The composition of Claim 1, wherein said alkali metal builder salt is a mixture of sodium tripolyphosphate and potassium pyrophosphate.

4. The composition of Claim 1 wherein said alkali metal builder salt is a mixture of sodium tripolyphosphate, 25 potassium tripolyphosphate, and potassium pyrophosphate and mixture thereof.

5. The composition of Claim 1, wherein the long chain fatty acid or salt thereof is present in an amount of from 0.02 to 2.0% by weight.

6. The composition of Claim 1 which further comprises 5 up to 2% by volume, based on the total volume of the composition, of air in the form of finely dispersed bubbles.

7. The composition of Claim 1 wherein the cross-linked poiyacrylic acid thickening is present in an amount of from 0.2 to 1.75% by weight of the composition. 10

8. The composition of Claim 1 wherein the K/Na ratio is from 1/1 to 3/1.

9. The composition of Claim 1 which the chlorine bleach compound is sodium hypochlorite.

10. The composition of Claim 1 further including a 15 fragrance.

11. The composition of Claim 1 further including a dyestuff or pigment.

12. The composition of Claim 1 wherein said bromide compound is a quarternaryammounium bromide.

13. A linear viscoelastic aqueous liquid automatic dishwasher detergent composition substantially as described herein . with reference to the Examples and/or the accompanying drawings.