IE53941B1 - Thixotropic resins, their preparations and use in coatings - Google Patents
Thixotropic resins, their preparations and use in coatingsInfo
- Publication number
- IE53941B1 IE53941B1 IE33/83A IE3383A IE53941B1 IE 53941 B1 IE53941 B1 IE 53941B1 IE 33/83 A IE33/83 A IE 33/83A IE 3383 A IE3383 A IE 3383A IE 53941 B1 IE53941 B1 IE 53941B1
- Authority
- IE
- Ireland
- Prior art keywords
- resin
- weight
- process according
- polyisocyanate
- reacting
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 45
- 239000011347 resin Substances 0.000 title claims abstract description 45
- 230000009974 thixotropic effect Effects 0.000 title claims abstract description 24
- 238000000576 coating method Methods 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title description 6
- 229920000180 alkyd Polymers 0.000 claims abstract description 39
- 239000004952 Polyamide Substances 0.000 claims abstract description 16
- 229920002647 polyamide Polymers 0.000 claims abstract description 16
- 239000008199 coating composition Substances 0.000 claims abstract description 15
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 15
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 14
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 12
- 238000000518 rheometry Methods 0.000 claims abstract description 3
- 239000003921 oil Substances 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 20
- 239000011230 binding agent Substances 0.000 claims description 9
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000000539 dimer Substances 0.000 claims description 4
- 150000007519 polyprotic acids Polymers 0.000 claims description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001281 polyalkylene Polymers 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000011248 coating agent Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 235000019198 oils Nutrition 0.000 description 19
- 239000007787 solid Substances 0.000 description 15
- 239000012948 isocyanate Substances 0.000 description 13
- 150000002513 isocyanates Chemical class 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 244000068988 Glycine max Species 0.000 description 8
- 235000010469 Glycine max Nutrition 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- -1 fatty acid ester Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 229920002396 Polyurea Polymers 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
- VJZWIFWPGRIJSN-XRHABHTOSA-N dilinoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O.CCCCC\C=C/C\C=C/CCCCCCCC(O)=O VJZWIFWPGRIJSN-XRHABHTOSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 101150043652 secs-1 gene Proteins 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/60—Polyamides or polyester-amides
- C08G18/606—Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8201437 | 1982-01-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE830033L IE830033L (en) | 1983-07-19 |
| IE53941B1 true IE53941B1 (en) | 1989-04-26 |
Family
ID=10527718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE33/83A IE53941B1 (en) | 1982-01-19 | 1983-01-07 | Thixotropic resins, their preparations and use in coatings |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP0086034B1 (forum.php) |
| JP (1) | JPS58127723A (forum.php) |
| AU (1) | AU1003183A (forum.php) |
| CA (1) | CA1193378A (forum.php) |
| CY (1) | CY1337A (forum.php) |
| DE (1) | DE3361574D1 (forum.php) |
| ES (1) | ES519072A0 (forum.php) |
| GB (1) | GB2113230B (forum.php) |
| IE (1) | IE53941B1 (forum.php) |
| IN (1) | IN159303B (forum.php) |
| MY (2) | MY8600732A (forum.php) |
| NZ (1) | NZ202952A (forum.php) |
| PT (1) | PT76103A (forum.php) |
| SG (1) | SG54286G (forum.php) |
| ZA (1) | ZA8336B (forum.php) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8500475A (nl) * | 1985-02-20 | 1986-09-16 | Akzo Nv | Thixotrope bekledingssamenstelling. |
| US4748211A (en) * | 1986-07-21 | 1988-05-31 | Ppg Industries, Inc. | Hydroxyl functional graft copolymers |
| US5591793A (en) * | 1994-04-15 | 1997-01-07 | The Sherwin-Williams Company | Thixotropic alkyd resins and the use thereof in coating compositions |
| DE19841405C2 (de) * | 1998-09-10 | 2000-12-21 | Basf Coatings Ag | Verfahren zur Herstellung eines thixotropen Bindemittels für Bautenanstrichmittel, thixotrope Bindemittel und Verwendung |
| DE202009004281U1 (de) | 2009-04-01 | 2009-08-06 | Albers, Sebastian | Außenfassade mit thixotropen Eigenschaften für Gebäude und Bauwerke u.dgl. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE479226A (forum.php) * | 1946-08-02 | |||
| DE2440267C2 (de) * | 1974-08-22 | 1984-10-11 | Bayer Ag, 5090 Leverkusen | Thixotrope Urethanalkydharze |
| AT367078B (de) * | 1980-02-27 | 1982-05-25 | Vianova Kunstharz Ag | Verfahren zur herstellung von zumischharzen zur thixotropierung von langoeligen alkydharzen |
-
1983
- 1983-01-04 ZA ZA8336A patent/ZA8336B/xx unknown
- 1983-01-04 IN IN6/DEL/83A patent/IN159303B/en unknown
- 1983-01-05 AU AU10031/83A patent/AU1003183A/en not_active Abandoned
- 1983-01-06 NZ NZ202952A patent/NZ202952A/en unknown
- 1983-01-07 CY CY133783A patent/CY1337A/xx unknown
- 1983-01-07 DE DE8383300079T patent/DE3361574D1/de not_active Expired
- 1983-01-07 GB GB08300395A patent/GB2113230B/en not_active Expired
- 1983-01-07 EP EP83300079A patent/EP0086034B1/en not_active Expired
- 1983-01-07 IE IE33/83A patent/IE53941B1/en unknown
- 1983-01-17 PT PT76103A patent/PT76103A/pt unknown
- 1983-01-18 ES ES519072A patent/ES519072A0/es active Granted
- 1983-01-19 CA CA000419780A patent/CA1193378A/en not_active Expired
- 1983-01-19 JP JP58005973A patent/JPS58127723A/ja active Pending
-
1986
- 1986-06-14 SG SG54286A patent/SG54286G/en unknown
- 1986-12-30 MY MY732/86A patent/MY8600732A/xx unknown
- 1986-12-30 MY MY629/86A patent/MY8600629A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58127723A (ja) | 1983-07-29 |
| AU1003183A (en) | 1983-07-28 |
| EP0086034B1 (en) | 1985-12-27 |
| DE3361574D1 (en) | 1986-02-06 |
| NZ202952A (en) | 1985-07-12 |
| SG54286G (en) | 1987-03-27 |
| MY8600629A (en) | 1986-12-31 |
| IN159303B (forum.php) | 1987-05-02 |
| CA1193378A (en) | 1985-09-10 |
| ES8502152A1 (es) | 1984-12-16 |
| CY1337A (en) | 1986-10-24 |
| GB2113230B (en) | 1985-04-17 |
| MY8600732A (en) | 1986-12-31 |
| GB2113230A (en) | 1983-08-03 |
| ZA8336B (en) | 1983-10-26 |
| PT76103A (en) | 1983-02-01 |
| GB8300395D0 (en) | 1983-02-09 |
| EP0086034A1 (en) | 1983-08-17 |
| IE830033L (en) | 1983-07-19 |
| ES519072A0 (es) | 1984-12-16 |
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