IE52256B1 - An acid-resistant flooring composition - Google Patents
An acid-resistant flooring compositionInfo
- Publication number
- IE52256B1 IE52256B1 IE2864/81A IE286481A IE52256B1 IE 52256 B1 IE52256 B1 IE 52256B1 IE 2864/81 A IE2864/81 A IE 2864/81A IE 286481 A IE286481 A IE 286481A IE 52256 B1 IE52256 B1 IE 52256B1
- Authority
- IE
- Ireland
- Prior art keywords
- composition
- chippings
- acid
- filler
- epoxy resin
- Prior art date
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Floor Finish (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The Specification describes an acid-resistant flooring composition intended principally for industrial use particularly in environments where spillage of acidic substances is a common hazard. The composition comprises an epoxy resin and a filler wherein the filler comprises chippings of an acid-resistant rock or mineral. The filler may also contain sand or silica flour and the chippings may be granite or quartz. The average particle diameter of the chippings is preferably in the 3 mm to 20 mm.
Description
This invention relates to an acid-resistant flooring composition. The composition is intended principally for industrial use, particularly in environments where spillage of acidic substances is a common hazard.
Acid-resistant flooring compositions based on epoxy resins are well known. They usually contain a filler or extender, which may be silica sand or silica flour or a mixture of the two. One reason for incorporating a filler is to reduce the cost of the composition per unit floor area covered, which cost would be prohibitive in the case of a flooring composition based on epoxy resins without a filler. Another reason is that the silica filler imparts desirable properties to a floor made from a composition containing it, such as hardness and durability.
Nevertheless known acid-resistant epoxy resin flooring compositions have certain disadvantages in use, which include their high cost, and a tendency to craze, split and fragment as a result of temperature variation.
Such compositions are normally laid on concrete bases, and have a coefficient of thermal expansion markedly different from that of concrete, which accounts for the above recited behaviour. The compositions are also somewhat deficient in toughness and resistance to wear.
B2256
- 3 Among the objects of the present invention is the elimination or alleviation of some or all of the above recited disadvantages.
In known compositions the sand filler, as stated, acts as an extender of the expensive epoxy resin. It is desirable to reduce the cost of epoxy resin flooring compositions as much as possible, by incorporating the maximum proportion of inexpensive filler consistent with adequate properties and performance of the resulting floor. It does not appear to have been realised in the past, just how far one can go in realising this ideal.
We have now found, surprisingly, that a ratio as great as 7:1 (filler to unset epoxy resin) can be used with satisfactory results, but only when the additional filler consists largely of sizeable chippings instead of sand.
The present invention accordingly provides an acid-resistant flooring composition comprising an epoxy resin, a filler including a major proportion of silica sand and chippings of an acid-resistant rock or mineral which include a major proportion of quartz.
The filler may include silica flour in addition to the silica sand chippings. The chippings may also include an amount of granite. It will be clear that minerals such as limestone, marble and chalk are unsuitable for lack of acid-resistance. Preferably the average particle diameter of the chippings is in the range 3 mm to 20 mm.
The proportion of filler in the composition can be expressed in terms of the ratio of the bulk volume of the filler to that of the epoxy resin mixture before it sets. The epoxy resin mixture includes an epoxy resin base and a hardener. Preferably this ratio is from 5:1 to 7:1, more preferably about 5.5 : 1.0.
The bulk volume of the sand to that of the chippings is desirably from 1.2 : 1.0 to 2.7 : l.O, more preferably about 1.75 : 1.0.
Known compositions containing sand are conventionally laid to a thickness of about 10 mm or 3/8. Compositions of the invention, however, are conveniently laid to a somewhat greater depth such as 20 to 30 mm. The precise depth required or desirable depends mainly on the mean particle size of the chippings used. The greater depths recommended in the performance of the invention result in floors which are no more expensive than those of the prior art having much smaller depths, and are often less expensive.
It will be seen that the invention exploits the unsuspectedly great covering power of the commercial grades of epoxy resins heretofore used for making flooring compositions, a covering power which had been by no means exhausted by the incorporation of the low proportions of sand or silica flour heretofore customary. Such grades include for example those marketed for the purpose by Ciba-Geigy of Switzerland under the Trade Mark ARALOITE and its variations.
The invention will be appreciated in greater detail from the following example of a particular and preferred embodiment thereof. Measurements are in parts by volume: in the case of sand and chippings bulk volume is intended, i.e. including the space between the particles
EXAMPLE
An epoxy resin composition was prepared by intimately mixing 5 parts Araldite base with 3 parts Araldite hardener. This mixture remains workable for several hours.
3
To 0.05 m of the above mixture was added 0.175 m of sharp washed silica sand and 0.1 m of sharp quartz chippings of mean particle diameter 12 mm, and the whole thoroughly mixed in a powered blender supplied by the suppliers of the resin.
- 5 A pre-existing concrete floor was cleaned of oil and grease, washed with water and allowed to dry, prior to the making up of the above composition.
The composition was deposited on the concrete from the blender, roughly distributed and then trowelled and floated to a mean thickness of 25 mm. Nine further similar batches were made and laid. The composition was practically self-levelling, and covered in all an area of 128 square meters, where it was allowed to harden.
In 36 hours the hardened composition provided a smooth, even, tough, acid-proof, strongly adhering floor, capable of withstanding a continuous traffic of heavy vehicles with narrow-rimmed steel wheels. Samples of the floor, when tested, proved to have a co-efficient of thermal expansion very near to that of the underlying concrete. Thus a major cause of cracking and crazing had been eliminated: conventional flooring compositions, when set, mostly have a coefficient of thermal expansion greater than that of concrete. A cost comparison showed that the material, with a thickness of 25 mm, was cheaper per unit area than a conventional composition laid to a conventional thickness of 10 mm.
Cupons of the laid composition were cut out for testing. Similarly sized cupons were removed from a typical composition floor of the prior art and used as controls.
Test and control cupons were immersed in various acidic liquors and examined periodically. The results are set out in the following Tables 1 and 2.
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TABLE 2
TEST: Cupons immersed in citric old liquor 10 days at 90°C.
Test Cupons Control Cupons % weight change + 0.5 + 14.6 Appearance Badly discoloured Badly discoloured Mechanical Soft on removing V. soft and surface Properties from liquor. cracked on removing, When cooled as when cooled brittle, original. easily broken.
Claims (11)
1. An acid-resistant flooring composition comprising an epoxy resin, a filler including a major proportion of silica sand and chippings of an acid-resistant rock or mineral which 5 include a major proportion of quartz.
2. A composition as claimed in claim 1, wherein the filler additionally includes silica flour.
3. A composition as claimed in claim 1 or 2 which includes granite chippings. 10
4. A composition as claimed in any of claims 1-3, wherein the average particle diameter of the chippings is in the range 3mm to 20mm.
5. A composition as claimed in any of claims 1-4, wherein the ratio of the bulk volume of the filler to that of epoxy 15 resin mixture before setting is from 5:1 to 7:1 said epoxy resin mixture comprising an epoxy resin base and a hardener.
6. A composition as claimed in claim 5, wherein the ratio is 5.5:1.0.
7. A composition as claimed in any preceding claim, wherein 20 the ratio of the bulk volume of the sand to that of the chippings is from 1.2:1.0 to 2.7:1.0.
8. A composition as claimed in claim 7 wherein the ratio is 1.75:1.0.
9. A composition as claimed in any of claims 1-8, substant25 ially as hereinbefore described and with reference to the Example. 5225 -διό.
10. A method of laying a composition as claimed in any of claims 1-9, substantially as hereinbefore described and with reference to the Example.
11. An acid-resistant floor which comprises a composition 5 as claimed in any of claims 1-9, substantially as hereinbefore described and with reference to the Example. Dated this the 3rd day of December, 1982.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IE2864/81A IE52256B1 (en) | 1981-12-04 | 1981-12-04 | An acid-resistant flooring composition |
GB08234498A GB2110693A (en) | 1981-12-04 | 1982-12-03 | An acid-resistant flooring composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IE2864/81A IE52256B1 (en) | 1981-12-04 | 1981-12-04 | An acid-resistant flooring composition |
Publications (2)
Publication Number | Publication Date |
---|---|
IE812864L IE812864L (en) | 1983-06-04 |
IE52256B1 true IE52256B1 (en) | 1987-08-19 |
Family
ID=11036823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
IE2864/81A IE52256B1 (en) | 1981-12-04 | 1981-12-04 | An acid-resistant flooring composition |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2110693A (en) |
IE (1) | IE52256B1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0906895A1 (en) * | 1997-06-12 | 1999-04-07 | Gebr. Knauf Westdeutsche Gipswerke | Flooring having a polyepoxide binder and a method of producing the same |
ES2310486B1 (en) * | 2007-06-26 | 2010-02-08 | Areniscas De Los Pinares Burgos-Soria, S.L. | POLYMER ARENISCA. |
CN104100071A (en) * | 2014-07-09 | 2014-10-15 | 北京亦龙鑫建筑装饰工程有限公司 | Floor paint application method |
CN109424156A (en) * | 2017-08-29 | 2019-03-05 | 王宁 | A kind of oil resistant anti-pollution floor structure level |
-
1981
- 1981-12-04 IE IE2864/81A patent/IE52256B1/en unknown
-
1982
- 1982-12-03 GB GB08234498A patent/GB2110693A/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
GB2110693A (en) | 1983-06-22 |
IE812864L (en) | 1983-06-04 |
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