IE50317B1 - Process for obtaining improved yields from plants by using a coating agent - Google Patents

Description

This invention relates to the treatment of plants and ocnpositicns for such treatment.

A large nurrber of leguninous plants, such as oilseed rape, peas and beans, are grown principally for their seed. These seeds are formed in pods which, cn ripening, split along their longitudinal axes. As a result, the seeds fall onto the ground. Where such crops are mechanically harvested, the problem of seed lost ty premature pod splitting can be a serious eccoanic problem. Oilseed rape, which is invariably harvested mechanically, has a stcngly narked tendency for its pods to split either just before or during harvesting.

Xn addition to leguninous crcps, the seeds or seedbearing heads or bodies of ornamental plants, cereals (especially barley), grasses grown for seed production and vegetables being raised for seed all suffer frcm premature loss of seed before harvesting.

Ihe present invention provides a method for the prevention or reduction Of loss of seeds ty splitting of seed-bearing bodies of plants, comprising applying to the plants, not more than fifteen days before the crop is reaty for harvesting, a coating or layering substance that acts as a semi-permeable membrane allowing water from the seed-bearing bodies to be lost but not substantially reabsorbed. Ihe fact that the treatment is carried out not more than fifteen days before the crcp is ready for harvesting distinguishes the treatment of this 0317 invention from that in prior Applications Number FCT/GB 80/00016, European 8032353-0 and UK 8022640, in which coating agents are usually applied at least fifteen days before harvest.

Substances that may be used for this purpose must not affect the subsequent germination of seeds that are destined to he planted. Of particular value are a group of pinolene products based on di-l-p-menthene under a variety of trade names including Miller Aide, Miller Gard, Nu-Film P, Nu-Film 17 and Vapor Gard. These products, which contain di-l-jj-menthene and certain of its polymers, further polymerize to form a film, and such further polymerization may take place or even he induced before application. Other monoterpenes of formula which correspond to two isoprene units, can also be used.

Pinolenes are naturally occurring substances and are both expensive and in short supply in relation to possible agricultural needs. It is therefore useful to extend them by using them in combination with other coating agents. Such compounds or mixtures of coating agents (which may he polymerized before application) can show properties unlike those of their individual components.

The mixtures contain from 2 to 10 coating agents, one or more of which is preferably a pinolene compound although mixtures without such compounds may be used.

Apart from the monoterpenes mentioned, the following compounds are suitable, though this is not an exhaustive lists25 1. Terpene hydrocarbons of the elementary composition θ15^24 (seE'Jni'*-erPenes) 2. Terpene hydrocarbons of the elementary composition C20H32 (Biterpenes) 3· Terpene hydrocarbons of the elementary composition (triterpenes) 4. Terpenes having 40 carbon atoms (tetraterpenes) . Bicyclic and tricyclic monoterpenes and their derivatives (e.g. oxygenated derivatives) such as a and β pinene, ^-camphor, dyborneol, d-tanacetone, β-thujone, _d—Δ—carene 317 6. Terpene resins (compounded with or without natural or synthetic rubbers) 7· Gum turpentine 8. Sulphate of turpentine 9. Wood turpentine . Fineoils 11. Terpineola 12. Alkyd Resins, Non-oxidizing - e.g. those of the castor oil, coconut oil, hydrogenated castor oil, lauric acid, oil-free, saturated acid and synthetic fatty acid types 13. Alkyd Resins, Oxidizing - e.g. acrylic-resin-modified, dehydrated castor oil types, epoxide-resin-modified, isophthalicacid-based types, linoleic-rich oil type, linseed oil types, linseed oil/dehydrated castor oil types, linseed oil/soya bean oil types, linseed oil/tung oil types, maleic-resin-nodified, marine oil types, phenolic-resin-modified, rosin-modified, safflower seed oil types, silicone-resin-oodified, soya bean oil types, soya bean oil/tung oil types, styrenated types, sunflowerseed oil types, tall oil types, tobaccoseed oil types, unmodified types, vinyltoluene-modified and water-soluble types 14. Benzoguanamine resins . Styrene polymers and copolymers, e.g. polystyrene and styrene/maleic anhydride and butadieue/styrene copolymer resins 16. Carbamide resins 17. Copal ester resins 18. Coumarone-indene resins 19. Cresylic resins . Epoxy resins - e.g. dehydrated castor oil types, linseed oil types, linseed oil/rosin types, phenolic-resin-modified, soya bean oil types, styrenated types, vinyltoluene-modified, unmodified types, Epikote 828 and Epikote 1001 21. Epoxide melamine condensates 22. Epoxide phenolic condensates 23. Ester gums S 311 24. Fumaric resins . Furan resins 26. Ketone resins 27. Maleic resins 28. Melamine resins - e.g. butylated types, hesamethozymethyl types and formaldehyde condensates 29. Metallic rosinates - e.g. calcium or zinc resinates, zinc/calcium mixtures both rosin or modified rosin . Phenolic resins and modified phenolic resins - e.g. phenol/aldehyde resole condensates adducted to rosin or modified rosin, as well as phenol/formaldehyde resins 31. Phenoxy resins 32. Polybutadiene resins 33· Polybutene resins 34. Polycarbonate resins · Polyisobutylene resins 36. Polyester resins - e.g. polyacrylate and polymethacrylate ester resins 37· Polysulphide resins 38. Polyurethane resins - e.g. modified types and oilmodified types 39. Polyvinyl acetal resins 40. Polyether resins - e.g. polyvinyl ether resins 41. Polyvinyl formal resins 42. Rosin derivatives - e.g. esters of rosin, copal, rosin acids or rosin modified by hydrogenation, polymerization, isomerization or disproportionation with glycerol, pentaerythritol or other polyhydric alcohols 43. Maleic/fumaric condensate resins - e.g. maleic or fumaric acid/anhydride adducts on rosin or modified rosins, their esters vzith glycerol, pentaerythritol or other polyhydric alcohols 44. Silicone resins and polymers 45. Urea resins - e.g. urea-formaldehyde 46. Xylene-formaldehyde resins I 311 VJ. Natural gums/resins - e.g. accoroides, arabic, benzoin, copals, damar, elemi, gamboge, karaya, mastic, rosin, sandarac, shellac and tragacanth 48. Acrylic polymers and copolymers - e.g. polyaerylic acid, polyacrylamide, polyacrylonitrile, poly(methyl methacrylate) and poly(ethyl acrylate/butyl acrylate) 49. Cellulose ethers - e.g. hydroxyethyl cellulose and sodium carboxymethyl cellulose 50. Cellulose esters - e.g. methyl cellulose 51. Hydrocarbon resins - e.g. petroleum resins 52. Polyamide resins 53· Rubbers - e.g. natural rubber, butyl rubber, nitrile rubber, polychloroprene, rubber/oil emuline and polyurethane rubber and cyclized rubber resine 54. Vinyl polymers and copolymers other than those already mentioned - e.g. poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl butyral), poly(vinyl pyrrolidone), poly(vinyl aeetate/vinyl chloride) and poly(vinyl acetate/acrylate) and 55· Natural drying oils - e.g. linseed oil and tung oil and mixtures of them.

Such substances may be used at rates of from one fluid ounce to ten pints per acre (70 to 14000 ml per hectare) applied in three to one hundred gallons of water per acre (33·7 to 1120 litres per hectare) of crop. It can he useful to include in the spray preparation a surfactant or wetting agent. Such surfactants include but are not limited tos1. alkyl phenolethylene oxide condensate 2. Triton X100 (ΐ.ϋ.) 3. Cittowet (trade mark of BASF) 4. alkylated aromatic sodium suphonate . amine salts or suphated fatty alcohols and 6. tall oil The coating or layering substance for checking seed loss hereinbefore described may conveniently he applied mixed with a 317 chemical desiccant, which is a substance that promotes the drying out of the plant to facilitate harvest and/or produces the harvested yield in better condition for storage. Such desiccants include hut are not limited to the hipyridilium herbicide diquat (sold under the trade mark Reglone hy ICI Ltd) and dinoseb. Diquat has been found especially useful to facilitate the harvesting of oilseed rape and is widely used for this purpose.

The use of the coating or layering substance hereinbefore described for preventing seed loss can result in an increase in the harvested seed yield of oilseed rape while the treatment of this crop with diquat can also result in an increase in the harvested seed yield. These two yield-improving factors act in different ways and, when used together, e.g. when applied either in tank mixtures or separately within seven days of one another, can give an increase in a harvested seed yield that is greeter than the sum of the effect of each additive singly.

In another aspect the use of the layering or coating substance hereinbefore described for controlling seed loss can enable a lower rate of desiccant to he applied to an oilseed rape crop or other suitable crop. Because pod splitting is checked the process of desiccation is less demanding, and amounts of desiccant can he reduced hy some 3θ$ over what would normally he recommended.

As is well know, certain weeds in- a ripening crop {Rat check ripening or interfere with harvesting must he controlled shortly before harvesting. An example of this is the control of sterile hrome grass in a cereal crop. Applying a herbicide in conjunction with a coating agent in accordance with the present invention can be used to oontrol such weeds, either Dy destroying the herbage or hy destroying or preventing production of weed seeds. Where the weed is green and alive at the time when the cereal or other crop plant has commenced the ripening process then the crop may be treated with a herbicide, for example glyphosate, that would kill or seriously damage a green (living) crop such as wheat or barley. By its use in conjunction with a coating agent in accordance with the present invention, the activity of the herbicide on the weed may he enhanced, while by checking or delaying the entry of the herbicide into the crop the specificity or crop safety of the herbicide is improved. With each additional day of ripening, the crop becomes less susceptible to damage hy a herbicide while, since less herbicide ia taken into the riper crop, there is a reduction with time in the tendency of the crop to accumulate undesirable residues of the pesticide that could result in the crop heing less suitable for human or for animal consumption and its value for seed or malting heing reduced since the presence of herbicide in the grain can reduce or slow down germination. The use of a coating agent in accordance with the present invention can make it possible to feed the grain to livestock without further processing and can enhance its value for seed or malting. Delaying the penetration of the herbicide while the crop is ripening before the weed is therefore a desirable objective.

A further value in the use of the coating agent during the ripening period is that, since the loss of seed may he checked, it becomes possible to leave the harvest in the field for a somewhat longer ripening period and thus reduce drying costs.

The tendency of the crop ripening process to be impeded hy the coating agent can usefully be overcome by the inclusion of a wetting (surfactant) agent such as ’Agral’ (T.MQ (alkylphenol ethylene oxide condensate). When the wetting agent is used in combination with the coating agent and glyphosate, its herbicidal activity can be enhanced by an amount over and above that which is obtainable by the use of either additive considered separately.

The coating agent used in accordance with the present invention can be used alone or in conjunction with a fungicide to prevent the development of fungal organisms on the pod or seedbearing body (such as the ear of a cereal plant) and/or the penetration of micro-organisms into the pod to cause loss of yield and/or quality as in the case of staining of peas. The control of ear disease in cereals, especially during the ripening process, at which 50311 time they are particularly susceptible to eladosporium (sooty mould) disease,may he controlled.

The coating agent may also serve as a physical harrier to the establishment of the fungal organism on the pod or seed-bearing body or seed including the sealing of a pod or seed-hearing structure against the penetration of micro-organisms.

Similarly an insecticide may be incorporated with the coating agent to control pre-harvest insect pests such as cereal aphids and midges. The coating agent, hy forming a water-repellent layer over the pod or other reproductive body, serves to speed its drying and hence to check micro-organism development, which requires moisture in which to flourish.

The coating agent may also he used to bind the fungicide and/or insecticide to the grain of cereal plants before harvesting to preserve them from post-harvest fungal and/or insect attack. This may encompass the use of such agricultural pesticides in a seed crop such that fungal and/or insect attack on the seed following planting is reduced.

Examples of fungicides and insecticides that may he used either by incorporation with the coating agent or hy use in tank mixture with the coating agent include, but are not limited to, the followings- henomyl ethirimol Bordeaux mixture fenitrothion captafol fentin hydroxide captan malathion carbendazim mancozeh carboxin man eh chlorothalonoil pirimiphos-methyl cyhexatin pyrethrum demephian streptomycin demeton-s-methyl sulphur diazinon thiabendazole dichlorvos triadimephon 803Π thiophanate-methyl tridemorph triforine zineh thiram dicofol dime thirimol dimethoate dithiocarbamate fungicide dodine The foregoing are the trivial names from the Pesticide Index. Herbicides or desiccants may additionally be included in combination with the fungicide and/or insecticide.

A further advantage of a water-repellent coating layer over a pod or seed-bearing body such as a cereal ear is the control or eprouting or premature seed germination. This can be a particular problem in both oilseed rape and cereals. In the case of barley, biochemical changes produced in response to germination (and hence water imbibition hy the seed during or after ripening) will lower the malting quality or even render the grain unsuitable for this purpose and hence of lower value.

HZ acting as a semi-permeable membrane the polymeric coating agents can also prevent re-absorption of moisture after harvest (although not impeding the ripening process).

The coating agent may be used to prevent the penetration of an agricultural chemical with which it is applied, for exanple diquat or paraquat desiccants, through the seed coat of plants such as oilseed rape and soya. Thus, wherever the edible part of the crop is contained within a non-edible structure it is preferable that an applied agricultural chemical he contained on this and not penetrate it and thereby increase the residues or levels of undesirable agricultural chemicals within the seed or other edible portion of the crop.

The coating agent may also he used in combination with a bird repellent. This can he of particular importance in sunflower. u 503Π The following experimental data show the effect of various coating agents in the control of pod shatter in oilseed rape. The agent was applied at the time when the pods were turning yellow and pliable, which is also the recommended time for applying the desiccant diquat.

Dried, hand harvested pods were subjected to a standard treatment of dropping and shaking in bags sufficient to induce 95% shatter in a control sample. Other samples were then similarly treated. In this test therefore a reduction in pod shatter from 95% to 90% represents a 100% increase in unbroken pods.

% Application Rate Pod Shatter (litres per hectare) Control 95 - A. Polyterpene Resin (Nitrez) 78 0.7 B. Hydrogenated methyl ester of rosin (100%) (Hercolyn D) ίτ.Μ?)56 0.7 C. Acrylic polymer emulsion (50%) (VINACRYL 4001) (R.T.M.) 80 1.4 D. Styrene Acrylic co-polymer emulsion (Vinacryl 7191) (T.M.) 75 1.4 E. Low molecular weight urea formaldehyde-resin (Casco 731) 92 1.4 F. Ester resin in oxital (90%) 90 0-7 G. Di-l-p-menthene 40 0.7 H. Di-l-p-menthene 35 0.7 Except in the case of (h), where application was made in tank mixture with the desiccant glyphosate (Roundup), , all applications were made in tank mixture with the desiccant diquat (Reglone) at 2| pints per acre (3.5 litres per hectare) using a spray volume of 50 gallons per acre (560 litres per hectare). Control plants were treated with diquat hut received no coating agent.

Whole pods taken from the samples described in the foregoing table before induction of shattering were placed in a polythene hag with sufficient water to induce moistening and growth of fungal moulds. After ten days they were scored from 0 (no growth) to 10 (the level of mould development on the control pods) and the results were as follows:Infestation Score Control 10 A, Polyterpene Resin (Nitres) 7 B. Hydrogenated methyl ester of rosin (100¾} (Hercolyn D) 7 G. Di-l-p-menthene (applied with diquat) 5 The foregoing data demonstrate that application of a coating agent can control pod shatter to a marked extent, with concurrent reduction in growth of fungal moulds.

Further experiments were carried out on peas and beans to demonstrate that levels of the pesticide dimethoate (which was used because it can readily be assayed accurately and specifically) were diminished hy application of a coating agent in accordance with the present invention.

All samples were treated with the standard commercial amounts of Reglone (diquat) + Agral wetting agent viz 3 pints of Reglone plus 6.4 fl oz of Agral per acre (4.2 litres of Reglone plus 450 ml of Agral per hectare) the spray volume being 40 gallons per acre (450 litres per hectare). The amount of di-l-p-menthene was 0.7 litres/ hectare (0.5 pints/acre) and of dimethoate 40¾ (w/v) was 840 ml per hectare (standard commercial rate).' Interval between spraying & harvest (days) ppm Dimethoate in seed Peas (Little Marvel) 5 (a) Control * 6 0.009 Dimethoate + Di-l-p- menthene 6 0.057 Dimethoate 6 0.049 Broad Beans (Express) (a) Control * Dimethoate + Di-l-pmenthene Dimethoate 6 6 6 0.004 0.031 0.10 (b) Control * 10 0.006 15 Dimethoate + Di-l-pmenthene 10 0.11 Dimethoate 10 0.15 All results are corrected for the average recovery * No dimethoate applied

Claims (7)

1. A matbod for the prevention or reduction of loss of seeds by splitting of seed-bearing bodies of plants, ccnprising applying to the plants, not more than fifteen days before the crop is ready 5 for harvesting, a coating or layering substance that acts as a semi-permeable meniorane allowing water from the seed-bearing bodies to be lost but not substantially reabsorbed.

2. A method according to Claim 1, in which the plants are oil-seed rape and the coating stbstance contains di-l-p-menthene 10 and/or its polymers.

3. A method according to Claim 2, in which the di-l-pmethene is applied together with diguat, which acts as a desiccant.

4. A method according to Claim 1, in which a desiccant is applied together with the coating substance. 15

5. A method according to any one of Claims 1 to 4, in which a herbicide is applied together with the coating substance to a ripening crop carrying seed.

6. A method according to any cne of Claims 1 to 5, in which a surface-active agent is applied together with the coating 20 substance.

7. A matbod according to Claim 1, in tdiich a herbicide is applied together with the coating substance to a ripening crop carrying seed whereby the level of harmful residues to animals in the seeds is reduced.