IE43758B1 - Heat-recoverable articles and methods for their application - Google Patents

Heat-recoverable articles and methods for their application

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Publication number
IE43758B1
IE43758B1 IE793/79A IE79379A IE43758B1 IE 43758 B1 IE43758 B1 IE 43758B1 IE 793/79 A IE793/79 A IE 793/79A IE 79379 A IE79379 A IE 79379A IE 43758 B1 IE43758 B1 IE 43758B1
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IE
Ireland
Prior art keywords
article
heat
cables
layer
recoverable
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Application number
IE793/79A
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IE43758L (en
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Raychem Corp
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Publication date
Priority claimed from US05/601,344 external-priority patent/US4085286A/en
Application filed by Raychem Corp filed Critical Raychem Corp
Priority claimed from IE2087/75A external-priority patent/IE43757B1/en
Publication of IE43758L publication Critical patent/IE43758L/en
Publication of IE43758B1 publication Critical patent/IE43758B1/en

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Description

This invention relates to heat recoverable articles, especially to heat shrinkable articles that may be positioned around a cable, pipe, or connector at a joint or splice and then caused to heat recover in place to encapsulate the joint or splice, and methods for applying them.
There are many applications where it is desirable to provide a sealing, insulating or protective encapsulating or enclosing member for elongate objects, for example cables or pipes. Such encapsulation is particularly important where pipes or cables are joined or spliced, particularly when a joint involving a plurality of pipes or cables is involved. In many instances, the ends of elongate objects (hereinafter the term cables will be used, although the invention is, of course, useful for enclosing or encapsulating pipes, cables, ducts, conduits and the like elongate substrates, especially at junctions between them) are not conveniently accessible to allow a tubular sealing member to be placed thereover. To overcome this shortcoming, closure members suitable for wrapping around the elongate objects have been developed. See for example, U.S. Patent Specifications Nos. 3,379,218, 3,455,336, and 3,770,556. These so-called wrap-around closures can be installed around an elongate substrate without access to a free end thereof. There is nevertheless a significant need for a closure, hereinafter referred to 37 58 - 3 as a splice case, suitable for enclosing electrical cable joints or splices which provides effective environmental protection, in particular, for a splice involving more than two incoming cable ends and/or splices between different sizes of cables but which may be applied without access to a free end of the cable.
The present invention is directed to a heatrecoverable splice case which can, in various embodiments, accommodate a plurality of cables of differing sizes, i.e. outside diameter, which can be removed and in some embodiments reapplied to a splice and which does not require access to a free end of the cable. The present design is not referred to as a wrap-around since it encapsulates a splice in a somewhat different fashion from the aforementioned wrap-around closures. In alternative embodiments the splice case of the present invention utilizes either a clam shell or separate base plate or member and cover member design.
The present- application is divided from Patent Specification No. 43757., In that application, there is described and claimed an article, at least a portion of which is heat-recoverable, the article being capable of being positioned around a conduit junction to be covered and sealed thereby on recovery thereof, the article having heating means connectable to and energizable by an electric power supply, the means including a material formed of an electrically conductive polymeric composition which exhibits a positive temperature coefficient of resistance and which is capable, when connected to an appropriate electrical supply, of heating the article or at least the recoverable portion thereof, to a temperature sufficient to cause recovery thereof.
In a modification, means other than the positive temperature coefficient (PTC) of the electrical resistance of the composition are used to control the maximum -'4 temperature to which the article is heated by passing electrical.current through the composition. The alternative means may, for example, be a thermostat.
The reader is directed to the parent application for a full discussion of the advantages of self-heating recoverable articles, especially those having PTC compositions forming their heating elements.
The present application is concerned with closure articles. The article provided by the present invention may be, but need not be, self-heating.
In one embodiment the present invention contemplates a splice case which will recover and encapsulate a cable or other splice when subjected to an external heat source, for example a propane torch or hot air blower.
In a further embodiment the splice case of the present invention has a built-in heating means, i.e. the splice case contains an integral electrical resistance heating element which, when connected to an appropriate external electric power supply, is capable of generating sufficient heat to cause the splice case to recover and encapsulate the splice. This heat recoverable splice case does not require an outside heating source, but instead may be caused to recover simply by connecting it to an electric power source, whether battery or mains, e.g. a 12 or 24 volt battery, or a 115 volt or other appropriate A.C. supply, and which, when connected to such a power source^ will recover and may also activate an adhesive or sealant on its inner surface. in formulating the materials which provide the fi integral heating element for use in the splice case of this invention, arrangements and compositions which provide uniform heating are important. In addition, for applications where the heating element must cause heat activation of an adhesive or sealant, as well as heat - 5 recovery of the splice case relatively high temperatures of the order of 120°C to 200°C. must be obtained, but carefully controlled. If temperatures above that necessary for heat recovery of the splice case and adhesive activation are reached, then permanent damage to the splice case, and/or to the part to be sealed, e.g. the cable, may result, such damage frequently not being apparent by visual inspection of the recovered splice case and immediately adjoining areas of the cable.
Thermostats and/or other heat control devices may be employed to control the temperature of the recovering and recovered article. But for many applications, this defeats the object of using a self-contained, i.e. selfheating, closure, in that expensive, sensitive and/or bulky external temperature control devices must be employed in what are sometimes virtually inaccessible places. Moreover, the temperature sensed by the control device is only that of its immediate environment, while other areas of the case may be at considerably lower or higher temperatures.
In recent years a new approach for electrical heating elements has been the use of self-regulating heating systems which utilize plastics materials exhibiting positive temperature coefficient of electrical resistance characteristics (hereinafter referred to as PTC characteristics or materials). Such materials generally comprise crystalline thermoplastics with a conductive particulate filler.
The shortcomings of the prior art PTC materials for articles such as the splice case of the present invention can be to a large extent overcome by the use of the compositions disclosed in British Patent Specification No. 1,528,622 by utilizing constructions of the type disclosed in Patent Specification No. 41728. However, it should be noted that, although prior art PTC materials are not preferred, they are suitable for use in the splice case - 6 of the present invention under many circumstances.
During use and operation of telephone cables, especially when the individual conductors are wrapped with a paper-based dielectric, it is required that moisture be excluded since, if the moisture content of the wire insulation increases beyond a certain relatively low critical level, the electrical characteristics of the wire are unacceptably impaired. For this reason it is customary when cables are spliced to place in the assembly just prior to closure, a small paper bag of desiccant (usually silica gel) in an amount sufficient to maintain the interior humidity of the splice at a very low level over the lifetime of the splice, whatever the outside humidity. In a typical instance, about 50 gram of silica gel might be used. As might be expected, the desiccant is frequently forgotton or, even if not, the bags (which are customarily sealed for storage) are sometimes left in an unsealed condition for extended periods of time before emplacement or, in the extreme, even dropped into water or wet mud and emplaced nonetheless. A preferred embodiment of this invention offers an alleviation of this problem.
Excess humidity leads to ari unacceptable drop in the level of paper-insulated cable performance. At 30% relative humidity (R.H.) and at 15°C the insulation resistance of paper insulated strands of the type often used in telephone cables decreases to an unacceptable level of about 0.5 giga ohm per kilometer. Below 30% R.H., performance is acceptable. We have found that the humidity inside the splice case need not be maintained at as low a value as possible but should simply be maintained below 30% whenever possible. Unexpected and surprising benefits are derived from encapsulating the desiccant in a container whose water vapour transmission characteristics have been carefully matched to those of the splice case itself so *3758 - Ί that the relative humidity inside the said splice case may in all normally encountered circumstances be maintained at less than 30% whatever the relative humidity outside, as the following exposition demonstrates.
For 100% R.H. outside and 0% R.H. inside, if a typical splice case of the instant invention has a moisture vapour transmission (MVT) of 100 yg/hr at 15°C, the container for the desiccant must have a MVT >100 yg/hr at 30% R.H. or >333 yg/hr at 100% R.H. Thus, if the desiccant container has a MVT of 500 yg/hr the requirement is satisfied.
Assume the container holds about 100 g. of desiccant such as silica gel which is capable of absorbing about 50 g. water. Under shelf storage conditions at 100% R.H. with no other protective covering the desiccant thus contained will lose half its absorptive capacity in about six years. Thus, a container of this type permanently affixed inside the splice case will suffer no appreciable diminution in effectiveness even if the splice case is removed from its protective wrapping during storage and periods of many months, e'lapse before it is used.
An especially useful feature of certain of the selfheating splice cases of the present invention is their potential re-enterability. The case may be re-entered by merely electrically connecting the installed splice case to an electrical power source, waiting a few minutes to soften the adhesive, removing the electrical contacts and the side and end clip members (if they have been left on) and separating the upper and lower splice case halves.
If desired, after necessary changes to the individual splices or replacement of any component, the whole splice case may be reassembled as before and a short period of reconnection to an electrical power source will result in a reforming of the adhesive bonds to yield an assembly of unimpaired structural integrity. This case of re4 3 7 5 3 - 8 enterability means that if not all the cable folds are required at the initial installation a plug or plugs may be used, sized to maintain the redundant folds in an expanded condition during initial installation. On subsequent re-entry, additional cables can be added at any time and; any newly added components sealed as effectively as any of the original components. Re-entry of the non-self-heating splice cases can also be effected by use of an external heat source to melt the adhesive.
The present invention is concerned with a heat recoverable closure article, e.g. a splice case, optionally having self contained heating means, said heating means optionally incorporating a positive temperature coefficient of resistance (PTC) material so as to regulate the heat output without resort to extraneous temperature control devices. The article is so configured that it can be positioned around a splice and then caused to heat recover and seal the splice. The terminology self-contained heating means’ or self-heating signifies that the splice case having such feature incorporates an electric resistance heating element which by connexion to an appropriate electric power source, e.g. a battery or alternating current, will generate sufficient heat to shrink the shrinkable portion of the splice case and activate (e.g. melt) any adhesive present in the splice ease. Also the invention is concerned with a splice case not having the self-heating feature (i.e. it does not incorporate an electric resistance heating element) and shrinking and adhesive activation are achieved by use of an external heat source) and also the invention is concerned with a method using such an article.
In one aspect, the present invention provides a closure article comprising first and second portions or members capable of being brought together to form a generally tubular structure having a central cavity 4 S7 Hi« - 9 portion, the first portion or member being heat-recoverable, and means for maintaining said portions or members together during heat recovery of said first portion or member, the structure so formed being capable at at least one end thereof of heat recovering around and sealing a junction between a plurality of cables inserted therein with at least one pair of the cables extending from the said end of the article, and of sealing opposed parts of the portions or members at the said end at least between the said pair of cables.
A method of encapsulating a junction between a plurality of elongate cables which comprises positioning an article, at least a part of which is heat-recoverable, about the junction with at least one pair of cables extending from one end of the article, applying over two opposed portions of the said end of the article between at least the pair of cables means for maintaining the opposed portions together during recovery, and heating the article to cause it to recover about and seal the junction, and to encapsulate the junction.
The means for maintaining opposed portions together during recovery may be, for example, a clamp, or a clip, which may be resilient.
The present invention accordingly provides a heatrecoverable closure article capable of being positioned around a conduit junction, for example, a cable junction, to be covered and sealed thereby on recovery thereof, and a method for the application of such an article. Optionally, the article has heating means connectable to and energizable by an electric power supply, the means advantageously including a material formed of an electrically conductive polymeric composition which is capable, when connected to an appropriate electrical supply, of heating the article to a temperature sufficient to cause recovery thereof. 3 7 5 8 - 10 The material of the conductive polymeric composition advantageously exhibits a positive temperature coefficient of resistance and advantageously the material is so shaped that its length and width are large compared with its thickness, and is preferably in the form of a layer or sheet, and electrodes are positioned so that current will flow through the thickness of the material, i.e. in the case of the layer or sheet, from one face thereof to the other.
Advantageously, the heat recoverable menfoers or portions of the article comprise · a polymeric material dimensionally changed from a heat stable configuration or form to a dimensionally heat unstable one, capable of recovering to or toward the stable form on the application of heat.
Preferably at least a part of the material that forms the heating means also forms the recoverable heat unstable portion of the article.
It will of course be appreciated that the particular heating means and the properties of the composition and electrodes will be chosen, in a particular case, bearing in mind the nature of the electric power supply available to the user.
The composition is advantageously a crystalline polymeric material, and advantageously has dispersed therein carbon particles, especially carbon black. The polymeric composition is advantageously crosslinked, by chemical means or by irradiation, and the polymer, the conductive particles and the proportion thereof will be chosen with the end use, and the power supply available, in mind.
The portions of the surface of the article which will face the substrate to be covered, and those portions which will contact each other when the article is positioned over the substrate, advantageously have a coating of heat-activatable sealant or adhesive thereon, 437S8 - 11 which preferably is activated at about the recovery temperature of the article. The portions which engage each other are preferably provided with means to hold them in engagement during recovery. The central portion of the article may be provided with a heat stable insert, which will define a cavity for surrounding the splice, while the end portions are shaped to recover individually around each of the cables which join at the splice.
Advantageously, the heating means is selfregulating and comprises a first layer of conductive polymeric material having a positive temperature coefficient of resistance, and in surface-to-surface contact with at least one face of the layer, a second layer of conductive polymeric material having a substantially constant resistance at least up to the recovery temperature of the article to give a substantially constant wattage and at least a pair of electrodes so positioned that current passing between them will pass through at least a portion of the constant wattage material and from one face to the other of the first layer.
Preferably, there is a constant wattage layer in face-to-face contact with each face of the first layer and the electrode is in contact with each constant wattage layer.
The article preferably contains an insulating layer, which may also be heat recoverable.
As indicated above, the article constructed in accordance with the invention can be recovered by an external heating means, and in those cases, of course, the conductive layers and the electrodes may be omitted.
The invention also provides a method of covering a junction, by recovering an article constructed in accordance with the invention, and a junction covered thereby, especially a cable splice. - 12 The optional self-contained heating means advantageously comprises a polymer having dispersed therein an electrically conductive filler to render it capable of conducting current at a given voltage (e.g. 12 or 24 volts from a battery) while having sufficient resistance at its operating temperature so that its heat output is capable of causing a relatively thick section of heat recoverable materials, of the order of some millimetres thickness, to heat to its recovery temperature and recover about the splice to be encapsulated. In addition, the heating means is advantageously capable of giving sufficient heat output to activate a high temperature thermoplastic or thermosetting adhesive or sealant.
When a PTC material is in the form of a structure having two comparatively large dimensions and one comparatively small dimension, e.g. a layer such as a sheet, passage of current along the small dimension is preferred for more uniform heating. When the current flow is along the plane of the PTC layer localized heating along certain conductive paths may result causing non-uniform heat output This in turn can cause an even greater problem, rendering the entire heating means useless for a majority of its heating cycle. If localized heating causes the material to reach Tg along a line transverse to the current path, it will prevent the flow of current along the path, in effect causing the heating means to shut down until the temperature of the thus formed hot-line drops below Tg, In other words, the hot-line across the layer between end electrodes effectively shuts down the heating means even though only a small surface area of the layer has achieved Tg. This renders the heating means so inefficient that it appears to exhibit a very low heating capacity. The hot-lining problem can be minimized by positioning the PTC material between the electrodes in a way that minimizes the lengths of the conductive paths «3758 across which hot-lining can occur. For maximum efficiency with minimum current path, the length to thickness ratio of the layer should be minimized. This is achieved, for example, with a sheet in which the electrodes sandwich the PTC material. However, because of the short current path, and limited surface contact available in some aplioations, inadequate heating for such a configuration may occur at lower power inputs. To remedy this, a material giving wattage or Joule heat output, at a given voltage, i.e. a material not having PTC characteristics, is advantageously laminated with the PTC layer so that the laminate exhibits good heating effectiveness yet is self-regulating, without hot-lining. For a more thorough discussion of the advantages of applying a current through the layer, as opposed to along its length, and fabricating a layered composite, see the above-mentioned Patent Specification No. 43757,' For a more detailed discussion of suitable PTC compositions which are preferably employed as layers for use in the present invention, especially for relatively high temperature applications, see the above-mentioned British Patent Specification No. 1,528,622.
Such compositions comprise blends of thermoplastic and elastomeric materials having conductive materials dispersed therein. As pointed out in the specification, such blends exhibit a steep rise in resistance at about the melting point of the thermoplastic component, the resistance continuing to rise with temperature thereafter. Because of the increased safety margin given by the further increases of resistance above the melting point such heating means can be designed to control switch off at temperatures above the theoretical Tg and have resistances at such temperatures well in excess of that at Tg but yet avoid the risk of thermal runaway and/or burn which occurs when prior art PTC compositions are 437S8 - 14 used in such designs. Such heating means, especially when the increase in resistance with temperature above Tg is very steep, are very demand insensitive that is, the operating temperature of the PTC material varies very little with thermal load. They can also be designed to generate very high powers up to Tg when electrically connected to a power source. Because of their excellent temperature control, they can be employed to activate adhesives and cause heat recoverable articles such as those of the present invention to recover around substrates such ) as thermoplastic telephone cable jackets with reduced risk of melting or deforming the substrate even if left connected for considerable periods of time.
It should be noted that a variety of closure means, including an adhesive as discussed above, for the splice i case can be employed. The closure means should be such as to withstand the heat recovery forces at the temperature of recovery, for example of which see U.S. Patent Specifications Nos. 3,379,218 and 3,455,336.
The articles for and methods of splice encapsulati ion provided for in the instant invention may differ substantially from and thereby overcome to some extent or otherwise avoid some of the deficiencies which characterize prior art devices and methods. For example, in one of the preferred embodiments of the invention, the heat recoverable article when positioned around the substrate, e.g. the cable, enfolds the substrate in such a manner that the opposing heat recoverable surfaces do not come in contact with one another but butt up against opposing surfaces of, for example, long fingers forming ridges on the mating surfaces of the non-heat recoverable base member. The forming of a splice case from a combination of a heat shrinkable and heat stable member as in certain preferred embodiments so that the areas of the members which abut to define the cavity containing the cable splice are not themselves heat shrinkable is another 4375g - 15 significant departure from the prior art as will be apparent from the following more detailed discussion.
It has been long realized that when a heatrecoverable article is folded or wrapped around a substrate and shrunk down the region in which the heat recoverable article is brought together and secured with a closure means constitutes an area of weakness both mechanically and in its resistance to the environment, for example, to penetration of water. In the abovementioned U.S. Patent Specification No. 3,455,336 are described ways to solve this problem by the use of a design with an overlapping flap under the abutting edges of the heat recoverable article and secured to the layer overlying it by an adhesive to provide a long leakage path. However, this solution fails if the substrate does not provide a firm foundation against which the heat recoverable article can press the flap so as to cause the adhesive to flow and wet the faying surfaces. When to this factor is added the difficulty of constructing a multiple entry splice case having overlapping heat recoverable regions it can be seen that an article constructed in accordance with U.S. Patent Specification No. 3,455,336, while extremely useful in most instances, does not solve all the problems which the instant invention solves.
These problems are solved in a surprisingly simple and highly effective manner by the preferred approach of the present invention. The optional provision of an intervening ridge or finger on the non-heat recoverable base member in combination with clips and flanges on the heat recoverable member, which flanges can be used precisely because the heat recoverable member in these regions contains non-heat recoverable segments, facilitates obtaining this highly desirable result.
A number of articles constructed in accordance 43728 - 16 with the invention, and methods carried out in accordance therewith, will now be described in greater detail by way of example only, with reference to the accompanying drawings, in which: FIGURE 1 is a perspective view of a first embodiment of a heat recoverable 0 article, i.e. a splice case, constructed in accordance with the invention, in which has been positioned and joined a plurality of cables of various dimensions FIGURE 2 is an end view of the article of Figure 1 prior to expansion to its heat unstable i.e. heat recoverable form; 5 FIGURE 3 is an end view of the article after expansion to its heat unstable form; FIGURE 4 is an end view of the article after it has been caused to heat recover about cables; 0 FIGURE 5 is taken along line 5-5 of Figure 3 showing in more detail, and to a larger scale, the layered construction of the article; FIGURE 6 is a perspective view of the article 5 prior to cable insertion; FIGURE 7 is a perspective view of an alternative configuration embodiment of an article constructed in accordance with the invention.
It should be noted that, with the exception of Figure 5, and the schematic electric circuit in Figure 6, Figures 1 to 7 are illustrative of a splice case whether or not it incorporates self-heating means. Figure 5 shows a layered construction which exemplifies an embodiment - 17 wherein the splice case incorporates self-heating means. Figures 8 to 11 show the structure of a third embodiment of a splice case constructed in accordance with the invention.
FIGURE 8 is a cross section through one end of the splice case; FIGURE 9 is a perspective view of one end of the case of Fig. 8 cut away to show the details of the structure; FIGURE 10 is a perspective view of the splice FIGURE 11 case of Fig. 8 from below the non-heat recoverable base member; is a longitudinal section through the splice case of Fig. 8 showing details of the internal cavity; FIGURES 12 to 19 show details of the preferred method of construction of a fourth form of splice case constructed in accordance with the invention. FIGURE 12 illustrates the formation of the preferred braid electrodes; FIGURE 13 shows the positioning of electrodes over, and attachment to, the bus bars; FIGURE 14 shows various layers (shown cut away to facilitate understanding) of the · blank for the heat recoverable member positioned in a jig prior to lamination; FIGURE 15 shows the blank being formed into the basic shape for the heat recoverable member; FIGURE 16 shows the heat recoverable member in its - 18 heat stable configuration after being cross-linked; FIGURE 17 shows the construction of the reinforcing flanges for the ends and sides of the heat recoverable member; FIGURE 18 shows the flanges being applied to the heat recoverable member positioned in a jig prior to expansion; FIGURE 19 shows the heat recoverable member at the 0 end of the expansion step; FIGURE 20 shows the upper and lower members of the splice case in perspective to show additional details of the interior; FIGURE 21 shows the especially preferred embodiment 5 after installation around a cable splice.
Referring now to the drawings, Figure 1 shows a heat recoverable closure article or splice case constructed in accordance with this invention, adapted for receiving a plurality of cables and having an enlarged central section for accommodating a splice between the cables. Such a configuration is particularly suited for low voltage telephone gables wherein a plurality of cables are to be joined quickly and efficiently at minimum exist.
The splice case shown in Figure 1 may be entirely made of a heat recoverable material, preferably having layered therein a self-heating composition, as shown in Figure 5, which will be discussed in more detail hereafter. Alternatively, only that portion of each end of the splice case comprising the folds, i.e. that portion of the splice case between the ends thereof and dashed lines 18, can be made heat recoverable with the center portion being non-heat recoverable. The layer or layers of heat recoverable material are crosslinked as, for example, by irradiation so as to render them heat recoverable. A heat recoverable part 10 comprising a layer is positioned in its stable, unexpanded state with folds 11 as shown in Figure 2. The unexpanded folds can, of course, take on any configuration, including the general configuration of the cables, provided that a sufficient excess of material for expansion is allowed. The folds are expanded by known techniques to dimensions greater than the diameters of the cables to be sealed, as shown in Figure 3. The material is sufficiently resilient and flexible that the cables may be snapped into the openings of the folds. As best seen in Figures 3 and 4, the openings may be of varying dimensions depending upon the sizes of the cables which are to be inserted, although it should be kept in mind that one size of opening is recoverable over, to seal, a wide range of cable sizes.
The heat recoverable part 10 is mated with a bottom part 12 of the splice case which is not heat recoverable although as shown, for example, in Figure 7, it may be heat recoverable in some embodiments. The bottom part 12 may serve as a permanent mounting for the cable splice, giving rigidity to the system. Alternatively, the parts 10 and 12 may have a co-operating hinge at one edge 14 (Figure 4) with a closure means at the opposite edge 16. Alternatively, where parts 10 and 12 are formed from the same material, they may be integral at the edge 14 (and the reference to first and second portions or members is to be construed as including such a case), utilizing a closure at the edge 16, or the parts 10 and 12 may be separate parts separated at both edges 14 and 16 in which case the heat shrinkable part 10 is merely lifted from the part 12 for insertion of the cables. If desired, the parts 10 and 12 may have reinforcing strips embedded therein along the long axes thereof, preferably adjacent the edges 14 and 16. Such strips can also serve as bus bars. 7 5 8 - 20 In sealing cable splices in accordance with the method of the invention, the parts 10 and 12 are separated and cables 20, 22 and 24 are placed therein. Referring more specifically to Figures 2, 3 and 6, where the parts 10 and 12 are neither integral nor hinged, a clamping device, for example, hinged clamps 52 and 54 are utilized such clamps being tightened by means of bolts 56 and wingnuts 58. The clamps may serve to maintain the parts 10 and 12 together during expansion (Figure 2) as well as during insertion of the cables and recovery thereover (Figure 4). Although such clamps could form a permanent part of the installation, they are preferably removed after installation and an adhesive such as, for example, that described in U.S. Patent Specification No. 3,770,556 is used to seal the edges permanently.
Also, at the ends, proper spacing between cables is most suitably assured by a clamping device. As best seen in Figure 6 this may be a plate separator 62 having openings therein to accommodate the folds 11 (Figure 2). such plate tightly sealing the parts 10 and 12 by clamps 64 and 66 during the expansion and sealing operations.
To add strength and further to protect the system, and where necessary to provide moisture vapour transmission protection or radio frequency shielding, the cable splice itself can optionally be encapsulated within a rigid can within the case, having an outline defined by dashed lines 18 and 18a located beneath the central portion of the heat recoverable portion generally designated 26 in Figure 1, Where the central portion 26 is heat recoverable, it will conform to the shape of the can which may suitably be frabricated of any rigid material, including metal or moulding plastics. The end openings 19, 21 and 23 are adapted to receive individual cables of varying dimensions. The other end of the heat recoverable portion will generally contain openings of similar dimensions to 3 7 3 8 - 21 accommodate the other cables to be joined, although all of the openings may be confined to one end.
Where a rigid can is employed for covering the splice, sealing at the central portion by the heat recoverable member may not be necessary. Therefore, as heretofore indicated, the heat recoverable portion of the article of this invention can be limited to the end portions so that it will seal the individual incoming cables up to the can. In this case, the central portion 26 can be of non-recoverable material or, if recoverable, need not be caused to recover. Alternatively, the material need not extend across the can so that the can is allowed to remain exposed, or only an insulation layer, for example the layers 30 or 31 of Figure 5, need extend across the can with remaining layers being confined to the ends.
Referring now more specifically to Figure 5, the heat recoverable portion preferably comprises a selfheating laminate having electrodes embedded therein, the electrodes being connectable to an appropriate power source. A suitable laminate is more fully described in Patent Specification No. 41728. Briefly, the laminate consists of an outer insulating layer 30, which is heat recoverable. A layer 34 comprises a polymer or polymer blend, for example a blend of a highly crystalline polyolefin and ethylene-propylene rubber, having dispersed therein conductive carbon black. The layer 34 preferably exhibits positive temperature coefficient of resistance properties to control the heating. The layer 34 is preferably interleaved between layers 32 and 36 which may also be polymer blends having carbon black dispersed therein, these layers preferably yielding constant wattage outputs at a given voltage over a wide temperature range and not exhibiting significant positive temperature coefficient of resistance properties. 3 7 5 8 - 22 An inner insulating layer 31 may also be provided. The layers 31, 32, 34 and 36 are preferably also heat recoverable. The inner layer can advantageously contain an adhesive coating (not shown) on its free surface for bonding and sealing to the cables.
Embedded in the’constant wattage layers 32 and 36 are electrode grids 38 and 40, which are capable of being connected to a suitable power source for example a battery as schematically shown in Figure 6. This configuration causes the current to pass through the PTC layer 34 from electrodes 38 to electrodes 40. A preferred type of electrode design and configuration is more fully described below.
Referring now more especially to Figure 7, an alternative configuration of the present invention is shown. Such a configuration may be formed and expanded out of a single sheet of material, generally having the layered configuration of Figure 5. After inserting the cables as previously described through openings 44, 46 and 48 the article is closed by bringing together the opposite edges 50 of the sheet by a suitable closure means 51. Such article may, of course, be made to conform to various cable diameters and shapes as shown. It can be a clam shell design having a closure means at 50 and self-hinging at 47.
An especially preferred embodiment of the invention is illustrated in cross-section in Figure 8.
It comprises upper and lower members 96 and 80. The upper member 96 comprises an outer splice case shell 67 affixed firmly to a heater which consists of outer and inner layers of constant wattage material 68 and 70 and a core layer of PTG material 69. To the inside surface of the inner constant wattage layer 70 is affixed an adhesive layer 71. The heater PTC core layer 69, preferably constructed as described in British Patent 3 7 5 8 - 23 Specification No. 1,528,622 is combined with constant wattage outer layers 68 and 70 of compositions whose thermoplastic polymer ingredients, if any, have lower melting points than that of the thermoplastic polymer component of the PTC composition. The constant wattage layers, if comprising thermoplastic polymers, may be made heat recoverable and preferably an additional outer shell comprising a layer of a heat recoverable polymer composition having a recovery temperature less than the melting point of the thermoplastic component of the PTC composition is also provided. An additional layer 71 of a hot melt adhesive or mastic may also be provided, the hot melt additive, if used, having a melting point similar to that of the heat recoverable member and an activation temperature less than the melting point of the thermoplastic component of the PTC composition. Such an embodiment has been found to be particularly advantageous where the substrate is heat sensitive, i.e. where if warmed above its melting point it will deform or flow.
As shown in greater detail in Figure 9, embedded in the constant wattage layers are flexible and compliant electrodes 72 which may be advantageously formed from braided wires. Each heat shrinkable end fold contains six electrodes 72, three being connected together for connexion to one terminal and three to another, opposed to each other in pairs and running transverse to the longitudinal axis of the shell. Electrodes of the first polarity are connected (as by welding, soldering, or glueing with a conductive adhesive at the areas of intersection) to bus electrodes 73 and 73a, and of the second polarity to bus electrodes 74 and 74a, running the length of each side of the case. The electrodes 73, 73a, 74 and 74a may be constructed from wire braid or thin metallic strip, optionally perforated. To the mid portion of electrode 73 on one side and to the mid portion Of 3 7 5 8 - 24 electrode 74a on the other side are affixed tabs 75 and 76 adapted for easy connexion to an electrical power source. On the top of the heat shrinkable layer (see also Figure 8) along each side and between the heat recoverable end fold structures are attached (by glueing or otherwise adhering) reinforcing flanges 77, 78 and 79, fabricated from any suitably rigid material. Especially suitable materials include metals, and engineering thermoplastics, for example, polycarbonates, acrylonitrile butadiene styrene or SAN resins and filled polymers for example polyamides or polyolefins. Especially preferred is a glass filled polyamide (nylon). The lower member 80, which is not heat recoverable, preferably has external ribs 81 for increased rigidity and, optionally, internal ridges 82 corresponding to and adapted to be mated with the open sides of the heat recoverable folds as also shown in Figure 10. The splice case may be assembled by bringing the upper and lower members together and securing with spring clips 83, 84 and 85 suitably constructed of similar materials to flanges 77, 78 and 79.
Turning now to Figure 11 there is shown a section along the longitudinal axis of the case. A central cavity 86 serves to contain the individual spliced wires from the cables. Optionally and advantageously, there is present a small container 95 (filled with a desiccant) whose walls permit water to diffuse through at a rate in excess of the diffusion rate into the splice case internal cavity, as previously explained in greater detail. A valve may be provided to afford access to cavity 86 enabling pressure testing of the installed splice case.
The preferred method of fabrication of a splice case will be illustrated, with particular reference to the embodiment of Figures 8 to 11, with reference to Figures 12 to 21. <3758 - 25 The electrode material, preferably a metallic braid, which may be, for example, formed from sixteen carriers each of four strands of 38 AWG (about 0.010cm diameter) tinned copper wire braided at as high a braid angle as possible (to achieve a high degree of compliability) is formed around a thin conductive or nonconductive thermoplastic tube. Excellent results have been obtained with a braid angle of 75° around a 6.25 mm outside diameter 0.25 mm wall tubing of the same composition as the constant wattage material. The braided tube is then heated to or above the softening temperature of the thermoplastic tube and flattened, care being taken to prevent stretching of the braid. These steps are shown in Figure 12.
The next stage in the process is the construction of the electrode/bus system comprising the steps of affixing the tab 75 to the side electrode 73, followed by attachment of the end electrodes 72. Suitable affixing methods include spot welding, soldering and glueing. When the electrodes comprise wire braid around a conductive core of the same material as the constant wattage layer it has been found that excellent results are obtained by hot bonding using the conductive thermoplastic cores to bond the electrodes together. Attachment of the electrodes to one another to form the basic configuration is facilitated by the use of a jig as shown in Figure 14. The material used for the end electrodes, in addition to the flattened braid referred to hereinabove, may include knitted or woven or plated metal wires, conductive fibres or metal plated polymer fibres or polymeric fibres containing conductive particles which have been so treated as to render them highly conductive in the fibre direction.
It is preferred in all these embodiments that the electrode be highly extensible and compliant so as not to - 26 offer any appreciable resistance to expansion or recovery of the heat recoverable portions of the splice case as occurs during manufacture and installation in service of the splice case.
Similar materials may be used for the side or bus electrodes. As these electrodes are not required to undergo any significant deformation during manufacture' and installation they may additionally be formed out of such relatively non-extensible and noncompliant materials as flat metal or otherwise highly conductive strips, preferably perforated and single or multiple stranded wires.
The construction of the blank for the splice case shell is shown in Figures 13 and 14. The various heater layers, prepared by, for example, extrusion, coextrusion or hot calendering, are conveniently assembled in a jig frame. In the particular embodiment illustrated, an outer layer 67 is placed in the frame and successively a constant wattage layer 68a, the first set of electrodes 72/73/73a (with the tab 75 pointing to the right as shown in the drawing), another constant wattage layer 68b, the PTC core layer 69, another constant wattage layer 70a, the second set of electrodes 72/74/74a (with the tab 76 pointing to the left), and a final constant wattage layer 70b laid over. The whole structure is sandwiched between polytetrafluoroethylene protective layers 97 and laminated together by heating under pressure. A jig is used to hold the various layers and the electrodes in fixed relation to one another during lamination, the minium pressure being applied.
After lamination and removal of the polytetrafluoroethylene layers, the assembled splice case shell blank is preferably sandwiched between foam rubber sheets 100 and annealed, for example, at about 185°C, for a sufficient period of time with minimum applied pressure - 27 to allow the constituent layers to relax thoroughly. Depending on the materials involved, annealing periods of as little as two minutes to over one hour are suitable, five minutes to fifteen minutes being preferred. The blank is removed while still at the annealing temperatures and conformed over a male mould as in Figure 15 using pressure as indicated by the arrows so as to form the unexpanded splice case shell configuration 87 shown in Figure 16. In this operation, as previously, care should be taken to ensure that the heater is not stretched during the forming operation. If desired a plurality of ridges, preferably wedge shaped, may be present on the upper surface of flanges 77, 78 and 79 which ridges subsequently serve to direct the compressive forces exerted by clips and clamps 83, 84 and 85.
The basic splice case shell 87 is then irradiated with ionizing radiation using techniques well known to those skilled in the art to ensure uniform irradiation. Suitable ionizing radiations include gamma rays, X-rays, and accelerated electrons. The dose required should be sufficient to ensure integrity of the configuration above the crystalline melting point of any of its polymeric constituents but not sufficiently high as adversely to affect the elongation behaviour during the expansion operation to form it into the heat recoverable configuration. A suitable irradiation dose range has been found to be 2 to 50 megarads, 5 to 20 megarads being preferred.
The blank which following irradiation may be considered to be in a heat stable configuration is then formed into the heat recoverable configuration 88 in the sequence of operations shown in Figures 17 to 19. After a preheat sufficient to warm the blank to about the melting point of its crystalline polymeric constituents the formed blank is inserted into - 28 a jig 89 as shown in Figure 18. The reinforcing flanges 77, 78 and 79 which have their contacting surfaces coated with an adhesive 90 as shown in Figure 17 are placed on the sides and ends of the blank. The end flange 78 (and the corresponding flange at the other end of the splice case) is made with a long break off tab 91 having locating holes 92 for mounting in the jig 89 as shown in Figures 17 and 18. All the flanges have turned down lips 98 at their outer edges to serve to contain and protect the edges of the heater from mechanical damage. The side flanges 77 and 79 each have a small shroud 99 in the middle outside edge surrounding the electrode tab 75 or 76 and sized to accept a standard quick disconnect connector 6.3 x 0.8 mm such as are supplied by the Arc-Less Company.
Pressure is supplied to the side and end flanges and the splice case shell folds and central cavity formed by suitable expansion means. Such expansion techniques are well known to the prior art and include mandrel expansion and pneumatic or vacuum forming. In this operation care should be taken to prevent longitudinal compression of the folds when a mandrel is used. Suitable means for minimizing such compression include provision of a radially expansible or circumferentially Segmented sleeve member between the mandrel and the fold which serves to decouple the longitudinal insertion forces exerted by the mandrel from the folds. Alternatively pneumatic or hydraulic expansion of an elastomeric tube longitudinally constrained may be used. The central splice case cavity is preferably formed pneumatically. The expanded blank is then cooled while under constraint as in Figure 19, removed from the jig and an adhesive layer 93 affixed to the surfaces that will butt on to the lower member and on to the interior surfaces of the folds. An adhesive layer can also be affixed to the abutting 3758 surface of member 80. At this stage if desired, a container 95 filled with a desiccant may be fixed to the inner wall 94 of the central cavity as shown in Figure 20.
In use, after completion of the splices and their incorporation into the splice case the complete splice case is assembled, as above described, by bringing the upper and lower members 96 and 80 together and securing with the side clips 83 and 85 and end clips 84. The heater is then electrically connected to a power source.
Because of the disposition of the electrodes in the splice case upper member and the relative resistances of the constant wattage and PTC layers, on connexion to a power source, for example, a 12 or 24 volt lead acid battery, heating to cause recovery and/or activation of the adhesive occurs predominantly at the folds and in the flange regions. Thus, the central cavity does not develop enough power to warm to a significant extent.
As has been mentioned hereinabove, the compositions used in the heater layers may be chosen so as to provide extremely quick heating of the splice case. For example, using the preferred PTC compositions of the type hereinabove referenced, it has been found that the heater in the fold areas typically heats to 115 - 120°C in less than one minute. On reaching such temperature the fold regions start to recover. In about two minutes the fold regions have shrunk around the substrate, e.g. cables, and after a further eight to thirteen minutes the adhesive layers have been thoroughly activated and have wet and sealed to the cable jackets and to the non-heat recoverable base member. Thus, in a typical instance the heater is appropriately connected to a power source for from ten to fifteen minutes during which time the assembly may be safely left unattended, allowing the 4375® - 30 assembler to proceed with other operations. Those skilled in the art will realise that the period of time the heater is under power will vary according to the temperature demands of the adhesive, the thermal load and other factors. Surprisingly, it has been found that the period of time required is relatively insensitive to the ambient temperature. It is believed that this may be due to the extremely sharp PTC cut off made possible by the particularly advantageous design combination of the instant invention.
After an appropriate period of time the electrical power source is removed and the splice case allowed to cool to ambient temperature. At this time the side and end clips may be removed or left in place to provide additional mechanical protection if desired.
A particularly advantageous result of the combination of elements in the instant invention is that because the heater is capable of maintaining itself in a particularly limited range of temperatures whatever the environmental thermal load, even if this temperature range is very close to the melting points of commonly used thermoplastic cable jacketing or individual wire insulating materials, the splice case may be left electrically connected to a power source for periods (e.g. of several hours) after the joint has been made and damage to the telephone wires or cables may be avoided.
In order to facilitate re-entry, the article may be provided with restraining means to inhibit the complete recovery of the recoverable member when the installed member is re-heated to soften it and any adhesive. The restraining means may comprise rigid, e.g., metal, tongues which will underlie the portions which are to surround the cable. Referring to Fig. 9, a tongue having the same width as the flat portion of the flange 78 between the cable entries is positioned on the surface of - 31 4 3 758 the flat portion, with a portion extending axially outwardly therefrom. Similar tongues may be positioned on the outer flat surfaces of flanges 77 and 79, and all the axially extending portions joined together by appropriately shaped connecting links to form an integral restraining means. This may be left in position during use, if desired.

Claims (24)

1. CLAIM Si1. A closure article comprising first and second portions or members capable of being brought together to form, a generally tubular structure having a central cavity portion, the first portion or member being heat-recoverable, and means for maintaining said portions or members together during heat recovery of said first portion or member, the structure so formed being capable at at least one end thereof of heat recovering around and sealing a junction between a plurality of cables inserted therein with at least one pair of the cables extending from the said end of the article, and of sealing opposed parts of the portions or members at the said end at least between the said pair of cables.
2. A closure article as claimed in claim 1, wherein the second portion or member is heat-recoverable.
3. An article as claimed in claim 1 or claim 2, which also comprises, at least between the pair of cables inserted in one end, means for maintaining together opposed parts of the end.
4. An article as claimed in any one of claims 1 to 3, wherein the means for maintaining together the opposed parts comprise a clip or clamp.
5. An article as claimed in any one of claims 1 to 4, which comprises means for heating the article, which means include a material formed of an electrically conductive polymeric composition having a positive temperature coefficient of resistance.
6. An article as claimed in claim 5, wherein at least the recoverable member or portion or members or portions of the article comprise a polymeric material - 33 dimensionally changed from a heat stable form to a heat unstable form capable of recovering to or towards its heat stable form on the application of heat, at least a part of which polymeric material also forms at least a part of the material of the conductive polymeric composition of the heating means,
7. An article as claimed in claim 5 or claim 6, wherein the conductive polymeric composition comprises a polymer having conductive carbon particles dispersed therein.
8. An article as claimed in claim 7, wherein the carbon is carbon black.
9. An article as claimed in any one of claims 1 to 8, which has, at least on its surface which will abut the cables to be covered, a coating of heat activatable adhesive or sealant.
10. An article as claimed in any one of claims 1 to 9, wherein the portions or members have first and second opposite edge regions adapted to be brought into engagement to form the generally tubular article, and means for engaging the regions and maintaining them together during recovery.
11. An article as claimed in claim 10, wherein the edge regions have a heat activated sealant or adhesive on their engageable surfaces.
12. An article as claimed in claim 1, wherein the central cavity portion is adapted for encapsulating a splice and at least one end of the article is adapted to recover and seal over each of a plurality of cables individually. - 34
13. An article as claimed in claim 12, wherein the central portion has positioned therein a rigid, dimensionally stable container member for surrounding the junction, the central portion of the article being conformable on recovery to the outer shape of the member.
14. An article as claimed in any one of claims 5 to 8 or of claims 9 to 11 when dependent on claim 5 wherein the heating means is self regulating and which heating means comprises 0 a first layer of conductive polymeric material having a positive temperature coefficient of resistance, and in surface-to-surface contact with at least one face of the layer a second layer of conductive polymeric material ί having a substantially constant resistance at least up to the recovery temperature of the article to give a substantially constant wattage at a given voltage, and at least a pair of electrodes so positioned that current passing between them will pass through at least a i portion of the constant wattage material and from one face to the other of the first layer.
15. An article as claimed in claim 14, wherein a constant wattage layer is positioned in face-to-face contact with each face of the first layer and wherein an electrode is in contact with each constant wattage layer.
16. An article as claimed in any one of claims 5 to 8 or of claims 9 to 11 when dependent upon claim 5 or claim 14, wherein the heating means is heat-recoverable.
17. An article as claimed in any one of claims 1 to 16, which also comprises an insulating polymeric layer. - 35
18. An article as claimed in claim 17, wherein the insulating polymeric layer is heat-recoverable.
19. An article as claimed in any one of claims 1 to 18, which has affixed to the internal surface thereof a container of desiccant, the water vapour transmission of the container being such as to maintain the relative humidity at less than 30% under the ambient conditions obtaining after recovery about the junction.
20. A closure article as claimed in claim 1, substantially as described with reference to and as illustrated by Figures 1 to 7 of the accompanying drawings.
21. A closure article as claimed in claim 1, substantially as described with reference to and as illustrated by Figures 8 to 21 of the accompanying drawings.
22. A method of encapsulating a junction between a plurality of elongate cables which comprises positioning an article, at least a part of which is heat-recoverable, about the junction with at least one pair of the cables extending from one end of the article, applying over two opposed portions of the said end of the article between at least the pair of cables means for maintaining the opposed portions together during recovery, and heating the article to cause it to recover about and seal the junction, and to encapsulate the junction.
23. A method as claimed in claim 22, wherein the means is a clamp or clip.
24. A method as claimed in claim 22, wherein the article is as claimed in any one of claims 5 to 21,
IE793/79A 1974-09-27 1975-09-24 Heat-recoverable articles and methods for their application IE43758B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US50983774A 1974-09-27 1974-09-27
US05/601,344 US4085286A (en) 1974-09-27 1975-08-04 Heat-recoverable sealing article with self-contained heating means and method of sealing a splice therewith
IE2087/75A IE43757B1 (en) 1974-09-27 1975-09-24 Heat-recoverable articles

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IE43758L IE43758L (en) 1976-03-27
IE43758B1 true IE43758B1 (en) 1981-05-20

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