IE37403B1 - A process for the recovery of rhenium and/or molybdenum values from aqueous acidic solutions - Google Patents
A process for the recovery of rhenium and/or molybdenum values from aqueous acidic solutionsInfo
- Publication number
- IE37403B1 IE37403B1 IE408/73A IE40873A IE37403B1 IE 37403 B1 IE37403 B1 IE 37403B1 IE 408/73 A IE408/73 A IE 408/73A IE 40873 A IE40873 A IE 40873A IE 37403 B1 IE37403 B1 IE 37403B1
- Authority
- IE
- Ireland
- Prior art keywords
- values
- organic phase
- aryl
- recovered
- unsubstituted alkyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/409—Mixtures at least one compound being an organo-metallic compound
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3844—Phosphonic acid, e.g. H2P(O)(OH)2
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B61/00—Obtaining metals not elsewhere provided for in this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
1366844 Extraction of Mo and/or Re values MOLYBDENUM CORP OF AMERICA 9 March 1973 [22 March 1972] 11483/73 Heading C1A Mo and/or Re values are recovered from aqueous acidic solutions by extraction using a water-immiscible organic solvent containing where R1, R2 and R3 represent substituted or unsubstituted alkyl, aryl or aralkyl groups, and where R<1>1 and R<1>2 represent substituted or unsubstituted alkyl, aryl, or aralkyl groups, and subsequent recovery of Mo and Re values from the organic phase. The organic phase may also contain an amine anion extractant or where R<11>1, R<11>2 and R<11>3 represent substituted or unsubstituted alkyl, aryl or aralkyl groups. Preferred extractants of the three types are (dibutyl) - butylphosphonate, di - (2 - ethylhexyl)- phosphoric acid and tributyl phosphate respectively. Amines may also be present. Other suitable extractants, and solvents and amines are listed. The Re may be recovered from the organic phase by stripping with water or the Mo and Re may be stripped from the organic phase with NH4OH and the Re may be selectively recovered from the eluate with a quaternary ammonium extractant. The Re values may be selectively extracted by contact with a compound of Formula I before extraction with the solvent containing compounds of Formulµ I and II. The initial aqueous solution is preferably obtained by leaching molybdenite with HNO3. In comparative examples (1,2) DBBP is used alone to extract Re and (5,6) Mo is subsequently extracted with a mixture of DEHPA, TBP and amine.
[GB1366844A]
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23683872A | 1972-03-22 | 1972-03-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IE37403L IE37403L (en) | 1973-09-22 |
| IE37403B1 true IE37403B1 (en) | 1977-07-20 |
Family
ID=22891181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IE408/73A IE37403B1 (en) | 1972-03-22 | 1973-03-13 | A process for the recovery of rhenium and/or molybdenum values from aqueous acidic solutions |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US3751555A (en) |
| JP (1) | JPS5233569B2 (en) |
| AR (1) | AR193931A1 (en) |
| AT (1) | AT326372B (en) |
| BE (1) | BE797167A (en) |
| BR (1) | BR7301909D0 (en) |
| CA (1) | CA977975A (en) |
| DE (1) | DE2312152C2 (en) |
| ES (1) | ES412887A1 (en) |
| FI (1) | FI56702C (en) |
| FR (1) | FR2177056B1 (en) |
| GB (1) | GB1366844A (en) |
| IE (1) | IE37403B1 (en) |
| IT (1) | IT982078B (en) |
| LU (1) | LU67235A1 (en) |
| NL (1) | NL7303494A (en) |
| NO (1) | NO133978C (en) |
| SE (1) | SE398892B (en) |
| ZA (1) | ZA731947B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4000244A (en) * | 1973-01-30 | 1976-12-28 | Molyscand Ab | Wet-chemical digestion of molybdenum sulphide containing material |
| SE372953B (en) * | 1973-01-30 | 1975-01-20 | Molyscand Ab | |
| JPS5678743U (en) * | 1979-11-20 | 1981-06-26 | ||
| US4255396A (en) * | 1979-12-18 | 1981-03-10 | Gte Products Corporation | Process for separating molybdenum values from tungsten values |
| US4275039A (en) * | 1980-01-17 | 1981-06-23 | Interox Chemicals Limited | Separation of tungsten and molybdenum by solvent extraction |
| US4599153A (en) * | 1983-01-13 | 1986-07-08 | American Cyanamid Company | Selective extraction of rhenium from aqueous sulfuric acid solutions |
| US4774003A (en) * | 1983-08-25 | 1988-09-27 | University Of Utah | Ion exchange extraction of metallic and non-metallic anions by control of the basicity of amine extractants |
| FR2691373B1 (en) * | 1992-05-21 | 1994-08-19 | Commissariat Energie Atomique | Process for the extraction and purification by an organic solvent of molybdenum present in a solution such as a solution of dissolution of impure calcium molybdate. |
| DE4438174C2 (en) * | 1994-10-26 | 1996-08-29 | Bayer Ag | Use of diethyl dodecane phosphonate for the extraction of acids and metal salts from aqueous solutions |
| US20100263490A1 (en) | 2009-04-16 | 2010-10-21 | Freeport-Mcmoran Copper & Gold Inc. | Methods and systems for recovering rhenium from a copper leach |
| RU2477328C1 (en) * | 2012-01-23 | 2013-03-10 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Processing method of low-grade molybdenite concentrates |
| US10280483B2 (en) * | 2015-05-12 | 2019-05-07 | Uchicago Argonne, Llc | Solvent extraction of transition metals |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB967823A (en) * | 1900-01-01 |
-
1972
- 1972-03-22 US US00236838A patent/US3751555A/en not_active Expired - Lifetime
- 1972-04-12 JP JP47036824A patent/JPS5233569B2/ja not_active Expired
-
1973
- 1973-02-07 CA CA163,072A patent/CA977975A/en not_active Expired
- 1973-03-09 GB GB1148373A patent/GB1366844A/en not_active Expired
- 1973-03-12 DE DE2312152A patent/DE2312152C2/en not_active Expired
- 1973-03-13 IE IE408/73A patent/IE37403B1/en unknown
- 1973-03-13 NL NL7303494A patent/NL7303494A/xx active Search and Examination
- 1973-03-16 LU LU67235A patent/LU67235A1/xx unknown
- 1973-03-19 AR AR247102A patent/AR193931A1/en active
- 1973-03-19 BR BR731909A patent/BR7301909D0/en unknown
- 1973-03-19 SE SE7303839A patent/SE398892B/en unknown
- 1973-03-20 ZA ZA731947A patent/ZA731947B/en unknown
- 1973-03-21 ES ES412887A patent/ES412887A1/en not_active Expired
- 1973-03-21 FI FI884/73A patent/FI56702C/en active
- 1973-03-21 IT IT9386/73A patent/IT982078B/en active
- 1973-03-21 NO NO1148/73A patent/NO133978C/no unknown
- 1973-03-22 BE BE129121A patent/BE797167A/en not_active IP Right Cessation
- 1973-03-22 FR FR7310349A patent/FR2177056B1/fr not_active Expired
- 1973-03-22 AT AT254773A patent/AT326372B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2177056A1 (en) | 1973-11-02 |
| AU5356273A (en) | 1974-09-26 |
| BE797167A (en) | 1973-09-24 |
| IE37403L (en) | 1973-09-22 |
| US3751555A (en) | 1973-08-07 |
| NL7303494A (en) | 1973-09-25 |
| FR2177056B1 (en) | 1979-01-12 |
| AR193931A1 (en) | 1973-05-31 |
| ATA254773A (en) | 1975-02-15 |
| CA977975A (en) | 1975-11-18 |
| BR7301909D0 (en) | 1974-06-27 |
| IT982078B (en) | 1974-10-21 |
| ZA731947B (en) | 1974-01-30 |
| LU67235A1 (en) | 1974-03-25 |
| JPS48103014A (en) | 1973-12-24 |
| FI56702C (en) | 1980-03-10 |
| JPS5233569B2 (en) | 1977-08-29 |
| AT326372B (en) | 1975-12-10 |
| NO133978B (en) | 1976-04-20 |
| ES412887A1 (en) | 1975-12-16 |
| DE2312152C2 (en) | 1982-12-09 |
| GB1366844A (en) | 1974-09-11 |
| NO133978C (en) | 1976-07-28 |
| FI56702B (en) | 1979-11-30 |
| DE2312152A1 (en) | 1973-10-04 |
| SE398892B (en) | 1978-01-23 |
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