IE36380B1 - Aqueous emulsion of vinyl acetate interpolymer resorcinol and formaldehyde - Google Patents

Aqueous emulsion of vinyl acetate interpolymer resorcinol and formaldehyde

Info

Publication number
IE36380B1
IE36380B1 IE654/72A IE65472A IE36380B1 IE 36380 B1 IE36380 B1 IE 36380B1 IE 654/72 A IE654/72 A IE 654/72A IE 65472 A IE65472 A IE 65472A IE 36380 B1 IE36380 B1 IE 36380B1
Authority
IE
Ireland
Prior art keywords
resorcinol
emulsion
formaldehyde
acid
parts
Prior art date
Application number
IE654/72A
Other versions
IE36380L (en
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of IE36380L publication Critical patent/IE36380L/en
Publication of IE36380B1 publication Critical patent/IE36380B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)

Abstract

1387185 Aqueous cross-linkable dispersions of vinyl acetate terpolymers AIR PRODUCTS & CHEMICALS Inc 23 May 1972 [2 June 1971] 24241/72 Headings C3P and C3R An aqueous emulsion for use as an adhesive comprises (a) a thermosettable terpolymer of of 5-20 wt. per cent polymerized N-methylol acrylamide, 1-3 wt. per cent polymerized acrylic acid and a balance consisting essentially of polymerized vinyl acetate, (b) 5-20 parts by wt. of resorcinol per 100 parts by wt. of the polymer and (c) formaldehyde, the mole ratio of formaldehyde to resorcinol being from 1 to 2, the resorcinol and formaldehyde being supplied to the emulsion either as unreacted resorcinol and paraformaldehyde or as a water soluble resorcinol-formaldehyde resin, the emulsion containing 40-60 wt. per cent of water and being substantially devoid of solid particles having a size larger than 150 mesh (U.S. Sieve Series). The emulsion preferably has a pH of 4-6 and a viscosity at 50 wt. per cent water content of 300-7000 cp. measured at 25‹ C. with a Brookfield viscometer using a No. 4 spindle at 6 r.p.m. The emulsion may be cured in situ between substrates using an acid curing catalyst such as chromium nitrate, aluminium chloride, phosphoric acid, chromic acid, oxalic acid and nitric acid, to form laminates. A cellulosic thickener may also be present in the emulsion. In examples 200, 179, 194À5 and 185 parts by weight of the polymer emulsion are mixed with 20 parts by wt. of a 75% solids resorcinolformaldehyde resin aqueous solution and small amounts of cellulosic additives or a polyoxyethylene polymer. A further example uses free resorcinol and paraformaldehyde. [GB1387185A]
IE654/72A 1971-06-02 1972-05-15 Aqueous emulsion of vinyl acetate interpolymer resorcinol and formaldehyde IE36380B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US14932771A 1971-06-02 1971-06-02

Publications (2)

Publication Number Publication Date
IE36380L IE36380L (en) 1972-12-02
IE36380B1 true IE36380B1 (en) 1976-10-27

Family

ID=22529776

Family Applications (1)

Application Number Title Priority Date Filing Date
IE654/72A IE36380B1 (en) 1971-06-02 1972-05-15 Aqueous emulsion of vinyl acetate interpolymer resorcinol and formaldehyde

Country Status (13)

Country Link
JP (1) JPS5543013B1 (en)
AU (1) AU461118B2 (en)
BE (1) BE784004A (en)
CA (1) CA984077A (en)
DE (1) DE2226832A1 (en)
FR (1) FR2141700B1 (en)
GB (1) GB1387185A (en)
IE (1) IE36380B1 (en)
IT (1) IT958172B (en)
LU (1) LU65443A1 (en)
NL (1) NL169191C (en)
NO (1) NO137390C (en)
ZA (1) ZA723300B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046823B1 (en) * 1980-08-29 1983-09-21 Wacker-Chemie GmbH Laminating and backing adhesive, preparation and use thereof
JPS629500U (en) * 1985-07-02 1987-01-21

Also Published As

Publication number Publication date
FR2141700B1 (en) 1973-07-13
AU4235672A (en) 1973-11-22
CA984077A (en) 1976-02-17
JPS5543013B1 (en) 1980-11-04
GB1387185A (en) 1975-03-12
NL7207323A (en) 1972-12-05
DE2226832A1 (en) 1972-12-14
AU461118B2 (en) 1975-05-15
NL169191C (en) 1982-06-16
NO137390B (en) 1977-11-14
IE36380L (en) 1972-12-02
LU65443A1 (en) 1972-11-08
FR2141700A1 (en) 1973-01-26
BE784004A (en) 1972-09-18
NL169191B (en) 1982-01-18
ZA723300B (en) 1973-02-28
NO137390C (en) 1978-02-22
IT958172B (en) 1973-10-20

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