HUT53132A - Olefin polymerization catalysts - Google Patents

Olefin polymerization catalysts

Info

Publication number
HUT53132A
HUT53132A HU90594A HU59490A HUT53132A HU T53132 A HUT53132 A HU T53132A HU 90594 A HU90594 A HU 90594A HU 59490 A HU59490 A HU 59490A HU T53132 A HUT53132 A HU T53132A
Authority
HU
Hungary
Prior art keywords
olefin polymerization
polymerization catalysts
catalysts
compound
olefins
Prior art date
Application number
HU90594A
Other languages
Hungarian (hu)
Other versions
HU900594D0 (en
HU218844B (en
Inventor
Luigi Resconi
Umberto Gianni
Enrico Albizzati
Original Assignee
Ausimont Srl
Himont Inc
Montedison Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27272005&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=HUT53132(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ausimont Srl, Himont Inc, Montedison Spa filed Critical Ausimont Srl
Publication of HU900594D0 publication Critical patent/HU900594D0/en
Publication of HUT53132A publication Critical patent/HUT53132A/en
Publication of HU218844B publication Critical patent/HU218844B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Catalysts for the polymerization of olefins, comprising the product of the reaction between: A) a cyclopentadienyl compound of Ti, Zr or Hf; B) an alumoxane compound of formula: <CHEM> in which R<1>, R<2>, R<3>, R<4>, the same or different from each other, are alkyl, alkenyl or alkylaryl radicals having 2 to 20 carbon atoms. y
HU94/90A 1989-01-31 1990-01-30 Olefin polymerization catalyst made from metallocene compound and alumoxane compound and process for making thereof HU218844B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT8919253A IT1237398B (en) 1989-01-31 1989-01-31 CATALYSTS FOR THE POLYMERIZATION OF OLEFINE.
IN83CA1990 IN173199B (en) 1989-01-31 1990-01-30
SU904743351A RU2031901C1 (en) 1989-01-31 1990-02-27 Method of synthesis of catalyst for ethylene polymerization

Publications (3)

Publication Number Publication Date
HU900594D0 HU900594D0 (en) 1990-04-28
HUT53132A true HUT53132A (en) 1990-09-28
HU218844B HU218844B (en) 2000-12-28

Family

ID=27272005

Family Applications (1)

Application Number Title Priority Date Filing Date
HU94/90A HU218844B (en) 1989-01-31 1990-01-30 Olefin polymerization catalyst made from metallocene compound and alumoxane compound and process for making thereof

Country Status (23)

Country Link
US (1) US5126303A (en)
EP (1) EP0384171B1 (en)
JP (1) JP2954251B2 (en)
KR (1) KR0145291B1 (en)
CN (1) CN1019579B (en)
AT (1) ATE89290T1 (en)
AU (1) AU626628B2 (en)
BR (1) BR9000415A (en)
CA (1) CA2008906C (en)
CZ (1) CZ281689B6 (en)
DE (1) DE69001565T2 (en)
ES (1) ES2041053T3 (en)
FI (1) FI103123B (en)
HU (1) HU218844B (en)
IL (1) IL93204A (en)
IN (1) IN173199B (en)
IT (1) IT1237398B (en)
MX (1) MX19309A (en)
NO (1) NO174106C (en)
PT (1) PT93023B (en)
RU (1) RU2031901C1 (en)
YU (1) YU17390A (en)
ZA (1) ZA90639B (en)

Families Citing this family (55)

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US5409874A (en) * 1991-06-20 1995-04-25 Mitsui Petrochemical Industries, Ltd. Catalyst for olefin polymerization, process for the polymerization of olefin, and transition metal compound employable for the catalyst
AU656033B2 (en) * 1991-10-28 1995-01-19 Shell Internationale Research Maatschappij B.V. Group IVA metal compounds and catalyst compositions based thereon
DE69224463T2 (en) * 1991-11-28 1998-07-09 Showa Denko Kk Novel metallocene and process for making polyolefins using the same
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (en) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Catalyst for olefin polymerization, process for its preparation and its use
US6034196A (en) * 1992-06-18 2000-03-07 Montell Technology Company Bv Super random copolymers of ethylene with olefinic monomers
US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
IT1255514B (en) * 1992-09-24 1995-11-09 Luigi Resconi ETHYLENE COPOLYMERS WITH OLEPHINIC MONOMERS, PROCESS FOR THEIR PREPARATION AND CATALYST
US5449650A (en) * 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
IT1256664B (en) 1992-12-28 1995-12-12 Spherilene Srl BITUMINOUS COMPOSITIONS MODIFIED WITH POLYOLEFINIC MATERIALS.
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
PT619325E (en) * 1993-04-07 2002-02-28 Atofina Res PROCESS AND CATALYSTS FOR THE PRODUCTION OF OLEFINS
US6468936B1 (en) * 1993-04-28 2002-10-22 Fina Technology, Inc. Solid MAO/metallocene catalyst complex for propylene polymerization
US5455741A (en) * 1993-10-26 1995-10-03 Pulse Engineering, Inc. Wire-lead through hole interconnect device
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5541272A (en) * 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
IT1273661B (en) * 1994-07-20 1997-07-09 Spherilene Srl CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
FR2729393B1 (en) * 1995-01-18 1997-03-21 Bp Chemicals Snc OLEFIN POLYMERIZATION PROCESS
IT1276752B1 (en) * 1995-06-20 1997-11-03 Spherilene S P A Ora Montell I CATALYSTS AND PROCEDURES FOR THE POLYMERIZATION OF OLEFINE
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
US5780659A (en) * 1996-03-29 1998-07-14 Phillips Petroleum Company Substituted indenyl unbridged metallocenes
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
DE19623707A1 (en) * 1996-06-14 1997-12-18 Hoechst Ag Transition metal compound
WO1998002247A1 (en) * 1996-07-15 1998-01-22 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
FI972230A (en) 1997-01-28 1998-07-29 Borealis As New homogeneous catalyst composition for polymerization of olefins
FI970349A (en) 1997-01-28 1998-07-29 Borealis As New activator systems for metallocene compounds
US6005463A (en) * 1997-01-30 1999-12-21 Pulse Engineering Through-hole interconnect device with isolated wire-leads and component barriers
EP0997480B1 (en) 1997-07-09 2007-02-14 Maruzen Petrochemical Co., Ltd. Catalytic components for the polymerization of olefins, polymerization catalysts, and process for polymerizing olefins by using the same
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
ZA989699B (en) 1997-10-29 1999-04-25 Montell Technology Company Bv Catalysts for the polymerization of olefins and process for the preparation thereof
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
DE69823969T2 (en) 1997-12-22 2005-05-12 Mitsui Chemicals, Inc. Catalyst component, catalyst and process for the polymerization of ethylenically unsaturated monomers
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6492292B2 (en) 1998-10-23 2002-12-10 Albemarle Corporation Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components
US20040002420A1 (en) * 1998-10-23 2004-01-01 Feng-Jung Wu Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use
US6462212B1 (en) 1998-10-23 2002-10-08 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
US6812182B2 (en) 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
US6555494B2 (en) 1998-10-23 2003-04-29 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components
US6160145A (en) * 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
JP5008794B2 (en) * 1998-11-25 2012-08-22 バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング Metallocene monohalide
EP2325215B1 (en) * 1999-12-16 2016-03-09 Chevron Phillips Chemical Company LP Polymer of specific melt index, polydispersity, shear ratio and molecular weight distribution and process for its preparation
CN1160381C (en) * 2001-09-27 2004-08-04 中国石油化工股份有限公司 Olefine polymerization catalyst containing double schiff base ligand and preparing method and use
JP2005511804A (en) * 2001-11-30 2005-04-28 エクソンモービル・ケミカル・パテンツ・インク Ethylene / α-olefin copolymers produced using non-single site catalyst / single site catalyst combinations and their production and use
US8188170B2 (en) 2006-06-20 2012-05-29 Chemtura Corporation Polymers with low gel content and enhanced gas-fading
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
US9376518B2 (en) * 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process

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US4490514A (en) * 1983-08-16 1984-12-25 Chemplex Company High-temperature ethylene polymerization and copolymerization using dialuminoxane cocatalysts
DE3443087A1 (en) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt METHOD FOR PRODUCING POLYOLEFINES
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
DE3789666T2 (en) * 1986-12-30 1994-08-04 Mitsui Petrochemical Ind SOLID CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR THE PRODUCTION THEREOF.
JPH0742301B2 (en) * 1987-02-14 1995-05-10 三井石油化学工業株式会社 Particulate aluminoxane, its manufacturing method and its use
JP2573613B2 (en) * 1987-08-14 1997-01-22 三菱化学株式会社 Ethylene polymerization method
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US4937301A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE3929693A1 (en) * 1989-09-07 1991-03-14 Hoechst Ag METHOD FOR PRODUCING A POLYOLEFIN WAX
MY107639A (en) * 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation

Also Published As

Publication number Publication date
JPH03197514A (en) 1991-08-28
NO900435L (en) 1990-08-01
CZ281689B6 (en) 1996-12-11
IT8919253A0 (en) 1989-01-31
CN1019579B (en) 1992-12-23
ZA90639B (en) 1990-10-31
RU2031901C1 (en) 1995-03-27
AU626628B2 (en) 1992-08-06
PT93023B (en) 1998-04-30
KR0145291B1 (en) 1998-07-15
NO900435D0 (en) 1990-01-30
NO174106C (en) 1994-03-16
DE69001565T2 (en) 1993-11-18
FI103123B1 (en) 1999-04-30
DE69001565D1 (en) 1993-06-17
BR9000415A (en) 1991-01-15
ATE89290T1 (en) 1993-05-15
IL93204A0 (en) 1990-11-05
KR900011794A (en) 1990-08-02
NO174106B (en) 1993-12-06
MX19309A (en) 1994-03-31
YU17390A (en) 1991-08-31
ES2041053T3 (en) 1993-11-01
HU900594D0 (en) 1990-04-28
CA2008906A1 (en) 1990-07-31
JP2954251B2 (en) 1999-09-27
FI103123B (en) 1999-04-30
IL93204A (en) 1993-03-15
EP0384171A1 (en) 1990-08-29
US5126303A (en) 1992-06-30
HU218844B (en) 2000-12-28
IT1237398B (en) 1993-06-01
CN1044822A (en) 1990-08-22
FI900467A0 (en) 1990-01-30
AU4889290A (en) 1990-08-09
PT93023A (en) 1990-07-31
EP0384171B1 (en) 1993-05-12
IN173199B (en) 1994-03-05
CA2008906C (en) 1999-11-16
CZ42890A3 (en) 1996-07-17

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Legal Events

Date Code Title Description
DGB9 Succession in title of applicant

Owner name: MONTELL TECHNOLOGY CO BV, NL

HMM4 Cancellation of final prot. due to non-payment of fee