HUP0303387A2 - Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound - Google Patents

Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound

Info

Publication number
HUP0303387A2
HUP0303387A2 HU0303387A HUP0303387A HUP0303387A2 HU P0303387 A2 HUP0303387 A2 HU P0303387A2 HU 0303387 A HU0303387 A HU 0303387A HU P0303387 A HUP0303387 A HU P0303387A HU P0303387 A2 HUP0303387 A2 HU P0303387A2
Authority
HU
Hungary
Prior art keywords
general formula
polymer
compound
free radical
ethylene
Prior art date
Application number
HU0303387A
Other languages
Hungarian (hu)
Inventor
Mathias Destarac
Original Assignee
Rhodia Chimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie filed Critical Rhodia Chimie
Publication of HUP0303387A2 publication Critical patent/HUP0303387A2/en
Publication of HUP0303387A3 publication Critical patent/HUP0303387A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

A találmány elsőgenerációs polimer előállítására vonatkozik, amelyneksorán egy, az alábbiakat tartalmazó készítményt szabadgyököspolimerizációnak vetnek alá: - legalább ez etilén típusú telítetlenkötést tartalmazó monomer; - egy szabadgyökforrás, - legalább egy (IA)vagy (IB) általános képletű (I) jelű vegyület, - egy (II) általánosképletű vegyület, a képletekben R1 jelentése alkil-, acil-, aril-,aralkil-, alkén- vagy alkincsoport, telített, telítetlen vagy aromáskarbociklus vagy heterociklus vagy polimerlánc, Z és Z1 jelentéseazonosan vagy különbözően alkil-, acil-, aril-, aralkil-, alkén- vagyalkincsoport vagy telített, telítetlen vagy aromás karbociklus vagyheterociklus, amely helyettesítve lehet, - OR2 általános képletűcsoport, - NR3R4 általános képletű csoport, p értéke 1 vagy 1-nélnagyobb egész szám. A találmány kiterjed egy N-edik generációs blokk-kopolimer szabadgyökös polimerizációval történő előállítására is,amelynek során egy elsőgenerációs polimer képződik: - legalább egyetilén típusú telítetlen kötést tartalmazó monomer, - egyszabadgyökforrás, - legalább egy (IA) vagy (IB) általános képletű (I)jelű vegyületület, N-1 számú további szabadgyökös polimerizációslépést hajtanak végre, mindegyik lépést az alábbi összetételűkészítmény alkalmazásával végzik: - legalább egy etilén típusútelítetlen kötést tartalmazó monomer, - egy szabadgyök-forrás, és - azelőző polimerizációs lépésben előállított polimer, ahol olyan etiléntípusú telítetlen monomer(eke)t használnak, amelyből az ezen lépésbenképződő blokk tulajdonságaiban eltérnek az előző lépésben képződöttblokkétól, és az első polimerizációs lépést és/vagy a következőpolimerizációs lépést legalább egy (II) képletű vegyület jelenlétébenvégzik. A találmány kiterjed továbbá a fenti eljárásokkal előállítottpolimer készítményekre. ÓThe invention relates to the production of a first-generation polymer, during which a composition containing the following is subjected to free-radical polymerization: - at least this is a monomer containing an ethylene-type unsaturated bond; - a source of free radicals, - at least one compound (I) of the general formula (IA) or (IB), - a compound of the general formula (II), in the formulas R1 is an alkyl, acyl, aryl, aralkyl, alkene or alkyne group , saturated, unsaturated or aromatic carbocycle or heterocycle or polymer chain, Z and Z1 are the same or different alkyl, acyl, aryl, aralkyl, alkene or alkyne group or a saturated, unsaturated or aromatic carbocycle or heterocycle, which may be substituted, - group of general formula OR2, - Group with the general formula NR3R4, the value of p is 1 or an integer greater than 1. The invention also covers the production of an Nth generation block copolymer by free radical polymerization, during which a first generation polymer is formed: - a monomer containing at least one ethylenically unsaturated bond, - one free radical source, - at least one (IA) or (IB) with the general formula (I ), an additional free radical polymerization step number N-1 is carried out, each step is carried out using the following composition: - a monomer containing at least one ethylene-type unsaturated bond, - a free radical source, and - a polymer produced in the previous polymerization step, where an ethylene-type unsaturated monomer (eke) is used, from which the properties of the block formed in this step differ from those of the block formed in the previous step, and the first polymerization step and/or the following polymerization step are performed in the presence of at least one compound of formula (II). The invention also covers polymer compositions produced by the above processes. HE

HU0303387A 2000-09-18 2001-09-11 Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound HUP0303387A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0011877A FR2814168B1 (en) 2000-09-18 2000-09-18 PROCESS FOR THE SYNTHESIS OF BLOCK POLYMERS BY CONTROLLED RADICAL POLYMERIZATION IN THE PRESENCE OF A DISULFIDE COMPOUND
PCT/FR2001/002821 WO2002022688A2 (en) 2000-09-18 2001-09-11 Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound

Publications (2)

Publication Number Publication Date
HUP0303387A2 true HUP0303387A2 (en) 2004-01-28
HUP0303387A3 HUP0303387A3 (en) 2005-03-29

Family

ID=8854411

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0303387A HUP0303387A3 (en) 2000-09-18 2001-09-11 Method for block polymer synthesis by controlled radical polymerisation in the presence of a disulphide compound

Country Status (19)

Country Link
US (1) US6916884B2 (en)
EP (1) EP1319027B1 (en)
JP (1) JP2004509181A (en)
KR (1) KR20030032031A (en)
CN (1) CN100343286C (en)
AT (1) ATE320451T1 (en)
AU (2) AU9000901A (en)
BR (1) BR0113941A (en)
CA (1) CA2422593A1 (en)
CZ (1) CZ2003751A3 (en)
DE (1) DE60118007T2 (en)
FR (1) FR2814168B1 (en)
HU (1) HUP0303387A3 (en)
MX (1) MXPA03002318A (en)
NO (1) NO20031231L (en)
PL (1) PL361423A1 (en)
SK (1) SK3112003A3 (en)
WO (1) WO2002022688A2 (en)
ZA (1) ZA200301563B (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2794463B1 (en) 1999-06-04 2005-02-25 Rhodia Chimie Sa PROCESS FOR THE SYNTHESIS OF POLYMERS BY CONTROLLED RADICAL POLYMERIZATION USING HALOGENATED XANTHATES
AU2003210236A1 (en) * 2002-02-11 2003-09-04 Rhodia Chimie Detergent composition comprising a block copolymer
FR2842814B1 (en) 2002-07-26 2004-10-22 Coatex Sas PROCESS FOR CONTROLLED RADICAL POLYMERIZATION OF ACRYLIC ACID AND ITS SALTS, THE POLYMERS OBTAINED, AND THEIR APPLICATIONS.
NL1025250C2 (en) * 2004-01-15 2005-07-18 Univ Eindhoven Tech Multi-functional and bi-functional dithiocarboxylate compounds, monofunctional alkoxycarbonyl dithiocarbamate compound, a process for the preparation of alkoxycarbonyl dithiocarbamate compounds as well as a process for preparing multiblock copolymers by radical polymerization.
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
ATE431368T1 (en) * 2006-08-17 2009-05-15 Rhodia Operations BLOCK COPOLYMERS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE IN EMULSIONS
US8362190B2 (en) 2007-09-12 2013-01-29 Nissan Chemical Industries, Ltd. Method for producing hyperbranched polymer
JP5534244B2 (en) * 2009-03-06 2014-06-25 日産化学工業株式会社 Method for producing hyperbranched polymer
JP5598470B2 (en) * 2009-07-16 2014-10-01 ダイキン工業株式会社 Method for producing fluorine-containing block copolymer
BR122022001868B1 (en) 2015-12-10 2022-09-13 Adama Makhteshim Ltd. AGRICULTURAL MATERIAL COMPOSITION, PEST PREVENTION AND CONTROL AND PLANT GROWTH IMPROVEMENT METHOD, AGRICULTURAL MATERIAL COMPOSITION PREPARATION PROCESS AND USE OF A BLOCK COPOLYMER
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
EP3472212A4 (en) * 2016-06-15 2020-02-19 Rhodia Operations High performance surfactant fee latexes for improved water resistance
BR112019004569A8 (en) * 2016-09-09 2023-02-07 Rhodia Operations SELF-THICKENING LATEX FOR AQUATIC SYSTEMS AND RELATED METHODS
AR114185A1 (en) 2018-01-23 2020-07-29 Adama Makhteshim Ltd SYNTHESIS OF 5-CHLORINE-2 - [(3,4,4-TRIFLUORO-3-BUTEN-1-IL) THIO] -THAZOLE
JP2022522446A (en) 2019-02-28 2022-04-19 ローディア オペレーションズ Composition for high stabilization of emulsion
WO2020182919A1 (en) 2019-03-12 2020-09-17 Rhodia Operations Stabilized friction reducer emulsions
FR3095447B1 (en) 2019-04-26 2021-12-24 Michelin & Cie MANUALLY TRANSPORTABLE VEHICLE WHEEL TIRE
CN110357992A (en) * 2019-07-09 2019-10-22 复旦大学 A kind of fluoropolymer-containing preparation method of super high molecular weight
FR3111636B1 (en) 2020-06-18 2022-08-26 Michelin & Cie Elastomeric composition comprising a phenolic compound and a compound from the ose family
FR3113905B1 (en) 2020-09-04 2022-08-05 Michelin & Cie RUBBER COMPOSITION BASED ON HIGHLY SATURATED DIENIQUE ELASTOMER
FR3113906B1 (en) 2020-09-04 2022-08-05 Michelin & Cie RUBBER COMPOSITION BASED ON HIGHLY SATURATED DIENIQUE ELASTOMER
WO2023210671A1 (en) * 2022-04-26 2023-11-02 京セラ株式会社 Copolymer, polymer film, measuring device, and support for measurement

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE156600C (en)
DE2756128A1 (en) * 1977-12-16 1979-06-21 Gerhard Kappes Folding chair with straight armrests - has easily detachable joint on rear stand holding armrests vertical
DE2756218C2 (en) * 1977-12-16 1983-03-10 Denki Kagaku Kogyo K.K., Tokyo A process for the preparation of a toluene-soluble liquid copolymer curable at room temperature with an amine compound
FR2442863A1 (en) * 1978-11-07 1980-06-27 Distugil PROCESS FOR THE PREPARATION OF SULFUR MODIFIED POLYCHLOROPRENE
DD156600A5 (en) * 1981-02-25 1982-09-08 Karin Wendler PROCESS FOR PREPARING LIQUID POLYMERES WITH REACTIVE END GROUPS
JPH0676516B2 (en) * 1985-11-28 1994-09-28 旭化成工業株式会社 Rubber composition for tire tread
DE3608556A1 (en) * 1986-03-14 1987-10-01 Akzo Gmbh TELECHELE POLYMERS
JPS6426672A (en) * 1987-04-01 1989-01-27 Yokohama Rubber Co Ltd Ultraviolet-curing type resin composition
JPH0753846B2 (en) * 1988-06-20 1995-06-07 株式会社クラレ Sulfur-containing adhesive
US5254198A (en) * 1988-06-20 1993-10-19 Kuraray Co., Ltd. Method of bonding a metal or alloy utilizing a polymerizable thiocarboxylic acid or a derivative thereof
JP2765137B2 (en) * 1988-12-15 1998-06-11 ジェイエスアール株式会社 Copolymer latex for paper coating composition and paper coating composition
JPH04198303A (en) * 1990-11-27 1992-07-17 Sanyo Chem Ind Ltd Polymerization initiator and polymerization process
JPH0649131A (en) * 1992-07-30 1994-02-22 Nippon Shokubai Co Ltd Production of @(3754/24)meth)acrylic polymer with high acid value
ATE210684T1 (en) * 1996-07-10 2001-12-15 Du Pont POLYMERIZATION WITH ßLIVINGß MARK
FR2755969B1 (en) * 1996-11-20 1998-12-24 Atochem Elf Sa POLYMERIZATION IN THE PRESENCE OF A STABLE FREE RADICAL AND AN INIFERTER
FR2764892B1 (en) * 1997-06-23 2000-03-03 Rhodia Chimie Sa PROCESS FOR THE SYNTHESIS OF BLOCK POLYMERS
NZ505654A (en) * 1997-12-18 2002-03-28 John Chiefair Living polymerisation process whereby photo-initiators of polymerisation utilises a thermal process resulting in polymers of controlled molecular weight and low polydispersity
FR2773161B1 (en) * 1997-12-31 2000-01-21 Rhodia Chimie Sa PROCESS FOR THE SYNTHESIS OF BLOCK POLYMERS
WO1999035177A1 (en) * 1997-12-31 1999-07-15 Rhodia Chimie Method for block polymer synthesis by controlled radical polymerisation from dithiocarbamate compounds
FR2802209B1 (en) * 1999-12-10 2002-03-01 Rhodia Chimie Sa LATEX WITH MODIFIED SURFACE CHEMISTRY AND REDISPERSABLE POWDERS, THEIR PRODUCTION AND THEIR USES

Also Published As

Publication number Publication date
HUP0303387A3 (en) 2005-03-29
FR2814168B1 (en) 2006-11-17
JP2004509181A (en) 2004-03-25
CA2422593A1 (en) 2002-03-21
CN1458937A (en) 2003-11-26
DE60118007D1 (en) 2006-05-11
PL361423A1 (en) 2004-10-04
MXPA03002318A (en) 2003-06-24
ATE320451T1 (en) 2006-04-15
WO2002022688A3 (en) 2002-06-20
BR0113941A (en) 2003-07-22
EP1319027B1 (en) 2006-03-15
WO2002022688A2 (en) 2002-03-21
DE60118007T2 (en) 2006-11-02
CZ2003751A3 (en) 2003-06-18
US20030187165A1 (en) 2003-10-02
EP1319027A2 (en) 2003-06-18
US6916884B2 (en) 2005-07-12
AU2001290009B2 (en) 2005-05-12
NO20031231D0 (en) 2003-03-17
NO20031231L (en) 2003-05-19
FR2814168A1 (en) 2002-03-22
KR20030032031A (en) 2003-04-23
AU9000901A (en) 2002-03-26
SK3112003A3 (en) 2003-09-11
CN100343286C (en) 2007-10-17
ZA200301563B (en) 2004-03-01

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