HUP0104979A2 - Tack free surface cures of polymers by organic peroxides in the presence of air - Google Patents

Tack free surface cures of polymers by organic peroxides in the presence of air

Info

Publication number
HUP0104979A2
HUP0104979A2 HU0104979A HUP0104979A HUP0104979A2 HU P0104979 A2 HUP0104979 A2 HU P0104979A2 HU 0104979 A HU0104979 A HU 0104979A HU P0104979 A HUP0104979 A HU P0104979A HU P0104979 A2 HUP0104979 A2 HU P0104979A2
Authority
HU
Hungary
Prior art keywords
sulfur
composition
polymers
molecular oxygen
free radicals
Prior art date
Application number
HU0104979A
Other languages
Hungarian (hu)
Inventor
Gary James Gullo
Michael Fred Novits
Leonard Henry Palys
Original Assignee
Atofina Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Chemicals, Inc. filed Critical Atofina Chemicals, Inc.
Publication of HUP0104979A2 publication Critical patent/HUP0104979A2/en
Publication of HUP0104979A3 publication Critical patent/HUP0104979A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415Five-membered rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyethers (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

A tal lm ny t rgya egy kompozíció, amely tartalmaz a) legal bb egy (A)vegyületet, amelyet a szilikon elasztomerek és az (I) ltal nos képletűvegyületek k"zül v lasztanak ki; és b) legal bb egy (B) vegyületet,amely a p-feniléndiamin b zisú antiozon nsok és kénnel térh lósíthatópolimerek kénes vulkaniz ciój t gyorsítani képes kéntartalmú szervesvegyületek, poliszulfit polimerek és fenti kéntartalmú szervesvegyületek keverékei k"zül kiv lasztott kéntartalmú szerves vegyületekk"zül v lasztanak ki. A fenti kompozíció adott esetben szervesperoxidok és azo inici torok k"zül kiv lasztott szabad gy"k"s inicitort is tartalmazhat, és lehetővé teszi polimerek felületi ragacsossgtól mentes kikeményítését molekul ris oxigén (levegő) jelenlétében. Atal lm ny tov bbi t rgya elj r s molekul ris oxigén jelenlé- tébenszabad gy"k"s inici tor boml s ból képződ"tt szabad gy"k"k ltalkikeményített felületi ragacsoss gtól mentes polimer elő llít s ra,amelyet oly módon hajtanak végre, hogy a polimert a fent defini ltkompozícióval kompound lj k és az anyaggal a polimerbe bevitt szabadgy"k"s inici tor boml s hoz elegendő hőenergi t k"z"lnek. A tal lm nytov bbi t rgya a fenti készítményt tartalmazó kompozíció form zotttermékekké alakít s ra szolg ló elj r s, mely szerint kompozíciót egyform zott t rggy alakítj k, majd molekul ris oxigén jelenlétében aszabad gy"k"s inici tor boml s hoz megfelelő hőmérsékletnek teszik ki,és így lényegében felületi ragacsoss gtól mentes kikeményített formzott t rgyat llítanak elő. ÓThe subject matter of the invention is a composition containing a) at least one (A) compound selected from silicone elastomers and compounds of formula (I); and b) at least one (B) compound , which can accelerate the sulfur vulcanization of p-phenylenediamine-based antiozones and sulfur-loadable polymers, is composed of sulfur-containing organic compounds, polysulfite polymers and sulfur-containing organic compounds extracted from mixtures of the above sulfur-containing organic compounds. The above composition may contain organic peroxides and it may also contain a free radical initiator extracted from those initiators, and enables the curing of polymers without surface stickiness in the presence of molecular oxygen (air). In the presence of molecular oxygen in the presence of molecular oxygen, the free radicals formed from the initiator decomposition of the free radicals lead to the production of a polymer without hardened surface tackiness, which is carried out in such a way that the polymer is compounded with the composition defined above and sufficient thermal energy is used for the initiator decomposition of the free radicals introduced into the polymer with the material. The further subject matter of the invention is that the composition containing the above composition is converted into molded products s process, according to which a composition is formed into a uniform material, then in the presence of molecular oxygen it is exposed to a temperature suitable for the initiator decomposition of free radicals, and thus a cured molded material essentially free of surface stickiness is applied out. Oh

HU0104979A 1999-11-09 2000-11-09 Tack free surface cures of polymers by organic peroxides in the presence of air HUP0104979A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16448899P 1999-11-09 1999-11-09
PCT/US2000/030953 WO2001034680A1 (en) 1999-11-09 2000-11-09 Tack free surface cures of polymers by organic peroxides in the presence of air

Publications (2)

Publication Number Publication Date
HUP0104979A2 true HUP0104979A2 (en) 2002-04-29
HUP0104979A3 HUP0104979A3 (en) 2004-04-28

Family

ID=22594715

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0104979A HUP0104979A3 (en) 1999-11-09 2000-11-09 Tack free surface cures of polymers by organic peroxides in the presence of air

Country Status (11)

Country Link
EP (1) EP1149122A4 (en)
JP (1) JP2003514088A (en)
CN (1) CN1336939A (en)
AU (1) AU1596301A (en)
BR (1) BR0007426A (en)
CA (1) CA2359148A1 (en)
HK (1) HK1041278A1 (en)
HU (1) HUP0104979A3 (en)
PL (1) PL348765A1 (en)
RU (1) RU2001122163A (en)
WO (1) WO2001034680A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060148942A1 (en) * 2004-12-30 2006-07-06 The Goodyear Tire & Rubber Company Rubber cure system and rubber composition incorporating same
CN101932634A (en) * 2008-02-20 2010-12-29 瑟迪崴(有限公司)玻璃与混合柱型隔离器欧洲公司 A kind of manufacturing has the method for the electric(al) insulator of the overcoat polymer that contains antiozonidate
JP5533208B2 (en) * 2010-05-06 2014-06-25 横浜ゴム株式会社 Rubber composition and hose
US9644089B2 (en) * 2013-03-14 2017-05-09 Arkema Inc. Methods for crosslinking polymer compositions in the presence of atmospheric oxygen
ES2632242T3 (en) 2013-03-26 2017-09-12 Akzo Nobel Chemicals International B.V. Procedure to cross-link EPM and EPDM
CN107001685B (en) * 2014-12-09 2019-09-27 阿科玛股份有限公司 The composition and method of cross-linked polymer in the presence of aerial oxygen
KR102519231B1 (en) * 2014-12-09 2023-04-07 알케마 인코포레이티드 Compositions and methods for crosslinking polymers in the presence of atmospheric oxygen
GB201506876D0 (en) 2015-04-22 2015-06-03 Uponor Innovation Ab Polyolefin pipe
JP6579704B2 (en) * 2015-09-18 2019-09-25 株式会社ブリヂストン Rubber composition and anti-vibration rubber
JP2017222810A (en) * 2016-06-17 2017-12-21 株式会社ブリヂストン Rubber composition and method for producing the same
JP2017222811A (en) * 2016-06-17 2017-12-21 株式会社ブリヂストン Rubber composition and method for producing the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4575522A (en) * 1985-03-07 1986-03-11 Hydril Company Rubber composition for geothermal application
US4929665A (en) * 1987-01-20 1990-05-29 Dainippon Ink And Chemicals, Inc. Thermoplastic resin composition
FR2612196B1 (en) * 1987-03-10 1989-06-16 Rhone Poulenc Chimie THERMOSTABLE POLYMERS BASED ON MALEIMIDES INCLUDING A BISMALEIMIDE SILOXANE AND AROMATIC DIAMINES AND PROCESSES FOR THEIR PREPARATION
CA2063478A1 (en) * 1991-03-22 1992-09-23 Michael F. Novits Scorch extending curing/crosslinking compositions

Also Published As

Publication number Publication date
JP2003514088A (en) 2003-04-15
RU2001122163A (en) 2003-06-10
EP1149122A1 (en) 2001-10-31
CN1336939A (en) 2002-02-20
BR0007426A (en) 2001-11-20
WO2001034680A1 (en) 2001-05-17
PL348765A1 (en) 2002-06-03
HUP0104979A3 (en) 2004-04-28
EP1149122A4 (en) 2003-03-12
HK1041278A1 (en) 2002-07-05
CA2359148A1 (en) 2001-05-17
AU1596301A (en) 2001-06-06

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