HUP0001248A2 - Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids - Google Patents
Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acidsInfo
- Publication number
- HUP0001248A2 HUP0001248A2 HU0001248A HUP0001248A HUP0001248A2 HU P0001248 A2 HUP0001248 A2 HU P0001248A2 HU 0001248 A HU0001248 A HU 0001248A HU P0001248 A HUP0001248 A HU P0001248A HU P0001248 A2 HUP0001248 A2 HU P0001248A2
- Authority
- HU
- Hungary
- Prior art keywords
- iii
- atoms
- donor atoms
- formula
- ligand
- Prior art date
Links
- 239000007844 bleaching agent Substances 0.000 title abstract 12
- 229910052751 metal Inorganic materials 0.000 title abstract 6
- 239000002184 metal Substances 0.000 title abstract 6
- 239000012190 activator Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 125000004429 atom Chemical group 0.000 abstract 20
- 239000003446 ligand Substances 0.000 abstract 11
- 150000003624 transition metals Chemical class 0.000 abstract 8
- 229910052723 transition metal Inorganic materials 0.000 abstract 7
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 abstract 6
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 4
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 abstract 3
- 238000004140 cleaning Methods 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 abstract 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract 2
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 abstract 2
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- MMIPFLVOWGHZQD-UHFFFAOYSA-N manganese(3+) Chemical compound [Mn+3] MMIPFLVOWGHZQD-UHFFFAOYSA-N 0.000 abstract 2
- WXHIJDCHNDBCNY-UHFFFAOYSA-N palladium dihydride Chemical compound [PdH2] WXHIJDCHNDBCNY-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- JYZIHLWOWKMNNX-UHFFFAOYSA-N benzimidazole Chemical compound C1=C[CH]C2=NC=NC2=C1 JYZIHLWOWKMNNX-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000000592 heterocycloalkyl group Chemical group 0.000 abstract 1
- 150000002460 imidazoles Chemical class 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
- 150000002678 macrocyclic compounds Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 150000003216 pyrazines Chemical class 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- 150000003230 pyrimidines Chemical class 0.000 abstract 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 150000003557 thiazoles Chemical class 0.000 abstract 1
- 150000003852 triazoles Chemical class 0.000 abstract 1
Landscapes
- Detergent Compositions (AREA)
Abstract
A laundry or cleaning composition comprises: (a) 0.0001-99.9 (especially 0.1-25)% of a bleach activator and/or organic percarboxylic acid; (b) 1-49% of a transition metal bleach catalyst comprising a complex of a transition metal and a cross-bridged macro-polycyclic ligand in which: (I) the metal is selected from Mn(II), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Co(I), Co(II), Co(III), Ni(I), Ni(II), Ni(III), Cu(I), Cu(II), Cr(III), Cr(IV), Cr(V), Cr(VI), V(III), V(IV), V(V), Mo(IV), Mo(V), Mo(VI), W(IV), W(VI), Pd(II), Ru(II), RU(III) and Ru(IV) ( especially Mn(II), Mn(III), Mn(IV), Fe(II), Fe(III), Fe(IV), Cr(II), Cr(III), Cr(IV), Cr(V) and/or Cr(VI)); (II) the macro-polycyclic rigid ligand is coordinated by preferably four or five, donor atoms to the same metal and comprising: (i) an organic macrocyclic ring containing four or more donor atoms, preferably at least three, more preferably at least four of the donor atoms being N, separated by covalent linkages of 2 or 3 non-donor atoms, two to five (preferably three to four, more preferably four) of the donor atoms being coordinated to the same transition metal atom in the complex; (ii) a cross-bridged chain, which covalently connects at least two, preferably non-adjacent, donor atoms of the ring, the donor atoms being bridgehead donor atoms coordinated to the same metal in the complex. The linking moiety, preferably a cross-bridged chain, comprises 2-10 atoms, the chain being selected from 2,3 or 4 non-donor atoms, and 4-6 non-donor atoms with a further donor atom; and (iii) optionally, one or more non-macro-polycyclic ligands, preferably selected from , preferably selected from H2O, ROH, NR3, RCN, OH-, OOH-, RS-, RO-, OCN-, SCN-, N3-, CN-, F-, Cl-, Br-, I-, O2-, NO3-, NO2-, SO42-, SO32-, PO43-, organic phosphates, organic phosphonates, organic sulphates, organic sulphonates, and aromatic N-donors such as pyridines, pyrazines, pyrazole(s), imidazole(s), benzimidazole(s), pyrimidines, triazoles, and thiazoles with R being H, optionally substituted alkyl or aryl; and (c) at least 0.1% adjunct ingredient(s), preferably oxygen bleaching agent; Also claimed are: (1) a laundry or cleaning composition comprising: (a) 0.0001-99.9 (especially 0.1-25)% of a bleach activator and/or organic percarboxylic acid; (b) 1 ppb-49% of a transition metal bleach catalyst comprising a complex of a transition metal and a cross-bridged macro-polycyclic ligand in which: (I) the metal is selected from Mn(II), Mn(IV), Mn(V), Fe(II), Fe(III), Fe(IV), Co(I), Co(II), Co(III), Ni(I), Ni(II), Ni(III), Cu(I), Cu(II), Cr(III), Cr(IV), Cr(V), Cr(VI), V(III), V(IV), V(V), Mo(IV), Mo(V), Mo(VI), W(IV), W(VI), Pd(II), Ru(II), RU(III) and Ru(IV); and (II) the macro-polycyclic rigid ligand is selected from (i) ligand of formula (A) having denticity of 4 or 5, (ii) ligand of formula (B) having denticity of 5 or 6, (iii) ligand of formula (C) having denticity of 6 or 7; and (iv) optionally one or more non-macro-polycyclic ligands as above; and (c) at least 0.1% adjunct ingredient(s), preferably oxygen bleaching agent; and (2) a laundry or cleaning composition comprising: (a) 1 ppm-99.9 (especially 0.1-25)% of bleach activator; (b) 1 ppb-99.9% (especially 0.05-500 ppm) of a transition metal bleach catalyst comprising a 1:1 mol complex of a catalytic Mn metal selected from Mn(II), Mn(III), Mn(IV) and a tetradentate cross-bridged macro-polycyclic ligand of formula (D); and optionally non-poly-macrocycle ligands; and (c) balance to 100%, preferably at least 0.1% of adjunct materials comprising oxygen bleaching agent selected from H2O2, perborate or percarbonate. In (A)-(C), E = moiety (CRn)a-X-(CRn)a'; X = O, S, NR or P, or a covalent bond (especially covalent bond); for each E the sum of a + a' = 1-5 (especially 2 and 3); G = (CRn)b; R = H, alkyl, alkenyl, alkynyl, aryl, alkylaryl or heteroaryl or two or more are covalently bonded to form an aromatic or heteroaromatic, cycloalkyl or hetero-cycloalkyl ring; D = donor atom selected from N,O, S, or P, at least two D atoms are bridge-head donor atoms coordinated to the transition metal; b = C or D or cycloalkyl or heterocyclic ring; n = 1 or 2, completing the valence of C atoms to which R moieties are bonded; n' = 0 or 1 completing the valence of D donor atoms to which R moieties are bonded; n'' = 0,1 or 2 completing the valence of B atoms to which R moieties are bonded; a, a' = 0-5, where a + a' = 2 or 3, the sum of all a + sum of all a' in formula (I) being 7-12, the sum of all a + a' in formula (II) being 6-12 (especially 8), the sum of all a + a' in formula (III) being 8-15 (especially 10) and the sum of all a + a' in formula (IV) being 10-18 (especially 12); b = 0-9 (especially 0-5) or one or more of the (CRn)b moieties covalently bonded from any D to the B atom is absent as long as at least two (CRn)b covalently bond two of the D donor atoms to the B atom and the sum of all b is 1-5. In (D), R1 = H or 1-20C alkyl, alkenyl or alkynyl and all N atoms in the rings are coordinated with the transition metal.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4015697P | 1997-03-07 | 1997-03-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0001248A2 true HUP0001248A2 (en) | 2000-07-28 |
HUP0001248A3 HUP0001248A3 (en) | 2001-11-28 |
Family
ID=21909427
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0001248A HUP0001248A3 (en) | 1997-03-07 | 1998-03-06 | Bleach compositions containing metal bleach catalyst, and bleach activators and/or organic percarboxylic acids |
Country Status (1)
Country | Link |
---|---|
HU (1) | HUP0001248A3 (en) |
-
1998
- 1998-03-06 HU HU0001248A patent/HUP0001248A3/en unknown
Also Published As
Publication number | Publication date |
---|---|
HUP0001248A3 (en) | 2001-11-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD9A | Lapse of provisional protection due to non-payment of fees |