HRP980518A2 - Process of inactivation, immobilization and stabilization of solid material resulting from the processing of various residues - Google Patents

Description

The area where the invention is located

Solidifieds are products of physico-chemical processing of substances and substances, whose final product is characterized by the shape of its state as a dry powder, of greater or lesser density and granulation, and which mostly do not contain moisture or it is insignificant, in traces or not at all.

According to this invention, solidifieds, which are prepared for inerting, neutralization and immobilization refer to those solidifieds, which are created from the physical-chemical processing of materials containing hydrocarbons, that is, those that are created from other processing processes of organic-inorganic substances and substances , and with the aim of increasing their stability, reducing pollutants and toxic substances in the eluate and their transformation into a state of inactivity, non-melting, non-decomposition, i.e. immutability of properties and stable state for a very long period of time.

According to the International Classification of Patents (IPC), the invention belongs to the following areas: C 02; C 08; C 10; G 21 F, G; B 01 J; F 26 B.

Technical problem

Solidifieds usually have different features, characteristics and properties, by which they differ from each other and according to which they are identified as: a) solidifieds for use in further processing purposes in industry; b) solidified as processing products for use in further technological procedures; c) solidified as by-products of technological or physico-chemical processing procedures; d) solidified as final ecological products, which are previously reduced in toxicity, toxicity or harm to nature and the environment; e) solidifieds that represent a material component of further technological procedures, physico-chemical and mechanical treatments, and f) solidifieds for the preparation of utilization in technological processes or for utilization in construction, road construction, or g) for utilization in the field of obtaining technical protective materials for the construction of barriers against the aggressive and harmful effects of other materials (eg radionuclides), etc.

Solidifieds are very often subjected to further technological procedures or some other processing due to their inappropriate, non-technical and non-technological conditions, as very fine powders, due to their flammability in air, hygroscopicity, content of harmful elements above the maximum permissible concentrations (MDK), etc.

Most often, solidifieds are directly used in powder form as additions to processes, then packed in so-called yumbo-bags (1000 kg) or solidified by pressing into plates, blocks and briquettes; agglomerate or pelletize.

Some solidifieds are not favorable for agglomeration and pelletization, and some displace liquid fractions (mineral and other oils, water and gaseous contents) when pressed at high pressures (>20 MPa).

Most often, such squeezed contents of compacted solids are ecologically inappropriate, and represent a new technical, ecological and technological problem.

Certain types of solidifieds, which after compaction, even with very high pressures, still contain harmful substances, and which are determined by analysis according to a known test standard (melting in a 5% acetic acid solution, 24 hours of intensive mixing, longer standing and finally analyzing the contents eluate).

In order for the solidified, which is intended to be disposed of, for example, in a landfill (the first ecological aspect of the processing of substances and substances) to have the highest possible stability, and when analyzing the eluate to show an appropriate condition in accordance with the regulations on waste classification, it must be subjected to one of the procedures, which will to achieve an improved state of its quality.

As according to the categorization of waste, which is disposed of in communal and/or sanitary landfills, there are problems of securing the method and place of disposal, large differences in the price of such disposal, methods of transport, etc., in technical-technological, ecological and economic terms, its inertization, stabilization and immobilization becomes all the more significant and important than the processing of substances and substances through the solidification process.

According to this invention, the indicated technical problem is solved, so that the solidifieds resulting from the processing of waste oils and special waste (hydrocarbons), as well as the solidifieds resulting from the processing of other types of organic and inorganic materials, acquire the characteristics of a stable, inert and immobilized material, which can be disposed of in a municipal landfill allows its chemical composition, mechanical properties and eluate analysis.

In the practice of processing waste hydrocarbons by the solidification process, a special technical problem is the thermal state of the solidified when leaving the reactor, because at temperatures above 105°C it is difficult to subject it to compaction, while in powder form it has a very low rate of cooling in the air and disperses into the environment and at the slightest wind.

Also, if the solidifieds contain volatile parts or combustible substances, they will burn in a cluster with a small bluish flame for several days at a time.

State of the art

The author of this invention is aware that efforts have been made to solidify the solidified by means of electrofilter ash, mixing it with straw, clay or injectors with silicate types of liquid substances.

Some other procedures of inertization, neutralization and immobilization of solidified are not known to the author of this invention at the time of this application.

In oil and oil refineries, in the process of refining and derivation of oil and in the process of the formation of various waste oils, tar, oil sludge, tar and fuel oil and other sediments and sludges, oily substances, etc., they are mostly disposed of in large tank tanks, lagoons (ground surfaces with a clay substrate, i.e. so-called "black pits"), concrete pools or steel tanks and cisterns, and are left as such (most often in the open), where after longer periods of time, the lower parts of the mixture solidify by themselves due to the precipitation of heavy fractions, bituminize and thus forming solid homogeneous layers at the bottom. Such a method of strengthening is not a favorable ecological solution, and such material is still risky and ecologically inappropriate for nature and the environment, and cannot be transported, further industrially exploited, incinerated, or disposed of in landfills.

The disposal of such materials in standard tin barrels with a usual volume of about 200 liters results in the corrosive disintegration of the tin barrels and the leakage of dangerous material into nature and the environment.

Recommendations with the injection of some types of liquid silicates into solidifieds (or during the material solidification process itself) turned out to be an insufficiently safe, expensive and technologically complicated process, which did not find widespread use, nor would the author of this invention have noticed anywhere as an adopted practical solution.

Mixing with straw, clay, earth and ashes of electrofilters is an inappropriate way of ecological solution, because such a form not only maintained the existing condition, but also additionally polluted the basic material and led to new forms of environmental pollution.

Incineration of such materials did not gain a favorable foothold in the legislation and regulations on waste, and the proposal recommending it for cement plants, brick factories and heating plants was previously determined to be unacceptable, and therefore incineration is not widely used.

The technology of solidification using earth and clay (the so-called "GSF"-process, or the process according to Bölsing and others), in which some heavy fatty acids (oleic, stearic) were used in the solidification process, or such a mixture was mixed with clay and earth , created huge amounts of materials that could not be safely disposed of, so they are still standing today in many places inside oil and petroleum refineries, petrochemical industries and oil derivative product distribution facilities, occupying large areas and significant volumes of commercial or natural spaces.

With such final solidification of solidification products, the resulting solidified material cannot be used further, and its disposal is allowed only in sanitary landfills, which again presents environmental problems and requires an enormously high cost for the necessary rehabilitation of the terrain.

Solidifieds were most often left in open spaces, where they were dispersed into the environment by strong winds, and over time hardened by themselves, forming a solid upper crust. The volumes of such occupied surfaces are usually very large.

By pouring large amounts of soil on solidifieds (eg "Cedre", Brest, France), such areas were greened, usually by grassing with more resistant types of grass, which turned out to be possible, but not safe enough for the protection of nature and the environment.

As far as the author of this invention is aware, the application of any technology adopted in practice for the process of inertization, immobilization and stabilization of solidified in an ecological-economical and technical-technological way is not found in the current state of the art.

Presentation of the essence of the invention

Solidification of substances and substances is a process commonly referred to as procedures in which liquids solidify, thus becoming dry products of the process.

Solidification, according to this invention, is a process in which either a liquid, a solid, or some other aggregated intermediate state of the input material is transformed into a completely dry state by evaporation of water, which, on exiting the reactor, still has the process temperature at which the change occurred.

Adding binders to such a solidified for the purpose of pressing is related to the problem of temperature differences, so additives such as straw, textile fibers, jute or similar structures fall, burn and finally disappear in the solidified, which then returns to powder.

The temperature of solidifieds after its creation and after leaving the reactor is difficult or very difficult to lower in the air (28 - 48°C per day), so there is a problem of very long time differences from the time of leaving the solidified to reaching the ambient temperature at which the pressing of the solidified can be done. perform successfully. Since solidifieds differ from each other in terms of their properties, depending on the materials they are made of and the way the solidification process is conducted, this application will describe the procedures for its inertization, immobilization and stabilization.

Solidifieds resulting from the processing of waste oils and special waste (hydrocarbons), which have already been previously reported to the State Institute for Intellectual Property of the Republic of Croatia, in applications by the same author, namely: P 940323 N (P 1279/86) P 940326 (P 578/90), P 940325 (P 2123/87), P 940324 (P 950/88), P 970498, P 970177 A, P 980049 A, P 970530 A and P 931506 have the characteristic of a dry and fine hydrophobic powder at the exit temperature from the process 105 - 130°C.

The retained internal calorific value of the solidified (from 5 to >20 MJ/kg) is reflected by its high heat and standing temperature for a relatively long period of time (3-5 days), although the solidified does not burn.

With the technical solution according to this application, such a solidified, and due to its excellent properties after leaving the reactor, and with its high exit temperature from the process, is passed through a tunnel on a belt conveyor, where it is cooled in the air stream, by spraying cold water mist, so when the solidified reaches a temperature of about 55°C after the solidification process is completed, then the granulate, which by its composition is a mixture of crushed glass and quartz sand, is dispersed uniformly.

After exiting the tunnel, the length of which depends on the processing capacity, such solidified is cooled to approximately outside temperature and subjected to pressing into blocks or briquettes.

Its retained internal caloric heat is spent on the absorption of the added granulate and finally stabilizes into a solid piece block, which no longer disintegrates during handling, nor when falling on solid ground or being rammed one on top of another.

After a few days, such a block shows very high strength and hardness, and almost completely inerts and immobilizes its contents.

In order to better explain the method of implementation of the hardening procedure and the essence of the formation of the stability of the structure of the solidified, which after that behaves highly resistant to impact and wear, acquires a better ability to compact and inertize, while the degree of purity of its content increases significantly when analyzing the quality of the eluate, in the future explain in more detail in the description.

In the further use of this solidified for the purpose of producing hydrophobic plates and blocks (garden substrates, forest and paths of parks and squares, plates and tiles for field insulation, coverings, coverings and the like), various metal and other fibers for mechanical connecting the solidified.

Due to the use of solidified for the purpose of making special waterproof boards or building technical barriers for the purpose of protection against the effects of poisonous, toxic, dangerous and radioactive materials, granulate, which contains powders, threads and fibers in addition to crushed glass and quartz sand, is also supplemented with heavy metal shavings, such as: lead, Pb; chromium Cr; Iron, Fe; Manganese, Mn; Wolfram, W; Vanadium, V; Nikal, Ni et al.

In the case of solidifieds created from organic sludge (sludge from wastewater treatment plants, oil sludge, oily bilge water, oily soil and mud), semi-dry cement mixture is added to the addition of granulates based on glass and quartz sand, which is evenly applied by spraying dry cement in a water mist. on the surface of solidified moving on a belt conveyor in a closed tunnel.

Solidifieds that were created by the processing of organic types of waste from the composition of special waste, and which are not characterized by a high temperature of the outgoing solidified, but rather a very high temperature of the solidified in the accumulation (due to the subsequent specific combustion of its mixed content of substances, which burn at temperatures above 120°C) they add increased contents of glass granules and quartz sand of higher granulation.

In addition to quartz sand, natural gravel is added to the solidifieds resulting from the processing of soil masses contaminated with pesticides (DDT, fungicides, herbicides, organic phosphorus and carbaimides, chlorinated hydrocarbons, acaricides, nematocides, rodenticides, limacides) in order to obtain a geo-composite with high compaction strength.

The purpose of such additives is to build a stable structure of the solidified mixture in which the process of absorption and removal of heat is realized, the formation of silicate crusts in the entire cross-section of the pressed block, and obtaining its strength and hardness with a tough core.

The internal heat of the solidified binds the remaining calcium, which, when obtaining the solidified according to this invention, is always in excess of the added granulate, forming complex silicate-calcium compounds, which have a higher degree of stability than the pure solidified and which then actively participate in the process until the complete polymerization of the total content.

In the sequence of the polymerization process, which directly affects the realization of the conditions of inertization of the composition of the entire compacted block, the goal was achieved, for which patent protection is requested according to this application.

Brief description of the drawing

The accompanying drawings, which are included in the description and form part of the description of the invention, illustrate the best mode of carrying out the invention thus far considered and assist in explaining the basic principles of the invention.

Figure 1 shows the block diagram of the plant for the implementation of the process of neutralization, ironobilization and solidification stabilization.

Figure 2 shows a vertical section of the tunnel for adding water mist mixed with granulate of crushed additives.

Figure 3 shows the compressed solidified in the form of a flat plate (or surface).

Figure 4 shows a compressed solidified in the form of a flat plate with a fibrous structure.

Figure 5 shows the solidified in the form of roller briquettes.

Figure 6 shows the solidified in the form of a cube.

Figure 7 shows the solidified in the form of a hollow cylinder (or tube).

Figure 1 shows the path of solidified 2 from the processing reactor 4, which falls on the belt conveyor 10 as hot powder. In order to cool it down to about 55°C, it is passed through a tunnel channel 8, above which is placed a double-clad overhang 6, through which cold water flows as a heat exchanger. The dosing system of additives that affect the polyinerization of the solidified is supplied with chambers A, B, C, D and E from which these additives are passed onto the solidified. With a press 12, such roe is compacted into blocks, and then they are taken by belt conveyor 14 into a container for shipping or storage.

The section above the tunnel space is shown in Figure 2, where the solidified 2 moves through the tunnel channel 8 by belt conveyor 10, and in chambers A/B, C, D and E there are additions for polymerization. By opening the shut-off valves in the double shell 6 of the tunnel 8, which is performed by automatic control from the control device, the speed and quantity of adding certain types of additives is determined, while the extraction of water vapor is performed by suction pumps at the openings 20.

Figures 3, 4, 5, 6 and 7 show some of the usual forms of press that can be obtained from the cooled solidified with appropriate binders, and according to the possible choice of press pressure.

Favorable pressures range from 5 to 15 Mpa.

Thus, it is possible to form flat panels according to Figure 3, that is, to create individual layers when laying the waterproofing carpet on the ground. Such layers can be from ≈ 200 mm up to 1,000 mm thick, where watertightness is achieved at the level of < 2-10-9 m/s. Thicker panels, according to Figure 4, are formed by installing mesh reinforcements 24 and their dimensions can be over 500 x 500 x 1000 mm.

Roller briquettes, according to Figure 5. They can be pressed in dimensions from ø 60 x 30 mm to ø 600 x 150 mm, and with the installation of a reinforcing mesh, they can also be pressed beyond these dimensions.

Square blocks of larger dimensions, according to Figure 6, resemble standard types, for example, as with concrete blocks (400 x 300 x 200 mm), which can be pressed with or without reinforcement 26, while with stronger mesh reinforcement these blocks can have dimensions of over 1000x1000 x 1000 mm

Shaped pieces, blanks and profiles, according to Figure 7, usually depend on the molds in which they are formed and where sufficient press pressures can be produced, so pipes can be produced from Ø 100 to Ø 1000 mm, and even more, and the length of such profiles it will depend on the moulds, number, quality and types of mesh reinforcements.

A detailed description of at least one way of realizing the invention

In the following description, every detail of the realization of the invention will be fully explained, one example of which is illustrated by the accompanying drawings.

Based on the insight into pictures 1 and 2, the method of cooling the solidified in a forced stream of cold air, which is achieved by the compressor-fan from the perforated wall 22 of the cover of the belt conveyor, is explained.

According to this patent application, a subcooler with recirculating water from the pool is used as a permanent heat exchanger. The pool is also constantly replaced with running cold water from any source as needed, especially during long-term operation.

By means of a large number of openings 22 located in the lower part of the arch with a double jacket 6 above the cover of the belt conveyor 10, additives A, B, C, D and E intended for uniform mixing with the solidified 2, which moves on the conveyor belt, are passed in the air stream 10.

The thickness of the solidified layer 2 on the conveyor 10 depends on the processing capacity and the width of the belt. The most favorable thickness of the solidified layer on the belt is about 5-6 mm, but at most 10 - 12 mm, which is adjusted by properly dimensioning the width of the belt and the speed of movement, so for for processing capacities < 5 m3/h, the belt conveyor with a belt width of about 500 mm and a speed of its movement of about 1 m/s should be advantageous.

With a processing capacity of 15-20 m3/h, such a belt conveyor must have a width of about 700 mm and a movement speed of about 2 - 4 m/s.

Very large processing capacities, for example around or > 50 m3/h of solidified, require special tunnel constructions with a belt conveyor, so for economic reasons it is best to distribute this amount of solidified in two output lanes of 25 m3/h each and in two tunnels of equal length.

The amount of additives A, B, C, D and E is variable and depends on many factors such as: the type of processing material from which the solidified was created, the exit temperature of the solidified, the cooling rate of the solidified, the purpose for which the solidified or its pressed form will be finally use etc.

For the average type of processing materials that have hydrocarbons and whose content is at the level of 20 - 30 vol % or greater than 30 vol % and less than 40 vol %, and with the aim of obtaining a solidified which will be disposed of as an inert material at a municipal landfill, the contents additives for good inertization amount to:

- 2 min of additions for every 6 mm of solidified thickness across the width of the strip, which for a strip of any width is an addition with a proportion of 33 vol %.

By uniformly distributing additives with a share of 33 vol%, it is distributed according to the ratio: about 65vol% of crushed glass additives and about 35vol% of quartz sand.

The water mist will be created by the condensation of subcooling air in the stream with water vapor released by the solidified, and then spread equally along the width of the strip with additives.

When obtaining a solidified which, after compaction, will be used as a waterproofing agent (hydro panels and blocks), it is best to subject it to as good cooling as possible and add) about 30 vol % of quartz sand, about 30 vol % of crushed glass, about 30 vol % of hard binder granules and about 10 vol % of cement powder.

As a binder for reinforcing larger panels, it is preferable to place mesh reinforcement or similar long binder threads in the press, which have the necessary resistance at the actual solidification temperatures during pressing.

In the case of solidifieds resulting from the processing of various substances containing heavy metal oxides (e.g. incinerator ash or metal shavings and grinding dust with emulsions), especially when the pressed solidified is intended to be used for the purpose of building protective technical barriers against the effects of toxic, dangerous, toxic and radioactive materials, such a solidified is cooled to a temperature of <55°C in a water mist with a forced flow of cold air, and metal dust containing lead, manganese, chromium, zinc, iron, etc. is added to it, and finally compacted into briquettes (eg Ø 60 x 30 mm).

Press pressures for briquetting solidifieds range between 5 and 15 MPa, with lower pressures being used for solidifieds that will later be used by kneading or shredding, and higher pressures for solidifieds that will be used as slabs or blocks. .

The length of the tunnel 8, in which the solidified from the reactor moves and cools, is dimensioned according to the temperature of the solidified and the amount of water vapor that will be released from the solidified on the belt conveyor 10.

It is best to use tunnels that have as much height as possible, and at least about 450 mm from the lane level.

With a processing capacity of about or < 5 m3/h, the best results of inertization, immobilization and stabilization of solids are achieved with tunnels whose height is about 500 - 600 mm, and with a capacity of about or >25 m3/h, the optimal tunnel height is about or >1000 mm.

Method of application of the invention

This invention, which is used for cooling the solidified, resulting from the processing of various types of waste materials containing hydrocarbons, and the implementation of its inertization, immobilization and stabilization, is applied according to the technical-technological solution presented in this application.

The proposed method of application of this invention and the technical solution that will achieve inertization, immobilization and stabilization of the solidified is reduced to the addition of certain additives and a mixture of additives, which consist of crushed glass, quartz sand, various fibers, brick dust, heavy metal oxide powders, cement powder, reinforcing fibers and similar binding materials under the conditions of creating a water mist in an even application to the solidified, which moves along the conveyor belt and which is cooled in the forced air flow by the exchanger in the recirculating water flow system.

The tabular representation will show the recommended content of additives and the conditions in which the best results of inertization, immobilization, stabilization and polymerization of certain types of solidified will be achieved.

[image]

Table 1.

If it happens that after drying for some time the scraps become loose, then for this type of solidified it is necessary to change the parameters of additives in favor of binding types and reinforcing fibers, and in particular to determine a more appropriate compaction force.

Optimum conditions are achieved in the tunnel, when the flow will be in conditions of relative air humidity of about 77-88%, whereby the additives are evenly distributed on the surface of the strip with solidified, and the solidified compaction pressures take place at the level of ≈10 MPa.

If the solidified is to be pressed into plates of larger dimensions, then it is necessary to place in the press a mesh reinforcement made of material resistant to the temperature at which the solidified is located (networked strands of hard densely woven wire mesh, etc.).

Briquetting of solidified into cylindrical smaller shapes (eg Ø 60 x 30 mm) should be used with solidified which is intended, for example, for the construction of waterproofing layers in civil engineering, in which case they will be crushed on the ground mixed with construction gravel, usually below the level of asphalt or concrete . In fact, such a solidified does not need special additives if its quality is high and, according to the analysis, it does not release oil, nor does it have illegal contents of certain elements and compounds, which would adversely affect the classification of the eluate (maximum permissible concentrations of tested substances: MDK). In order to create the greatest possible inertness of the solidified, quartz sand and crushed glass are added to it in a fixed ratio and a defined total amount. The quality of the glass used when adding to the solidify is not particularly important. The glass can be white, colored or mixed, and the granulation is determined according to the final purpose of utilizing the solidified spray.

For larger dimensions of solidified blocks, a larger glass granulation (about 4-15 mm) is preferable, while for smaller plates, blocks and briquettes, a lower granulation is used (about 2-4 mm). Quartz sand is the usual silicate sand, which has different granulations, and in practice it has been shown that the one with a granulation of 2-3 mm is the most favorable for mixing and good absorption. Lower temperatures when mixing the indicated additives than 55°C have an unfavorable effect on the formation of hard crusts created from calcium-silicate compounds, which encourage polymerization and stabilization of the entire structure of the compacted solidified, and temperatures above 70°C lead to too fast absorption and loss of mixing effects, and disintegrate during cooling in the air and change to the initial powdery state.

Depending on the compaction force of the solidified, it will harden faster or slower or crumble into powder, so the most favorable pressures are those of around 10 MPa. When obtaining highly hydrophobic sprays, this pressure can be higher, but a maximum of 15 MPa, because above it the so-called squeezing and "sweating" of the solidified.

Such solidifieds are practically impermeable and have a coefficient of waterproofness at the level of 1-10-9 < κ ν < 2-10-9 m/s, and density at the level of 935 < δ< 975 [kg/m3].

Solidifieds intended for the construction of technical protective barriers have several times higher density: 1124<δ < 1311 [kg/m3], due to the presence of a higher proportion of heavy metal content.

Claims (17)

1. The procedure of inertization, immobilization and stabilization of the solidified obtained from the processing of various types of waste, characterized by the fact that the cooling of the solidified leaving the process reactor is carried out using the flow of cold and moist air over a conveyor belt in a tunnel covered with a double jacket, from a temperature of ≈115° C to level temperature ≈ 45° C. 2. The method according to claim 1, indicated by the fact that additives based on crushed glass and quartz sand are added to the subcooled solidified in the forced air flow, which flows in the double shell of the tunnel, which, in contact with calcium from the solidified, create conditions for the formation of complex silicate-calcium compounds and which, under the conditions of maintained internal calorific value of the solidified, form the conditions of stabilization and polymerization of the solidified. 3. The process according to claims 1-2, indicated by the fact that the structure of the solidified is changed from a free dry and loose powder to a structure composed of compounds with higher properties of inertness and stability, by creating layers of solid crusts in a section of the compacted solidified. 4. The method according to claims 1-3, characterized by the fact that the introduction of cold and moist air is ensured by recirculation of water through the heat exchanger in the double shell of the tunnel, whereby condensed water vapor appears in the air flow due to the temperature difference between the pipeline and the water vapor of the solidified and in which additives based on crushed glass, quartz sand, mechanical fibers, cement powder, heavy metal oxide powder, and stone and coal dust are added in a uniform flow. 5. The process according to claims 1-4, characterized by the fact that the contents of additives according to claim 4 are placed in the solidified in the process of its cooling and moistening, and thus the quality of the solidified suitable for use in construction as a waterproofing material is achieved, for the purpose of building protective technical barrier, for energy purposes or for the purpose of technological additions to a large number of industrial processes. 6. Process according to claims 1-5, characterized by the fact that additives based on crushed glass and quartz sand act on the thermodynamic process of absorption in the structure of the powdery solidified, and by compacting such a solidified, an internal reaction is realized due to the retained heat of the solidified before its final cooling to the ambient temperature . 7. Process according to claims 1-6, characterized by the fact that the solidified is compacted upon exiting the tunnel with pressures between 5 and 15 MPa, whereby briquettes, slabs and blocks of different dimensions of increased density, strength and hardness are obtained. 8. The method according to claims 1-7, characterized by the fact that the solidified that has passed through the tunnel and after compacting, in addition to its volume reduced several times, has the inert properties of a solidly polymerized material, which no longer contains harmful substances in the eluate, even though they are present as solidified in powder contained, and that its stability and resistance to atmospheric conditions, external influences, impact and breakage have significantly increased. 9. The process according to claims 1-8, characterized by the fact that the solidified stabilization process is carried out just as well with solidifieds resulting from the process of treating oily pollution with hydrocarbons as with other organic and inorganic waste materials, whereby the pressed solidified obtained is inert, stable and suitable for further industrial exploitation. 10. The process according to claims 1-9, characterized by the fact that inertization and stabilization is equally successfully carried out on solidifieds obtained during the processing of waste by filtration of substances from purification systems and other similar industrial purifiers, whereby the solidified is stabilized in tunnel subcooling with the addition of powdered materials made of brick, cement and sand, as well as their mixtures with the addition of crushed glass. 11. The process according to claims 1-10, indicated that such a process is carried out on solidifieds obtained during the processing of waste materials and substances contaminated with pesticides (fungicides, herbicides, organic phosphorus and carbamates, chlorinated hydrocarbons, acaricides, nematocides, rodenticides, limicides, etc. .). 12. The process according to claims 1-11, characterized by the fact that such a process is carried out on solidifieds obtained during the processing of low and medium radioactive materials, whereby stabilization, inertization and immobilization is possible in a protected closed tunnel space with the addition of heavy metal oxide powders of which especially: lead (Pb), chromium (Cr), manganese (Mn), nickel (Ni) and iron (Fe), as well as a mixture based on cement and crushed glass, and when pressing they use pressures between 13 and 17 MPa. 13. The process according to requirements 1-12, indicated that such a process is carried out on solidifieds obtained during the processing of organic types of waste from municipal and industrial sources where, in the absence of hydrocarbons, they are added to the process up to 15 vol % of their content, and during subcooling in powders based on crushed glass and sand are added to the tunnel in a ratio of 1:1, and the formation of blocks is achieved by compacting the solidified at pressures of 8-12 MPa. 14. The process according to claims 1-13, characterized by the fact that such a process is carried out on solidifieds formed during the processing of incinerator ash, pyrolysis, incineration and combustion, electrofiltration or other forms of its formation, with the fact that in the tunnel subcooling of the solidified, an excess of the addition of silicate sands is realized , and the additions of crushed glass and cement powder equalize the volume at temperatures between 60 and 75° C, and when pressing they apply pressures at the level of 12 MPa. 15. The process according to claims 1-14, characterized by the fact that such a process is carried out on solidifieds formed during the processing of asbestos, its types and subtypes, whereby mixtures of cement powder, brick and coal dust are added in the tunnel undercooling in an equal ratio with the amount of added silicate sands , with the fact that the total volume of additives to the solidified is 1:1.5, and briquette compaction pressures range from 7 - 14 MPa. 16. The process according to claims 1-15, characterized by the fact that the stabilized solidifieds are used as polymerized and solid products for general construction purposes, in road construction, as a waterproofing material, as an additive for mixing in asphalt, and in the construction of technical protective barriers against the influence of dangerous , poisonous, toxic and radioactive materials. 17. The procedure according to requirements 1-16, indicated by the fact that it is carried out in a safe manner, without harmful effects on people, nature and the environment, and that the entire procedure, as well as all parts of the technological process, is carried out ecologically and technologically reliably, and appropriate to the standards and regulations determined in that sphere of activity.