GR32442B - METHOD OF PREPARATION OF NEW BASIC ETHERS. - Google Patents
METHOD OF PREPARATION OF NEW BASIC ETHERS.Info
- Publication number
- GR32442B GR32442B GR670132442A GR670132442A GR32442B GR 32442 B GR32442 B GR 32442B GR 670132442 A GR670132442 A GR 670132442A GR 670132442 A GR670132442 A GR 670132442A GR 32442 B GR32442 B GR 32442B
- Authority
- GR
- Greece
- Prior art keywords
- preparation
- alkali metal
- new basic
- basic ethers
- salts
- Prior art date
Links
- 150000002170 ethers Chemical class 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 150000001339 alkali metal compounds Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- -1 aminoethyl halides Chemical class 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
- C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C217/48—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being unsaturated and containing rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
έθοδος διά την παρασκευήν νέων βασικών αιθέρων του γενικού τύπου (Ι) είς τον οποιον R είναι κατωτέρα ομάς αλκυλιου και R1 αλκύλιον ή ριζα αλκυλίου ή αρυλαλκυλίου τά άλατα αυτών χαρακτηριζομένη έκ τουότι βενζυδρυλαιθήρ τουγενικού τύπου (ΙΙ), είς τονοποίον R καθορίζεται ως ανωτερω, αντιδρά, εντός υγράς αμμωνίας ώς διαλυτικού μένου, μετ' ενώσεων αλκαλιμετάλλων ώς αλκαλιαμιδών ή αλκαλιμεταλλοργανικών ενώσεω έν συνεχεία δέ αντιδράσεως της δημιουργουμένης ενώσεως του τύπου (ΙΙΙ) είς τον οποίον Me είναι ατομον αλκαλιμετάλλου και R καθορίζεται ώς ανωτέρω επίσης εντός υγράς αμμωνίας, μετά είς την Ν θέσιν υποκατεστημέων αμυνοαιθυλοαλογονιδίων του γενικού τύπου (VI) είς τον οποίον Hal σημαίνει άτομον αλογόνου και R1 καθορίζεται ώς ανωτέρω ή μετά των αλάτων αυτού, και δημιουργίας έκ των λαμβανομένων ενώσεων είτε των αλάτων των είτε βάσεων έκ των αλάτων αυτών. A process for the preparation of new basic ethers of general formula (I) in which R is a lower alkyl group and R 1 is alkyl or an alkyl or arylalkyl radical thereof, characterized in that benzydryl ether of type (II) is defined as R , in liquid ammonia as a solvent, with alkali metal compounds such as alkaliamides or alkali metal compounds then reacting with the resulting compound of formula (III) in which Me is an alkali metal atom and R is defined as above also in liquid N Position of substituted aminoethyl halides of general formula (VI) wherein Hal denotes a halogen atom and R1 is defined as above or after its salts, and is formed from the resulting compounds or salts or bases thereof.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT429366A AT264501B (en) | 1966-05-06 | 1966-05-06 | Process for the production of new basic ethers and their salts |
Publications (1)
Publication Number | Publication Date |
---|---|
GR32442B true GR32442B (en) | 1967-07-04 |
Family
ID=3562127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GR670132442A GR32442B (en) | 1966-05-06 | 1967-03-21 | METHOD OF PREPARATION OF NEW BASIC ETHERS. |
Country Status (8)
Country | Link |
---|---|
AT (1) | AT264501B (en) |
CH (1) | CH480293A (en) |
DK (1) | DK115707B (en) |
ES (1) | ES338752A1 (en) |
FI (1) | FI44803C (en) |
GR (1) | GR32442B (en) |
SE (1) | SE350027B (en) |
YU (1) | YU32072B (en) |
-
1966
- 1966-05-06 AT AT429366A patent/AT264501B/en active
-
1967
- 1967-03-21 GR GR670132442A patent/GR32442B/en unknown
- 1967-03-31 ES ES338752A patent/ES338752A1/en not_active Expired
- 1967-04-10 CH CH502267A patent/CH480293A/en not_active IP Right Cessation
- 1967-04-16 YU YU0680/67A patent/YU32072B/en unknown
- 1967-04-27 SE SE05981/67A patent/SE350027B/xx unknown
- 1967-05-05 DK DK237367AA patent/DK115707B/en unknown
- 1967-05-05 FI FI671295A patent/FI44803C/en active
Also Published As
Publication number | Publication date |
---|---|
YU32072B (en) | 1974-04-30 |
SE350027B (en) | 1972-10-16 |
ES338752A1 (en) | 1968-04-01 |
FI44803C (en) | 1972-01-10 |
FI44803B (en) | 1971-09-30 |
AT264501B (en) | 1968-09-10 |
CH480293A (en) | 1969-10-31 |
YU68067A (en) | 1973-10-31 |
DK115707B (en) | 1969-11-03 |
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