GB991085A - Improvements in or relating to the production of unsaturated aliphatic aldehydes - Google Patents

Improvements in or relating to the production of unsaturated aliphatic aldehydes

Info

Publication number
GB991085A
GB991085A GB23157/63A GB2315763A GB991085A GB 991085 A GB991085 A GB 991085A GB 23157/63 A GB23157/63 A GB 23157/63A GB 2315763 A GB2315763 A GB 2315763A GB 991085 A GB991085 A GB 991085A
Authority
GB
United Kingdom
Prior art keywords
oxide
antimony
catalyst
molecular oxygen
isobutene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23157/63A
Inventor
Wilhelmus Teunis Van Der Meer
Barry Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Distillers Co Yeast Ltd
Distillers Co Ltd
Original Assignee
Distillers Co Yeast Ltd
Distillers Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Distillers Co Yeast Ltd, Distillers Co Ltd filed Critical Distillers Co Yeast Ltd
Priority to GB23157/63A priority Critical patent/GB991085A/en
Priority to DE19641693078D priority patent/DE1693078B1/en
Priority to DE1964D0050315 priority patent/DE1568390B1/en
Priority to NL6406548A priority patent/NL6406548A/xx
Priority to FR977888A priority patent/FR1410247A/en
Publication of GB991085A publication Critical patent/GB991085A/en
Priority to JP41012102A priority patent/JPS4816490B1/ja
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0573—Selenium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6445—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Acrolein is made by reacting at elevated temperature in the vapour phase propylene or isobutene with molecular oxygen over an oxidation catalyst comprising antimony oxide combined with or admixed with an oxide of V, Cr, Mn, Fe, Ni, Zn, Ga, Ge, Se, Rb, Y, Nb, Ru, Rh, Pd, In, Os, Ir and/or U. The catalyst (see Division B1) may be on a support, especially silica or alumina. The reaction feed may contain 1 to 20% by volume of olefin, 1 to 20% oxygen and may also contain an inert diluent. Listed diluents include nitrogen, propane, butane, isobutane, carbon dioxide and steam. The reaction temperature of 250 DEG to 550 DEG C. is advantageous. The aldehyde may be recovered by countercurrent extraction with water at a pH at or below 7 followed by fractional distillation of the product. The examples include details of catalyst preparation.ALSO:Catalysts suitable for oxidation of propylene or isobutene in the vapour phase with molecular oxygen (see Division C2) comprise antimony oxide in combination or admixture with an oxide of V, Cr, Mn, Fe, Ni, Zn, Ga, Ge, Se, Rb, Y, Nb, Ru, Rh, Pd, In, Os, Ir, and/or U. The catalyst, which may be supported e.g. on silica or alumina and may be heated, in molecular oxygen prior to use, at between 400 DEG C. and 1000 DEG C. may be produced by an admixture of antimony oxide, especially the hydrated oxide ex metal and nitric acid, with an oxide or hydroxide of one of the specified metals, or by coprecipitation from aqueous solution or suspensions of salts of antimony and one of the other specified metals. In the examples the preparation of catalysts comprising antimony and Fe, U, Ni, V, Cr, Zn, In, is described.
GB23157/63A 1963-06-11 1963-06-11 Improvements in or relating to the production of unsaturated aliphatic aldehydes Expired GB991085A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB23157/63A GB991085A (en) 1963-06-11 1963-06-11 Improvements in or relating to the production of unsaturated aliphatic aldehydes
DE19641693078D DE1693078B1 (en) 1963-06-11 1964-05-20 Process for the production of acrolein or methacrolein from propylene or isobutene
DE1964D0050315 DE1568390B1 (en) 1963-06-11 1964-05-20 Process for the production of acrolein or methycrolein
NL6406548A NL6406548A (en) 1963-06-11 1964-06-10
FR977888A FR1410247A (en) 1963-06-11 1964-06-11 Improvements in the production of unsaturated aliphatic aldehydes
JP41012102A JPS4816490B1 (en) 1963-06-11 1966-03-01

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB23157/63A GB991085A (en) 1963-06-11 1963-06-11 Improvements in or relating to the production of unsaturated aliphatic aldehydes

Publications (1)

Publication Number Publication Date
GB991085A true GB991085A (en) 1965-05-05

Family

ID=10191087

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23157/63A Expired GB991085A (en) 1963-06-11 1963-06-11 Improvements in or relating to the production of unsaturated aliphatic aldehydes

Country Status (5)

Country Link
JP (1) JPS4816490B1 (en)
DE (2) DE1568390B1 (en)
FR (1) FR1410247A (en)
GB (1) GB991085A (en)
NL (1) NL6406548A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3933751A (en) * 1967-05-15 1976-01-20 The Standard Oil Company Promoted catalysts for the oxidation of olefins

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1137427B (en) * 1962-10-04 Knapsack Ag Process for the production of acrolein
BE607864A (en) * 1959-02-17
FR1272358A (en) * 1960-10-28 1961-09-22 Shell Int Research Improvements in hydrocarbon oxidation processes
DE1177628B (en) * 1961-03-06 1964-09-10 Stamicarbon N. V., Heerlen (Niederlande) Process for the production of acrolein or methakrolein by the catalytic oxidation of propylene or isobutylene.
GB971952A (en) * 1961-05-29 1964-10-07 Shell Int Research Process for the production of alpha,beta-unsaturated aldehydes
FR1290737A (en) * 1961-06-02 1962-04-13 Ruhrchemie Ag Process for preparing unsaturated aliphatic aldehydes, especially acrolein
FR1293960A (en) * 1961-06-30 1962-05-18 Edison Soc Process for the production of oxygenates by direct catalytic oxidation of lower olefins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3933751A (en) * 1967-05-15 1976-01-20 The Standard Oil Company Promoted catalysts for the oxidation of olefins

Also Published As

Publication number Publication date
DE1568390B1 (en) 1971-12-02
JPS4816490B1 (en) 1973-05-22
DE1693078B1 (en) 1971-12-09
NL6406548A (en) 1964-12-14
FR1410247A (en) 1965-09-10

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