GB985615A - Polyvinyl chloride resin stabilisers and resin compositions stabilised for use in food packaging - Google Patents

Polyvinyl chloride resin stabilisers and resin compositions stabilised for use in food packaging

Info

Publication number
GB985615A
GB985615A GB28444/63A GB2844463A GB985615A GB 985615 A GB985615 A GB 985615A GB 28444/63 A GB28444/63 A GB 28444/63A GB 2844463 A GB2844463 A GB 2844463A GB 985615 A GB985615 A GB 985615A
Authority
GB
United Kingdom
Prior art keywords
zinc
mannitol
fatty acid
acid salts
magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28444/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Argus Chemical NV
Argus Chemical Corp
Original Assignee
Argus Chemical NV
Argus Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Argus Chemical NV, Argus Chemical Corp filed Critical Argus Chemical NV
Publication of GB985615A publication Critical patent/GB985615A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098Metal salts of carboxylic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Compositions comprise a vinyl chloride polymer resin and a stabilizer composition comprising a mixture of magnesium and zinc salts of benzoic acid and/or fatty acids derived from edible fats and oils, and a non-toxic polyhydric alcohol, in the proportion of 25 to 40 parts by weight of zinc salt, 25 to 40 parts by weight of magnesium salt and 20 to 50 parts by weight of polyhydric alcohol. The resin may be polyvinyl chloride, chlorinated polyvinyl chloride, copolymers of vinyl chloride with vinyl acetate, maleic of fumaric acids or esters, or styrene, or mixtures of polyvinyl chloride with chlorinated polyethylene or copolymers of acrylonitrile, butadiene and styrene. The fatty acids may be derived from tallow, lard, or sardine, olive, coconut, cottonseed, soyabean, corn or peanut oils. Specified polyhydric alcohols are mannitol, sorbitol, glycerol and pentaerythritol. The compositions may also comprise non-toxic antioxidants and conventional plasticizers, e.g. dioctyl phthalate, octyl diphenyl phosphate and epoxidized soya bean oil. Examples describe compositions comprising polyvinyl chloride and (1) magnesium benzoate, zinc tallow fatty acid salts and mannitol, (3) magnesium benzoate, zinc tallow fatty acid salts and glycerol, (4) magnesium and zinc tallow fatty acid salts and mannitol, (5) magnesium benzoate, zinc tallow fatty acid salts and sorbitol, (6) magnesium benzoate, zinc tallow fatty acid salts and pentaerythritol, (7) magnesium benzoate, zinc tallow fatty acid salts, mannitol and 2,6-d-t. -butyl-4-methylphenol, 4,41-methylene bis-(2,6-di-t. -butylphenol) or 4,41-thio-bis-(2-t.-butyl-5-methylphenol), (8) magnesium benzoate, zinc tallow fatty acid salts, mannitol and 2,6-di-t. -butyl-4-methylphenol, (9) magnesium coconut fatty acid salts, zinc benzoate and mannitol, (10) magnesium and zinc corn oil fatty acid salts and mannitol, (11) magnesium benzoate, zinc tallow fatty acid salts, mannitol, dioctyl phthalate, epoxidized soya bean oil and 2,6-t. -butyl-4-methylphenol, (12) magnesium benzoate, zinc hydrogenated peanut fatty acid salts and mannitol, (13) magnesium benzoate, zinc hydrogenated cottonseed fatty acid salts and mannitol, (16) magnesium benzoate, zinc olive oil fatty acid salts and mannitol, (17) magnesium benzoate, zinc salts of lard fatty acids and mannitol, and (18) magnesium benzoate, zinc sardine oil fatty acid salts and mannitol; a vinyl chloride-vinyl acetate copolymer and (2) magnesium benzoate, zinc tallow fatty acid salts and mannitol; blends of polyvinyl chloride with an acrylonitrile-butadiene-styrene copolymer, a butadiene-methacrylic ester graft copolymer or chlorinated polyethylene and (14) magnesium benzoate, zinc salts of tallow fatty acids, mannitol and 2,6-di-t.-butyl-4-methylphenol; and chlorinated polyvinyl chloride and (15) magnesium benzoate, zinc tallow fatty acid salts, mannitol and 2,6-di-t. -butyl-4-methylphenol. The compositions may be used in the manufacture of food packaging materials. Specification 983,288 is referred to.
GB28444/63A 1962-07-23 1963-07-18 Polyvinyl chloride resin stabilisers and resin compositions stabilised for use in food packaging Expired GB985615A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US21187762A 1962-07-23 1962-07-23

Publications (1)

Publication Number Publication Date
GB985615A true GB985615A (en) 1965-03-10

Family

ID=22788647

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28444/63A Expired GB985615A (en) 1962-07-23 1963-07-18 Polyvinyl chloride resin stabilisers and resin compositions stabilised for use in food packaging

Country Status (7)

Country Link
AT (1) AT250025B (en)
BE (1) BE635264A (en)
CH (1) CH433726A (en)
DE (1) DE1569372B1 (en)
ES (1) ES289596A1 (en)
GB (1) GB985615A (en)
NL (2) NL128715C (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3077173B2 (en) * 1990-07-09 2000-08-14 住友化学工業株式会社 Surface matte products

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL121885C (en) * 1960-03-15

Also Published As

Publication number Publication date
ES289596A1 (en) 1963-12-01
BE635264A (en)
CH433726A (en) 1967-04-15
AT250025B (en) 1966-10-25
NL128715C (en)
NL295565A (en)
DE1569372B1 (en) 1971-04-01

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