GB981931A - Heat hardenable resinous composition - Google Patents

Heat hardenable resinous composition

Info

Publication number
GB981931A
GB981931A GB3749461A GB3749461A GB981931A GB 981931 A GB981931 A GB 981931A GB 3749461 A GB3749461 A GB 3749461A GB 3749461 A GB3749461 A GB 3749461A GB 981931 A GB981931 A GB 981931A
Authority
GB
United Kingdom
Prior art keywords
interpolymer
resins
hydrogen
butadiene resin
amide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3749461A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
Pittsburgh Plate Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pittsburgh Plate Glass Co filed Critical Pittsburgh Plate Glass Co
Publication of GB981931A publication Critical patent/GB981931A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D157/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
    • C09D157/12—Homopolymers or copolymers containing elements other than carbon and hydrogen containing nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters

Abstract

A heat hardenable resinous composition comprises a butadiene resin and an interpolymer of an unsaturated carboxylic acid amide with at least one other monomer having a CH2=C< group, said interpolymer having amido hydrogen atoms replaced by the structure <FORM:0981931/C3/1> where R is hydrogen or a saturated aliphatic hydrocarbon radical containing up to 5 carbon atoms and R1 is hydrogen or a saturated aliphatic hydrocarbon radical containing up to 10 carbon atoms. Said interpolymer may be prepared by polymerizing the amide with the CH2=C<containing monomer and then reacting the polymer produced with an aldehyde, preferably in the presence of an alcohol. Lists of amides and monomeric compounds having at least one CH2=C< group are given. Preferably the interpolymer should contain from 2 to 50% by weight of the amide. Alternatively the interpolymer may be prepared by polymerizing an N-alkoxyalkyl amide of an unsaturated carboxylic acid with one or more of the CH2=C< monomers, no reaction with an aldehyde being necessary. The resin blended with the interpolymer may be any butadiene resin, preferably a styrene-butadiene resin. Such resins may be modified with epoxidized triglyceride oils or acids. From 5 to 95% of the butadiene resin is blended with from 95 to 5% of the interpolymer; the method of blending may be in a mixer without a solvent or by incorporating the two components in a suitable solvent or dissolving each component in a solvent and combining the two solutions. In the coating composition of the invention other resinous materials may be included, e.g. vinyl resins, alyd resins, epoxy resins, amine resins, phenolic resins and polyacrylate resins. Low temperature cure blends of the interpolymer with an adduct of a hydroxyl-containing polymer with a carboxylic acid anhydride may be used either together with said interpolymer or in place of said interpolymer. Specifications 826,652 and 920,809 are referred to.ALSO:Electrolytic tin plate and glass are coated with a heat hardenable resinous composition comprising a butadiene resin and an interpolymer of an unsaturated carboxylic acid amide with at least one other monomer having a <FORM:0981931/B1-B2/1> group, said interpolymer having amido hydrogen atoms replaced by the structure <FORM:0981931/B1-B2/2> where R is hydrogen or a saturated aliphatic hydrocarbon radical containing up to 5 carbon atoms and R1 is hydrogen or a saturated aliphatic hydrocarbon radical containing up to 10 carbon atoms. The preferred butadiene resin is a butadiene-styrene resin and such resins may be modified with epoxidized triglyceride oils or acids. Other resinous materials such as vinyl resins, alkyd resins, epoxy resins, amine resins, phenolic resins and palyacrylate resins, may be added to the coating composition. In the examples solutions of the coating compositions are drawn on the electrolytic tin plate or glass and then (a) baked at 400 DEG F. and then boiled in water or (b) merely cured at 400 DEG F. Cans may be formed from the coated tin plate. Specifications 826,652 and 920,809 are referred to.
GB3749461A 1960-10-31 1961-10-19 Heat hardenable resinous composition Expired GB981931A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US6593860A 1960-10-31 1960-10-31

Publications (1)

Publication Number Publication Date
GB981931A true GB981931A (en) 1965-01-27

Family

ID=22066167

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3749461A Expired GB981931A (en) 1960-10-31 1961-10-19 Heat hardenable resinous composition

Country Status (3)

Country Link
BE (1) BE609749A (en)
DE (1) DE1272478B (en)
GB (1) GB981931A (en)

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559947A (en) * 1947-08-01 1951-07-10 Phillips Petroleum Co 1,2-diolefins as modifiers in the alkali-metal-catalyzed polymerization of conjugateddiolefins
US2631175A (en) * 1948-12-23 1953-03-10 Phillips Petroleum Co Production of liquid polybutadiene
US2636910A (en) * 1949-04-22 1953-04-28 Phillips Petroleum Co Process for treating polymers produced by alkali metal catalyzed polymerizations
US2652342A (en) * 1949-07-01 1953-09-15 Standard Oil Dev Co Synthetic drying oil and enamel paint and process of making same
US2683162A (en) * 1949-07-23 1954-07-06 Standard Oil Dev Co Synthetic drying oil modified by after-treatment with polar compounds
US2672425A (en) * 1950-07-29 1954-03-16 Standard Oil Dev Co Heat treatment of hydrocarbon drying oils
US2802808A (en) * 1953-07-31 1957-08-13 Firestone Tire & Rubber Co Compositions of a styrene-acrylonitrile resin, a graft of styrene and acrylonitrile upon a diene rubber and a diene rubber
NL102413C (en) * 1955-02-24
US2907669A (en) * 1956-06-07 1959-10-06 Glidden Co Treatment of hydrocarbon drying oils with epoxidized triglyceride oils

Also Published As

Publication number Publication date
DE1272478B (en) 1968-07-11
BE609749A (en)

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