GB980269A - Improved motor fuel composition - Google Patents

Improved motor fuel composition

Info

Publication number
GB980269A
GB980269A GB33023/62A GB3302362A GB980269A GB 980269 A GB980269 A GB 980269A GB 33023/62 A GB33023/62 A GB 33023/62A GB 3302362 A GB3302362 A GB 3302362A GB 980269 A GB980269 A GB 980269A
Authority
GB
United Kingdom
Prior art keywords
alkyl
specifications
phosphosulphurized
referred
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33023/62A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB980269A publication Critical patent/GB980269A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/36Oxygen or sulfur atoms
    • C07D207/402,5-Pyrrolidine-diones
    • C07D207/4042,5-Pyrrolidine-diones with only hydrogen atoms or radicals containing only hydrogen and carbon atoms directly attached to other ring carbon atoms, e.g. succinimide
    • C07D207/408Radicals containing only hydrogen and carbon atoms attached to ring carbon atoms
    • C07D207/412Acyclic radicals containing more than six carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D211/00Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/80Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D211/84Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen directly attached to ring carbon atoms
    • C07D211/86Oxygen atoms
    • C07D211/88Oxygen atoms attached in positions 2 and 6, e.g. glutarimide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/238Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/26Organic compounds containing phosphorus
    • C10L1/2691Compounds of uncertain formula; reaction of organic compounds (hydrocarbons acids, esters) with Px Sy, Px Sy Halz or sulfur and phosphorus containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)

Abstract

In Example 7, a bright stock solvent having a viscosity of 32 cs. at 210 DEG F. is reacted with 10 wt. per cent of P2S5 and the resulting phospho-sulphurized product is at least partially neutralized with 10 wt. per cent ethylene oxide at 285 DEG F. Specifications 792,553 and 838,928 are referred to.ALSO:An inside derivative of a polyisobutenyl methyl succinic acid is prepared by reacting a polyisobutylene having a viscosity of between 200 and 10,000 S.S.U. at 210 DEG F. with itaconic acid to form an anhydride which is then reacted in exylene solution with tripropylene diamine to form the imide (see Example 2). Specifications 792,553 and 838,928 are referred to.ALSO:A motor fuel composition comprises a major amount of a liquid petroleum motor fuel boiling in the gasoline range and a minor amount of a mixture of (1) a dispersant additive having the general formula <FORM:0980269/C4-C5/1> where R is a radical derived from a polymer of a C2- 6 olefin having a M.W. of 600-3000, R1 is hydrogen or C1- 4 alkyl, R11 is a methylene or ethylene radical which may be substituted by C1- 4 alkyl radicals, R111 is a C1- 4 alkylene radical, and x is 1-6, and (2) an oil soluble detergent additive of M.W. less than 20,000, the additive components being present in a weight ratio of dispersant to detergent of from 5 : 1 to 1 : 5. The detergent additive may be an alkali or alkaline earth petroleum sulphonate, an alkyl phenol sulphide or salt thereof, or a phenate, but is preferably a phosphosulphurized hydrocarbon or a hydrolysed and/or neutralization reaction product thereof. Hydrocarbon which may be phosphosulphurized include paraffins, olefins and diolefins, acetylenes, aromatics, cyclic aliphatics, mixtures thereof such as a bright stock residuum, or polymers of C2- 6 olefins (particularly polyisobutylene). The neutralization of phosphosulphurized hydrocarbons may be achieved, using alkali or alkaline earth metal hydroxides, carbonates and oxides, ammonia, amines, polyamines, epoxides (particually C2- 6 alkylene oxides), urea, thiourea, guanidine, ammonium and amine salts of carbonic acid, urethanes, urylenes and carbamates. Optional additives which may be present include alkyl and olefinic lead anti-knock agents (e.g. triethyl vinyl lead, TEL), other organometallic additives containing Pb, Ni, Fe, Si or Mn, tert-butyl acetate, tri-b -chloroethyl phosphate, isopropanol, hexylene glycol, and ethylene dibromide and dichloride. Specifications 792,553 and 838,928 are referred to.
GB33023/62A 1961-09-11 1962-08-28 Improved motor fuel composition Expired GB980269A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US137037A US3223495A (en) 1961-09-11 1961-09-11 Motor fuel composition

Publications (1)

Publication Number Publication Date
GB980269A true GB980269A (en) 1965-01-13

Family

ID=22475540

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33023/62A Expired GB980269A (en) 1961-09-11 1962-08-28 Improved motor fuel composition

Country Status (3)

Country Link
US (1) US3223495A (en)
DE (1) DE1245209B (en)
GB (1) GB980269A (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3443918A (en) * 1965-09-21 1969-05-13 Chevron Res Gasoline composition
US4098585A (en) * 1976-06-07 1978-07-04 Texaco Inc. Amine-alkenylsuccinic acid or anhydride reaction product
US4325708A (en) * 1977-09-09 1982-04-20 Phillips Petroleum Company Fuel detergent compositions containing lubricating oil
US4240803A (en) * 1978-09-11 1980-12-23 Mobil Oil Corporation Fuel containing novel detergent
US4863487A (en) * 1987-04-29 1989-09-05 Nalco Chemical Company Hydrocarbon fuel detergent
US4895578A (en) * 1987-04-29 1990-01-23 Nalco Chemical Company Hydrocarbon fuel detergent
WO1990012857A1 (en) * 1989-04-25 1990-11-01 Mobil Oil Corporation Novel lubricant additives
WO1993006194A1 (en) * 1991-09-13 1993-04-01 Chevron Research And Technology Company Fuel additive compositions containing polyisobutenyl succinimides
CA2180498C (en) * 1995-07-06 2008-03-25 Richard E. Cherpeck Method and composition for reduction of combustion chamber deposits
EP1803771B1 (en) * 2005-12-28 2017-12-06 Bridgestone Corporation A rubber composition having good wet-traction properties and a low aromatic-oil content
US7700673B2 (en) * 2006-12-22 2010-04-20 Bridgestone Corporation Reduced oil rubber compositions including N-substituted polyalkylene succinimide derivates and methods for preparing such compositions
KR101596953B1 (en) 2007-12-31 2016-02-23 가부시키가이샤 브리지스톤 Metal Soaps Incorporated in Rubber Compositions and Method for Incorporating Such Soaps in Rubber Compositions
WO2009158604A2 (en) * 2008-06-26 2009-12-30 Bridgestone Corporation Rubber compositions including metal-functionalized polyisobutylene derivatives and methods for preparing such compositions
US8389609B2 (en) 2009-07-01 2013-03-05 Bridgestone Corporation Multiple-acid-derived metal soaps incorporated in rubber compositions and method for incorporating such soaps in rubber compositions
US9803060B2 (en) * 2009-09-10 2017-10-31 Bridgestone Corporation Compositions and method for making hollow nanoparticles from metal soaps
US8802755B2 (en) 2011-01-18 2014-08-12 Bridgestone Corporation Rubber compositions including metal phosphate esters
WO2014071301A1 (en) 2012-11-02 2014-05-08 Bridgestone Corporation Rubber compositions comprising metal carboxylates and processes for making the same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2296069A (en) * 1940-03-21 1942-09-15 Allied Chem & Dye Corp Fuel for internal combustion engines
US2280419A (en) * 1940-07-16 1942-04-21 Chester E Wilson Compounded oil
US2768999A (en) * 1952-08-27 1956-10-30 Exxon Research Engineering Co Phosphosulfurized hydrocarbons and production thereof
US2781319A (en) * 1954-03-22 1957-02-12 Shell Dev Lubricating compositions
FR1131205A (en) * 1955-09-08 1957-02-19 Exxon Standard Sa Improved lubricating oil compositions
NL255194A (en) * 1959-08-24
US3080223A (en) * 1960-06-29 1963-03-05 Exxon Research Engineering Co Stabilized distillate fuels

Also Published As

Publication number Publication date
DE1245209B (en) 1967-07-20
US3223495A (en) 1965-12-14

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