GB980120A - Improvements in or relating to diorganotin dimercaptides - Google Patents
Improvements in or relating to diorganotin dimercaptidesInfo
- Publication number
- GB980120A GB980120A GB5533/63A GB553363A GB980120A GB 980120 A GB980120 A GB 980120A GB 5533/63 A GB5533/63 A GB 5533/63A GB 553363 A GB553363 A GB 553363A GB 980120 A GB980120 A GB 980120A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compounds
- reacting
- carbon atoms
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 abstract 12
- 125000004432 carbon atom Chemical group C* 0.000 abstract 7
- 239000004215 Carbon black (E152) Substances 0.000 abstract 5
- 229930195733 hydrocarbon Natural products 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 3
- 239000004800 polyvinyl chloride Substances 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- -1 alkali metal salt Chemical class 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 abstract 2
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 abstract 2
- LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 150000002430 hydrocarbons Chemical group 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical group [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention comprises compounds containing one or more units of formula <FORM:0980120/C2/1> where R is a hydrocarbon or heterocyclic radical containing 1 to 18 carbon atoms, R1 and R11 are hydrogen atoms or alkyl radicals containing 1 to 18 carbon atoms, the total carbon atoms in R1 and R11 not exceeding 20, Y is an aromatic hydrocarbon radical (which may be halogenated) having n free valencies, x is 0 or 1 and n is 2, 3 or 4. When n is 2 the compounds may have the formula <FORM:0980120/C2/2> When n is 2 the compounds may have the formula <FORM:0980120/C2/3> where m is 1 or more and Z is a monovalent hydrocarbon radical or the radical <FORM:0980120/C2/4> The compounds are prepared by reacting a polymercapto compound of formula <FORM:0980120/C2/5> or an alkali metal salt thereof, with a compound of formula <FORM:0980120/C2/6> where X is halogen or a hydroxyl radical. In examples, compounds are obtained by reacting a ,a 1 - dimercapto - p - xylene with dibutyltin oxide, alone and with lauryl mercaptan, by reacting a ,a 1-dimercapto-p-xylene with dioctyltin oxide, and by reacting a ,a 1-dimercapto-p-xylene with dibutyltin dichloride, alone and with dibutyltin dilauryl mercaptide.ALSO:The invention comprises polymeric compounds containing units of formula <FORM:0980120/C3/1> where R is a hydrocarbon or heterocyclic radical containing 1 to 18 carbon atoms, R1 and R11 are hydrogen atoms or alkyl radicals containing 1 to 18 carbon atoms, the total carbon atoms in R1 and R11 not exceeding 20, Y is an aromatic hydrocarbon radical (which may be halogenated) having n free valencies, x is 0 or 1 and n is 2, 3 or 4. When n is 2 the polymeric compounds have the formula <FORM:0980120/C3/2> where m is a number up to 100 and Z is a monovalent hydrocarbon radical or the radical <FORM:0980120/C3/3> The compounds are prepared by reacting a polymercapto compound of formula <FORM:0980120/C3/4> or an alkali metal salt thereof, with a compound of formula <FORM:0980120/C3/5> or <FORM:0980120/C3/6> where X is halogen or a hydroxyl radical. The extent of polymerization may be controlled by including in the reaction mixture up to 10 mole per cent based on the polymercapto compound of a chain stopping agent of formula R111SH, where R111 is a hydrocarbon radical of 1 to 18 carbon atoms which may be halogenated. The compounds of the invention may be incorporated in amounts of 0.1 to 5% by weight in halogenated resins as stabilizers. Resins which may be stabilized are polyvinyl chloride, copolymers of vinyl chloride and vinyl acetate, and compositions containing polyvinyl chloride and a copolymer of butadiene, acrylonitrile and styrene. In examples, polymeric compounds are obtained by reacting a ,a 1-dimercapto-p-xylene with dibutyltin oxide, alone and with lauryal mercaptan, by reacting a ,a 1-dimercapto-p-xylene with dioctyltin oxide, and by reacting a ,a 1-dimercapto-p-xylene with dibutyltin dichloride, alone and with dibutyltin dilauryl mercaptide; the first polymeric compound is used to stabilize polyvinyl chloride.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17332462A | 1962-02-15 | 1962-02-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB980120A true GB980120A (en) | 1965-01-13 |
Family
ID=22631507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5533/63A Expired GB980120A (en) | 1962-02-15 | 1963-02-11 | Improvements in or relating to diorganotin dimercaptides |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB980120A (en) |
-
1963
- 1963-02-11 GB GB5533/63A patent/GB980120A/en not_active Expired
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