GB978096A - Polyurethane plastics - Google Patents
Polyurethane plasticsInfo
- Publication number
- GB978096A GB978096A GB2086362A GB2086362A GB978096A GB 978096 A GB978096 A GB 978096A GB 2086362 A GB2086362 A GB 2086362A GB 2086362 A GB2086362 A GB 2086362A GB 978096 A GB978096 A GB 978096A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- groups
- active hydrogen
- chlorinated
- hydrogen containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
- C08G18/3817—Hydroxylated esters of higher fatty acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A process for the preparation of a flame resistant polyurethane comprises reacting an organic polyisocyanate with an organic compound containing at least two active hydrogen containing groups as determined by the Zerenwitinoff method (the groups being reactive towards an isocyanate group), at least one of the components being mixed with a chlorinated or brominated unsaturated monocarboxylic acid, containing at least 10 carbon atoms in the molecule. The unsaturated acids which may be brominated or chlorinated may be for example, delta-9-decylenic, stillingic, delta-9-dodecylenic, palmitoleic, oleic, ricinoleic, petroselinic, raccenic, linoleic, linolenic, eleostearic, licanic, parinaric, gadoleic, arachidonic, cetoleic erucic, nervonic, abietic, laevopimaric, d-pimaric, neoabietic and dihydroabietic acids or mixtures thereof such as tall oil. Many polyisocyanates are specified including blocked polyisocyanates, for example, with phenol. The active hydrogen containing compounds may be monomeric such as the alkane, alkene and alkyne diols, triols and tetrols (including those which normally exist in a tautomeric form); alkane, alkene and alkyne polythiols; aromatic aliphatic and heterocyclic polyamines; amino-alcohols; other compounds containing more than one group chosen from -SM, -OM and -NH2 groups; such compounds containing substituents or groups such as halogen atoms, nitro, alkoxy, carboalkoxy, dialkylamino, mercapto, carbonyl, thiocarbonyl, phosphonyl and phosphate groups; and mixtures of such compounds: many such compounds are specified. Polymeric active hydrogen containing compounds may also be used such as polyesters, polyhydric polyalkylene ethers, polyhydric polythioethers, and polyesteramides: many starting materials for the preparation of such polymers are specified. In the preparation of foams blowing agents such as water, nitrogen, carbon dioxide, air, argon, halogenohydrocarbons, hydrocarbons or ethers may be added together with emulsifiers such as sulphonated castor oil and foam stabilizers such as polysiloxanes and alkylsilane-polyoxyalkylene or siloxane-polyoxyalkylene block copolymers, if desired, Catalysts such as tertiary amines, molybdenum glycolate, stannous chloride and organotin compounds may also be present. The polyisocyanate may be used in the form of a prepolymer made by reaction with part of the active hydrogen containing compound. The products may be reacted with cross-linking agents such as a polyamine, polyol, water or further polyisocyanate. The reaction may be performed in an inert solvent. Pigments such as iron oxide, carbon black, titanium dioxide, zinc oxide, chrome green or lithol red may be added. The products may be mouldings, castings, coatings, caulks, sealants, putties, adhesives, foams, sound or thermal insulating materials, gaskets, the potting of electrical components, bushings or the moulding of the counter portion of shoes.ALSO:Wood and steel are coated with a polyurethane-forming solution in 2-ethoxyethyl acetate of an isocyanate-terminated prepolymer, N,N,N1,N1-tetrakis(2-hydroxypropyl)ethylene-diamine and chlorinated tall oil. The prepolymer is a reaction product of a mixture of 2,4-toluylene and 2,6-toluylene di-isocyanates, polypropylene ether glycol, and a trihydric polypropylene ether which is the reaction product of glycerine and propylene oxide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12561461A | 1961-05-31 | 1961-05-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB978096A true GB978096A (en) | 1964-12-16 |
Family
ID=22420588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2086362A Expired GB978096A (en) | 1961-05-31 | 1962-05-30 | Polyurethane plastics |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE618391A (en) |
DE (1) | DE1167522B (en) |
GB (1) | GB978096A (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL112087C (en) * | 1958-10-02 |
-
0
- BE BE618391D patent/BE618391A/xx unknown
-
1962
- 1962-05-23 DE DEM52954A patent/DE1167522B/en active Pending
- 1962-05-30 GB GB2086362A patent/GB978096A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE618391A (en) | |
DE1167522B (en) | 1964-04-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
SU1741605A3 (en) | Internal anti-adhesion lubricant for moulding polyurethane products, polyol composition for moulding polyurethane products, and method of moulding polyurethane products | |
US3635848A (en) | Isocyanurates, polyisocyanurates and polyurethanes and their preparation using as a catalyst a coordination compound of an organic borate ester and an alkali or alkaline earth metal | |
US3310533A (en) | Preparing polyurethanes | |
US3211674A (en) | Polyurethane foam from hydroxylated tall oil | |
US2957832A (en) | Cellular polyurethane elastomer and preparation of same using pyridine catalyst | |
US3681125A (en) | Process for the production of microporous sheet structures | |
US3755242A (en) | Polycarbodiimide prepolymers | |
US3562189A (en) | Process for cellular polymers containing imide groups | |
US3523103A (en) | Process for polyurethane formation and catalysts therefor | |
US4156064A (en) | Process for the manufacture of polyurethane adhesives | |
US2953533A (en) | Highly cross-linked non flammable polyurethane foams and preparation of same | |
US3661885A (en) | Polyurethane catalyst | |
US2818404A (en) | Curing of polyurethanes with a di(isocyanatoaryl) urea | |
US3054755A (en) | Polyurethane plastics | |
US3634361A (en) | Polyisocyanate compositions | |
US3095386A (en) | Polyurethane polymers containing tall oil | |
US3635908A (en) | Process of preparing polyurethane-urea thermoplastic products base on a polyamine carbamate as chain extender | |
US3660326A (en) | Polyurethane prepolymer composition containing the reaction produc of a carboxylic acid and a monomeric isocyanate | |
US2858298A (en) | Fluid, curable polyalkyleneether glycol compositions and cured elastomers obtained therefrom | |
GB2264499A (en) | Polyurea-based dispersions, foams prepared therefrom and a process for the preparation thereof | |
US3505250A (en) | Polyurethane plastics | |
US4407982A (en) | Process for the manufacture of foamed structures | |
US4151345A (en) | Method of making polyurethane utilizing nickel acetylacetonate | |
GB978096A (en) | Polyurethane plastics | |
US3655588A (en) | Urethane-containing aminic polyols and foams derived therefrom |