GB977820A - Coating composition - Google Patents

Coating composition

Info

Publication number
GB977820A
GB977820A GB907863A GB907863A GB977820A GB 977820 A GB977820 A GB 977820A GB 907863 A GB907863 A GB 907863A GB 907863 A GB907863 A GB 907863A GB 977820 A GB977820 A GB 977820A
Authority
GB
United Kingdom
Prior art keywords
copolymer
silane
formaldehyde
butanol
acrylamide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB907863A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
Pittsburgh Plate Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pittsburgh Plate Glass Co filed Critical Pittsburgh Plate Glass Co
Publication of GB977820A publication Critical patent/GB977820A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Paints Or Removers (AREA)

Abstract

A coating composition comprises a copolymer of an ethylenic carboxylic acid amide with at least one other monomer containing a terminal methylene group, the copolymer having at least part of the amido hydrogen atoms replaced by the group <FORM:0977820/C3/1> wherein R is hydrogen or a lower aliphatic or heterocyclic radical and R1 is hydrogen or an alkyl, cycloalkyl or aralkyl radical containing up to 20 carbon atoms, and at least 0.5% by weight of the copolymer of a hydrolysable aminosilane, e.g. aminoalkylalkoxysilanes. Preferred copolymers are those made by reacting with formaldehyde a copolymer of acrylamide or methacrylamide. If the formaldehyde is used in the form of a solution in an alcohol, then the reaction is accompanied by etherification of the methylol groups produced. The compositions may also contain ethylene polymers, vinyl halide polymers, epoxy resins, nitrocellulose, alkyd resins, epoxidized oils, aminoplasts, pigments, pine oil and solvents, e.g. toluene, xylol, butanol methyl isobutyl ketone, isophorone, butyl acetate, isopropyl acetate, ethyl alcohol and ethylene glycol monoethyl ether acetate. The resulting compositions are applied to glass surfaces and cured by heating. The examples describe compositions containing the following polymeric ingredients and hydrolysable aminosilanes: (1) an acrylamide/styrene/ethyl acrylate copolymer reacted with formaldehyde and butanol and gamma-aminopropyltriethoxysilane; (3) a copolymer and silane as in (1) and an epoxy resin made by reacting bisphenol A with epichlorohydrin; (4) an acrylamide/styrene/methacrylic acid copolymer reacted with formaldehyde and butanol, delta-aminobutylmethyldiethoxysilane and an epoxy resin as in (3); (5) an acrylamide/ethyl acrylate copolymer reacted with formaldehyde and butanol, N-(beta-aminoethyl) -beta-aminoethyltriethoxy silane and nitrocellulose; (6) a copolymer as in (1), a silane as in (5) and an alkyd resin prepared from tall oil acids, coconut oil acids, glycerin and phthalic anhydride; (7) a copolymer and silane as in (1) and polyethylene; and (8) a copolymer and silane as in (1) and a vinyl chloride/vinyl acetate/maleic acid copolymer. Specification 826,652 is referred to.ALSO:Glass panels are coated with a composition comprising a copolymer of an ethylenic carboxylic acid amide with at least one other monomer containing a terminal methylene group, the copolymer having at least part of the amido hydrogen atoms replaced by the group: <FORM:0977820/B1-B2/1> wherein R is hydrogen or a lower aliphatic or heterocyclic radical and R1 is hydrogen or a C1-C20 alkyl, cycloalkyl or aralkyl radical (see Division C3), and at least 0,5% by weight of the copolymer of a hydrolysable amino organosilane. The compositions may also contain solvents, e.g. toluene, xylol, butanol, methyl isobutyl ketone, isophorone, butyl acetate, isopropyl acetate, ethyl alcohol and ethylene glycol monoethyl ether acetate, ethylene polymers, vinyl halide polymers, epoxy resins, nitrocellulose, alkyd resins, epoxidized oils, aminoplasts, pigments and pine oil. After application to glass surfaces the compositions are cured by heating. The examples describe the application by spraying, brushing or drawing to glass surfaces of solutions containing the following polymeric ingredients and hydrolysable aminosilanes: (1) an acrylamide/styrene/ethyl acrylate copolymer reacted with formaldehyde and butanol, and gamma-aminopropyltriethoxy silane; (3) a copolymer and silane as in (1) and an epoxy resin; (4) an acrylamide/styrene/methacrylic acid copolymer reacted with formaldehyde and butanol, delta-aminobutylmethyldiethoxy silane and an epoxy resin; (5) an acrylamide/ethyl acrylate copolymer reacted with formaldehyde and butanol, N-(beta-aminoethyl)-beta-aminoethyltriethoxy silane and nitrocellulose; (6) a copolymer as in (1), a silane as in (5) and an alkyd resin; (7) a copolymer and silane as in (1) and polyethylene; and (8) a copolymer and silane as in (1) and a vinyl chloride/vinyl acetate/maleic acid copolymer. Specification 826,652 is referred to.
GB907863A 1962-03-08 1963-03-07 Coating composition Expired GB977820A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17827762A 1962-03-08 1962-03-08

Publications (1)

Publication Number Publication Date
GB977820A true GB977820A (en) 1964-12-16

Family

ID=22651911

Family Applications (1)

Application Number Title Priority Date Filing Date
GB907863A Expired GB977820A (en) 1962-03-08 1963-03-07 Coating composition

Country Status (3)

Country Link
BE (1) BE629374A (en)
GB (1) GB977820A (en)
NL (1) NL289807A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5505989A (en) * 1992-07-11 1996-04-09 Pilkington Glass Limited Method for coating a hot glass ribbon
US5576885A (en) * 1994-01-10 1996-11-19 Pilington Glass Limited Heatable mirror including a non-metallic reflecting coating on a glass substate
WO1997047563A1 (en) * 1996-06-11 1997-12-18 Elf Atochem Vlissingen B.V. Glassware with abrasion resistant, transparent protective coating capable of being labelled and method for producing same
US5757564A (en) * 1994-01-10 1998-05-26 Pilkington Glass Limited Coatings on glass
US5764415A (en) * 1994-01-10 1998-06-09 Pilkington Glass Limited Coatings on glass
US5910360A (en) * 1996-06-11 1999-06-08 Elf Atochem Vlissingen B.V. Glass article carrying a transparent protective layer which is resistant to abrasion and can be labeled and process for obtaining it

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5505989A (en) * 1992-07-11 1996-04-09 Pilkington Glass Limited Method for coating a hot glass ribbon
US5745291A (en) * 1992-07-11 1998-04-28 Pilkington Glass Limited Mirror including a glass substrate and a pyrolytic silicon reflecting layer
US5576885A (en) * 1994-01-10 1996-11-19 Pilington Glass Limited Heatable mirror including a non-metallic reflecting coating on a glass substate
US5700305A (en) * 1994-01-10 1997-12-23 Pilkington Glass Limited Method of producing heatable mirrors by depositing coatings on glass
US5757564A (en) * 1994-01-10 1998-05-26 Pilkington Glass Limited Coatings on glass
US5764415A (en) * 1994-01-10 1998-06-09 Pilkington Glass Limited Coatings on glass
WO1997047563A1 (en) * 1996-06-11 1997-12-18 Elf Atochem Vlissingen B.V. Glassware with abrasion resistant, transparent protective coating capable of being labelled and method for producing same
US5910360A (en) * 1996-06-11 1999-06-08 Elf Atochem Vlissingen B.V. Glass article carrying a transparent protective layer which is resistant to abrasion and can be labeled and process for obtaining it

Also Published As

Publication number Publication date
NL289807A (en)
BE629374A (en)

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