GB976896A - Termination of synthetic rubber emulsion polymerization - Google Patents
Termination of synthetic rubber emulsion polymerizationInfo
- Publication number
- GB976896A GB976896A GB1665963A GB1665963A GB976896A GB 976896 A GB976896 A GB 976896A GB 1665963 A GB1665963 A GB 1665963A GB 1665963 A GB1665963 A GB 1665963A GB 976896 A GB976896 A GB 976896A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerization
- soaps
- diolefins
- methyl
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007720 emulsion polymerization reaction Methods 0.000 title abstract 2
- 229920003051 synthetic elastomer Polymers 0.000 title abstract 2
- 239000005061 synthetic rubber Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 5
- 239000000344 soap Substances 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical class C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 abstract 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- VJOWMORERYNYON-UHFFFAOYSA-N 5-ethenyl-2-methylpyridine Chemical compound CC1=CC=C(C=C)C=N1 VJOWMORERYNYON-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 230000002528 anti-freeze Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical group C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 abstract 1
- 235000010288 sodium nitrite Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20209262A | 1962-06-13 | 1962-06-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB976896A true GB976896A (en) | 1964-12-02 |
Family
ID=22748467
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1665963A Expired GB976896A (en) | 1962-06-13 | 1963-04-29 | Termination of synthetic rubber emulsion polymerization |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1520997B1 (enrdf_load_stackoverflow) |
GB (1) | GB976896A (enrdf_load_stackoverflow) |
NL (2) | NL293827A (enrdf_load_stackoverflow) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4371678A (en) * | 1980-06-05 | 1983-02-01 | Solvay & Cie. | Process for rapidly terminating the polymerization of vinyl chloride in aqueous suspension |
-
0
- NL NL122893D patent/NL122893C/xx active
- NL NL293827D patent/NL293827A/xx unknown
-
1963
- 1963-04-24 DE DE19631520997 patent/DE1520997B1/de not_active Withdrawn
- 1963-04-29 GB GB1665963A patent/GB976896A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4371678A (en) * | 1980-06-05 | 1983-02-01 | Solvay & Cie. | Process for rapidly terminating the polymerization of vinyl chloride in aqueous suspension |
Also Published As
Publication number | Publication date |
---|---|
NL122893C (enrdf_load_stackoverflow) | |
DE1520997B1 (de) | 1969-09-11 |
NL293827A (enrdf_load_stackoverflow) |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB842563A (en) | Hydrophilic interpolymers of polymerisable ethylenically unsaturated compounds and sulpho esters of ª-methylene carboxylic acids | |
US2380474A (en) | Catalysts for the addition polymerization of unsaturated organic compounds | |
GB715434A (en) | Improvements in or relating to a process for producing high polymer latices | |
US2313233A (en) | Preparation of butadiene copolymers | |
US2578910A (en) | Polymerization of vinyl compounds in the presence of heterocyclic nitrogen compounds as activators | |
US2397201A (en) | Acceleration of the polymerization of butadiene-1, 3 hydrocarbons | |
GB976896A (en) | Termination of synthetic rubber emulsion polymerization | |
GB1092265A (en) | Process for stopping polymerizations | |
GB835674A (en) | Improvements in catalysts for aqueous emulsion polymerizations | |
US2417034A (en) | Butadiene emulsion polymerization in the presence of water soluble complex metal cyanides | |
US2469017A (en) | Method of terminating the polymerization of butadiene-1,3 hydrocarbons | |
US3095398A (en) | Process of increasing the particle size of synthetic rubber latex | |
GB892160A (en) | Improvements in and relating to polymerisation | |
GB719174A (en) | Improvements in or relating to an aqueous emulsion polymerization process | |
GB798565A (en) | Improvements in the production of aqueous dispersions of ethylene polymers | |
US3322736A (en) | Shortstop for emulsion polymerization | |
GB802648A (en) | Improvements in emulsion polymerization of unsaturated hydrocarbons | |
US3004943A (en) | Synthetic rubber latex | |
US2588975A (en) | Reaction rate of an emulsion polymerization process | |
GB681017A (en) | Improvements in or relating to polymerization | |
US2634258A (en) | Process for the polymerization of unsaturated organic materials | |
GB946061A (en) | Synthetic rubber latex | |
US2450416A (en) | Process for polymerizing butadiene in aqueous emulsion in the presence of an alkali metal salt of hydroxytetrahydrocabietic acid | |
US3014040A (en) | Method of increasing the particle size of synthetic rubber latex comprising the incorporation of a polyvinylpyridine resin latex therein | |
US2366327A (en) | Polymerization of butadienes-1,3 |