GB970431A - - Google Patents

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Publication number
GB970431A
GB970431A GB970431DA GB970431A GB 970431 A GB970431 A GB 970431A GB 970431D A GB970431D A GB 970431DA GB 970431 A GB970431 A GB 970431A
Authority
GB
United Kingdom
Prior art keywords
acid ester
acetone
butyl
esters
acetyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication date
Publication of GB970431A publication Critical patent/GB970431A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/313—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of doubly bound oxygen containing functional groups, e.g. carboxyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

970,431. Preparation of esters. WACKERCHEMIE G.m.b.H. Jan. 24, 1962 [Feb. 4, 1961], No. 2712/62. Heading C2C. Esters are prepared by transesterification of an ester with an alcohol, or by esterification of an acid with an alcohol in the presence, as a catalyst, of titanium, zirconium, hafnium, or thorium chelates, of general formula in which X is a chelate-former and/or a whole number, and titanium may be replaced by the other Group IV( A ) metals mentioned. Chelate formers, i.e. substances bound to the metal atom by valency bond and by a co-ordinate link through a oxygen or nitrogen are listed, and include those formed from acetyl acetone, diacetoacetic acid ester, acetyl-mesityl oxide, acetonyl-acetone, benzoyl-acetone, triazyl-methane, benzoyl-diacetyl-methane, formyl-acetyl-acetone, acetoacetic acid ester and substituted acetoacetic acid esters, propionyl-propionic and butyl-butyric acid ester, acetone-dicarboxylic acid esters, oxaloacetic acid ester, mono-, di-, or tri-ethanolamine, polyols, lactic acid ester, or glycollic acid ester, hydroxy-succinic acid ester, hydroxybutyric acid ester, glycerine acid ester, malic acid ester, dihydroxysuccinic acid ester, citric acid ester, diacetone alcohol, dihydroxyacetone, hydroxymalonic-dialdehydes and higher condensation products of acetone (acetone oils). The process may be continuous with the catalyst in a column, or discontinuous by the addition of the reaction components to the catalyst which may be supported on carriers such as aluminium silicate, coke, active charcoal, porous ceramic substances, silica gel, and aluminium oxide. Examples describe the use of various catalysts in the preparation of butyl #-methoxypropionate, n-hexyl chloracetate, butyl butyrate, 2-ethyl butyl acrylate, 2-ethylhexyl #-butoxypropionate, allyl acetate, dibutyl carbonate, phenyl isobutyrate, butyl acrylate, butyl 2-ethoxyisobutyrate, triethylene glycol dibutyrate, dihexyl sulphate, butyl benzoate, diethylene glycol phthalate, 2-ethylbutyl benzoate, ethyl acetate, and butyl acetate.
GB970431D 1961-02-04 Expired GB970431A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEW29411A DE1225177B (en) 1961-02-04 1961-02-04 Process for the production of carboxylic acid esters

Publications (1)

Publication Number Publication Date
GB970431A true GB970431A (en) 1900-01-01

Family

ID=7599227

Family Applications (1)

Application Number Title Priority Date Filing Date
GB970431D Expired GB970431A (en) 1961-02-04

Country Status (4)

Country Link
BE (1) BE613426A (en)
CH (1) CH412843A (en)
DE (1) DE1225177B (en)
GB (1) GB970431A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225503A (en) * 1977-11-28 1980-09-30 Imperial Chemical Industries Limited Manufacture of esters
US4788172A (en) * 1987-07-27 1988-11-29 Deardorff Donald L Titanium compounds
US4960927A (en) * 1987-02-23 1990-10-02 Bp Chemicals Limited Process for the continuous preparation of acetates
US5866710A (en) * 1996-06-11 1999-02-02 Tioxide Specialties Limited Esterification process
WO2004000784A1 (en) * 2002-06-21 2003-12-31 Pcbu Services, Inc. Preparation of protected amino acids
FR2855518A1 (en) * 2003-05-26 2004-12-03 Inst Francais Du Petrole Transesterification of vegetable or animal oils, useful for preparation of fuels and pure glycerine, involves using heterogeneous catalysts based on zirconium and aluminum
EP1660619A1 (en) * 2003-08-29 2006-05-31 Nippon Shokubai Co., Ltd. Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
CN104045555A (en) * 2013-03-15 2014-09-17 中国石油化工股份有限公司 Preparation method of triethylene glycol dicarboxylate

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1234837A (en) * 1983-06-28 1988-04-05 Robert J. Knopf Continuous process for producing linear, secondary, aliphatic alcohols
CN114516796B (en) * 2022-03-30 2023-05-26 北京化工大学 Method for preparing 5-oxo caproate

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056818A (en) * 1955-10-13 1962-10-02 Goodrich Co B F Titanium and zirconium esterification catalysts

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225503A (en) * 1977-11-28 1980-09-30 Imperial Chemical Industries Limited Manufacture of esters
US4960927A (en) * 1987-02-23 1990-10-02 Bp Chemicals Limited Process for the continuous preparation of acetates
US4788172A (en) * 1987-07-27 1988-11-29 Deardorff Donald L Titanium compounds
US5866710A (en) * 1996-06-11 1999-02-02 Tioxide Specialties Limited Esterification process
WO2004000784A1 (en) * 2002-06-21 2003-12-31 Pcbu Services, Inc. Preparation of protected amino acids
FR2855518A1 (en) * 2003-05-26 2004-12-03 Inst Francais Du Petrole Transesterification of vegetable or animal oils, useful for preparation of fuels and pure glycerine, involves using heterogeneous catalysts based on zirconium and aluminum
EP1660619A1 (en) * 2003-08-29 2006-05-31 Nippon Shokubai Co., Ltd. Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
EP1660619A4 (en) * 2003-08-29 2009-08-05 Nippon Catalytic Chem Ind Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
US7605281B2 (en) 2003-08-29 2009-10-20 Nippon Shokubai Co., Ltd. Method of production of fatty acid alkyl esters and/or glycerine and fatty acid alkyl ester-containing composition
CN104045555A (en) * 2013-03-15 2014-09-17 中国石油化工股份有限公司 Preparation method of triethylene glycol dicarboxylate
CN104045555B (en) * 2013-03-15 2016-02-24 中国石油化工股份有限公司 A kind of preparation method of triglycol dicarboxylic ester

Also Published As

Publication number Publication date
CH412843A (en) 1966-05-15
DE1225177B (en) 1966-09-22
BE613426A (en) 1962-08-02

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