GB960101A - Moulding composition - Google Patents
Moulding compositionInfo
- Publication number
- GB960101A GB960101A GB2087860A GB2087860A GB960101A GB 960101 A GB960101 A GB 960101A GB 2087860 A GB2087860 A GB 2087860A GB 2087860 A GB2087860 A GB 2087860A GB 960101 A GB960101 A GB 960101A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde
- resin
- cellulose
- aggregates
- melamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Heat and/or pressure mouldable moulding compositions contain a binder and a filler comprising cellulose crystallite aggregates having an average level-off degree of polymerisation of 15 to 375 anhydroglucose units. The cellulose crystallite aggregates are the insoluble fraction obtained by the acid hydrolysis of cellulose, which fraction is free from amorphous cellulose. The crystallite aggregates may have been further reduced in size by mechanical disintegration or mixtures of disintegrated and undisintegrated aggregates may be used. The binder is defined as any plastic, resin or the like capable of being mixed with a filler material to form any type of suitable article. The binder may be a urea-formaldehyde, thiourea-formaldehyde, melamine-formaldehyde, phenol-formaldehyde or alkyd resin; an unsaturated polyester; a protein, e.g. zein or casein, plastic; vulcanised or unvulcanised polyisobutylene; cellulose acetate or acetate butyrate; polyvinyl chloride; a vinyl chloride-vinyl acetate copolymer; an acrylic resin; polyethylene or polypropylene; polyterpenes; fluorethylene and styrene polymers; petroleum resins; furans; silicones; polyamides, e.g. nylon; and polyurethanes. The compositions may also contain moulding catalysts, mould lubricants, plasticizers, pigments and auxiliary fillers such as cotton flock or fabric, wood pulp, asbestos, mica, glass fibre, regenerated cellulosefibre, linen, nylon, wood flour, and diatomaceous earth. In examples compositions of cellulose crystallite aggregates and the following materials are disclosed:- (1) aqueous urea-formaldehyde resin syrup, zinc stearate, a pigment and a catalyst; (2) aqueous melamine-formaldehyde precondensate, zinc stearate, a pigment and a latent curing catalyst; (3) cellulose acetate; (4) a 2-stage moulding resin formed by mixing an acid-catalyzed phenol-formaldehyde precondensate, hexamethylene tetramine, calcium hydroxide, and calcium stearate; (5) urea-formaldehyde precondensate and alum; (6) melamine-formaldehyde precondensate, hydrochloric acid (in Examples 5 and 6 the cellulose crystallite aggregates are mixed with a dilute aqueous solution of the resin etc. and stirred, the mixture is filtered and the residue used as a moulding composition); (7) vinyl chloridevinyl acetate copolymer (the composition being prepared by adding water to a suspension of the aggregates in an acetone solution of the copolymer); (8) phenol-formaldehyde condensate and hexamethylene-tetramine; (9) phenol-formaldehyde condensate or an aniline-formaldehyde resin or polyformaldehyde resin. Urea-formaldehyde resin syrup is prepared in Example 1 by condensing a mixture of urea and formalin in the presence of formic acid, hexamethylenetetramine and ammonium benzoate. Melamine-formaldehyde resin precondensate is prepared by heating a mixture of melamine and formalin neutralised by triethanolamine. Cellulose crystallite aggregates are prepared in examples 5 and 8 by hydrolysing wood pulp or sulphite wood pulp with 0.5% by weight aqueous solution of HCl for one hour at 121 DEG C. Specification 231,431 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US82300659A | 1959-06-26 | 1959-06-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB960101A true GB960101A (en) | 1964-06-10 |
Family
ID=25237546
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2087860A Expired GB960101A (en) | 1959-06-26 | 1960-06-14 | Moulding composition |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1469804B2 (en) |
GB (1) | GB960101A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1241981B (en) * | 1965-02-13 | 1967-06-08 | Ruhrchemie Ag | Molding compounds made from mixtures of thermoplastics and wood flour |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10209812A1 (en) * | 2001-03-22 | 2002-09-26 | Degussa Construction Chem Gmbh | Water-soluble polysaccharide derivatives used as dispersants for mineral binder suspensions, optionally contain hydroxyalkyl and/or sulfate groups |
-
1960
- 1960-06-14 GB GB2087860A patent/GB960101A/en not_active Expired
- 1960-06-27 DE DE19601469804 patent/DE1469804B2/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1241981B (en) * | 1965-02-13 | 1967-06-08 | Ruhrchemie Ag | Molding compounds made from mixtures of thermoplastics and wood flour |
Also Published As
Publication number | Publication date |
---|---|
DE1469804A1 (en) | 1969-01-30 |
DE1469804B2 (en) | 1970-01-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2649439A (en) | Preparation of plastic condensable alkyl acrylate polymers and subsequent elasto-condensation thereof | |
US3883462A (en) | Novel resinous compositions comprising sequential reaction product of formaldehyde, inorganic acid, triethanolamine and urea | |
US2647884A (en) | Isocyanates and products prepared therefrom and methods of making the same | |
US3033842A (en) | Process of producing water-insoluble polymers of polyvinyl alcohol | |
US1780636A (en) | Substituted guanidine-aldehyde condensation product | |
US4182696A (en) | Process for producing particulate filler-containing resole molding compositions from aqueous dispersion | |
US2496480A (en) | Preparation of polyvinyl acetal resins of improved stability | |
GB960101A (en) | Moulding composition | |
US2584177A (en) | Modified aminoplasts and products prepared therefrom | |
JP2001514982A (en) | Continuous production of amino plastic and / or phenolic resin | |
US2331376A (en) | Reaction product of an aldehyde and a biguanido carbocyclic sulphonamide | |
US2410395A (en) | Acid-curing synthetic resin combined with olefine-sulfur dioxide polymer | |
US4005036A (en) | Frothed molding compositions | |
US2518963A (en) | Production of thermosetting aldehyde reaction products | |
US2436363A (en) | Aminoamide resins | |
US2436080A (en) | Resinous composition of urea-aldehyde and hydrolyzed interpolymer of a vinyl ester | |
US3752781A (en) | Polyalkylenimine urea aldehyde cationic resins | |
GB824200A (en) | Improvements in vinyl chloride polymer compositions and mixtures containing them | |
US2188272A (en) | Shaped article and process of preparing it | |
US2038142A (en) | Synthetic resins and process of making same | |
US2456567A (en) | Aminotriazine product | |
US2689238A (en) | Polymerizable and polymerized compositions produced from a polymer of an unsaturated guanamine | |
US2393752A (en) | Reaction products of dimethylol urea and a halogenated acetamide | |
US2326728A (en) | Plasticizing thermosetting resins | |
US2199155A (en) | Manufacture of molded products |