GB944964A - Vinyl addition polymers - Google Patents

Vinyl addition polymers

Info

Publication number
GB944964A
GB944964A GB3924561A GB3924561A GB944964A GB 944964 A GB944964 A GB 944964A GB 3924561 A GB3924561 A GB 3924561A GB 3924561 A GB3924561 A GB 3924561A GB 944964 A GB944964 A GB 944964A
Authority
GB
United Kingdom
Prior art keywords
glycidyl
methyl
methacrylates
butyl
allyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3924561A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB944964A publication Critical patent/GB944964A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10—Homopolymers or copolymers of methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3209—Epoxy compounds containing three or more epoxy groups obtained by polymerisation of unsaturated mono-epoxy compounds

Abstract

Vinyl addition polymers which comprise at least one ester of methacrylic acid with C 1 - 8 alkanols and having substituents each of which bears on adjacent carbon atoms a hydroxyl radical and an amino radical bearing at least one active hydrogen atom, said amino radicals in said substituents containing from 0.01 to 1.0% of amino nitrogen based on the weight of the polymer, and said polymers having a glass transition temperature of from 35 to 100 DEG C. and a degree of polymerization of at least 1,200, may be used as adhesives. The polymers may be prepared by copolymerizing methacrylate esters, e.g. methyl, ethyl, n-propyl, n-butyl, n-amyl, 3-methylpentyl, n-hexyl, 2-methylhexyl, n-heptyl and n-octyl methacrylate, with epoxy monomers, e.g. glyeidyl acrylate, glycidyl methacrylate, glycidyl sorbate, glycidyl ricinoleate, glycidyl vinyl phthalate, glycidyl allyl phthalate, glycidyl allyl maleate, allyl a ,b -epoxyisovalerate, allyl glycidyl ether, butadiene monoepoxide, vinyl cyclohexene epoxide and glycidyl oxyethyl vinyl sulphide, and reacting the copolymer with ammonia or a primary alkylamino or alkanolamine, e.g. methylamine, ethylamine, isopropylamine, n-butylamine, isobutylamine, stearylamine, cyclohexylamine, naphthylamine, aniline, toluidine, 2-aminofuran, furfurylamine, ethanolamine, propanolamine, 2-amino-1-butanol, benzylamine, o-propylaminophenol, a -methoxypropylamine, a -aminopropionitrile, t-butylamine, t-octylamine, soya amine and tall amine. Amination may be effected in a solvent, e.g. toluene, benzene, cyclohexane, octane, butanol, pentanol, isopropanol and ethoxyethanol, and product diluted with further solvent for application as adhesive. Examples describe the polymerization in toluene and isopropanol in the presence of azodiisobutyronitrile, which is added incrementally, of (1 and 5) glycidyl, methyl and n-butyl methacrylates; (2) ethyl and glycidyl methacrylates; (3) methyl, n-hexyl and glycidyl methacrylates; (4) methyl, ethyl and glycidyl methacrylates; and the reaction of the products with ammonia; (6) methyl, n-butyl and glycidyl methacrylates and the reaction of the product with methylamine; and (7) methyl, n-butyl and glycidyl methacrylates and the reaction of the product with ethanolamine. The adhesives may be used in the preparation of laminates.
GB3924561A 1960-11-15 1961-11-02 Vinyl addition polymers Expired GB944964A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US6924760A 1960-11-15 1960-11-15

Publications (1)

Publication Number Publication Date
GB944964A true GB944964A (en) 1963-12-18

Family

ID=22087685

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3924561A Expired GB944964A (en) 1960-11-15 1961-11-02 Vinyl addition polymers

Country Status (3)

Country Link
BE (1) BE610317A (en)
FR (1) FR1309515A (en)
GB (1) GB944964A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0158881A2 (en) * 1984-04-04 1985-10-23 Hans-Joachim Dr. Kiessling Soluble polymers, their preparation and use in manufacturing objects
US4857580A (en) * 1984-10-04 1989-08-15 Herberts Gesellschaft Mit Beschraenkter Haftung Crosslinked coating resin

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4166079A (en) * 1977-01-04 1979-08-28 Sumitomo Chemical Co. Ltd. Dyeable polyolefin composition
JPS5394586A (en) * 1977-01-31 1978-08-18 Sony Corp Production of adhesive

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0158881A2 (en) * 1984-04-04 1985-10-23 Hans-Joachim Dr. Kiessling Soluble polymers, their preparation and use in manufacturing objects
EP0158881A3 (en) * 1984-04-04 1986-12-17 Hans-Joachim Dr. Kiessling Soluble polymers, their preparation and use in manufacturing objects
US4857580A (en) * 1984-10-04 1989-08-15 Herberts Gesellschaft Mit Beschraenkter Haftung Crosslinked coating resin

Also Published As

Publication number Publication date
BE610317A (en) 1962-05-14
FR1309515A (en) 1962-11-16

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