GB944904A - Polyurethane foam and method of making same - Google Patents

Polyurethane foam and method of making same

Info

Publication number
GB944904A
GB944904A GB351360A GB351360A GB944904A GB 944904 A GB944904 A GB 944904A GB 351360 A GB351360 A GB 351360A GB 351360 A GB351360 A GB 351360A GB 944904 A GB944904 A GB 944904A
Authority
GB
United Kingdom
Prior art keywords
specified
methyl
sodium
glycerol
stearate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB351360A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aerojet Rocketdyne Holdings Inc
Original Assignee
General Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Tire and Rubber Co filed Critical General Tire and Rubber Co
Publication of GB944904A publication Critical patent/GB944904A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
    • C08G18/163—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22 covered by C08G18/18 and C08G18/22
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A method of making a polyurethane foam comprises reacting a polyalkylene ether polyol and an organic polyisocyanate (or a prepolymer formed therefrom) in the presence of a foaming agent, a metal containing catalyst and a minor amount of polysiloxane-polyoxyalkylene block copolymer. Specified polyalkylene ether polyols are those derived by condensing one or more alkylene oxides with a polyhydric alcohol e.g. glycerol, hexanetriol-1:2:6 and pentaerythritol. Specified metal containing compounds are polymeric organo-tin compounds, dibutyl tin laurate, tin maleate, potassium stearate, zinc stearate, sodium stearate, potassium acetate, sodium acetate, sodium and potassium hydroxide and carbonate and sodium methyl siliconate. Specified polysiloxane-polyoxyalkylene block copolymers are those of the formula: <FORM:0944904/C3/1> where R1, R2 and R11 are monovalent hydrocarbon radicals, p, q, and r are integers, n is an integer from 2 to 4 and s is an integer of at least 5. Water is the specified foaming agent. Cross-linking agents e.g. trimethylol propane, glycerol, 1:2:4-butamediol, hexanetriol, pentaerythritol, the b -ethanol ether of 2-methyl-2-methylol-4-methyl-5-hydroxypropane, N:N:N1:N1-tetrakis(2-hydroxypropyl) ethylene diamine and hexamethylene diamine may be present in the reaction mixture as may tertiary amine catalysts, e.g. di(ethylene amino alcohol) adipate, dibutyl aminoethanol, butyl diethanolamine, triethylamine, trihexylamine, tributylamine, tripropylamine, N-methyl morpholine, N-octyl morpholine, 4-pyridine propanol and 4-n-amyl pyridine. In the examples, foamed polyurethanes are made by reacting a condensation product of propylene oxide and glycerol with toluylene diisocyanate in the presence of: <FORM:0944904/C3/2> (where (CnH2nO)w is a mixed polyoxyethylene-oxypropylene block containing n oxyethylene and 13 oxypropylene units), dimethyl cetyl t-amine, a mixture of mono- and di-phenyl-n-heptylamines and (1) aqueous sodium hydroxide; (2) aqueous sodium hydroxide, zinc stearate and starch and (3) zinc stearate and water. Specification 804,369 and U.S.A. Specification 2,834,748 are referred to.
GB351360A 1959-02-02 1960-02-01 Polyurethane foam and method of making same Expired GB944904A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US79032359A 1959-02-02 1959-02-02

Publications (1)

Publication Number Publication Date
GB944904A true GB944904A (en) 1963-12-18

Family

ID=25150322

Family Applications (1)

Application Number Title Priority Date Filing Date
GB351360A Expired GB944904A (en) 1959-02-02 1960-02-01 Polyurethane foam and method of making same

Country Status (4)

Country Link
CA (1) CA924850A (en)
DE (1) DE1494075A1 (en)
ES (1) ES255426A1 (en)
GB (1) GB944904A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008021034A2 (en) * 2006-08-10 2008-02-21 Dow Global Technologies, Inc. Method for preparing viscoelastic polyurethane foam

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4176218A (en) * 1977-10-17 1979-11-27 Basf Wyandotte Corporation High resilience flexible foamed polyurethanes, foamable mixtures and process therefor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008021034A2 (en) * 2006-08-10 2008-02-21 Dow Global Technologies, Inc. Method for preparing viscoelastic polyurethane foam
WO2008021034A3 (en) * 2006-08-10 2008-05-22 Dow Global Technologies Inc Method for preparing viscoelastic polyurethane foam
CN101522742B (en) * 2006-08-10 2012-07-04 陶氏环球技术有限责任公司 Method for preparing viscoelastic polyurethane foam

Also Published As

Publication number Publication date
DE1494075A1 (en) 1970-04-09
ES255426A1 (en) 1960-06-01
CA924850A (en) 1973-04-17

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