GB939466A - Solution and method for treating glass fibres - Google Patents
Solution and method for treating glass fibresInfo
- Publication number
- GB939466A GB939466A GB22984/61A GB2298461A GB939466A GB 939466 A GB939466 A GB 939466A GB 22984/61 A GB22984/61 A GB 22984/61A GB 2298461 A GB2298461 A GB 2298461A GB 939466 A GB939466 A GB 939466A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silane
- vinyl
- allyl
- triethoxy
- aminopropyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003365 glass fiber Substances 0.000 title abstract 6
- -1 trialkoxy silyl alkylamine Chemical class 0.000 abstract 12
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 7
- 229910000077 silane Inorganic materials 0.000 abstract 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 4
- 229920000126 latex Polymers 0.000 abstract 4
- 239000004753 textile Substances 0.000 abstract 4
- 239000000080 wetting agent Substances 0.000 abstract 4
- 125000004423 acyloxy group Chemical group 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 238000004513 sizing Methods 0.000 abstract 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 abstract 2
- WRLLYJNYOVNQSC-UHFFFAOYSA-N (acetyloxy-ethenyl-propanoyloxysilyl) propanoate Chemical compound C(=C)[Si](OC(CC)=O)(OC(CC)=O)OC(C)=O WRLLYJNYOVNQSC-UHFFFAOYSA-N 0.000 abstract 2
- HXJZEGBVQCRLOD-UHFFFAOYSA-N 1-triethoxysilylpropan-2-amine Chemical compound CCO[Si](CC(C)N)(OCC)OCC HXJZEGBVQCRLOD-UHFFFAOYSA-N 0.000 abstract 2
- RWLDCNACDPTRMY-UHFFFAOYSA-N 3-triethoxysilyl-n-(3-triethoxysilylpropyl)propan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCNCCC[Si](OCC)(OCC)OCC RWLDCNACDPTRMY-UHFFFAOYSA-N 0.000 abstract 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- 239000004793 Polystyrene Substances 0.000 abstract 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- 239000007983 Tris buffer Substances 0.000 abstract 2
- HTIAQFHCIJXSBN-UHFFFAOYSA-N [di(butanoyloxy)-ethenylsilyl] butanoate Chemical compound CCCC(=O)O[Si](OC(=O)CCC)(OC(=O)CCC)C=C HTIAQFHCIJXSBN-UHFFFAOYSA-N 0.000 abstract 2
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 abstract 2
- WWADDWJFBMINFK-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] propanoate Chemical compound C(=C)[Si](OC(CC)=O)(OC(C)=O)OC(C)=O WWADDWJFBMINFK-UHFFFAOYSA-N 0.000 abstract 2
- XRLWQTOZMISADO-UHFFFAOYSA-N [diacetyloxy(prop-2-enyl)silyl] acetate Chemical compound CC(=O)O[Si](CC=C)(OC(C)=O)OC(C)=O XRLWQTOZMISADO-UHFFFAOYSA-N 0.000 abstract 2
- XBJMDQNMFHPWHO-UHFFFAOYSA-N [ethenyl-di(propanoyloxy)silyl] propanoate Chemical compound CCC(=O)O[Si](OC(=O)CC)(OC(=O)CC)C=C XBJMDQNMFHPWHO-UHFFFAOYSA-N 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 2
- 239000003822 epoxy resin Substances 0.000 abstract 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- GHLZUHZBBNDWHW-UHFFFAOYSA-N nonanamide Chemical compound CCCCCCCCC(N)=O GHLZUHZBBNDWHW-UHFFFAOYSA-N 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- 229920000647 polyepoxide Polymers 0.000 abstract 2
- 229920001225 polyester resin Polymers 0.000 abstract 2
- 239000004645 polyester resin Substances 0.000 abstract 2
- 229920002223 polystyrene Polymers 0.000 abstract 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 2
- 239000011118 polyvinyl acetate Substances 0.000 abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract 2
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 2
- ADCFFIGZZVYRNB-UHFFFAOYSA-N silyl propanoate Chemical compound CCC(=O)O[SiH3] ADCFFIGZZVYRNB-UHFFFAOYSA-N 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 2
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- 238000009941 weaving Methods 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 230000002787 reinforcement Effects 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- UCSBCWBHZLSFGC-UHFFFAOYSA-N tributoxysilane Chemical compound CCCCO[SiH](OCCCC)OCCCC UCSBCWBHZLSFGC-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1896—Compounds having one or more Si-O-acyl linkages
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/40—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
Aqueous compositions for sizing glass fibre filaments comprise a synthetic latex made by the emulsion polymerization of an ethylenic monomer, an alkenyl acyloxy silane, a textile softener for glass fibre filaments and a trialkoxy silyl alkylamine other than gammaaminopropyl triethoxy silane. Specified latices are polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride and polystyrene. The alkenyl acyloxy silane may be vinyl triacetoxy silane, vinyl diacetoxy propionoxy silane, vinyl acetoxy dipropionoxy silane, allyl triacetoxy silane, vinyl tributyroxy silane, vinyl tripropionoxy silane, allyl diacetoxy propionoxy silane, allyl acetoxy dipropionoxy silane, allyl tripropionoxy silane and vinyl trimonochloracetoxy silane. The textile softener may be an acid solubilized fatty acid amide, e.g. pelargonic acid amide solubilized with acetic acid, or an alkyl imidazoline derivative, e.g. the reaction product of tetraethylene pentamine and stearic acid. The trialkoxy silyl alkylamine may be gamma-aminopropyl trimethoxy silane, gamma-aminopropyl tripropoxy silane, betaaminopropyl triethoxy silane, bis(triethoxy silyl propyl) amine, tris(triethoxy silyl propyl) amine, bis(tripropoxy silyl propyl) amine or gammaaminopropyl tributoxy silane. The sizing compositions may also comprise wetting agents, particularly cationic or non-ionic wetting agents, and melamine-formaldehyde condensates. The compositions may be applied to glass fibre strands before twisting, plying and weaving, particularly where the fibres are to be used for reinforcing polyester or epoxy resins, e.g. in the preparation of laminates.ALSO:Strands of glass fibre filaments are sized before twisting, plying and weaving, by applying thereto aqueous compositions comprising a synthetic latex made by emulsion polymerization of an ethylenic monomer, an alkenyl acyloxy silane, a textile softener for glass fibre filaments and a trialkoxy silyl alkylamine other than gamma-aminopropyl triethoxy silane, and drying. Specified latices are of polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride and polystyrene. Specified alkenyl silanes are vinyl triacetoxy silane, vinyl diacetoxy propionoxy silane, vinyl acetoxy dipropionoxy silane, allyl triacetoxy silane, vinyl tributyroxy silane, vinyl tripropionoxy silane, allyl diacetoxy propionoxy silane, allyl acetoxy dipropionoxy silane, allyl tripropionoxy silane, and vinyl trimonochloracetoxy silane. Specified textile softeners are pelargonic acid amide solubilized with acetic acid, and the reaction product of tetraethylene pentamine and stearic acid. Specified trialkoxy silyl alkylamines are gamma-aminopropyl trimethoxy silane, gamma-aminopropyl tripropoxy silane, beta aminopropyl triethoxy silane, bis (triethoxy silyl propyl)amine, tris(triethoxy silyl propyl)amine, bis(tripropoxy silyl propyl) amine, and gamma-aminopropyl tributoxy silane. The sized strands may be used for the fabrication of cloth, chopped strand mats and woven rovings for the reinforcement of polyester and epoxy resins, e.g. in the manufacture of laminates. The sizing compositions may also comprise wetting agents, particularly cationic or non-ionic wetting agents, and melamine-formaldehyde condensates.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79031A US3168389A (en) | 1960-12-28 | 1960-12-28 | Silane forming size and glass fiber strands threated therewith for resin reinforcement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB939466A true GB939466A (en) | 1963-10-16 |
Family
ID=22147977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB22984/61A Expired GB939466A (en) | 1960-12-28 | 1961-06-26 | Solution and method for treating glass fibres |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3168389A (en) |
| BE (1) | BE606417R (en) |
| DE (1) | DE1157353B (en) |
| GB (1) | GB939466A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885198A (en) * | 2019-11-23 | 2020-03-17 | 单县大道玻纤有限公司 | Medium-alkali wax-free glass fiber yarn |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3318757A (en) * | 1961-12-06 | 1967-05-09 | Burlington Industries Inc | Polyvinyl chloride resin glass bond with secondary aminoalkyl silane primer |
| US3287204A (en) * | 1962-08-22 | 1966-11-22 | Owens Corning Fiberglass Corp | Elastomeric-glass fiber products and process and elements for use in same |
| US3869306A (en) * | 1964-09-22 | 1975-03-04 | Owens Corning Fiberglass Corp | Glass fiber reinforced elastomers |
| NL6512528A (en) * | 1964-09-30 | 1966-03-31 | ||
| US3418094A (en) * | 1964-12-29 | 1968-12-24 | Union Carbide Corp | Anti-static agents for glass fiber materials |
| US3484223A (en) * | 1965-09-08 | 1969-12-16 | Exxon Research Engineering Co | Method for sizing glass fibers |
| US3513049A (en) * | 1965-10-28 | 1970-05-19 | Owens Corning Fiberglass Corp | Glass fiber treatment for elastomeric reinforcement and compositions |
| US3425862A (en) * | 1966-01-20 | 1969-02-04 | Monsanto Co | Method of making polymer coated inorganic filamentary materials |
| US3504625A (en) * | 1968-05-03 | 1970-04-07 | Monsanto Graphic Syst | Electrostatic printing |
| US3953648A (en) * | 1972-04-17 | 1976-04-27 | Owens-Corning Fiberglas Corporation | Glass fiber reinforced elastomers |
| US4001154A (en) * | 1973-09-04 | 1977-01-04 | The Dow Chemical Company | Primer adhesive composition |
| DE2365272A1 (en) * | 1973-12-31 | 1975-07-10 | Dynamit Nobel Ag | BETA-AMINOAETHYLSILANES AND PROCESS FOR PREPARING THESE COMPOUNDS |
| FR2421982A1 (en) * | 1978-04-03 | 1979-11-02 | Saint Gobain | SIZING COMPOSITION AND GLASS FIBERS TREATED WITH THIS COMPOSITION |
| US4298653A (en) * | 1978-12-15 | 1981-11-03 | Ppg Industries, Inc. | Method for producing an improved bundle of a plurality of fiber glass strands |
| US4233809A (en) * | 1978-12-20 | 1980-11-18 | Ppg Industries, Inc. | Size composition for glass fibers |
| US4185138A (en) * | 1978-12-20 | 1980-01-22 | Ppg Industries, Inc. | Size composition and method of producing same to render glass fiber having improved dispersibility in aqueous solutions |
| USRE30699E (en) * | 1979-04-02 | 1981-08-04 | J. M. Huber Corporation | Polyurethanes containing amino organosilane modified clay |
| USRE30450E (en) * | 1979-04-02 | 1980-12-16 | J. M. Huber Corporation | Surface modified pigments |
| US4286019A (en) * | 1979-06-04 | 1981-08-25 | Ppg Industries, Inc. | Polymer sizing compositions and methods yielding sized glass fibers having reduced tackiness |
| US4455343A (en) * | 1980-12-29 | 1984-06-19 | Ppg Industries, Inc. | Aqueous treating composition for glass fiber strands used to produce mats for thermoplastics |
| EP0075989B1 (en) * | 1981-09-25 | 1987-05-13 | THE PROCTER & GAMBLE COMPANY | Fabric softening compositions containing amino-silanes |
| US4517916A (en) * | 1982-09-30 | 1985-05-21 | Ppg Industries, Inc. | Applicator for treating textile filaments with chemical treatments |
| DK608788A (en) * | 1988-11-01 | 1990-05-02 | Rockwool Int | PROCEDURE FOR MANUFACTURING A BINDING CONTAINER MINERAL WOOL PRODUCT |
| US7638160B2 (en) * | 2005-05-02 | 2009-12-29 | Johns Manville | Method for producing fiberglass materials and compositions resulting from the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE517856A (en) * | 1952-02-23 | 1900-01-01 | ||
| US2754237A (en) * | 1953-11-06 | 1956-07-10 | Us Rubber Co | Method of making composite resin-glass structures |
| US2832754A (en) * | 1955-01-21 | 1958-04-29 | Union Carbide Corp | Alkoxysilylpropylamines |
| DE1068462B (en) * | 1955-11-18 | 1959-11-05 | General Aniline S. Film Corporation, New York, N. Y. (V. St. A.) | Process for the production of fiberglass laminates |
| US3045036A (en) * | 1957-11-18 | 1962-07-17 | Union Carbide Corp | End-blocked aminoalkylpolysiloxanes and process for cyclic aminoalkyl-siloxanes |
| US2994619A (en) * | 1958-08-01 | 1961-08-01 | Pittsburgh Plate Glass Co | Method of treating glass fibers with a size comprising an alkenyl triacyloxy silane and a synthetic latex, and glass fibers so treated |
| US2934464A (en) * | 1958-12-18 | 1960-04-26 | Dow Corning | Organosiloxane resin compositions and glass laminates impregnated therewith |
-
1960
- 1960-12-28 US US79031A patent/US3168389A/en not_active Expired - Lifetime
-
1961
- 1961-06-26 GB GB22984/61A patent/GB939466A/en not_active Expired
- 1961-06-28 DE DEP27445A patent/DE1157353B/en active Pending
- 1961-07-20 BE BE606417A patent/BE606417R/en active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110885198A (en) * | 2019-11-23 | 2020-03-17 | 单县大道玻纤有限公司 | Medium-alkali wax-free glass fiber yarn |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1157353B (en) | 1963-11-14 |
| BE606417R (en) | 1962-01-22 |
| US3168389A (en) | 1965-02-02 |
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