GB939465A - Polyurethane foam - Google Patents
Polyurethane foamInfo
- Publication number
- GB939465A GB939465A GB7180/62A GB718062A GB939465A GB 939465 A GB939465 A GB 939465A GB 7180/62 A GB7180/62 A GB 7180/62A GB 718062 A GB718062 A GB 718062A GB 939465 A GB939465 A GB 939465A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyol
- mixture
- tall oil
- trichlorofluoromethane
- listed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/329—Hydroxyamines containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
- C08G18/6765—Low-molecular-weight compounds containing the unsaturation at least partially in a cyclic ring having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A process for the production of a substantially rigid polyurethane foam having predominantly closed pores comprises reacting an organic polyisocyanate, a polyol having a molecular weight of from 100 to 600 and containing at least one tertiary nitrogen atom and at least three hydroxyl groups, and tall oil (the amount of tall oil in the resulting mixture calculated on the combined weight of the polyol and the tall oil being from 30% by weight to 90% by weight) and simultaneously or subsequently foaming the reaction mixture by means of a blowing agent. Suitable polyisocyanates are listed, and include crude 4,41-diphenylmethane diisocyanate and crude 2,4- or 2,6-toluene diisocyanates which contain hydrolysable chlorine, such materials giving products of greater dimensional stability. A mixture of di- and tri-isocyanates can be used. The polyol containing tertiary nitrogen can be obtained by condensing a polyamine with an alkylene oxide. A number of aliphatic, aromatic and heterocyclic polyamines are listed. The aromatic compounds may contain alkyl, alkoxy, nitro or hydroxyalkylene substituents. A diamine which contains one primary and one secondary amino group can also be used. Hydroxy poly(alkylene thioether) derivatives are also suitable starting materials. Blowing of the products can result from the presence in the reaction mixture of water, an inert gas such as air, nitrogen, carbon dioxide or argon, or trichlorofluoromethane or other chlorofluoroalkane, or pentane or hexane. One shot or prepolymer methods can be used. As catalysts tin compounds and tertiary amines are listed. A silane oxyalkylene block copolymer is also preferably present in the reaction mixture. In Example (1) there are mixed tall oil and N,N,N1,N1-tetrakis-(2-hydroxypropyl) ethylene diamine, and then, using the apparatus of Specification 769,682, there are mixed in crude 4,41-diphenylmethane diisocyanate containing hydrolysable chloride, a silicone oil, and trichlorofluoromethane. The mixture is discharged into a cavity and rises and sets to a rigid foam. In other generally similar Examples (2) to (5) the polyol is a propylene oxide/tolylene diamine condensate and there are used as catalysts a mixture of 1-methyl-4-dimethylaminoethyl-piperazine and stannous octoate. In Example (5) water replaces trichlorofluoromethane as blowing agent. Specifications 769,680, 804,369 and 939,464 also are referred to.ALSO:A process for the production of a substantially rigid polyurethane foam having predominantly closed pores comprises reacting an organic polyisocyanate, a polyol having a molecular of from 100 to 600 and containing at least one tertiary nitrogen atom and at least three hydroxyl groups, and tall oil (the amount of tall oil in the resulting mixture calculated on the combined weight of the polyol and the tall oil being from 30% by weight to 90% by weight) and simultaneously or subsequently foaming the reaction mixture by means of a blowing agent. Suitable polyisocyanates are listed, and include crude 4, 41- diphenyl-methane diisocyanate and crude 2, 4- or 2, 6-toluene diisocyanates which contain hydrolysable chlorine, such materials giving products of greater dimensional stability. A mixture of di- and triisocyanates can be used. The polyol containing tertiary nitrogen can be obtained by condensing a polyamine with an alkylene oxide. A number of aliphatic, aromatic and heterocyclic polyamines are listed. The aromatic compounds may contain alkyl, alkoxy, nitor or hydroxyalkylene substituents. A diamine which contains one primary and one secondary amino group can also be used. Hydroxy poly(alkylene thioether) derivatives are also suitable starting materials. Blowing of the products can result from the presence in the reaction mixture of water, an inert gas such as air, nitrogen, carbon dioxide or argon, or trichlorofluoromethane or other chlorofluoroalkane, or pentane or hexane. One-shot or prepolymer methods can be used. As catalysts tin compounds and tertiary amines are listed. A silane oxyalkylene block copolymer is also preferably present in the reaction mixture. In Example (1) there are mixed tall oil and N, N, N1, N1- tetrakis(3-hydroxypropyl)ethylene diamine, and then, using the apparatus described in Specification 769,682, there are mixed in crude 4, 41-diphenylmethane diisocyanate containing hydrolysable chloride, a silicone oil, and trichlorofluoromethane. The mixture is discharged into a cavity and rises and sets to a rigid foam. In other, generally similar Examples (2) to (5) the polyol is a propylene oxide/tolylene diamine condensate and there are used as catalysts a mixture of 1-methyl-4 dimethyl-aminoethyl-piperazine and stannous octoate. In Example (5) water replaces trichlorofluoromethane as blowing agent. Specifications 769,680, 804,369 and 939,464 also are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9090961A | 1961-02-23 | 1961-02-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB939465A true GB939465A (en) | 1963-10-16 |
Family
ID=22224911
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7180/62A Expired GB939465A (en) | 1961-02-23 | 1962-02-23 | Polyurethane foam |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE614134A (en) |
DE (1) | DE1160613B (en) |
GB (1) | GB939465A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI77676C (en) * | 1986-01-22 | 1989-04-10 | Lohja Ab Oy | FOERFARANDE FOER FRAMSTAELLNING AV ETT ISOCYANURATMODIFIERAT POLYURETANSKUM OCH MEDELST FOERFARANDET FRAMSTAELLT POLYURETANSKUM. |
CN113214731A (en) * | 2021-04-26 | 2021-08-06 | 中科院广州化灌工程有限公司 | Durable plant oil-based anti-graffiti easy-to-clean coating and preparation method and application thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT699971A (en) * | 1958-08-15 |
-
1962
- 1962-02-03 DE DEM51672A patent/DE1160613B/en active Pending
- 1962-02-20 BE BE614134A patent/BE614134A/en unknown
- 1962-02-23 GB GB7180/62A patent/GB939465A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1160613B (en) | 1964-01-02 |
BE614134A (en) | 1962-06-18 |
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