GB935420A - Fibrous articles and latices for use in the manufacture thereof - Google Patents

Fibrous articles and latices for use in the manufacture thereof

Info

Publication number
GB935420A
GB935420A GB24599/59A GB2459959A GB935420A GB 935420 A GB935420 A GB 935420A GB 24599/59 A GB24599/59 A GB 24599/59A GB 2459959 A GB2459959 A GB 2459959A GB 935420 A GB935420 A GB 935420A
Authority
GB
United Kingdom
Prior art keywords
alpha
vinyl
methyl
chloro
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB24599/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milky Way Products Co
Original Assignee
Milky Way Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US752429A external-priority patent/US3156581A/en
Application filed by Milky Way Products Co filed Critical Milky Way Products Co
Publication of GB935420A publication Critical patent/GB935420A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/205—Adhesives in the form of films or foils characterised by their carriers characterised by the backing impregnating composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/21—Paper; Textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

A copolymer comprising a conjugated diene and a polycarboxylic acid, or a compound from which such acid may be derived, is used for internally bonding paper (see Group VIII). The copolymer may be prepared, in the form of a synthetic rubber latex, by emulsion polymerization, in an aqueous medium, of monomeric material containing 20 to 90%, by weight, of at least one aliphatic conjugated diene, preferably having 4 to 10 carbon atoms per molecule, 10 to 75% of at least one non-carboxylic mono-olefinic compound, 0,5 to 20% of at least one olefinically unsaturated polycarboxylic acid and, optionally, 0,5 to 5% of an olefinically unsaturated monocarboxylic acid. Specified conjugated dienes are:- butadiene1,3 and its 2-methyl, 2,3-dimethyl, 2-neopentenyl, 2-chloro, 1- or 2-cyano derivatives, piperylene (pentadienes) and the hexadienes. Specified non-carboxylic monoolefinic compounds are:- acrylonitrile, alpha-chloroacrylonitrile, methacrylonitrile, methacrylonitrile, ethacrylonitrile, methyl acrylate, methyl and butyl methacrylate, methyl and isobutyl dichloroacrylate, methyl ethacrylate, styrene and its alpha-methyl, alpha-chloro, p-cyano and pphenyl derivatives, e.g. vinyl toluene; vinyl pyridine, vinyl naphthalene and vinylidene chloride. The olefinically unsaturated polycarboxylic acid may have the formula:-R-CH=CX-(Z)n,COOH in which R is preferably hydrogen or carboxyl, but may be a carboxylic ester, alkyl or alkenyl group, X is hydrogen, a halogen, a carboxyl, cyano, sulpho, alkyl, aryl, thienyl or furyl group, Z is a methylene, substituted methylene, allyl, arylene, thienylene or furylene group, n is zero or an integer not greater than 3 and at least one of the groups R and X is carboxyl or Z contains carboxyl. Specified olefinically unsaturated polycarboxylic acids are:- fumaric, maleic, ethyl maleic, citraconic, mesaconic, itaconic, methyl itaconic, aconitic, muconic, hydromuconic, glutaconic, 3-carboxy-pentadiene(2,4)-oic-1, beta-(p-carboxyphenyl) acrylic, 2,4pentadiendioic-1,3, and the dimer and trimer of methacrylic acid (which are regarded as being monomers). Anhydrides, esters, partial esters, nitriles, amides and acid chlorides of these acids may be used and subsequently hydrolysed. Specified olefinically unsaturated mono-carboxylic acids are:- acrylic and its alpha-chloro, alpha- and beta-vinyl, alpha-isopropenyl, alpha-furyl, alpha-styryl derivatives, e.g. 2-carboxy-4-phenyl-1,3-butadiene; methacrylic, ethacrylic, sorbic and its alpha-methyl, alpha-ethyl, alpha-chloro, alpha-bromo, beta-chloro, alpha-beta and gamma-epsilon dimethyl derivatives, hydrosorbic, 2,4-heptadienoic, 2-4-hexadienoic, crotonic, alpha-chlorocrotonic, cinnamic and its m-chloro, p-chloro and alpha-vinyl derivatives, vinyl-thiophenic, vinyl-furoic p-vinyl-benzoic and vinyl-naphthoic. The aqueous emulsion undergoing polymerization may contain an emulsifier, a chelating agent, an initiator, a modifier and a stabilizer, specific examples of which are given. An antioxidant, such as a polyalkyl polyphenol, a melamineformaldehyde resin and a pigment, such as titanium dioxide, may be mixed with the resulting latex.
GB24599/59A 1958-08-01 1959-07-17 Fibrous articles and latices for use in the manufacture thereof Expired GB935420A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US752429A US3156581A (en) 1958-08-01 1958-08-01 Pressure-sensitive adhesive tape and impregnated fibrous web
US288466A US3256234A (en) 1958-08-01 1963-06-17 Latex compositions

Publications (1)

Publication Number Publication Date
GB935420A true GB935420A (en) 1963-08-28

Family

ID=26965032

Family Applications (1)

Application Number Title Priority Date Filing Date
GB24599/59A Expired GB935420A (en) 1958-08-01 1959-07-17 Fibrous articles and latices for use in the manufacture thereof

Country Status (5)

Country Link
US (1) US3256234A (en)
BE (1) BE636527A (en)
DE (1) DE1191683B (en)
GB (1) GB935420A (en)
NL (2) NL241913A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4272426A (en) 1979-03-07 1981-06-09 The International Synthetic Rubber Company Ltd. Preparation of latices
GB2157296A (en) * 1984-04-10 1985-10-23 Polysar Ltd Latex compositions for impregnating non-woven webs
WO2001007515A1 (en) * 1999-07-26 2001-02-01 Reichhold, Inc. Compositions suitable for making elastomeric articles of manufacture

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE638244A (en) * 1962-11-26
US3422050A (en) * 1964-07-22 1969-01-14 Standard Brands Chem Ind Inc Copolymers of conjugated diolefins and partial esters of unsaturated polybasic acids
US3335827A (en) * 1964-11-17 1967-08-15 Pellon Corp Shaped articles and method of producing same
US3444121A (en) * 1965-12-23 1969-05-13 Firestone Tire & Rubber Co Aqueous rubbery terpolymer latex containing an epoxy resin
US3505156A (en) * 1966-10-19 1970-04-07 Ici Ltd Process of applying polymeric latices to a textile article and the resulting article
US3489820A (en) * 1967-03-24 1970-01-13 Dow Chemical Co Elastic fibers from emulsion polymers
GB1349586A (en) * 1970-12-11 1974-04-03 Polysar Ltd Latex composition and process for producing the same
US3864195A (en) * 1972-01-27 1975-02-04 Henry G Patterson Stable synthetic carpet backing material
US4044196A (en) * 1972-03-30 1977-08-23 Bayer Aktiengesellschaft Crosslinked copolymers of α,β-olefinically unsaturated dicarboxylic anhydrides
US4087572A (en) * 1972-11-16 1978-05-02 The Dow Chemical Company Method of preventing environmental erosion
US3874905A (en) * 1973-06-28 1975-04-01 Union Oil Co Wax coated paper of improved water resistance
US4268546A (en) * 1979-01-18 1981-05-19 The Dow Chemical Company Method of making non-woven fabrics from synthetic fibers
DE3018385A1 (en) * 1980-05-14 1982-01-21 Bayer Ag, 5090 Leverkusen METHOD FOR TREATING FIBER MATERIALS
US4405746A (en) * 1981-02-27 1983-09-20 Ppg Industries, Inc. Aqueous, adhesive coating composition with a non-self-crosslinkable elastomer for use with filamentary materials
US4436866A (en) 1981-02-27 1984-03-13 Ppg Industries, Inc. Aqueous, adhesive coating composition with a non-selfcrosslinkable elastomer for use with filamentary materials
US4439556A (en) * 1981-02-27 1984-03-27 Ppg Industries, Inc. Aqueous, adhesive coating composition with a non-selfcrosslinkable elastomer for use with filamentary materials
US4434208A (en) 1981-02-27 1984-02-28 Ppg Industries, Inc. Aqueous, adhesive coating composition with a non-self-crosslinkable elastomer for use with filamentary materials
US4440881A (en) * 1981-02-27 1984-04-03 Ppg Industries, Inc. Aqueous, adhesive coating composition with a non-selfcrosslinkable elastomer for use with filamentary materials
US4359546A (en) * 1981-06-18 1982-11-16 Owens-Corning Fiberglas Corporation Mats for asphalt underlay
US4378272A (en) * 1981-06-24 1983-03-29 Gaf Corporation Water purifying latex binder
EP0149880A3 (en) * 1983-05-26 1986-07-16 BASF Aktiengesellschaft Non-woven webs of synthetic fibres consolidated by means of carboxylated styrene-butadiene latices, and disposable articles made therefrom
US5444118A (en) * 1989-06-30 1995-08-22 Japan Synthetic Rubber Co., Ltd. Process for producing copolymer latex and paper coating composition, carpet backing composition or adhesive composition comprising said latex
DE69013995T2 (en) * 1989-06-30 1995-03-16 Japan Synthetic Rubber Co Ltd Process for making a copolymer latex and paper coating composition, carpet back coating composition or adhesive mixture containing this latex.
US5403640A (en) * 1993-08-27 1995-04-04 Reichhold Chemicals, Inc. Textile coating and method of using the same
US6110525A (en) * 1997-09-12 2000-08-29 Pro-Sol, Inc. Coating composition for protecting surfaces and method of using same

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE914213C (en) * 1939-05-27 1954-06-28 Basf Ag Process for finishing paper
DE862956C (en) * 1941-10-30 1953-01-15 Basf Ag Process for the production of copolymers
US2723195A (en) * 1950-07-29 1955-11-08 Monsanto Chemicals Paper products and processes
US2698318A (en) * 1950-10-05 1954-12-28 Goodrich Co B F Rubbery interpolymers of butadiene-1, 3 hydrocarbons with polyunsaturated carboxylic acids
US2724707A (en) * 1950-11-01 1955-11-22 Goodrich Co B F Elastic synthetic rubber composition and method of making same
NL84147C (en) * 1951-04-09
DE876035C (en) * 1951-07-08 1953-05-07 Dynamit Nobel Ag Process for the surface finishing of paper
BE532766A (en) * 1953-10-23
US2952043A (en) * 1953-12-24 1960-09-13 Phillips Petroleum Co Production of films from carboxylic acid containing conjugated diene polymer and an amine containing conjugated diene polymer
US2849426A (en) * 1954-01-19 1958-08-26 Firestone Tire & Rubber Co Treatment of carboxyl-containing polymers
US2880186A (en) * 1954-04-16 1959-03-31 Int Latex Corp Compositions containing natural rubber and a carboxyl-containing diene polymer, a film thereof, and method of making same
US2959821A (en) * 1955-02-11 1960-11-15 Bayer Ag Dipping process wherein cross-linking agent is applied in coagulating bath
NL99606C (en) * 1955-06-29
US2859193A (en) * 1956-07-30 1958-11-04 Goodrich Co B F Aqueous dispersion comprising carboxyl containing elastomer, vulcanizing agent, and formaldehyde
US2947733A (en) * 1957-04-19 1960-08-02 Firestone Tire & Rubber Co Process of curing a rubbery copolymer of a conjugated diene and a carboxylic acid oranhydride with dicyandiamide, and cured product obtained thereby
US2944044A (en) * 1958-06-09 1960-07-05 Monsanto Chemicals Polymer blend of a carboxyl-containing monovinylidene aromatic polymer and a carboxyl-containing conjugated 1, 3-diene polymer

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4272426A (en) 1979-03-07 1981-06-09 The International Synthetic Rubber Company Ltd. Preparation of latices
GB2157296A (en) * 1984-04-10 1985-10-23 Polysar Ltd Latex compositions for impregnating non-woven webs
FR2566010A1 (en) * 1984-04-10 1985-12-20 Polysar Ltd PROCESS FOR PRODUCING A NON-WOVEN ETOFF OF NATURAL OR SYNTHETIC FIBERS
WO2001007515A1 (en) * 1999-07-26 2001-02-01 Reichhold, Inc. Compositions suitable for making elastomeric articles of manufacture
US6369154B1 (en) 1999-07-26 2002-04-09 Reichhold, Inc. Compositions suitable for making elastomeric articles of manufacture

Also Published As

Publication number Publication date
NL241913A (en)
DE1191683B (en) 1965-04-22
NL129802C (en)
BE636527A (en)
US3256234A (en) 1966-06-14

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