GB935098A - Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials - Google Patents

Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials

Info

Publication number
GB935098A
GB935098A GB19130/60A GB1913060A GB935098A GB 935098 A GB935098 A GB 935098A GB 19130/60 A GB19130/60 A GB 19130/60A GB 1913060 A GB1913060 A GB 1913060A GB 935098 A GB935098 A GB 935098A
Authority
GB
United Kingdom
Prior art keywords
ammonia
sulphite
solution
compounds
aqueous solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19130/60A
Inventor
Harold Coates
Brian Chalkley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay Solutions UK Ltd
Original Assignee
Albright and Wilson Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL259535D priority Critical patent/NL259535A/xx
Priority to NL129265D priority patent/NL129265C/xx
Priority to NL124172D priority patent/NL124172C/xx
Priority to NL265324D priority patent/NL265324A/xx
Priority to GB3567656A priority patent/GB882993A/en
Priority claimed from GB33719/59A external-priority patent/GB906314A/en
Priority to GB33719/59A priority patent/GB906314A/en
Priority to US85638059 priority patent/US2983623A/en
Application filed by Albright and Wilson Ltd filed Critical Albright and Wilson Ltd
Priority to CH690361A priority patent/CH393905A/en
Priority to CH1117660A priority patent/CH372272A/en
Priority to US6255760 priority patent/US3096201A/en
Priority to FR845840A priority patent/FR1280804A/en
Priority to FR863172A priority patent/FR1305971A/en
Priority to DE19611419366 priority patent/DE1419366A1/en
Priority to CH1451561A priority patent/CH416094A/en
Priority to CH625961A priority patent/CH372633A/en
Publication of GB935098A publication Critical patent/GB935098A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/34—Ignifugeants
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/06—Phosphorus linked to carbon only
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D06M15/415—Phenol-aldehyde or phenol-ketone resins modified by compounds containing phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
    • D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
    • D06M15/673—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain containing phosphorus and nitrogen in the main chain
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/02—Chemical or biochemical treatment
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0002—Flame-resistant papers; (complex) compositions rendering paper fire-resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Polymers are derived from methylol phosphorus compounds (such as reaction products of tetrakis(hydroxymethyl) phosphonium chloride (THPC) or tris(hydroxymethyl) phosphine oxide (THPO) with compounds capable of condensing with formaldehyde or of esterifying methanol. Suitable such compounds are (1) nitrogen compounds such as (a) urea, guanidine, melamine or methylol melamine, (b) polyamines, e.g. hexamethylene pentamine, (c) primary amines, e.g. cetylamine, cyclohexylamine, aniline, diethanolamine, (d) cyclic imines, e.g. ethylene imine, (e) polypeptides, e.g. poly(hexamethylene adipamide) or a protein, and (2) phenolic compounds. The reactants are heated in aqueous solution with ammonium sulphite or a mixture of an ammonium salt and a sulphite, with or without the addition of a buffer, e.g. sodium bicarbonate, and then treated with an aqueous ammonia system (solution of NH4OH or an ammonium salt of a weak acid which salt is readily hydrolysed, e.g. carbonate or carbamate, or mixtures of steam and ammonia gas). The heating is preferably to 85 DEG -120 DEG C., and the process may conveniently be carried out by impregnating a cellulosic material with an aqueous solution of the polymer and sulphite, heating to 85 DEG -120 DEG C. to dry it and then treating with the ammonia system followed preferably by washing, suitably in a solution of soap or detergent and H2O2 in water, rinsing in hot water, and drying, e.g. at 120 DEG C. Most of the examples relate to the impregnation of fabrics. Specifications 740,269, 761,985, 764,312, 764,313, 764,314, 775,325, 790,641 and 906,314 also are referred to.ALSO:Cellulosic textiles are filled or rendered flameresistant or rot-resistant and have their dyeing properties or lustre modified by (A) impregnating with a polymer prepared from a methylol phosphorus compound and an amino-compound or phenolic compound (see Group IV(a)) in aqueous solution containing ammonium sulphite, or a mixture of an ammonium salt and a sulphite, (B) drying by heat preferably at 85 DEG -120 DEG C. and (C) treating with an aqueous solution of ammonia or of a hydrolysable salt of ammonia and a weak acid (carbonic or carbamic) or with gaseous ammonia in steam. The solution in (A) may also contain a buffer, e.g. sodium bicarbonate. In the examples, cotton drill fabric, cotton wool, viscose, and filter-paper are treated in this way. The fabrics are usually washed in a solution of soap or detergent and hydrogen peroxide and rinsed in hot water before drying. Specifications 740,269, 761,985, 764,312, 764,313, 764,314, 775,325, 790,641 and 906,314 also are referred to.
GB19130/60A 1959-10-05 1960-05-30 Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials Expired GB935098A (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
NL259535D NL259535A (en) 1959-10-05
NL129265D NL129265C (en) 1959-10-05
NL124172D NL124172C (en) 1959-10-05
NL265324D NL265324A (en) 1959-10-05
GB3567656A GB882993A (en) 1959-10-05 1956-11-21 Flame-proofing agents derived from methylol phosphorus polymers
GB33719/59A GB906314A (en) 1960-05-30 1959-10-05 Process for improving the properties of cellulose material
US85638059 US2983623A (en) 1959-10-05 1959-12-01 Flame proofing agents derived from methylol phosphorus polymers
CH690361A CH393905A (en) 1959-10-05 1960-10-05 Method for improving the properties of a non-textile cellulosic material
CH1117660A CH372272A (en) 1959-10-05 1960-10-05 Method for fixing an insoluble phosphorus polymer on a cellulosic textile material and cellulosic textile material obtained by this method
US6255760 US3096201A (en) 1959-10-05 1960-10-14 Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials
FR845840A FR1280804A (en) 1959-10-05 1960-12-03 Process for improving the properties of a cellulosic material
FR863172A FR1305971A (en) 1959-10-05 1961-05-29 Process for increasing the degree of polymerization and insolubility of polymers
DE19611419366 DE1419366A1 (en) 1959-10-05 1961-05-30 Process for rendering further polymerizable methylolphosphorus polymers insoluble
CH1451561A CH416094A (en) 1959-10-05 1961-05-30 Process for increasing the degree of polymerization and insolubility of a still polymerizable methylol-phosphorus polymer and application of this process to modify the properties of a non-textile cellulosic material
CH625961A CH372633A (en) 1959-10-05 1961-05-30 Process for charging a cellulosic textile material with an insoluble phosphorus-containing organic polymer and cellulosic textile material resulting from the implementation of this process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB33719/59A GB906314A (en) 1960-05-30 1959-10-05 Process for improving the properties of cellulose material
DEA0037561 1961-05-30

Publications (1)

Publication Number Publication Date
GB935098A true GB935098A (en) 1963-08-28

Family

ID=25963605

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19130/60A Expired GB935098A (en) 1959-10-05 1960-05-30 Insolubilisation of further-polymerisable methylol-phosphorus polymeric materials

Country Status (1)

Country Link
GB (1) GB935098A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3897205A (en) * 1973-07-06 1975-07-29 Us Agriculture Fireproofing cellulose textiles with tetrakis (hydroxymethyl) phosphonium chloride and aniline
US4185037A (en) * 1971-09-10 1980-01-22 Ciba-Geigy Corporation Process for the manufacture of phosphorus-containing condensation products, the products and their use as flameproofing agents
US4673509A (en) * 1983-08-26 1987-06-16 Albright & Wilson Limited Biocidal water treatment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4185037A (en) * 1971-09-10 1980-01-22 Ciba-Geigy Corporation Process for the manufacture of phosphorus-containing condensation products, the products and their use as flameproofing agents
US3897205A (en) * 1973-07-06 1975-07-29 Us Agriculture Fireproofing cellulose textiles with tetrakis (hydroxymethyl) phosphonium chloride and aniline
US4673509A (en) * 1983-08-26 1987-06-16 Albright & Wilson Limited Biocidal water treatment

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