GB932951A - Improvements in or relating to guanidines - Google Patents
Improvements in or relating to guanidinesInfo
- Publication number
- GB932951A GB932951A GB366659A GB366659A GB932951A GB 932951 A GB932951 A GB 932951A GB 366659 A GB366659 A GB 366659A GB 366659 A GB366659 A GB 366659A GB 932951 A GB932951 A GB 932951A
- Authority
- GB
- United Kingdom
- Prior art keywords
- addition salt
- acid addition
- formula
- alkyl
- straight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C281/00—Derivatives of carbonic acid containing functional groups covered by groups C07C269/00 - C07C279/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
- C07C281/16—Compounds containing any of the groups, e.g. aminoguanidine
- C07C281/18—Compounds containing any of the groups, e.g. aminoguanidine the other nitrogen atom being further doubly-bound to a carbon atom, e.g. guanylhydrazones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention comprises alkylidene- and alkenylidene-aminoguanidines of the formula <FORM:0932951/IV(a)/1> and acid addition salts thereof, wherein R1 represents a C5-17 alkyl or alkenyl group of which not more than 13 carbon atoms are in a straight chain, and R2 represents hydrogen or a straight or branched C1-5 alkyl group. The compounds are prepared by reacting aminoguanidine, or an addition salt thereof, with a carbonyl compound of the formula R1.CO.R2 and, if desired, converting the product into an acid addition salt or converting such acid addition salt into an addition salt of a different acid.ALSO:A fungicidal composition comprises an alkylidene- or alkenylidene-aminoguanidine of the formula <FORM:0932951/VI/1> or an acid addition salt thereof, e.g. hydrochlorides, phosphates, nitrates, sulphonates, borates, acetates, succinates and phthalates wherein R1 represents a C5-17 alkyl or alkenyl group of which not more than 13 carbon atoms are in a straight chain, and R2 represents hydrogen or a straight or branched C1-5 alkyl group, in admixture with a solid or liquid diluent. Known fungicides, insecticides, bactericides, fertilizers or plant growth regulants may be added. The composition may be formulated as a wettable powder or self-emulsifying concentrate with the aid of an ionic or non-ionic wetting and/or dispersing agent; as a dust obtained by dispersing the active material in sufficient inert absorbent carrier to form a free-flowing powder and diluting the powder with one or more inert carriers; as a fungicidal smoke; or as an aerosol.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB366659A GB932951A (en) | 1959-02-02 | 1959-02-02 | Improvements in or relating to guanidines |
FR817324A FR1247136A (en) | 1959-02-02 | 1960-02-02 | New guanidine derivatives, their preparation and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB366659A GB932951A (en) | 1959-02-02 | 1959-02-02 | Improvements in or relating to guanidines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB932951A true GB932951A (en) | 1963-07-31 |
Family
ID=9762645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB366659A Expired GB932951A (en) | 1959-02-02 | 1959-02-02 | Improvements in or relating to guanidines |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1247136A (en) |
GB (1) | GB932951A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997045401A1 (en) * | 1996-05-24 | 1997-12-04 | Boehringer Ingelheim Kg | New guanidine derivatives, methods of preparing them and their use as drugs |
DE10149919A1 (en) * | 2001-10-10 | 2003-04-24 | Biosphings Ag | New carboxylic acid salts of guanidine derivatives useful as sphingomyelinase inhibitors for treating e.g. tumor, cardiovascular or viral diseases |
WO2015190504A1 (en) * | 2014-06-10 | 2015-12-17 | 三菱瓦斯化学株式会社 | Alkylidene aminoganidine and salt thereof, modifier composition, modified rubber for tire, rubber composition for tire, and tire |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5130324A (en) * | 1984-03-19 | 1992-07-14 | The Rockefeller University | 2-alkylidene-aminoguanidines and methods of use therefor |
-
1959
- 1959-02-02 GB GB366659A patent/GB932951A/en not_active Expired
-
1960
- 1960-02-02 FR FR817324A patent/FR1247136A/en not_active Expired
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997045401A1 (en) * | 1996-05-24 | 1997-12-04 | Boehringer Ingelheim Kg | New guanidine derivatives, methods of preparing them and their use as drugs |
AU734871B2 (en) * | 1996-05-24 | 2001-06-21 | Biosphings Ag | New guanidine derivatives, methods of preparing them, and their use as drugs |
US6284798B1 (en) * | 1996-05-24 | 2001-09-04 | Cancer Research Ventures Limited | Guanidine derivatives, methods of preparing them and their use as drugs |
US6444706B2 (en) | 1996-05-24 | 2002-09-03 | Cancer Research Ventures Limited | Guanidine derivatives, processes for preparing them and their use as pharmaceutical compositions |
DE10149919A1 (en) * | 2001-10-10 | 2003-04-24 | Biosphings Ag | New carboxylic acid salts of guanidine derivatives useful as sphingomyelinase inhibitors for treating e.g. tumor, cardiovascular or viral diseases |
US7078566B2 (en) | 2001-10-10 | 2006-07-18 | Biosphinks Aktiengesellschaft | Salts of guanidine derivatives and pharmaceutical preparations consisting thereof |
WO2015190504A1 (en) * | 2014-06-10 | 2015-12-17 | 三菱瓦斯化学株式会社 | Alkylidene aminoganidine and salt thereof, modifier composition, modified rubber for tire, rubber composition for tire, and tire |
JP5975369B2 (en) * | 2014-06-10 | 2016-08-23 | 三菱瓦斯化学株式会社 | Rubber modifying composition and method for producing the same, tire modified rubber, tire rubber composition and tire |
CN106458870A (en) * | 2014-06-10 | 2017-02-22 | 三菱瓦斯化学株式会社 | Alkylidene aminoganidine and salt thereof, modifier composition, modified rubber for tire, rubber composition for tire, and tire |
US20170129850A1 (en) * | 2014-06-10 | 2017-05-11 | Mitsubishi Gas Chemical Company, Inc. | Alkylidene aminoguanidine and salt thereof, modifying composition, modified rubber for tire, rubber composition for tire, and tire |
EP3156394A4 (en) * | 2014-06-10 | 2017-11-08 | Mitsubishi Gas Chemical Company, Inc. | Alkylidene aminoganidine and salt thereof, modifier composition, modified rubber for tire, rubber composition for tire, and tire |
US10173973B2 (en) * | 2014-06-10 | 2019-01-08 | Mitsubishi Gas Chemical Company, Inc. | Alkylidene aminoguanidine and salt thereof, modifying composition, modified rubber for tire, rubber composition for tire, and tire |
CN106458870B (en) * | 2014-06-10 | 2019-02-19 | 三菱瓦斯化学株式会社 | Alkylidene amino guanidine and its salt, composition for modifying, tire modified rubber, rubber composition for tire and tire |
Also Published As
Publication number | Publication date |
---|---|
FR1247136A (en) | 1960-11-25 |
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