GB932047A - Lubricant compositions and additives for use therein - Google Patents

Lubricant compositions and additives for use therein

Info

Publication number
GB932047A
GB932047A GB27823/59A GB2782359A GB932047A GB 932047 A GB932047 A GB 932047A GB 27823/59 A GB27823/59 A GB 27823/59A GB 2782359 A GB2782359 A GB 2782359A GB 932047 A GB932047 A GB 932047A
Authority
GB
United Kingdom
Prior art keywords
hydrocarbon
alcohol
ingredient
alkyl
neutralized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27823/59A
Inventor
Leonard August Mattano
Roger William Watson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE581706D priority Critical patent/BE581706A/xx
Application filed by Standard Oil Co filed Critical Standard Oil Co
Priority to GB27823/59A priority patent/GB932047A/en
Priority to FR802839A priority patent/FR1233858A/en
Publication of GB932047A publication Critical patent/GB932047A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04Phosphate esters
    • C10M137/10Thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/123Reaction products obtained by phosphorus or phosphorus-containing compounds, e.g. P x S x with organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/082Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/12Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy
    • C10M2223/121Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of organic compounds, e.g. with PxSy, PxSyHal or PxOy of alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2225/00Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2225/04Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
    • C10M2225/041Hydrocarbon polymers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

A normally liquid lubricant which does not gel at elevated temperatures comprises (a) a major proportion of a hydrocarbon lubricating oil, (b) 0,01-25% by weight of an alkaline-earth-neutralized reaction product of a phosphorus sulphide and a normally non-gaseous hydrocarbon and (c) 0,05-10% by weight of a zinc dialkyl dithiophosphate formed from the acid product produced by reacting P2S5 with an alcohol selected from C4-C18 primary alkyl alcohols and mixtures of alkyl alcohols consisting of 30-70 mol. per cent of primary C4-C18 alkyl alcohol and 70-30 mol. per cent of secondary C3-C18 alkyl alcohol, at least one of the alkyl alcohols of such mixtures containing at least 8 carbon atoms, and the ratio of ingredient (b) to ingredient (c) being from 0,75:1 to 20:1 by weight. The term "alkyl" is used to include both saturated and unsaturated aliphatic hydrocarbon radicals. If desired a concentrate of ingredients (a), (b) and (c) may be prepared containing more than 25% of (b) and more than 10% of (c) and the lubricant prepared when desired by diluting the concentrate with further hydrocarbon lubricating oil. The lubricant may contain additional ingredients such as corrosion inhibitors (e.g. sulphurized dipentene), a polymerized high molecular weight fatty acid, pour point depressors, anti-wear agents, anti-oxidants, sulphonates and V.I. improvers. Oils suitable as ingredient (a) are petroleum distillates or residuums, synthetic hydrocarbon oils or mixtures thereof. The non-gaseous hydrocarbon used in preparing ingredient (b) may be an olefin polymer or copolymer, a high molecular weight olefinic hydrocarbon (e.g. cetene, cerotene, melene, paraffin wax olefins or alkenes from cracked petroleum oils), an aromatic hydrocarbon, an essentially paraffinic hydrocarbon material (e.g. brightstock residuums, lubricating oil distillates, petrolatums, paraffin waxes), or the condensation product of such paraffinic material with aromatic hydrocarbons. The phosphorus sulphide may be P2S5, P2S3, P4S3 or P3S7 and may be used in the presence of a sulphurizing agent. The phosphosulphurized material may be subjected to various treatments such as hydrolysis with steam and contact with an adsorbent material or a basic alkaline earth compound before being neutralized with a basic alkaline earth compound such as barium oxide or hydroxide. In the examples, ingredient (a) is a petroleum lubricating oil, ingredient (b) is a barium-neutralized reaction product of P2S5 and polybutene and ingredient (c) is a zinc dialkyl dithiophosphate derived from iso-octyl alcohol, n-amyl alcohol, n-heptyl alcohol, a mixture of isopropyl alcohol and iso-octyl alcohol or a mixture of isopropyl alcohol and n-heptyl alcohol. In some examples, the lubricant also contains sulphurized dipentene and/or polymerized linoleic acid. For comparison purposes, the effect of using a zinc dialkyl dithiophosphate prepared from methyl isobutyl carbinol as ingredient (c) in the compositions of the examples is described. Specification 744,779 is referred to.ALSO:An alkaline-earth-neutralized reaction product of a phosphorus sulphide and an olefin polymer is employed as an ingredient of a lubricating composition (see Group III). The olefin polymer may result from the polymerization of low molecular weight mono-olefinic hydrocarbons or iso-mono-olefinic hydrocarbons, such as propylenes, butylenes and amylenes, or the copolymers obtained by the polymerization of hydrocarbon mixtures containing isomono-olefins and mono-olefins of less than 6 carbon atoms. Thus materials which may be polymerized include a mixture (derived from cracked petroleum) comprising isobutylene, butylenes and butanes and a mixture comprising propane and propylene. The phosphorus sulphide may be P2S5, P2S3, P4S3 or P3S7 and may be used in the presence of a sulphurizing agent. It is preferred to use P2S5 at elevated temperature in the presence of nitrogen or other non-oxidizing atmosphere. The phosphosulphurized material may be subjected to various treatments such as hydrolysis with steam and contact with an adsorbent or a basic alkaline earth compound before being neutralized with a basic alkaline earth compound such as barium oxide or hydroxide. In the examples of lubricating compositions, the salt of a phosphosulphurized polymer employed is a barium-neutralized reaction product of P2S5 and a polybutene of about 1,000 molecular weight. Specification 744,779 is referred to.ALSO:Ingredients of a lubricating composition (see Group III) include (1) a zinc dialkyl dithiophosphate formed from the acid product produced by reacting P2S5 with an alcohol selected from C4-C18 primary alkyl alcohols and mixtures of alkyl alcohols consisting of 30-70 mol per cent of primary C4-C18 alkyl and 70-30 mol per cent of secondary C3-C18 alkyl alcohol, at least one of the alkyl alcohols of such mixtures containing at least 8 carbon atoms and the term "alkyl" being used to include both saturated and unsaturated aliphatic hydrocarbon radicals and (2) an alkaline-earth-neutralized reaction product of a phosphorus sulphide and a normally nongaseous hydrocarbon. The zinc dialkyl dithiophosphate may be derived from such primary alcohols as n- and iso-butanols, pentanols, octanols and nonanols, n-decanol, n-dodecanol, 2-ethyl-1-hexanol, isooleyl, cetyl or stearyl alcohol and the oxo alcohols, or mixtures thereof with such secondary alcohols as isopropanol, methyl ethyl, methyl n-propyl, methyl n-hexyl or methyl isobutyl carbinols and 1-methyl-1-pentanol. In an example, a mixture of n-decanol and isopropanol is reacted with a mineral oil slurry of P2S5 at elevated temperature and the acid product neutralized with a mineral oil slurry of zinc oxide at elevated temperature, blown with inert gas while hot and filtered. In further examples, using the same method, the alcohol employed is isooctanol, n-decanol, or a mixture of isopropanol and iso-octanol with or without n-butanol. The alkaline earth salt of phosphosulphurised hydrocarbon may be derived from such non-gaseous hydrocarbons as high molecular weight olefinic hydrocarbons (e.g. cetene, cerotene, melene, paraffin wax olefins or alkenes from cracked petroleum oils), aromatic hydrocarbons, essentially paraffinic hydrocarbon materials (e.g. bright stock residuums, lubricating oil distillates, petrolatums or paraffin waxes) or the condensation products of such paraffinic materials with aromatic hydrocarbons. The phosphorus sulphide may be P2S5, P2S3, P4S3 or P3S7 and may be used in the presence of a sulphurizing agent. It is preferred to use P2S5 at elevated temperature in the presence of nitrogen or other nonoxidizing atmosphere. The phosphosulphurised material may be subjected to various treatments such as hydrolysis with steam and contact with an adsorbent material or a basic alkaline earth compound before being neutralized with a basic alkaline earth compound such as barium oxide or hydroxide. Specification 744,779 is referred to.
GB27823/59A 1959-08-14 1959-08-14 Lubricant compositions and additives for use therein Expired GB932047A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BE581706D BE581706A (en) 1959-08-14
GB27823/59A GB932047A (en) 1959-08-14 1959-08-14 Lubricant compositions and additives for use therein
FR802839A FR1233858A (en) 1959-08-14 1959-08-14 Lubricating composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB27823/59A GB932047A (en) 1959-08-14 1959-08-14 Lubricant compositions and additives for use therein

Publications (1)

Publication Number Publication Date
GB932047A true GB932047A (en) 1963-07-24

Family

ID=10265877

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27823/59A Expired GB932047A (en) 1959-08-14 1959-08-14 Lubricant compositions and additives for use therein

Country Status (2)

Country Link
BE (1) BE581706A (en)
GB (1) GB932047A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090257959A1 (en) * 2008-04-11 2009-10-15 Whitmire Micro-Gen Research Laboratories, Inc. Pesticidal compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090257959A1 (en) * 2008-04-11 2009-10-15 Whitmire Micro-Gen Research Laboratories, Inc. Pesticidal compositions
US9005644B2 (en) * 2008-04-11 2015-04-14 Basf Corporation Pesticidal compositions

Also Published As

Publication number Publication date
BE581706A (en)

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