GB930881A - Antistatic treatment of textiles - Google Patents
Antistatic treatment of textilesInfo
- Publication number
- GB930881A GB930881A GB4332659A GB4332659A GB930881A GB 930881 A GB930881 A GB 930881A GB 4332659 A GB4332659 A GB 4332659A GB 4332659 A GB4332659 A GB 4332659A GB 930881 A GB930881 A GB 930881A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene oxide
- bromide
- iodide
- polyethenoxy
- halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004753 textile Substances 0.000 title abstract 6
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 12
- 150000004820 halides Chemical class 0.000 abstract 10
- 229920000768 polyamine Polymers 0.000 abstract 10
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- 125000002947 alkylene group Chemical group 0.000 abstract 5
- 239000007795 chemical reaction product Substances 0.000 abstract 5
- -1 iodide ions Chemical class 0.000 abstract 5
- 150000003839 salts Chemical class 0.000 abstract 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 abstract 4
- 125000005843 halogen group Chemical group 0.000 abstract 4
- 229920001281 polyalkylene Polymers 0.000 abstract 4
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 abstract 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 abstract 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 abstract 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- 239000000600 sorbitol Substances 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 abstract 2
- 229960001124 trientine Drugs 0.000 abstract 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A composition suitable for treating textiles comprises (1) a reaction product (ABC) obtained by condensing a polyalkylene polyamine (A) with up to 1 mole of an alkylene oxide (B) per nitrogen atom in the polyamine and reacting the condensate (AB), preferably in the presence of an acid-binding agent, with a halide of an ethylene oxide condensate (C) of average molecular weight within the range 200-1,500, and (2) a salt containing bromide or iodide ions when (ABC) contains unreacted chlorine atoms or a bromide or iodide of an ethylene oxide condensate (D), which may be the same as or different from the halide of the ethylene oxide condensate (C). The halides of the ethylene oxide condensates (C) contain two or more halogen atoms and are obtained by replacing the hydroxyl groups of ethylene oxide condensates, e.g. polyethylene glycols and condensation products of ethylene oxide, with polyhydric alcohols such as glycerol, pentaerythritol or sorbitol, amines such as ethylamine, dodecylamine or cetylamine, or amides, with halogen atoms. The molecular ratio of total polyethenoxy halide to polyamine/alkylene oxide condensate (AB) is 1:5 to 5:1, the molecular ratio of polyethenoxy halide (C) to polyamine/alkylene oxide condensate (AB) when a polyethenoxy bromide or iodide (D) is also used does not exceed 2:1 and the molecular ratio of polyethenoxy bromide or iodide (D) or the equivalent quantity of the salt containing bromide or iodide ions to the reaction product (ABC) is 0.2:1 to 3:1. Suitable polyalkylene polyamines (A) are ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine and bishexamethylene triamine. The composition is preferably applied to the textile as an aqueous solution and the textile is then dried and baked at a temperature within the range 130 DEG -210 DEG C.ALSO:Textiles, e.g. polyamide, polyester and polyacrylontrile fibres, are rendered anti-static by treating them with (1) a reaction product (ABC) obtained by condensing a polyalkylene polyamine (A) with up to 1 mole of an alkylene oxide (B) per nitrogen atom in the polyamine and reacting the condensate (AB), preferably in the presence of an acid-binding agent, with a halide of an ethylene oxide condensate (C) of average molecular weight within the range 200-1500, and (2) a salt containing bromide or iodide ions when (ABC) contains unreacted chlorine atoms or with a bromide or iodide of an ethylene oxide condensate (D), which may be the same as or different from the halide of the ethylene oxide condensate (C), and then drying and baking them at a temperature within the range 130 DEG -210 DEG C. The halides of the ethylene oxide condensates (C) contain two or more halogen atoms and are obtained by replacing the hydroxyl groups of ethylene oxide condensates, e.g. polyethylene glycols and condensation products of ethylene oxide with polyhydric alcohols such as glycerol, pentaerythritol or sorbitol, amines such as ethylamine, dodecylamine or cetylamine, or amides, with halogen atoms. The molecular ratio of total polyethenoxy halide to poly amine/alkylene oxide condensate (AB) is 1:5 to 5:1, the molecular ratio of polyethenoxy halide (C) to polyamine/alkylene oxide condensate (AB) when a polyethenoxy bromide or iodide (D) is also applied it does not exceed 2:1 and the molecular ratio of polyethenoxy bromide or iodide (D) or the equivalent quantity of the salt containing bromide or iodide ions to reaction product (ABC) is 0.2:1 to 3:1. Suitable polyalkylene polyamines (A) are ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine and bishexamethylene triamine. The reaction product (ABC) is preferably applied to the textile from an aqueous solution which also contains the salt containing bromide or iodide ions or the polyethenoxy bromide or iodide (D).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4332659A GB930881A (en) | 1959-12-21 | 1959-12-21 | Antistatic treatment of textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4332659A GB930881A (en) | 1959-12-21 | 1959-12-21 | Antistatic treatment of textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB930881A true GB930881A (en) | 1963-07-10 |
Family
ID=10428281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4332659A Expired GB930881A (en) | 1959-12-21 | 1959-12-21 | Antistatic treatment of textiles |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB930881A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2242502A1 (en) * | 1971-09-01 | 1973-03-15 | Basf Wyandotte Corp | ANTISTATIC AGENTS FOR MELT MOLDED POLYMERS |
-
1959
- 1959-12-21 GB GB4332659A patent/GB930881A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2242502A1 (en) * | 1971-09-01 | 1973-03-15 | Basf Wyandotte Corp | ANTISTATIC AGENTS FOR MELT MOLDED POLYMERS |
| DE2266030C3 (en) * | 1971-09-01 | 1986-05-07 | BASF Wyandotte Corp., Wyandotte, Mich. | Use of a nitrogen-containing polyether as an antistatic additive in polymer compositions that can be molded from the melt |
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