GB930341A - Catalytic oxidation of hydrobromic acid with air - Google Patents
Catalytic oxidation of hydrobromic acid with airInfo
- Publication number
- GB930341A GB930341A GB18959/61A GB1895961A GB930341A GB 930341 A GB930341 A GB 930341A GB 18959/61 A GB18959/61 A GB 18959/61A GB 1895961 A GB1895961 A GB 1895961A GB 930341 A GB930341 A GB 930341A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrobromic acid
- reaction zone
- bromine
- acid
- brine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title 1
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 238000006243 chemical reaction Methods 0.000 abstract 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000012267 brine Substances 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 238000011065 in-situ storage Methods 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- YKIOKAURTKXMSB-UHFFFAOYSA-N adams's catalyst Chemical compound O=[Pt]=O YKIOKAURTKXMSB-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000031709 bromination Effects 0.000 abstract 1
- 238000005893 bromination reaction Methods 0.000 abstract 1
- -1 bromine ions Chemical class 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 abstract 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/09—Bromine; Hydrogen bromide
- C01B7/096—Bromine
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6521—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A process for the recovery of molecular bromine from aqueous hydrobromic acid comprises contacting said acid in the liquid phase with a gas containing molecular oxygen in the presence of a catalyst comprising a dissolved soluble salt containing gold, cerium, copper, iron, chromium, nickel, platinum, thorium, titanium, or vanadium. The catalyst may be formed in situ from a precursor for the bromide of one of the metals, e.g. by dissolving iron, titanium, manganous oxide or platinum dioxide in the hydrobromic acid. Numerous catalysts are mentioned. The reaction is preferably carried out under superatmospheric pressure, and the mixture may be agitated. Air and oxygen are referred to as suitable gases, while the aqueous hydrobromic acid may be any acidified solution containing bromine ions, for example those obtained from fuel cells, brine, and effluent streams from bromination processes. Strong mineral acid may be added to brine to provide the necessary acidity in situ in the reaction zone. The vapours from the reaction zone may be fractionated to recover bromine, and any hydrobromic acid passing over returned to the reaction zone.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3260360A | 1960-05-31 | 1960-05-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB930341A true GB930341A (en) | 1963-07-03 |
Family
ID=21865804
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9796/61A Expired GB956244A (en) | 1960-05-31 | 1961-03-17 | Triazinyl alkyl thiophosphate esters, method of preparation, and pesticidal compositions containing same |
| GB18959/61A Expired GB930341A (en) | 1960-05-31 | 1961-05-25 | Catalytic oxidation of hydrobromic acid with air |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9796/61A Expired GB956244A (en) | 1960-05-31 | 1961-03-17 | Triazinyl alkyl thiophosphate esters, method of preparation, and pesticidal compositions containing same |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE601889A (en) |
| DE (1) | DE1292639B (en) |
| FR (1) | FR1288314A (en) |
| GB (2) | GB956244A (en) |
| NL (1) | NL262753A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3179498A (en) * | 1963-12-02 | 1965-04-20 | Air Prod & Chem | Recovery of bromine by the nitrite catalytic oxidation of bromide ion in an acid medium |
| US3353916A (en) * | 1966-04-25 | 1967-11-21 | Universal Oil Prod Co | Quantitative recovery of bromine by two stage catalytic oxidation of hydrogen bromide |
| US3437445A (en) * | 1967-04-19 | 1969-04-08 | Gulf Research Development Co | Process for oxidizing hydrogen bromide to obtain bromine |
| US5366949A (en) * | 1992-02-04 | 1994-11-22 | Catalytica, Inc. | CeBr3 catalyst |
| WO2008024747A2 (en) * | 2006-08-25 | 2008-02-28 | Albemarle Corporation | Processes for oxidation of bromides to produce bromine and catalysts useful therein |
| EP2399889A1 (en) * | 2008-07-18 | 2011-12-28 | GRT, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8232441B2 (en) | 2004-04-16 | 2012-07-31 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to liquid hydrocarbons |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US20130156681A1 (en) * | 2011-12-19 | 2013-06-20 | Marathon Gtf Technology, Ltd. | Processes and Systems for Oxidizing Aqueous Metal Bromide Salts |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| US9206093B2 (en) | 2004-04-16 | 2015-12-08 | Gtc Technology Us, Llc | Process for converting gaseous alkanes to liquid hydrocarbons |
-
1961
- 1961-03-17 GB GB9796/61A patent/GB956244A/en not_active Expired
- 1961-03-22 FR FR856391A patent/FR1288314A/en not_active Expired
- 1961-03-23 NL NL262753D patent/NL262753A/xx unknown
- 1961-03-28 BE BE601889A patent/BE601889A/en unknown
- 1961-05-25 GB GB18959/61A patent/GB930341A/en not_active Expired
- 1961-05-27 DE DEC24219A patent/DE1292639B/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3179498A (en) * | 1963-12-02 | 1965-04-20 | Air Prod & Chem | Recovery of bromine by the nitrite catalytic oxidation of bromide ion in an acid medium |
| US3353916A (en) * | 1966-04-25 | 1967-11-21 | Universal Oil Prod Co | Quantitative recovery of bromine by two stage catalytic oxidation of hydrogen bromide |
| US3437445A (en) * | 1967-04-19 | 1969-04-08 | Gulf Research Development Co | Process for oxidizing hydrogen bromide to obtain bromine |
| US5366949A (en) * | 1992-02-04 | 1994-11-22 | Catalytica, Inc. | CeBr3 catalyst |
| US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
| US9206093B2 (en) | 2004-04-16 | 2015-12-08 | Gtc Technology Us, Llc | Process for converting gaseous alkanes to liquid hydrocarbons |
| US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
| US8232441B2 (en) | 2004-04-16 | 2012-07-31 | Marathon Gtf Technology, Ltd. | Process for converting gaseous alkanes to liquid hydrocarbons |
| CN101506092B (en) * | 2006-08-25 | 2013-01-02 | 雅宝公司 | Processes for oxidation of bromides to produce bromine and catalysts useful therein |
| US7713510B2 (en) | 2006-08-25 | 2010-05-11 | Albemarle Corporation | Processes for oxidation of bromides to produce bromine and catalysts useful therein |
| JP2013049626A (en) * | 2006-08-25 | 2013-03-14 | Albemarle Corp | Process for oxidation of bromide to produce bromine and catalyst useful therein |
| WO2008024747A2 (en) * | 2006-08-25 | 2008-02-28 | Albemarle Corporation | Processes for oxidation of bromides to produce bromine and catalysts useful therein |
| WO2008024747A3 (en) * | 2006-08-25 | 2008-05-08 | Albemarle Corp | Processes for oxidation of bromides to produce bromine and catalysts useful therein |
| US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| EP2399889A1 (en) * | 2008-07-18 | 2011-12-28 | GRT, Inc. | Continuous process for converting natural gas to liquid hydrocarbons |
| US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
| US9133078B2 (en) | 2010-03-02 | 2015-09-15 | Gtc Technology Us, Llc | Processes and systems for the staged synthesis of alkyl bromides |
| US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
| US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
| US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
| US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
| US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
| US20130156681A1 (en) * | 2011-12-19 | 2013-06-20 | Marathon Gtf Technology, Ltd. | Processes and Systems for Oxidizing Aqueous Metal Bromide Salts |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1288314A (en) | 1962-03-24 |
| GB956244A (en) | 1964-04-22 |
| DE1292639B (en) | 1969-04-17 |
| NL262753A (en) | 1964-05-25 |
| BE601889A (en) | 1961-09-28 |
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