GB928147A - Phosphorus-containing esters - Google Patents
Phosphorus-containing estersInfo
- Publication number
- GB928147A GB928147A GB3409761A GB3409761A GB928147A GB 928147 A GB928147 A GB 928147A GB 3409761 A GB3409761 A GB 3409761A GB 3409761 A GB3409761 A GB 3409761A GB 928147 A GB928147 A GB 928147A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- hydrogen
- halogen atom
- alkyl radical
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 3
- 150000002148 esters Chemical class 0.000 title abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 3
- 239000011574 phosphorus Substances 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 4
- 125000005843 halogen group Chemical group 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- 239000001301 oxygen Substances 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- -1 chalk Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 229920000151 polyglycol Polymers 0.000 abstract 1
- 239000010695 polyglycol Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000004071 soot Substances 0.000 abstract 1
- 239000000454 talc Substances 0.000 abstract 1
- 229910052623 talc Inorganic materials 0.000 abstract 1
- 239000010455 vermiculite Substances 0.000 abstract 1
- 229910052902 vermiculite Inorganic materials 0.000 abstract 1
- 235000019354 vermiculite Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/653—Five-membered rings
- C07F9/65324—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6536—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and sulfur atoms with or without oxygen atoms, as the only ring hetero atoms
- C07F9/6539—Five-membered rings
- C07F9/6541—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention comprises phosphorus-containing esters of the general formula:- <FORM:0928147/IV(a)/1> wherein X1, X2 and X3 are selected from oxygen and sulphur atoms, Y is a hydrogen or halogen atom or a nitro group or alkyl radical containing up to 4 carbon atoms and R and R1 are selected from alkyl and alkoxy radicals containing from 1 to 4 carbon atoms, with the proviso that when X1 and X2 are both oxygen and Y is a hydrogen or halogen atom then R is an alkyl radical. They may be obtained by reacting a compound of the formula:- <FORM:0928147/IV(a)/2> with salts of appropriate dialkylthiol- or dialkyl thionothiol-phosphoric, -phosphonic or phosphinic acids respectively. The reaction is preferably carried out at between 20 DEG C. and 60 DEG C. and preferably in the presence of an inert solvent, e.g. a ketone or an aqueous alcohol. Several examples are given and the products have insecticidal properties (see Group VI). Specification 809,355 is referred to.ALSO:A pesticidal composition contains a solid or liquid diluent or carrier and a phosphorus-containing ester of the formula <FORM:0928147/VI/1> wherein X1, X2 and X3 are selected from oxygen and sulphur atoms, Y is a hydrogen or halogen atom or a nitro group or a C1-C4 alkyl radical and R and R1 are selected from alkyl and alkoxy radicals containing from 1 to 4 carbon atoms with the proviso that when X1 and X2 are both oxygen and Y is a hydrogen or halogen atom then R is an alkyl radical (see Group IV (b)). Specified carriers or diluents are talc, chalk, bentonite, vermiculite, soot, clay, water (with an emulsifier, e.g. an aryl oxy polyglycol ether), alcohols, e.g. methanol or ethanol, ketones, e.g. acetone or methyl ethyl ketone, liquid hydrocarbons, and dimethyl formamide. Known insecticides and/or fertilizers may also be present. Specification 809,355 is referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0032171 | 1960-09-22 | ||
| DEF32583A DE1226584B (en) | 1960-09-22 | 1960-11-19 | Process for the preparation of thiophosphonic acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB928147A true GB928147A (en) | 1963-06-06 |
Family
ID=25974778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3409761A Expired GB928147A (en) | 1960-09-22 | 1961-09-22 | Phosphorus-containing esters |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH409964A (en) |
| DE (1) | DE1226584B (en) |
| DK (1) | DK102940C (en) |
| GB (1) | GB928147A (en) |
| NL (1) | NL138945B (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT213905B (en) * | 1958-12-30 | 1961-03-10 | Albert Ag Chem Werke | Process for the preparation of new thiol or thionothiol phosphoric acid esters |
-
1960
- 1960-11-19 DE DEF32583A patent/DE1226584B/en active Pending
-
1961
- 1961-09-14 CH CH1067361A patent/CH409964A/en unknown
- 1961-09-21 DK DK375661A patent/DK102940C/en active
- 1961-09-21 NL NL269468A patent/NL138945B/en not_active IP Right Cessation
- 1961-09-22 GB GB3409761A patent/GB928147A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL138945B (en) | 1973-05-15 |
| DE1226584B (en) | 1966-10-13 |
| DK102940C (en) | 1965-10-25 |
| CH409964A (en) | 1966-03-15 |
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